arXiv subjects

Paul Brumer

Publications and source records attributed to Paul Brumer.

At least 109 records · Page 6Linked to original sources

arXiv2008

Minimum requirements for laser-induced symmetry breaking in quantum and classical mechanics

Necessary conditions for generating phase controllable asymmetry in spatially symmetric systems using lasers are identified and are shown to be identical in quantum and classical mechanics. First, by studying the exact dynamics of harmonic systems in the presence of an arbitrary radiation field, it is demonstrated that anharmonicities in the system's potential are a necessary requirement for phase controllability. Then, by analyzing the space-time symmetries of the laser-driven Liouville dynamics for classical and quantum systems, a common set of temporal symmetries for the driving field that need to be violated to induce transport are identified. The conditions apply to continuous wave lasers and to symmetry breaking effects that do not rely on the control of the absolute phase of the field. Known examples of laser fields that can induce transport in symmetric systems are seen to be particular cases of these symmetry constraints.

quant-ph↗

arXiv2007

Robust ultrafast currents in molecular wires through Stark shifts

A novel way to induce ultrafast currents in molecular wires using two incident laser frequencies, $ω$ and $2ω$, is demonstrated. The mechanism relies on Stark shifts, instead of photon absorption, to transfer population to the excited states and exploits the temporal profile of the field to generate phase controllable transport. Calculations in a \emph{trans}-polyacetylene oligomer coupled to metallic leads indicate that the mechanism is highly efficient and robust to ultrafast electronic dephasing processes induced by vibronic couplings.

quant-ph↗

arXiv2007

Entanglement and Timing-Based Mechanisms in the Coherent Control of Scattering Processes

The coherent control of scattering processes is considered, with electron impact dissociation of H$_2^+$ used as an example. The physical mechanism underlying coherently controlled stationary state scattering is exposed by analyzing a control scenario that relies on previously established entanglement requirements between the scattering partners. Specifically, initial state entanglement assures that all collisions in the scattering volume yield the desirable scattering configuration. Scattering is controlled by preparing the particular internal state wave function that leads to the favored collisional configuration in the collision volume. This insight allows coherent control to be extended to the case of time-dependent scattering. Specifically, we identify reactive scattering scenarios using incident wave packets of translational motion where coherent control is operational and initial state entanglement is unnecessary. Both the stationary and time-dependent scenarios incorporate extended coherence features, making them physically distinct. From a theoretical point of view, this work represents a large step forward in the qualitative understanding of coherently controlled reactive scattering. From an experimental viewpoint, it offers an alternative to entanglement-based control schemes. However, both methods present significant challenges to existing experimental technologies.

quant-ph↗

arXiv2007

Coherent Control and Entanglement in the Attosecond Electron Recollision Dissociation of D2+

We examine the attosecond electron recollision dissociation of D2+ recently demonstrated experimentally [H. Niikura et al., Nature (London) 421, 826 (2003)] from a coherent control perspective. In this process, a strong laser field incident on D2 ionizes an electron, accelerates the electron in the laser field to eV energies, and then drives the electron to recollide with the parent ion, causing D2+ dissociation. A number of results are demonstrated. First, a full dimensional Strong Field Approximation (SFA) model is constructed and shown to be in agreement with the original experiment. This is then used to rigorously demonstrate that the experiment is an example of coherent pump-dump control. Second, extensions to bichromatic coherent control are proposed by considering dissociative recollision of molecules prepared in a coherent superposition of vibrational states. Third, by comparing the results to similar scenarios involving field-free attosecond scattering of independently prepared D2+ and electron wave packets, recollision dissociation is shown to provide an example of wave-packet coherent control of reactive scattering. Fourth, this analysis makes clear that it is the temporal correlations between the continuum electron and D2+ wave packet, and not entanglement, that are crucial for the sub-femtosecond probing resolution demonstrated in the experiment. This result clarifies some misconceptions regarding the importance of entanglement in the recollision probing of D2+. Finally, signatures of entanglement between the recollision electron and the atomic fragments, detectable via coincidence measurements, are identified.

