arXiv subjects

Patricia de la Presa

Publications and source records attributed to Patricia de la Presa.

5 recordsLinked to original sources

arXiv2026

Molecular-based coordination polymer as reversible and precise acetonitrile electro-optical readout

Efficient detection of harmful organic volatile compounds is a major health and environmental need in industrialized societies. Tailor-made metal-organic frameworks and other coordination polymers are emerging as promising sensing molecular materials thanks to their responsivity to a wide variety of external stimuli, and could be used to complement conventional sensors. Here, a non-porous crystalline 1D Fe(II) coordination polymer acting as a porous acetonitrile host is presented. The desorption of interstitial acetonitrile is accompanied by magneto-structural transitions easily detectable in the optical and electronic properties of the material. The structural switch and therefore its (opto)electronic readout are reversible under exposition of the crystal to acetonitrile vapor. Coordination polymers can be versatile sensors for volatile acetonitrile and potentially other organic compounds.

cond-mat.mtrl-sci↗

arXiv2025

High Magnetic Sensitivity at the Coercive Field Induced by Shear Horizontal SAW in Polycrystalline FeGa Films

A Love wave device was designed to generate surface acoustic waves (SAWs) with strong shear-horizontal polarization, interacting with a polycrystalline Fe72Ga28 magnetostrictive layer. The shear strain induced by these waves at a frequency of approximately 160 MHz, coupled with magnetoelastic effects, leads to domain magnetization oscillation, resulting in unique responses that are particularly pronounced near the coercive field. Experimental results reveal that the response of the sensor is highly sensitive to the angle between the applied magnetic field and the wave propagation direction, with profiles that can vary significantly depending on this angle, with some configurations resulting in practically opposite responses. A particularly relevant case arises when the magnetic field is aligned with the Love wave propagation direction. In this case, the sensor response shows mainly a monotonic increase with the magnetic field, except near the coercive field, where a sharp peak emerges and then abruptly collapses, resulting in a magnetic sensitivity of 4.92 Hz/nT. This high sensitivity near the coercive field opens the door to the development of high-performance sensors, simplifying electronics while leveraging the key advantages of SAW technology, including low power consumption, compact size, real-time response, and portability. A theoretical model is also discussed to further understand the underlying phenomena and optimize the design of next-generation devices, which hold significant potential for sensor applications across various fields.

physics.app-ph↗

arXiv2019

Versatile Hall magnetometer with variable sensitivity assembly for characterization of the magnetic properties of nanoparticles

A Hall magnetometer with variable sensitivity is constructed to measure the magnetic properties of magnetic nanoparticles manufactured by different methods. This novel magnetometer can also be used to measure bulk materials and samples in liquids. The magnetometer is constructed with two commercial Hall-effect sensors in an acrylic structure, which serves as the support for a micrometer and the circuit board with the sensors. For operation, the magnetometer it acquires a complete magnetization curve in a few minutes. If has a magnetic moment sensitivity of 1.3*10-9 Am2 to sensitivity of 493 mV/mT, the sensitivity can be adjustable in the range of 10 to 493 mV/mT. Its performance is tested with magnetic nanoparticles. As an application example, we estimate the mean diameter of the nanoparticles using the magnetic curves. The results are compared with those obtained by other techniques, such as transmission electron microscopy (TEM), X-ray diffraction (XRD) and dynamic light scattering (DLS). The magnetization results are also compared with those obtained by independent commercial magnetometers, which reveals errors of approximately 0.31 Am2/kg (i.e., 0.6%) in the saturation region.

physics.ins-det↗

arXiv2011

Magnetic capsules for NMR imaging: Effect of magnetic nanoparticles spatial distribution and aggregation

Magnetic and NMR relaxivity properties of γ-Fe2O3 nanoparticles embedded into the walls of polyelectrolyte multilayer capsules and freely dispersed in a sodium borate buffer solution have been investigated. The different geometric distribution of both configurations provides the opportunity to study the relationship of water accessibility and magnetic properties of particles on the NMR relaxivity. Changes in their blocking temperature and average dipolar field were modeled as a function of packing fraction in the ensemble of free and entrapped nanoparticles. For free nanoparticles with relatively low concentration, relaxivity values increase with packing fraction according to an increase in the dipolar field and larger water accessibility. However for embedded NPs in the capsule wall, packing fractions should be limited to optimise the efficiency of this system as magnetic resonance imaging (MRI) contrast agent.

cond-mat.soft↗

arXiv2009

Gold Nanoparticles Generated in Ethosome Bilayers, As Revealed by Cryo-Electron-Tomography

Gold nanoparticles have been synthesized inside ethosomes, vesicles composed of phospholipid, ethanol and water, which could be very efficient not only in delivery probes to the skin but also as diagnostic and therapeutic multimodal agents. High efficiency encapsulation of gold nanoparticles is achieved by a simple strategy: the nanoparticles synthesis occurs simultaneously with the ethosomes formation, in the absence of any undesirable reducing agents. A three-dimensional reconstruction of a gold-embedded ethosome generated by cryoelectron tomography reveals that the gold particle is localized inside the lipid bilayer, leaving the ethosome surface and core free for further functionalization. The resulting gold nanoparticles are homogeneous in size and shape and, depending on synthesis temperature, the size ranges from 10 to 20 nm, as revealed by TEM. The ethosome-nanoparticles hybrids size has been investigated by means of dynamic light scattering and has been found to vary with temperature and gold salt concentration from 700 to 400 nm. Gold nanoparticles encapsulated ethosomes offer a versatile platform for the enhancement of pharmacological efficacy in transdermal and dermal delivery systems.

physics.chem-ph↗