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Paul Mollière

Publications and source records attributed to Paul Mollière.

At least 55 records · Page 3Linked to original sources

The 12CO/13CO isotopologue ratio of a young, isolated brown dwarf. Possibly distinct formation pathways of super-Jupiters and brown dwarfs

Linking atmospheric characteristics of planets to their formation pathways is a central theme in the study of extrasolar planets. Although the 12C/13C isotope ratio shows little variation in the solar system, the atmosphere of a super-Jupiter was recently shown to be rich in 13CO, possibly as a result of dominant ice accretion beyond the CO snowline during its formation. In this paper we aim to measure the 12CO/13CO isotopologue ratio of a young, isolated brown dwarf. While the general atmospheric characteristics of young, low mass brown dwarfs are expected to be very similar to those of super-Jupiters, their formation pathways may be different, leading to distinct isotopologue ratios. We analyse archival K-band spectra of the L dwarf 2MASS J03552337+1133437 taken with NIRSPEC at the Keck telescope. A free retrieval analysis is applied to the data to determine the isotopologue ratio 12CO/13CO in its atmosphere. The isotopologue 13CO, is detected in the atmosphere through the cross-correlation method at a signal-to-noise of ~8.4. The detection significance is determined to be ~9.5 sigma using Bayesian model comparison between two retrieval models. We retrieve an isotopologue ratio 12CO/13CO of 97(+25/-18), marginally higher than the local interstellar standard. Its C/O ratio of ~0.56 is consistent with the solar value. Although only one super-Jupiter and one brown dwarf have now a measured 12CO/13CO ratio, it is intriguing that they are different, possibly hinting to distinct formation pathways. Albeit spectroscopic similarities, isolated brown dwarfs may experience a top-down formation via gravitational collapse, which resembles star formation, while giant exoplanets favorably form through core accretion, which potentially alters isotopologue ratios in their atmospheres depending on the material they accrete from protoplanetary disks. (abridged)

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The 13O-rich atmosphere of a young accreting super-Jupiter

Isotope abundance ratios play an important role in astronomy and planetary sciences, providing insights in the origin and evolution of the Solar System, interstellar chemistry, and stellar nucleosynthesis. In contrast to deuterium/hydrogen ratios, carbon isotope ratios are found to be roughly constant (~89) in the Solar System, but do vary on galactic scales with 12C/13C~68 in the current local interstellar medium. In molecular clouds and protoplanetary disks, 12CO/13CO isotopologue ratios can be altered by ice and gas partitioning, low-temperature isotopic ion exchange reactions, and isotope-selective photodissociation. Here we report on the detection of 13CO in the atmosphere of the young, accreting giant planet TYC 8998-760-1 b at a statistical significance of >6 sigma. Marginalizing over the planet's atmospheric temperature structure, chemical composition, and spectral calibration uncertainties, suggests a 12CO/13CO ratio of 31 [+17,-10] (90% confidence), a significant enrichment in 13C with respect to the terrestrial standard and the local interstellar value. Since the current location of TYC 8998 b at >160 au is far beyond the CO snowline, we postulate that it accreted a significant fraction of its carbon from ices enriched in 13C through fractionation. Future isotopologue measurements in exoplanet atmospheres can provide unique constraints on where, when and how planets are formed.

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Magma ocean evolution of the TRAPPIST-1 planets

