arXiv subjects

Paul M. Chaikin

Publications and source records attributed to Paul M. Chaikin.

At least 19 recordsLinked to original sources

arXiv2025

Active diffusing crystals in a 2D non-equilibrium system

We investigate a 2D dynamical absorbing state model of monodisperse disks, in which rich phase behavior arises from interactions consisting solely of repulsive displacements between overlapping particles. The phase diagram reveals several unconventional features, including a disordered and static absorbing configuration, where no particles overlap, separated by a second-order phase transition to a continuously evolving active hexagonal crystal with collective ring diffusion, which in turn undergoes a first-order phase transition to an active isotropic liquid. The only driving parameter is $ε$, the maximum size of the random repulsive kicks. Small $ε$ facilitates self-organization into an ordered state, but large $ε$ prevents this organization from occurring. This is very different from typical order-disorder transitions, where there are two competing influences, energy and entropy, that drive the transition.

cond-mat.soft↗

arXiv2024

Large FCC colloidal crystals under microgravity

Here we report the results of microgravity experiments performed on the International Space Station (ISS) to study crystallized, metastable colloidal liquids in the region of the hard sphere phase diagram that has been found to be glassy on Earth. Using confocal microscopy, we observed the self-assembly of high density, three-dimensional colloidal crystals from micron-size hard spheres suspended within a fluid medium. The largest face-centered cubic (FCC) phase measured 27 x 1.5 x 0.15 mm. From a practical aspect, the fact that a single, topological defect-free FCC colloidal crystal can be grown in microgravity and the crystal returned from orbit suggests new routes for manufacturing colloidal devices, particularly optical elements in space.

cond-mat.soft↗

arXiv2024

Stealthy and hyperuniform isotropic photonic bandgap structure in 3D

In photonic crystals the propagation of light is governed by their photonic band structure, an ensemble of propagating states grouped into bands, separated by photonic band gaps. Due to discrete symmetries in spatially strictly periodic dielectric structures their photonic band structure is intrinsically anisotropic. However, for many applications, such as manufacturing artificial structural color materials or developing photonic computing devices, but also for the fundamental understanding of light-matter interactions, it is of major interest to seek materials with long range non-periodic dielectric structures which allow the formation of {\it isotropic} photonic band gaps. Here, we report the first ever 3D isotropic photonic band gap for an optimized disordered stealthy hyperuniform structure for microwaves. The transmission spectra are directly compared to a diamond pattern and an amorphous structure with similar node density. The band structure is measured experimentally for all three microwave structures, manufactured by 3D-Laser-printing for meta-materials with refractive index up to $n=2.1$. Results agree well with finite-difference-time-domain numerical investigations and a priori calculations of the band-gap for the hyperuniform structure: the diamond structure shows gaps but being anisotropic as expected, the stealthy hyperuniform pattern shows an isotropic gap of very similar magnitude, while the amorphous structure does not show a gap at all. The centimeter scaled microwave structures may serve as prototypes for micrometer scaled structures with bandgaps in the technologically very interesting region of infrared (IR).

physics.app-ph↗

arXiv2023

Dynamical approach to the jamming problem

A simple dynamical model, Biased Random Organization, BRO, appears to produce configurations known as Random Close Packing (RCP) as BRO's densest critical point in dimension $d=3$. We conjecture that BRO likewise produces RCP in any dimension; if so, then RCP does not exist in $d=1-2$ (where BRO dynamics lead to crystalline order). In $d=3-5$, BRO produces isostatic configurations and previously estimated RCP volume fractions 0.64, 0.46, and 0.30, respectively. For all investigated dimensions ($d=2-5$), we find that BRO belongs to the Manna universality class of dynamical phase transitions by measuring critical exponents associated with the steady-state activity and the long-range density fluctuations. Additionally, BRO's distribution of near-contacts (gaps) displays behavior consistent with the infinite-dimensional theoretical treatment of RCP when $d \ge 4$. The association of BRO's densest critical configurations with Random Close Packing implies that RCP's upper-critical dimension is consistent with the Manna class $d_{uc} = 4$.