quant-ph↗

arXiv2007

Controlled Quantum State Transfer in a Spin Chain

Control of the transfer of quantum information encoded in quantum wavepackets moving along a spin chain is demonstrated. Specifically, based on a relationship with control in a paradigm of quantum chaos, it is shown that wavepackets with slow dispersion can automatically emerge from a class of initial superposition states involving only a few spins, and that arbitrary unspecified travelling wavepackets can be nondestructively stopped and later relaunched with perfection. The results establish an interesting application of quantum chaos studies in quantum information science.

quant-ph↗

arXiv2006

Cold Atomic Collisions: Coherent Control of Penning and Associative Ionization

Coherent Control techniques are computationally applied to cold (1mK < T < 1 K) and ultracold (T < 1 microK) Ne*(3s,3P2) + Ar(1S0) collisions. We show that by using various initial superpositions of the Ne*(3s,3P2) M = {-2,-1,0,1,2} Zeeman sub-levels it is possible to reduce the Penning Ionization (PI) and Associative Ionization (AI) cross sections by as much as four orders of magnitude. It is also possible to drastically change the ratio of these two processes. The results are based on combining, within the "Rotating Atom Approximation", empirical and ab-initio ionization-widths.

physics.chem-ph↗

arXiv2006

Generic Quantum Ratchet Accelerator with Full Classical Chaos

A simple model of quantum ratchet transport that can generate unbounded linear acceleration of the quantum ratchet current is proposed, with the underlying classical dynamics fully chaotic. The results demonstrate that generic acceleration of quantum ratchet transport can occur with any type of classical phase space structure. The quantum ratchet transport with full classical chaos is also shown to be very robust to noise due to the large linear acceleration afforded by the quantum dynamics. One possible experiment allowing observation of these predictions is suggested.

quant-ph↗

arXiv2006

The Born Rule in Quantum and Classical Mechanics

Considerable effort has been devoted to deriving the Born rule (e.g. that $|ψ(x)|^2 dx$ is the probability of finding a system, described by $ψ$, between $x$ and $x + dx$) in quantum mechanics. Here we show that the Born rule is not solely quantum mechanical; rather, it arises naturally in the Hilbert space formulation of {\it classical} mechanics as well. These results provide new insights into the nature of the Born rule, and impact on its understanding in the framework of quantum mechanics.

quant-ph↗

arXiv2005

Mechanisms in Adaptive Feedback Control: Photoisomerization in a Liquid

The underlying mechanism for Adaptive Feedback Control in the experimental photoisomerization of NK88 in methanol is exposed theoretically. With given laboratory limitations on laser output, the complicated electric fields are shown to achieve their targets in qualitatively simple ways. Further, control over the cis population without laser limitations reveals an incoherent pump-dump scenario as the optimal isomerization strategy. In neither case are there substantial contributions from quantum multiple-path interference or from nuclear wavepacket coherence. Environmentally induced decoherence is shown to justify the use of a simplified theoretical model.

quant-ph↗

arXiv2005

Analytic solution to N vs. M photon phase control in an open two-level system

Decoherence effects on the traditional N vs. M photon coherent control of a two-level system are investigated, with 1 vs. 3 used as a specific example. The problem reduces to that of a two-level system interacting with a single mode field, but with an effective Rabi frequency that depends upon the fundamental and third harmonic fields. The resultant analytic control solution is explored for a variety of parameters, with emphasis on the dependence of control on the relative phase of the lasers. The generalization to off-resonant cases is noted.

quant-ph↗

arXiv2005

Decoherence Effects in Reactive Scattering

Decoherence effects on quantum and classical dynamics in reactive scattering are examined using a Caldeira-Leggett type model. Through a study of dynamics of the collinear H+H2 reaction and the transmission over simple one-dimensional barrier potentials, we show that decoherence leads to improved agreement between quantum and classical reaction and transmission probabilities, primarily by increasing the energy dispersion in a well defined way. Increased potential nonlinearity is seen to require larger decoherence in order to attain comparable quantum-classical agreement.