Recent observations of the potentially habitable planets TRAPPIST-1 e, f, and g suggest that they possess large water mass fractions of possibly several tens of wt% of water, even though the host star's activity should drive rapid atmospheric escape. These processes can photolyze water, generating free oxygen and possibly desiccating the planet. After the planets formed, their mantles were likely completely molten with volatiles dissolving and exsolving from the melt. In order to understand these planets and prepare for future observations, the magma ocean phase of these worlds must be understood. To simulate these planets, we have combined existing models of stellar evolution, atmospheric escape, tidal heating, radiogenic heating, magma ocean cooling, planetary radiation, and water-oxygen-iron geochemistry. We present MagmOc, a versatile magma ocean evolution model, validated against the rocky Super-Earth GJ 1132b and early Earth. We simulate the coupled magma ocean-atmospheric evolution of TRAPPIST-1 e, f, and g for a range of tidal and radiogenic heating rates, as well as initial water contents between 1 and 100 Earth oceans. We also reanalyze the structures of these planets and find they have water mass fractions of 0-0.23, 0.01-0.21, and 0.11-0.24 for planets e, f, and g, respectively. Our model does not make a strong prediction about the water and oxygen content of the atmosphere of TRAPPIST-1 e at the time of mantle solidification. In contrast, the model predicts that TRAPPIST-1 f and g would have a thick steam atmosphere with a small amount of oxygen at that stage. For all planets that we investigated, we find that only 3-5% of the initial water will be locked in the mantle after the magma ocean solidified.

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TOI-1231 b: A Temperate, Neptune-Sized Planet Transiting the Nearby M3 Dwarf NLTT 24399

We report the discovery of a transiting, temperate, Neptune-sized exoplanet orbiting the nearby ($d$ = 27.5 pc), M3V star TOI-1231 (NLTT 24399, L 248-27, 2MASS J10265947-5228099). The planet was detected using photometric data from the Transiting Exoplanet Survey Satellite and followed up with observations from the Las Cumbres Observatory and the Antarctica Search for Transiting ExoPlanets program. Combining the photometric data sets, we find that the newly discovered planet has a radius of 3.65$^{+0.16}_{-0.15}$ R$_{\oplus}$, and an orbital period of 24.246 days. Radial velocity measurements obtained with the Planet Finder Spectrograph on the Magellan Clay telescope confirm the existence of the planet and lead to a mass measurement of 15.5$\pm$3.3 M$_{\oplus}$. With an equilibrium temperature of just 330K TOI-1231 b is one of the coolest small planets accessible for atmospheric studies thus far, and its host star's bright NIR brightness (J=8.88, K$_{s}$=8.07) make it an exciting target for HST and JWST. Future atmospheric observations would enable the first comparative planetology efforts in the 250-350 K temperature regime via comparisons with K2-18 b. Furthermore, TOI-1231's high systemic radial velocity (70.5 k\ms) may allow for the detection of low-velocity hydrogen atoms escaping the planet by Doppler shifting the H I Ly-alpha stellar emission away from the geocoronal and ISM absorption features.

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Indications for very high metallicity and absence of methane for the eccentric exo-Saturn WASP-117b

We investigate the atmospheric composition of the long period ($P_{\rm orb}=$ 10 days), eccentric exo-Saturn WASP-117b. WASP-117b could be in atmospheric temperature and chemistry similar to WASP-107b. In mass and radius WASP-117b is similar to WASP-39b, which allows a comparative study of these planets. We analyze a near-infrared transmission spectrum of WASP-117b taken with Hubble Space Telescope/WFC3 G141, which was reduced with two independent pipelines. High resolution measurements were taken with VLT/ESPRESSO in the optical. We report the robust ($3σ$) detection of a water spectral feature. Using a 1D atmosphere model with isothermal temperature, uniform cloud deck and equilibrium chemistry, the Bayesian evidence of a retrieval analysis of the transmission spectrum indicates a preference for a high atmospheric metallicity ${\rm [Fe/H]}=2.58^{+0.26}_{-0.37}$ and clear skies. The data are also consistent with a lower-metallicity composition ${\rm [Fe/H]}<1.75$ and a cloud deck between $10^{-2.2} - 10^{-5.1}$ bar, but with weaker Bayesian preference. We retrieve a low CH$_4$ abundance of $<10^{-4}$ volume fraction within $1 σ$ and $<2\cdot 10^{-1}$ volume fraction within $3 σ$. We cannot constrain the equilibrium temperature between theoretically imposed limits of 700 and 1000~K. Further observations are needed to confirm quenching of CH$_4$ with $K_{zz}\geq 10^8$~cm$^2$/s. We report indications of Na and K in the VLT/ESPRESSO high resolution spectrum with substantial Bayesian evidence in combination with HST data.

