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Patrick G. J. Irwin

Publications and source records attributed to Patrick G. J. Irwin.

At least 37 records · Page 2Linked to original sources

Long term variability of Jupiter's northern auroral 8-micron CH4 emissions

We present a study of the long term variability of Jupiter's mid-infrared auroral CH4 emissions. 7.7 - 7.9 micron images of Jupiter recorded by Earth-based telescopes over the last three decades were collated in order to quantify the magnitude and timescales over which the northern auroral hotspot's CH4 emissions varies. We find that the ratio of the radiance of the poleward northern auroral emissions to a lower-latitude zonal mean, henceforth 'Relative Poleward Radiance' or RPR, exhibits a 37% variability over a range of timescales. We searched for patterns of variability in order to test whether seasonally-varying solar insolation, the 11-year solar cycle, or short-term solar wind variability at Jupiter's magnetopause could explain the observed evolution. The variability of the RPR exhibits a weak (r < 0.2) correlation with the solar insolation received at Jupiter's high-northern latitudes. This rules out the hypothesis suggested in previous work (e.g. Sinclair et al., 2017a) that shortwave solar heating of aurorally-produced haze particles is the dominant heating mechanism in the lower stratosphere. We also find the variability exhibits negligible (r < 0.18) correlation with the monthly-mean sunspot number, which rules out variability associated with the solar cycle. On shorter timescales, we find moderate correlations of the RPR with solar wind conditions at Jupiter in the preceding days before images were recorded. For example, we find correlations of r = 0.45 and r = 0.51 of the RPR with the mean and standard deviation on the solar wind dynamical pressure in the preceding 7 days. The moderate correlation suggests that either: 1) only a subset of solar wind compressions lead to brighter, poleward, CH4 emissions and/or 2) a subset of CH4 emission brightening events are driven by internal magnetospheric and independent of the solar wind.

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Hazy blue worlds: A holistic aerosol model for Uranus and Neptune, including Dark Spots

We present a reanalysis (using the Minnaert limb-darkening approximation) of visible/near-infrared (0.3 - 2.5 micron) observations of Uranus and Neptune made by several instruments. We find a common model of the vertical aerosol distribution that is consistent with the observed reflectivity spectra of both planets, consisting of: 1) a deep aerosol layer with a base pressure > 5-7 bar, assumed to be composed of a mixture of H2S ice and photochemical haze; 2) a layer of photochemical haze/ice, coincident with a layer of high static stability at the methane condensation level at 1-2 bar; and 3) an extended layer of photochemical haze, likely mostly of the same composition as the 1-2-bar layer, extending from this level up through to the stratosphere, where the photochemical haze particles are thought to be produced. For Neptune, we find that we also need to add a thin layer of micron-sized methane ice particles at ~0.2 bar to explain the enhanced reflection at longer methane-absorbing wavelengths. We suggest that methane condensing onto the haze particles at the base of the 1-2-bar aerosol layer forms ice/haze particles that grow very quickly to large size and immediately 'snow out' (as predicted by Carlson et al. 1988), re-evaporating at deeper levels to release their core haze particles to act as condensation nuclei for H2S ice formation. In addition, we find that the spectral characteristics of 'dark spots', such as the Voyager-2/ISS Great Dark Spot and the HST/WFC3 NDS-2018, are well modelled by a darkening or possibly clearing of the deep aerosol layer only.

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Sub-Seasonal Variation in Neptune's Mid-Infrared Emission

We present an analysis of all currently available ground-based imaging of Neptune in the mid-infrared. Dating between 2003 and 2020, the images reveal changes in Neptune's mid-infrared ($\sim 8-25μ$m) emission over time in the years surrounding Neptune's 2005 southern summer solstice. Images sensitive to stratospheric ethane ($\sim12μ$m), methane ($\sim8μ$m), and CH$_3$D ($\sim9μ$m) display significant sub-seasonal temporal variation on regional and global scales. Comparison with H$_2$ S(1) hydrogen-quadrupole ($\sim17.035μ$m) spectra suggests these changes are primarily related to stratospheric temperature changes. The stratosphere appears to have cooled between 2003 and 2009 across multiple filtered wavelengths, followed by a dramatic warming of the south pole between 2018 and 2020. Conversely, upper-tropospheric temperatures -- inferred from $\sim 17-25$-micron imaging -- appear invariant during this period, except for the south pole, which appeared warmest between 2003 and 2006. We discuss the observed variability in the context of seasonal forcing, tropospheric meteorology, and the solar cycle. Collectively, these data provide the strongest evidence to date that processes produce sub-seasonal variation on both global and regional scales in Neptune's stratosphere.