cond-mat.stat-mech↗

arXiv2023

Hydrodynamic spin-orbit coupling in asynchronous optically driven micro-rotors

Vortical flows of rotating particles describe interactions ranging from molecular machines to atmospheric dynamics. Yet to date, direct observation of the hydrodynamic coupling between artificial micro-rotors has been restricted by the details of the chosen drive, either through synchronization (using external magnetic fields) or confinement (using optical tweezers). Here we present a new active system that illuminates the interplay of rotation and translation in free rotors. We developed a non-tweezing circularly polarized beam that simultaneously rotates hundreds of silica-coated birefringent colloids. The particles rotate asynchronously in the optical torque field while freely diffusing in the plane. We observe that neighboring particles orbit each other with an angular velocity that depends on their spins. We derive an analytical model in the Stokes limit for pairs of spheres that quantitatively explains the observed dynamics. We then find that the geometrical nature of the low Reynolds fluid results in a universal hydrodynamic spin-orbit coupling. Our findings are of significance for the understanding and development of far-from-equilibrium materials.

cond-mat.soft↗

arXiv2022

Play. Pause. Rewind. Measuring local entropy production and extractable work in active matter

Time-reversal symmetry breaking and entropy production are universal features of nonequilibrium phenomena. Despite its importance in the physics of active and living systems, the entropy production of systems with many degrees of freedom has remained of little practical significance because the high-dimensionality of their state space makes it difficult to measure. Here we introduce a local measure of entropy production and a numerical protocol to estimate it. We establish a connection between the entropy production and extractability of work in a given region of the system and show how this quantity depends crucially on the degrees of freedom being tracked. We validate our approach in theory, simulation, and experiments by considering systems of active Brownian particles undergoing motility induced phase separation, as well as active Brownian particles and E. Coli in a rectifying device in which the time-reversal asymmetry of the particle dynamics couples to spatial asymmetry to reveal its effects on a macroscopic scale.

cond-mat.soft↗

arXiv2022

Coupled dynamical phase transitions in driven disk packings

Under the influence of oscillatory shear, a mono-layer of frictional granular disks exhibits two dynamical phase transitions: a transition from an initially disordered state to an ordered crystalline state, and a dynamic active-absorbing phase transition. Although there is no reason, {\it a-priori}, for these to be at the same critical point, they are. The transitions may also be characterized by the disk trajectories, which are non-trivial loops breaking time-reversal invariance.

cond-mat.soft↗

arXiv2020

Correlation lengths in the language of computable information

Computable Information Density (CID), the ratio of the length of a losslessly compressed data file to that of the uncompressed file, is a measure of order and correlation in both equilibrium and nonequilibrium systems. Here we show that correlation lengths can be obtained by decimation - thinning a configuration by sampling data at increasing intervals and recalculating the CID. When the sampling interval is larger than the system's correlation length, the data becomes incompressible. The correlation length and its critical exponents are thus accessible with no a-priori knowledge of an order parameter or even the nature of the ordering. The correlation length measured in this way agrees well with that computed from the decay of two-point correlation functions $g_{2}(r)$ when they exist. But the CID reveals the correlation length and its scaling even when $g_{2}(r)$ has no structure, as we demonstrate by "cloaking" the data with a Rudin-Shapiro sequence.

cond-mat.stat-mech↗

arXiv2020

Vicsek Model by Time-Interlaced Compression: a Dynamical Computable Information Density

Collective behavior, both in real biological systems as well as in theoretical models, often displays a rich combination of different kinds of order. A clear-cut and unique definition of "phase" based on the standard concept of order parameter may therefore be complicated, and made even trickier by the lack of thermodynamic equilibrium. Compression-based entropies have been proved useful in recent years in describing the different phases of out-of-equilibrium systems. Here, we investigate the performance of a compression-based entropy, namely the Computable Information Density (CID), within the Vicsek model of collective motion. Our entropy is defined through a crude coarse-graining of the particle positions, in which the key role of velocities in the model only enters indirectly through the velocity-density coupling. We discover that such entropy is a valid tool in distinguishing the various noise regimes, including the crossover between an aligned and misaligned phase of the velocities, despite the fact that velocities are not used by this entropy. Furthermore, we unveil the subtle role of the time coordinate, unexplored in previous studies on the CID: a new encoding recipe, where space and time locality are both preserved on the same ground, is demonstrated to reduce the CID. Such an improvement is particularly significant when working with partial and/or corrupted data, as it is often the case in real biological experiments.