quant-ph↗

arXiv2004

Directed anomalous diffusion without a biased field: A ratchet accelerator

Directed classical current that increases linearly with time without using a biased external field is obtained in a simple model Hamiltonian system derived from a modified kicked rotor model, by breaking the spatial symmetry of the transporting regular islands in the classical phase space. A parallel study of the corresponding quantum dynamics suggests that although quantum coherence effects suppress the directed current and can even induce a current reversal, directed quantum current that increases linearly with time can nonetheless be realized in a quantum system that is far from the classical limit.

nlin.CD↗

arXiv2004

Coherent Control of Resonance-Mediated Reactions: F + HD

Cross sections resulting from scattering that proceeds via an intermediate resonance are shown to be exceptionally controllable using a coherent superposition of only two intial states. Full quantum computations on F+HD(v=0;j=0,1) --> H+DF, D+HF, which exhibits a resonance in one of the reactive channels, support the formal arguments, showing that control is indeed vast. In this case the ratio of reactive integral cross sections can be altered by a factor of 62 (compared to a noncoherent factor of only 3.3), while the ratio of reactive differential cross sections can be altered by a factor of over 6000 (compared to a noncoherent factor of less than 7). These results constitute the first prediction of extensive quantum control in a collisional process.

quant-ph↗

arXiv2003

Chaos and Quantum-Classical Correspondence via Phase Space Distribution Functions

Quantum-classical correspondence in conservative chaotic Hamiltonian systems is examined using a uniform structure measure for quantal and classical phase space distribution functions. The similarities and differences between quantum and classical time-evolving distribution functions are exposed by both analytical and numerical means. The quantum-classical correspondence of low-order statistical moments is also studied. The results shed considerable light on quantum-classical correspondence.

quant-ph↗

arXiv2003

Control of Dynamical Localization

Control over the quantum dynamics of chaotic kicked rotor systems is demonstrated. Specifically, control over a number of quantum coherent phenomena is achieved by a simple modification of the kicking field. These include the enhancement of the dynamical localization length, the introduction of classical anomalous diffusion assisted control for systems far from the semiclassical regime, and the observation of a variety of strongly nonexponential lineshapes for dynamical localization. The results provide excellent examples of controlled quantum dynamics in a system that is classically chaotic and offer new opportunities to explore quantum fluctuations and correlations in quantum chaos.

quant-ph↗

arXiv2003

Coherent Manipulation of Quantum Delta-kicked Dynamics: Faster-than-classical Anomalous Diffusion

Large transporting regular islands are found in the classical phase space of a modified kicked rotor system in which the kicking potential is reversed after every two kicks. The corresponding quantum system, for a variety of system parameters and over long time scales, is shown to display energy absorption that is significantly faster than that associated with the underlying classical anomalous diffusion. The results are of interest to both areas of quantum chaos and quantum control.

quant-ph↗

arXiv2003

Classical-Wigner Phase Space Approximation to Cumulative Matrix Elements in Coherent Control

The classical limit of the Wigner-Weyl representation is used to approximate products of bound-continuum matrix elements that are fundamental to many coherent control computations. The range of utility of the method is quantified through an examination of model problems, single-channel Na_2 dissociation and multi-arrangement channel photodissociation of CH_2IBr. Very good agreement with the exact quantum results is found for a wide range of system parameters.

physics.chem-ph↗

arXiv2003

Intrinsic Decoherence Dynamics in Smooth Hamiltonian Systems: Quantum-classical Correspondence

A direct classical analog of the quantum dynamics of intrinsic decoherence in Hamiltonian systems, characterized by the time dependence of the linear entropy of the reduced density operator, is introduced. The similarities and differences between the classical and quantum decoherence dynamics of an initial quantum state are exposed using both analytical and computational results. In particular, the classicality of early-time intrinsic decoherence dynamics is explored analytically using a second-order perturbative treatment, and an interesting connection between decoherence rates and the stability nature of classical trajectories is revealed in a simple approximate classical theory of intrinsic decoherence dynamics. The results offer new insights into decoherence, dynamics of quantum entanglement, and quantum chaos.

quant-ph↗