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Meridional variations of C$_2$H$_2$ in Jupiter's stratosphere from Juno UVS observations

The UVS instrument on the Juno mission records far-ultraviolet reflected sunlight from Jupiter. These spectra are sensitive to the abundances of chemical species in the upper atmosphere and to the distribution of the stratospheric haze layer. We combine observations from the first 30 perijoves of the mission in order to study the meridional distribution of acetylene (C$_2$H$_2$) in Jupiter's stratosphere. We find that the abundance of C$_2$H$_2$ decreases towards the poles by a factor of 2-4, in agreement with previous analyses of mid-infrared spectra. This result is expected from insolation rates: near the equator, the UV solar flux is higher, allowing more C$_2$H$_2$ to be generated from the UV photolysis of CH$_4$. The decrease in abundance towards the poles suggests that horizontal mixing rates are not rapid enough to homogenize the latitudinal distribution.

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How Does Thermal Scattering Shape the Infrared Spectra of Cloudy Exoplanets? A Theoretical Framework and Consequences for Atmospheric Retrievals in the JWST era

Observational studies of exoplanets are suggestive of a ubiquitous presence of clouds. The current modelling techniques used in emission to account for the clouds tend to require prior knowledge of the cloud condensing species and often do not consider the scattering effects of the cloud. We explore the effects that thermal scattering has on the emission spectra by modelling a suite of hot Jupiter atmospheres with varying cloud single-scattering albedos (SSAs) and temperature profiles. We examine cases ranging from simple isothermal conditions to more complex structures and physically driven cloud modelling. We show that scattering from nightside clouds would lead to brightness temperatures that are cooler than the real atmospheric temperature if scattering is unaccounted for. We show that scattering can produce spectral signatures in the emission spectrum even for isothermal atmospheres. We identify the retrieval degeneracies and biases that arise in the context of simulated JWST spectra when the scattering from the clouds dominates the spectral shape. Finally, we propose a novel method of fitting the SSA spectrum of the cloud in emission retrievals, using a technique that does not require any prior knowledge of the cloud chemical or physical properties.

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Longitudinal Variations in the Stratosphere of Uranus from the Spitzer Infrared Spectrometer

NASA's Spitzer Infrared Spectrometer (IRS) acquired mid-infrared (5-37 microns) disc-averaged spectra of Uranus very near to its equinox in December 2007. A mean spectrum was constructed from observations of multiple central meridian longitudes, spaced equally around the planet, which has provided the opportunity for the most comprehensive globally-averaged characterisation of Uranus' temperature and composition ever obtained (Orton et al., 2014 a [arXiv:1407.2120], b [arXiv:1407.2118]). In this work we analyse the disc-averaged spectra at four separate central meridian longitudes to reveal significant longitudinal variability in thermal emission occurring in Uranus' stratosphere during the 2007 equinox. We detect a variability of up to 15% at wavelengths sensitive to stratospheric methane, ethane and acetylene at the ~0.1-mbar level. The tropospheric hydrogen-helium continuum and deuterated methane absorption exhibit a negligible variation (less than 2%), constraining the phenomenon to the stratosphere. Building on the forward-modelling analysis of the global average study, we present full optimal estimation inversions (using the NEMESIS retrieval algorithm, Irwin et al., 2008 [10.1016/j.jqsrt.2007.11.006]) of the Uranus-2007 spectra at each longitude to distinguish between thermal and compositional variability. We found that the variations can be explained by a temperature change of less than 3 K in the stratosphere. Near-infrared observations from Keck II NIRC2 in December 2007 (Sromovsky et al., 2009 [arXiv:1503.01957], de Pater et al., 2011 [10.1016/j.icarus.2011.06.022]), and mid-infrared observations from VLT/VISIR in 2009 (Roman et al., 2020 [arXiv:1911.12830]), help to localise the potential sources to either large scale uplift or stratospheric wave phenomena.

