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Patrick Huang

Publications and source records attributed to Patrick Huang.

5 recordsLinked to original sources

It Takes a Good Model to Train a Good Model: Generalized Gaussian Priors for Optimized LLMs

Despite rapid progress in large language models (LLMs), the statistical structure of their weights, activations, and gradients-and its implications for initialization, training dynamics, and efficiency-remains largely unexplored. We empirically show that these quantities in LLMs are well modeled by generalized Gaussian (GG) distributions, and introduce a unified, end-to-end optimization framework grounded in this observation. Our contributions are threefold: (1) a GG-based initialization that aligns with trained model statistics, accelerating convergence and improving accuracy; (2) ACT, a progressive activation-constrained training method that reduces redundancy and propagation overhead; and (3) GCT, a gradient-constrained training algorithm that substantially lowers communication cost in distributed training. Experiments across diverse architectures demonstrate consistently smaller, faster models with minimal communication overhead that match or surpass standard baselines. By anchoring LLM optimization in principled statistical modeling, this work advances efficient, scalable, and hardware-aware AI systems.

cs.LG

Structure and energetics of helium adsorption on nanosurfaces

The ground and excited state properties of small helium clusters, 4He_N, containing nanoscale (~3-10 Angstroms) planar aromatic molecules have been studied with quantum Monte Carlo methods. Ground state structures and energies are obtained from importance-sampled, rigid-body diffusion Monte Carlo. Excited state energies due to helium vibrational motion are evaluated using the projection operator, imaginary time spectral evolution technique. We examine the adsorption of N helium atoms (N less than or equal to 24) on a series of planar aromatic molecules (benzene, naphthalene, anthracene, tetracene, phthalocyanine). The first layer of helium atoms is well-localized on the molecule surface, and we find well-defined localized excitations due to in-plane vibrational motion of helium on the molecule surface. We discuss the implications of these confined excitations for the molecule spectroscopy.

physics.chem-ph

Localized helium excitations in 4He_N-benzene clusters

We compute ground and excited state properties of small helium clusters 4He_N containing a single benzene impurity molecule. Ground-state structures and energies are obtained for N=1,2,3,14 from importance-sampled, rigid-body diffusion Monte Carlo (DMC). Excited state energies due to helium vibrational motion near the molecule surface are evaluated using the projection operator, imaginary time spectral evolution (POITSE) method. We find excitation energies of up to ~23 K above the ground state. These states all possess vibrational character of helium atoms in a highly anisotropic potential due to the aromatic molecule, and can be categorized in terms of localized and collective vibrational modes. These results appear to provide precursors for a transition from localized to collective helium excitations at molecular nanosubstrates of increasing size. We discuss the implications of these results for analysis of anomalous spectral features in recent spectroscopic studies of large aromatic molecules in helium clusters.

physics.chem-ph

The finite-temperature Monte Carlo method and its application to superfluid helium clusters

We review the use of the path integral Monte Carlo (PIMC) methodology to the study of finite-size quantum clusters, with particular emphasis on recent applications to pure and impurity-doped He clusters. We describe the principles of PIMC, the use of the multilevel Metropolis method for sampling particle permutations, and the methods used to accurately incorporate anisotropic molecule-helium interactions into the path integral scheme. Applications to spectroscopic studies of embedded atoms and molecules are summarized, with discussion of the new concepts of local and nanoscale superfluidity that have been generated by recent PIMC studies of the impurity-doped He clusters.

physics.chem-ph

Efficient implementation of the Projection Operator Imaginary Time Spectral Evolution (POITSE) method for excited states

We describe and systematically analyze new implementations of the Projection Operator Imaginary Time Spectral Evolution (POITSE) method for the Monte Carlo evaluation of excited state energies. The POITSE method involves the computation of a correlation function in imaginary time. Decay of this function contains information about excitation energies, which can be extracted by a spectral transform. By incorporating branching processes in the Monte Carlo propagation, we compute these correlation functions with significantly reduced statistical noise. Our approach allows for the stable evaluation of small energy differences in situations where the previous POITSE implementation was limited by this noise.

physics.comp-ph