arXiv subjects

Pascale Chelin

Publications and source records attributed to Pascale Chelin.

3 recordsLinked to original sources

arXiv2026

Measurements and predictions of H2 pressure-broadening coefficients of CO2 absorption lines for exoplanet atmosphere studies

Accurate and comprehensive H2 pressure-induced broadening data for CO2 infrared lines over a wide temperature range are essential for modeling atmospheric opacity of exoplanets. However, available data are currently limited, some of which are affected by large uncertainties. In this work, H2 induced pressure-broadening and pressure-shift coefficients were determined at room temperature for the entire nu3 band of CO2 in the 4.3 micrometer spectral region using a high-resolution Fourier transform spectrometer. In addition, requantized molecular dynamics simulations of the CO2-H2 system were performed using an accurate intermolecular potential. These simulations provide theoretical predictions of H2-broadening coefficients for CO2 lines over a temperature range of 200-1000 K and for rotational quantum number up to J=120. The predicted results show very good agreement with the experimental data, with difference of less than 3%, well below the precision required for exoplanet atmosphere studies. This work provides the first accurate and comprehensive dataset of H2 broadening coefficients for CO2 lines, suitable for modeling of H2-rich exoplanetary atmospheres.

astro-ph.EP↗

arXiv2019

The CO2-broadened H2O continuum in the 100-1500 cm-1 region. Measurements, predictions and empirical model

Transmission spectra of H$_2$O+CO$_2$ mixtures have been recorded, at 296, 325 and 366 K, for various pressures and mixture compositions using two experimental setups. Their analysis enables to retrieve values of the 'continuum' absorption by the CO$_2$-broadened H$_2$O line wings between 100 and 1500 cm$^{-1}$. The results are in good agreement with those, around 1300 cm$^{-1}$, of the single previous experimental study available. Comparisons are also made with direct predictions based on line-shape correction factors $\chi$ calculated, almost thirty years ago, using a quasistatic approach and an input H$_2$O-CO$_2$ intermolecular potential. They show that this model quite nicely predicts, with slightly overestimated values, the continuum over a spectral range where it varies by more than three orders of magnitude. An empirical correction is proposed, based on the experimental data, which should be useful for radiative transfer and climate studies in CO$_2$ rich planetary atmospheres.

astro-ph.EP↗

arXiv2018

Measurements and modeling of absorption by CO2+H2O mixtures in the spectral region beyond the CO2 nu3-band head

In this work, we measured the absorption by CO2+H2O mixtures from 2400 to 2600 cm-1 which corresponds to the spectral region beyond the nu3 band head of CO2. Transmission spectra of CO2 mixed with water vapor were recorded with a high-resolution Fourier-transform spectrometer for various pressure, temperature and concentration conditions. The continuum absorption by CO2 due to the presence of water vapor was determined by subtracting from measured spectra the contribution of local lines of both species, that of the continuum of pure CO2 as well as of the self- and CO2-continua of water vapor induced by the H2O-H2O and H2O-CO2 interactions. The obtained results are in very good agreement with the unique previous measurement (in a narrower spectral range). They confirm that the H2O-continuum of CO2 is significantly larger than that observed for pure CO2. This continuum thus must be taken into account in radiative transfer calculations for media involving CO2+H2O mixture. An empirical model, using sub-Lorentzian line shapes based on some temperature-dependent correction factors chi is proposed which enables an accurate description of the experimental results.

astro-ph.EP↗