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Vertical Structure and Color of Jovian Latitudinal Cloud Bands during the Juno Era

The identity of the coloring agent(s) in Jupiter's atmosphere and the exact structure of Jupiter's uppermost cloud deck are yet to be conclusively understood. The Crème Brûlée model of Jupiter's tropospheric clouds, originally proposed by Baines et al. (2014) and expanded upon by Sromovsky et al. (2017) and Baines et al. (2019), presumes that the chromophore measured by Carlson et al. (2016) is the singular coloring agent in Jupiter's troposphere. In this work, we test the validity of the Crème Brûlée model of Jupiter's uppermost cloud deck using spectra measured during the Juno spacecraft's 5$^{\mathrm{th}}$ perijove pass in March 2017. These data were obtained as part of an international ground-based observing campaign in support of the Juno mission using the NMSU Acousto-optic Imaging Camera (NAIC) at the 3.5-m telescope at Apache Point Observatory in Sunspot, NM. We find that the Crème Brûlée model cloud layering scheme can reproduce Jupiter's visible spectrum both with the Carlson et al. (2016) chromophore and with modifications to its imaginary index of refraction spectrum. While the Crème Brûlée model provides reasonable results for regions of Jupiter's cloud bands such as the North Equatorial Belt and Equatorial Zone, we find that it is not a safe assumption for unique weather events, such as the 2016-2017 Southern Equatorial Belt outbreak that was captured by our measurements.

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Uranus' stratospheric HCl upper limit from Herschel/SPIRE

Herschel/SPIRE observations of Uranus are used to search for stratospheric hydrogen chloride (HCl) emission at 41.74 cm$^{-1}$. HCl was not detected and instead 3$σ$ upper limits were determined; $<$6.2 ppb ($<$2.0$\times$10$^{14}$ molecules/cm$^{2}$) for a 0.1 mbar step profile and $<$0.40 ppb ($<$1.2$\times$10$^{14}$ molecules/cm$^{2}$) for a 1 mbar step profile. HCl is expected to have an external source and these upper limits are consistent with abundances of other external species (CO, H$_2$O, CO$_2$) and a solar composition source.

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Detection of Cyclopropenylidene on Titan with ALMA

We report the first detection on Titan of the small cyclic molecule cyclopropenylidene (c-C3H2) from high sensitivity spectroscopic observations made with the Atacama Large Millimeter/sub-millimeter Array (ALMA). Multiple lines of cyclopropenylidene were detected in two separate datasets: ~251 GHz in 2016 (Band 6) and ~352 GHz in 2017 (Band 7). Modeling of these emissions indicates abundances of 0.50 +/- 0.14 ppb (2016) and 0.28 +/- 0.08 (2017) for a 350 km step model, which may either signify a decrease in abundance, or a mean value of 0.33 +/- 0.07 ppb. Inferred column abundances are (3-5)E12 cm-2 in 2016 and (1-2)E12 cm-2 in 2017, similar to photochemical model predictions. Previously the C3H3+ ion has been measured in Titan's ionosphere by Cassini's Ion and Neutral Mass Spectrometer (INMS), but the neutral (unprotonated) species has not been detected until now, and aromatic versus aliphatic structure could not be determined by the INMS. Our work therefore represents the first unambiguous detection of cyclopropenylidene, the second known cyclic molecule in Titan's atmosphere along with benzene (C6H6) and the first time this molecule has been detected in a planetary atmosphere. We also searched for the N-heterocycle molecules pyridine and pyrimidine finding non-detections in both cases, and determining 2-σ upper limits of 1.15 ppb (c-C5H5N) and 0.85 ppb (c-C4H4N2) for uniform abundances above 300 km. These new results on cyclic molecules provide fresh constraints on photochemical pathways in Titan's atmosphere, and will require new modeling and experimental work to fully understand the implications for complex molecule formation.

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Ice Giant Circulation Patterns: Implications for Atmospheric Probes

Atmospheric circulation patterns derived from multi-spectral remote sensing can serve as a guide for choosing a suitable entry site for a future in situ probe mission. Since the Voyager-2 flybys in the 1980s, three decades of observations from ground- and space-based observatories have generated a picture of Ice Giant circulation that is complex, perplexing, and altogether unlike that seen on the Gas Giants. This review seeks to reconcile the various competing circulation patterns from an observational perspective, accounting for spatially-resolved measurements of: zonal albedo contrasts and banded appearances; cloud-tracked zonal winds; temperature and para-H$_2$ measurements above the condensate clouds; and equator-to-pole contrasts in condensable volatiles (methane and hydrogen sulphide) in the deeper troposphere. These observations identify three distinct latitude domains: an equatorial domain of deep upwelling and upper-tropospheric subsidence, potentially bounded by peaks in the retrograde zonal jet and analogous to Jovian cyclonic belts; a mid-latitude transitional domain of upper-tropospheric upwelling, vigorous cloud activity, analogous to Jovian anticyclonic zones; and a polar domain of strong subsidence, volatile depletion, and small-scale (and potentially seasonally-variable) convective activity. Taken together, the multi-wavelength observations suggest a tiered structure of stacked circulation cells (at least two in the troposphere and one in the stratosphere), potentially separated in the vertical by (i) strong molecular weight gradients associated with cloud condensation, and by (ii) transitions from a thermally-direct circulation regime at depth to a wave-driven circulation regime at high altitude. The inferred circulation can be tested in the coming decade by 3D simulations and by observations from future world-class facilities. [Abridged]