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The multi-planet system TOI-421 -- A warm Neptune and a super puffy mini-Neptune transiting a G9 V star in a visual binary

We report the discovery of a warm Neptune and a hot sub-Neptune transiting TOI-421 (BD-14 1137, TIC 94986319), a bright (V=9.9) G9 dwarf star in a visual binary system observed by the TESS space mission in Sectors 5 and 6. We performed ground-based follow-up observations -- comprised of LCOGT transit photometry, NIRC2 adaptive optics imaging, and FIES, CORALIE, HARPS, HIRES, and PFS high-precision Doppler measurements -- and confirmed the planetary nature of the 16-day transiting candidate announced by the TESS team. We discovered an additional radial velocity signal with a period of 5 days induced by the presence of a second planet in the system, which we also found to transit its host star. We found that the inner mini-Neptune, TOI-421b, has an orbital period of Pb =5.19672 +- 0.00049 days, a mass of Mb = 7.17 +- 0.66 Mearth and a radius of Rb = 2.68+0.19-0.18 Rearth, whereas the outer warm Neptune, TOI-421 c, has a period of Pc =16.06819 +- 0.00035 days, a mass of Mc = 16.42+1.06-1.04 Mearth, a radius of Rc = 5.09+0.16-0.15 Rearth and a density of rho_c =0.685+0.080-0.072 g cm-3 . With its characteristics the inner planet (rho_b=2.05+0.52-0.41 g cm-3) is placed in the intriguing class of the super-puffy mini-Neptunes. TOI-421b and TOI-421c are found to be well suitable for atmospheric characterization. Our atmospheric simulations predict significant Ly-alpha transit absorption, due to strong hydrogen escape in both planets, and the presence of detectable CH_4 in the atmosphere of TOI-421c if equilibrium chemistry is assumed.

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Is TiO emission present in the ultra-hot Jupiter WASP-33b? A reassessment using the improved ExoMol Toto line list

[abridged] Efficient absorption of stellar UV and visible radiation by TiO and VO is predicted to drive temperature inversions in the upper atmospheres of hot Jupiters. However, few inversions or detections of TiO or VO have been reported, and results are often contradictory. Using the improved ExoMol Toto line list, we searched for TiO emission in the dayside spectrum of WASP-33b using the same data in which the molecule was previously detected with an older line list at 4.8$σ$. We intended to confirm the molecular detection and quantify the signal improvement offered by the ExoMol Toto line list. Data from the High Dispersion Spectrograph on the Subaru Telescope was extracted and reduced in an identical manner to the previous study. Stellar and telluric contamination were then removed. High-resolution TiO emission models of WASP-33b were created using the radiative transfer code petitRADTRANS and cross-correlated with the data. We measure a 4.3$σ$ TiO emission signature using the ExoMol Toto models, corresponding to a WASP-33b orbital velocity semi-amplitude of $K_\mathrm{p}=252.9^{+5.0}_{-5.3}\ \mathrm{km\ s^{-1}}$ and a system velocity of $v_\mathrm{sys}=-23.0^{+4.7}_{-4.6}\ \mathrm{km\ s^{-1}}$. Injection-recovery tests using models based on the new and earlier line lists indicate that if the new models provide a perfect match to the planet spectrum, the significance of the TiO detection should have increased by a factor of $\sim$2. Although the TiO signal we find is statistically significant, comparison with previous works makes our result too ambiguous to claim a clear-cut detection. Unexpectedly, the new ExoMol Toto models provide a weaker signal than that found previously, which is offset in $K_\mathrm{p}$-$v_\mathrm{sys}$ space. This sheds some doubt on both detections, especially in light of a recently published TiO non-detection using a different dataset.