cond-mat.stat-mech↗

arXiv2020

Hyperuniform structures formed by shearing colloidal suspensions

In periodically sheared suspensions there is a dynamical phase transition characterized by a critical strain amplitude $γ_c$ between an absorbing state where particle trajectories are reversible and an active state where trajectories are chaotic and diffusive. Repulsive non-hydrodynamic interactions between "colliding" particles' surfaces have been proposed as a source of this broken time reversal symmetry. A simple toy model called Random Organization qualitatively reproduces the dynamical features of this transition. Random Organization and other absorbing state models exhibit hyperuniformity, a strong suppression of density fluctuations on long length-scales quantified by a structure factor $S(q \rightarrow 0) \sim q^α$ with $α> 0$, at criticality. Here we show experimentally that the particles in periodically sheared suspensions organize into structures with anisotropic short-range order but isotropic, long-range hyperuniform order when oscillatory shear amplitudes approach $γ_c$.

cond-mat.soft↗

arXiv2019

Conching chocolate: A prototypical transition from frictionally jammed solid to flowable suspension with maximal solid content

The mixing of a powder of 10-50μm primary particles into a liquid to form a dispersion with the highest possible solid content is a common industrial operation. Building on recent advances in the rheology of such 'granular dispersions', we study a paradigmatic example of such powder incorporation: the conching of chocolate, in which a homogeneous, flowing suspension is prepared from an inhomogeneous mixture of particulates, triglyceride oil and dispersants. Studying the rheology of a simplified formulation, we find that the input of mechanical energy and staged addition of surfactants combine to effect a considerable shift in the jamming volume fraction of the system, thus increasing the maximum flowable solid content. We discuss the possible microscopic origins of this shift, and suggest that chocolate conching exemplifies a ubiquitous class of powder-liquid mixing.

cond-mat.soft↗

arXiv2018

Quantifying hidden order out of equilibrium

While the equilibrium properties, states, and phase transitions of interacting systems are well described by statistical mechanics, the lack of suitable state parameters has hindered the understanding of non-equilibrium phenomena in diverse settings, from glasses to driven systems to biology. The length of a losslessly compressed data file is a direct measure of its information content: The more ordered the data is, the lower its information content and the shorter the length of its encoding can be made. Here, we describe how data compression enables the quantification of order in non-equilibrium and equilibrium many-body systems, both discrete and continuous, even when the underlying form of order is unknown. We consider absorbing state models on and off-lattice, as well as a system of active Brownian particles undergoing motility-induced phase separation. The technique reliably identifies non-equilibrium phase transitions, determines their character, quantitatively predicts certain critical exponents without prior knowledge of the order parameters, and reveals previously unknown ordering phenomena. This technique should provide a quantitative measure of organization in condensed matter and other systems exhibiting collective phase transitions in and out of equilibrium.

cond-mat.soft↗

arXiv2018

Freezing on a Sphere

The best-understood crystal ordering transition is that of two-dimensional freezing, which proceeds by the rapid eradication of lattice defects as the temperature is lowered below a critical threshold. But crystals that assemble on closed surfaces are required by topology to have a minimum number of lattice defects, called disclinations, that act as conserved topological charges; consider the 12 pentagons on a soccer ball or the 12 pentamers in a viral capsid. Moreover, crystals assembled on curved surfaces can spontaneously develop additional defects to alleviate the stress imposed by the curvature. How then can we have crystallization on a sphere, the simplest curved surface where it is impossible to eliminate these defects? Here we show that freezing on a sphere proceeds by the formation of a single, encompassing "continent," which forces defects into 12 isolated "seas" with the same icosahedral symmetry as soccer balls and viruses. We use this broken symmetry - aligning the vertices of an icosahedron with the defect seas and unfolding the faces onto a plane - to construct a new order parameter that reveals the underlying long-range orientational order of the lattice. These results further our understanding of the thermodynamic and mechanical properties of naturally occurring structures, such as viral capsids, lipid vesicles, and bacterial s-layers, and show that the spontaneous sequestration and organization of defects can produce mechanical and dynamical inhomogeneities in otherwise homogeneous materials.