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Understanding and Mitigating Biases when Studying Inhomogeneous Emission Spectra with JWST

Exoplanet emission spectra are often modelled assuming that the hemisphere observed is well represented by a horizontally homogenised atmosphere. However this approximation will likely fail for planets with a large temperature contrast in the James Webb Space Telescope (JWST) era, potentially leading to erroneous interpretations of spectra. We first develop an analytic formulation to quantify the signal-to-noise ratio and wavelength coverage necessary to disentangle temperature inhomogeneities from a hemispherically averaged spectrum. We find that for a given signal-to-noise ratio, observations at shorter wavelengths are better at detecting the presence of inhomogeneities. We then determine why the presence of an inhomogeneous thermal structure can lead to spurious molecular detections when assuming a fully homogenised planet in the retrieval process. Finally, we quantify more precisely the potential biases by modelling a suite of hot Jupiter spectra, varying the spatial contributions of a hot and a cold region, as would be observed by the different instruments of JWST/NIRSpec. We then retrieve the abundances and temperature profiles from the synthetic observations. We find that in most cases, assuming a homogeneous thermal structure when retrieving the atmospheric chemistry leads to biased results, and spurious molecular detection. Explicitly modelling the data using two profiles avoids these biases, and is statistically supported provided the wavelength coverage is wide enough, and crucially also spanning shorter wavelengths. For the high contrast used here, a single profile with a dilution factor performs as well as the two-profile case, with only one additional parameter compared to the 1-D approach.

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2.5-D retrieval of atmospheric properties from exoplanet phase curves: Application to WASP-43b observations

We present a novel retrieval technique that attempts to model phase curve observations of exoplanets more realistically and reliably, which we call the 2.5-dimension (2.5-D) approach. In our 2.5-D approach we retrieve the vertical temperature profile and mean gaseous abundance of a planet at all longitudes and latitudes \textbf{simultaneously}, assuming that the temperature or composition, $x$, at a particular longitude and latitude $(Λ,Φ)$ is given by $x(Λ,Φ) = \bar{x} + (x(Λ,0) - \bar{x})\cos^nΦ$, where $\bar{x}$ is the mean of the morning and evening terminator values of $x(Λ,0)$, and $n$ is an assumed coefficient. We compare our new 2.5-D scheme with the more traditional 1-D approach, which assumes the same temperature profile and gaseous abundances at all points on the visible disc of a planet for each individual phase observation, using a set of synthetic phase curves generated from a GCM-based simulation. We find that our 2.5-D model fits these data more realistically than the 1-D approach, confining the hotter regions of the planet more closely to the dayside. We then apply both models to WASP-43b phase curve observations of HST/WFC3 and Spitzer/IRAC. We find that the dayside of WASP-43b is apparently much hotter than the nightside and show that this could be explained by the presence of a thick cloud on the nightside with a cloud top at pressure $< 0.2$ bar. We further show that while the mole fraction of water vapour is reasonably well constrained to $(1-10)\times10^{-4}$, the abundance of CO is very difficult to constrain with these data since it is degenerate with temperature and prone to possible systematic radiometric differences between the HST/WFC3 and Spitzer/IRAC observations. Hence, it is difficult to reliably constrain C/O.