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MIRACLES: atmospheric characterization of directly imaged planets and substellar companions at 4-5 $μ$m. II. Constraints on the mass and radius of the enshrouded planet PDS 70 b

The circumstellar disk of PDS 70 hosts two forming planets, which are actively accreting gas from their environment. In this work, we report the first detection of PDS 70 b in the Br$α$ and $M'$ filters with VLT/NACO, a tentative detection of PDS 70 c in Br$α$, and a reanalysis of archival NACO $L'$ and SPHERE $H23$ and $K12$ imaging data. The near side of the disk is also resolved with the Br$α$ and $M'$ filters, indicating that scattered light is non-negligible at these wavelengths. The spectral energy distribution of PDS 70 b is well described by blackbody emission, for which we constrain the photospheric temperature and photospheric radius to $T_\mathrm{eff}=1193 \pm 20$ K and $R=3.0 \pm 0.2$ $R_\mathrm{J}$. The relatively low bolometric luminosity, $\log(L/L_\odot) = -3.79 \pm 0.02$, in combination with the large radius, is not compatible with standard structure models of fully convective objects. With predictions from such models, and adopting a recent estimate of the accretion rate, we derive a planetary mass and radius in the range of $M_\mathrm{p}\approx 0.5-1.5$ $M_\mathrm{J}$ and $R_\mathrm{p}\approx 1-2.5$ $R_\mathrm{J}$, independently of the age and post-formation entropy of the planet. The blackbody emission, large photospheric radius, and the discrepancy between the photospheric and planetary radius suggests that infrared observations probe an extended, dusty environment around the planet, which obscures the view on its molecular composition. Finally, we derive a rough upper limit on the temperature and radius of potential excess emission from a circumplanetary disk, $T_\mathrm{eff}\lesssim256$ K and $R\lesssim245$ $R_\mathrm{J}$, but we do find weak evidence that the current data favors a model with a single blackbody component.

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A Highly Eccentric Warm Jupiter Orbiting TIC 237913194

The orbital parameters of warm Jupiters serve as a record of their formation history, providing constraints on formation scenarios for giant planets on close and intermediate orbits. Here, we report the discovery of TIC 237913194b, detected in full frame images from Sectors 1 and 2 of TESS, ground-based photometry (CHAT, LCOGT), and FEROS radial velocity time series. We constrain its mass to $M_\mathrm{P} = 1.942_{-0.091}^{+0.091}\,{\rm M_{J}} $, and its radius to $R_\mathrm{P} = 1.117_{-0.047}^{+0.054}\,{\rm R_J}$, implying a bulk density similar to Neptune's. It orbits a G-type star (${\rm M}_{\star} = 1.026_{-0.055}^{+0.057}\,{\rm M}_{\odot}$, $V = 12.1$ mag) with a period of $15.17\,$d on one of the most eccentric orbits of all known warm giants ($e \approx 0.58$). This extreme dynamical state points to a past interaction with an additional, undetected massive companion. A tidal evolution analysis showed a large tidal dissipation timescale, suggesting that the planet is not a progenitor for a hot Jupiter caught during its high-eccentricity migration. TIC 237913194b further represents an attractive opportunity to study the energy deposition and redistribution in the atmosphere of a warm Jupiter with high eccentricity.

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Evidence of Three Mechanisms Explaining the Radius Anomaly of Hot Jupiters

The radii of hot Jupiters are still not fully understood and all of the proposed explanations are based on the idea that these close-in giant planets possess hot interiors. We approach the radius anomaly problem by adopting a statistical approach. We infer the internal luminosity for the sample of hot Jupiters, study its effect on the interior structure, and put constraints on which mechanism is the dominant one. We develop a flexible and robust hierarchical Bayesian model that couples the interior structure of exoplanets to their observed properties. We apply the model to 314 hot Jupiters and infer the internal luminosity distribution for each planet and study at the population level ({\it i}) the mass-luminosity-radius distribution and as a function of equilibrium temperature the distributions of the ({\it ii}) heating efficiency, ({\it iii}) internal temperature, and the ({\it iv}) pressure of the radiative-convective-boundary (RCB). We find that hot Jupiters tend to have high internal luminosity leading to hot interiors. This has important consequences on the cooling rate and we find that the RCB is located at low pressures. Assuming that the ultimate source of the extra heating is the irradiation from the host star, we illustrate that the heating efficiency follows a Gaussian distribution, in agreement with previous results. We discuss our findings in the context of the proposed heating mechanisms and illustrate that ohmic dissipation, advection of potential temperature, and thermal tides are in agreement with certain trends inferred from our analysis and thus all three models can explain aspects of the observations. We provide new insights on the interior structure of hot Jupiters and show that with our current knowledge it is still challenging to firmly identify the universal mechanism driving the inflated radii.