cond-mat.soft↗

arXiv2017

Charged hydrophobic colloids at an oil/aqueous phase interface

Hydrophobic PMMA colloidal particles, when dispersed in oil with a relatively high dielectric constant, can become highly charged. In the presence of an interface with a conducting aqueous phase, image charge effects lead to strong binding of colloidal particles to the interface, even though the particles are wetted very little by the aqueous phase. In this paper, we study both the behavior of individual colloidal particles as they approach the interface, and the interactions between particles that are already interfacially bound. We demonstrate that using particles which are minimally wetted by the aqueous phase allows us to isolate and study those interactions which are due solely to charging of the particle surface in oil. Finally, we show that these interactions can be understood by a simple image-charge model in which the particle charge $q$ is the sole fitting parameter.

cond-mat.soft↗

arXiv2017

Phase behavior of charged colloids at a fluid interface

We study the phase behavior of a system of charged colloidal particles that are electrostatically bound to an almost flat interface between two fluids. We show that, despite the fact that our experimental system consists of only $10^{3}$ - $10^{4}$ particles, the phase behavior is consistent with the theory of melting due to Kosterlitz, Thouless, Halperin, Nelson and Young (KTHNY). Using spatial and temporal correlations of the bond-orientational order parameter, we classify our samples into solid, isotropic fluid, and hexatic phases. We demonstrate that the topological defect structure we observe in each phase corresponds to the predictions of KTHNY theory. By measuring the dynamic Lindemann parameter, $γ_{L}(τ)$, and the non-Gaussian parameter, $α_{2}(τ)$, of the displacements of the particles relative to their neighbors, we show that each of the phases displays distinctive dynamical behavior.

cond-mat.soft↗

arXiv2016

Long Wavelength Fluctuations and the Glass Transition in 2D and 3D

Phase transitions significantly differ between two-dimensional and three-dimensional systems, but the influence of dimensionality on the glass transition is unresolved. We use microscopy to study colloidal systems as they approach their glass transitions at high concentrations, and find differences between 2D and 3D. We find that in 2D particles can undergo large displacements without changing their position relative to their neighbors, in contrast with 3D. This is related to Mermin-Wagner long-wavelength fluctuations that influence phase transitions in 2D. However, when measuring particle motion only relative to their neighbors, 2D and 3D have similar behavior as the glass transition is approached, showing that the long wavelength fluctuations do not cause a fundamental distinction between 2D and 3D glass transitions.

cond-mat.soft↗

arXiv2015

Artificial Rheotaxis

Motility is a basic feature of living microorganisms, and how it works is often determined by environmental cues. Recent efforts have focused on develop- ing artificial systems that can mimic microorganisms, and in particular their self-propulsion. Here, we report on the design and characterization of syn- thetic self-propelled particles that migrate upstream, known as positive rheo- taxis. This phenomenon results from a purely physical mechanism involving the interplay between the polarity of the particles and their alignment by a viscous torque. We show quantitative agreement between experimental data and a simple model of an overdamped Brownian pendulum. The model no- tably predicts the existence of a stagnation point in a diverging flow. We take advantage of this property to demonstrate that our active particles can sense and predictably organize in an imposed flow. Our colloidal system represents an important step towards the realization of biomimetic micro-systems withthe ability to sense and respond to environmental changes

cond-mat.soft↗

arXiv2013

Isotropic Band Gaps and Freeform Waveguides Observed in Hyperuniform Disordered Photonic Solids

Recently, disordered photonic media and random textured surfaces have attracted increasing attention as strong light diffusers with broadband and wide-angle properties. We report the first experimental realization of an isotropic complete photonic band gap (PBG) in a two-dimensional (2D) disordered dielectric structure. This structure is designed by a constrained-optimization method, which combines advantages of both isotropy due to disorder and controlled scattering properties due to low density fluctuations (hyperuniformity) and uniform local topology. Our experiments use a modular design composed of Al2O3 walls and cylinders arranged in a hyperuniform disordered network. We observe a complete PBG in the microwave region, in good agreement with theoretical simulations, and show that the intrinsic isotropy of this novel class of PBG materials enables remarkable design freedom, including the realization of waveguides with arbitrary bending angles impossible in photonic crystals. This first experimental verification of a complete PBG and realization of functional defects in this new class of materials demonstrates their potential as building blocks for precise manipulation of photons in planar optical micro-circuits and has implications for disordered acoustic and electronic bandgap materials.

cond-mat.mes-hall↗