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Colour and Tropospheric Cloud Structure of Jupiter from MUSE/VLT: Retrieving a Universal Chromophore

Recent work by Sromovsky et al. (2017, Icarus 291, 232-244) suggested that all red colour in Jupiter's atmosphere could be explained by a single colour-carrying compound, a so-called 'universal chromophore'. We tested this hypothesis on ground-based spectroscopic observations in the visible and near-infrared (480-930 nm) from the VLT/MUSE instrument between 2014 and 2018, retrieving a chromophore absorption spectrum directly from the North Equatorial Belt, and applying it to model spatial variations in colour, tropospheric cloud and haze structure on Jupiter. We found that we could model both the belts and the Great Red Spot of Jupiter using the same chromophore compound, but that this chromophore must exhibit a steeper blue-absorption gradient than the proposed chromophore of Carlson et al. (2016, Icarus 274, 106-115). We retrieved this chromophore to be located no deeper than 0.2+/-0.1 bars in the Great Red Spot and 0.7+/-0.1 bars elsewhere on Jupiter. However, we also identified some spectral variability between 510 nm and 540 nm that could not be accounted for by a universal chromophore. In addition, we retrieved a thick, global cloud layer at 1.4+/-0.3 bars that was relatively spatially invariant in altitude across Jupiter. We found that this cloud layer was best characterised by a real refractive index close to that of ammonia ice in the belts and the Great Red Spot, and poorly characterised by a real refractive index of 1.6 or greater. This may be the result of ammonia cloud at higher altitude obscuring a deeper cloud layer of unknown composition.

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Uranus in Northern Mid-Spring: Persistent Atmospheric Temperatures and Circulations Inferred from Thermal Imaging

We present results from mid-infrared imaging of Uranus at wavelengths of 13.0 micron and 18.7 micron, sensing emission from the stratosphere and upper troposphere, acquired using the VISIR instrument at the Very Large Telescope (VLT), September 4-October 20, 2018. Using a combination of inverse and forward modeling, we analyze these northern mid-spring (L_s~46) images and compare them to archival data to assess seasonal changes since the 1986 southern solstice and subsequent equinox. We find the data are consistent with little change (< 0.3 K) in the upper tropospheric temperature structure, extending the previous conclusions of Orton et al (2015) well past equinox, with only a subtle increase in temperature at the emerging north pole. Additionally, spatial-temporal variations in 13 micron stratospheric emission are investigated for the first time, revealing meridional variation and a hemispheric asymmetry not predicted by models. Finally, we investigate the nature of the stratospheric emission and demonstrate that the observed distribution appears related and potentially coupled to the underlying tropospheric emission six scale heights below. The observations are consistent with either mid-latitude heating or an enhanced abundance of acetylene. Considering potential mechanisms and additional observations, we favor a model of acetylene enrichment at mid-latitudes resulting from an extension of the upper-tropospheric circulation, which appears capable of transporting methane from the troposphere, through the cold trap, and into the stratosphere for subsequent photolysis to acetylene.

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Exoplanetary Monte Carlo Radiative Transfer with Correlated-k I. Benchmarking Transit and Emission Observables

Current observational data of exoplanets are providing increasing detail of their 3D atmospheric structures. As characterisation efforts expand in scope, the need to develop consistent 3D radiative-transfer methods becomes more pertinent as the complex atmospheric properties of exoplanets are required to be modelled together consistently. We aim to compare the transmission and emission spectra results of a 3D Monte Carlo Radiative Transfer (MCRT) model to contemporary radiative-transfer suites. We perform several benchmarking tests of a MCRT code, Cloudy Monte Carlo Radiative Transfer (CMCRT), to transmission and emission spectra model output. We add flexibility to the model through the use of k-distribution tables as input opacities. We present a hybrid MCRT and ray tracing methodology for the calculation of transmission spectra with a multiple scattering component. CMCRT compares well to the transmission spectra benchmarks at the 10s of ppm level. Emission spectra benchmarks are consistent to within 10% of the 1D models. We suggest that differences in the benchmark results are likely caused by geometric effects between plane-parallel and spherical models. In a practical application, we post-process a cloudy 3DHD 189733b GCM model and compare to available observational data. Our results suggest the core methodology and algorithms of CMCRT produce consistent results to contemporary radiative transfer suites. 3D MCRT methods are highly suitable for detailed post-processing of cloudy and non-cloudy 1D and 3D exoplanet atmosphere simulations in instances where atmospheric inhomogeneities, significant limb effects/geometry or multiple scattering components are important considerations.

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Latitudinal variation in the abundance of methane (CH4) above the clouds in Neptune's atmosphere from VLT/MUSE Narrow Field Mode Observations

Observations of Neptune, made in 2018 using the new Narrow Field Adaptive Optics mode of the Multi Unit Spectroscopic Explorer (MUSE) instrument at the Very Large Telescope (VLT) from 0.48 - 0.93 micron, are analysed here to determine the latitudinal and vertical distribution of cloud opacity and methane abundance in Neptune's observable troposphere (0.1 - ~3 bar). Previous observations at these wavelengths in 2003 by HST/STIS (Karkoschka and Tomasko 2011, Icarus 205, 674-694) found that the mole fraction of methane above the cloud tops (at ~2 bar) varied from ~4% at equatorial latitudes to ~2% at southern polar latitudes, by comparing the observed reflectivity at wavelengths near 825 nm controlled primarily by either methane absorption or H2-H2/H2-He collision-induced absorption. We find a similar variation in cloud-top methane abundance in 2018, which suggests that this depletion of methane towards Neptune's pole is potentially a long-lived feature, indicative of long-term upwelling at mid-equatorial latitudes and subsidence near the poles. By analysing these MUSE observations along the central meridian with a retrieval model, we demonstrate that a broad boundary between the nominal and depleted methane abundances occurs at between 20 - 40S. We also find a small depletion of methane near the equator, perhaps indicating subsidence there, and a local enhancement near 60 - 70S, which we suggest may be associated with South Polar Features (SPFs) seen in Neptune's atmosphere at these latitudes. Finally, by the use of both a reflectivity analysis and a principal component analysis, we demonstrate that this depletion of methane towards the pole is apparent at all locations on Neptune's disc, and not just along its central meridian.

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Measurement of CH$_3$D on Titan at Submillimeter Wavelengths

We present the first radio/submillimeter detection of monodeuterated methane (CH$_3$D) in Titan's atmosphere, using archival data from of the Atacama Large Millimeter/submillimeter Array (ALMA). The $J_K=2_1-1_1$ and $J_K=2_0-1_0$ transitions at 465.235 and 465.250 GHz ($\sim0.644$ mm) were measured at significance levels of $4.6σ$ and $5.7σ$, respectively. These two lines were modeled using the Non-linear optimal Estimator for MultivariatE spectral analySIS (NEMESIS) radiative transfer code to determine the disk-averaged CH$_3$D volume mixing ratio = $6.157\times10^{-6}$ in Titan's stratosphere (at altitudes $\gt130$ km). By comparison with the CH$_4$ vertical abundance profile measured by Cassini-Huygens mass spectrometry, the resulting value for D/H in CH$_4$ is $(1.033\pm0.081)\times10^{-4}$. This is consistent with previous ground-based and in-situ measurements from the Cassini-Huygens mission, though slightly lower than the average of the previous values. Additional CH$_3$D observations at higher spatial resolution will be required to determine a value truly comparable with the Cassini-Huygens CH$_4$ measurements, by measuring CH$_3$D with ALMA close to Titan's equator. In the post-Cassini era, spatially resolved observations of CH$_3$D with ALMA will enable the latitudinal distribution of methane to be determined, making this an important molecule for further studies.

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Analysis of gaseous ammonia (NH$_3$) absorption in the visible spectrum of Jupiter - Update

An analysis of currently available ammonia (NH$_3$) visible-to-near-infrared gas absorption data was recently undertaken by Irwin et al. (Icarus, 302 (2018) 426) to help interpret Very Large Telescope (VLT) MUSE observations of Jupiter from 0.48 - 0.93 $μ$m, made in support of the NASA/Juno mission. Since this analysis a newly revised set of ammonia line data, covering the previously poorly constrained range 0.5 - 0.833 $μ$m, has been released by the ExoMol project, "C2018" (Coles et al., JQSRT 219, 199 - 122, 2018), which demonstrates significant advantages over previously available data sets, and providing for the first time complete line data for the previously poorly constrained 5520- and 6475-Å bands of NH$_3$. In this paper we compare spectra calculated using the ExoMol-C2018 data set (Coles et al., JQSRT 219, 199 - 122, 2018) with spectra calculated from previous sources to demonstrate its advantages. We conclude that at the present time the ExoMol-C2018 dataset provides the most reliable ammonia absorption source for analysing low- to medium-resolution spectra of Jupiter in the visible/near-IR spectral range, but note that the data are less able to model high-resolution spectra owing to small, but significant inaccuracies in the line wavenumber estimates. This work is of significance not only for solar system planetary physics, but for future proposed observations of Jupiter-like planets orbiting other stars, such as with NASA's planned Wide-Field Infrared Survey Telescope (WFIRST).

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