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The ExoMolOP Database: Cross-sections and k-tables for Molecules of Interest in High-Temperature Exoplanet Atmospheres

A publicly available database of opacities for molecules of astrophysical interest, ExoMolOP, has been compiled for over 80 species, based on the latest line list data from the ExoMol, HITEMP and MoLLIST databases. These data are generally suitable for characterising high temperature exoplanet or cool stellar/substellar atmospheres, and have been computed at a variety of pressures and temperatures, with a few molecules included at room-temperature only from the HITRAN database. The data are formatted in different ways for four different exoplanet atmosphere retrieval codes; ARCiS, TauREx, NEMESIS and petitRADTRANS, and include both cross-sections (at R~=~$\fracλ{Δλ}$~=~15,000) and k-tables (at R~=~$\fracλ{Δλ}$~=~1000) for the 0.3~-~50$μ$m wavelength region. Opacity files can be downloaded and used directly for these codes. Atomic data for alkali metals Na and K are also included, using data from the NIST database and the latest line shapes for the resonance lines. Broadening parameters have been taken from the literature where available, or from those for a known molecule with similar molecular properties where no broadening data are available. The data are available from www.exomol.com.

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The role of clouds on the depletion of methane and water dominance in the transmission spectra of irradiated exoplanets

Observations suggest an abundance of water and paucity of methane in the majority of observed exoplanetary atmospheres. We isolate the effect of atmospheric processes to investigate possible causes. Previously, we studied the effect of effective temperature, surface gravity, metallicity, carbon-to-oxygen ratio, and stellar type assuming cloud-free thermochemical equilibrium and disequilibrium chemistry. However, under these assumptions, methane remains a persisting spectral feature in the transmission spectra of exoplanets over a certain parameter space, the Methane Valley. In this work we investigate the role of clouds on this domain and we find that clouds change the spectral appearance of methane in two direct ways: 1) by heating-up the photosphere of colder planets, and 2) by obscuring molecular features. The presence of clouds also affects methane features indirectly: 1) cloud heating results in more evaporation of condensates and hence releases additional oxygen, causing water dominated spectra of colder carbon-poor exoplanets, and 2) HCN/CO production results in a suppression of depleted methane features by these molecules. The presence of HCN/CO and a lack of methane could be an indication of cloud formation on hot exoplanets. Cloud heating can also deplete ammonia. Therefore, a simultaneous depletion of methane and ammonia is not unique to photochemical processes. We propose that the best targets for methane detection are likely to be massive but smaller planets with a temperature around 1450 K orbiting colder stars. We also construct Spitzer synthetic color-maps and find that clouds can explain some of the high contrast observations by IRAC's channel 1 and 2.

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Tracing bulk elemental ratios in exoplanetary atmospheres with TiO chemistry

Knowing the bulk elemental abundances of an exoplanetary atmosphere is not an easy task, but it is crucial to understand the formation history of planets. The purpose of this work is to show that the observability of TiO features at optical wavelengths in the transmission spectra of hot Jupiter atmospheres is sensitive to the bulk chemical properties of the atmosphere. For that, we run a grid of chemical models which include TiO formation and destruction, for the ultra-hot Jupiter WASP-19b and an ultra-hot version of HD~209458b. We take into account non-equilibrium chemistry and changes in the temperature and pressure structure of these atmospheres caused by different C/O ratios. We calculate synthetic transmission spectra for these models, and study the relative strengths of TiO and \ce{H2O} features quantitatively. To compare with observations, we use a model independent metric for molecular abundances, $ΔZ_{\rm TiO-H_2O}/H_{\rm eq}$ that has been previously used in observational studies of exoplanetary atmospheres. We find that with this metric we can differentiate between different chemical models and place constraints on the atmosphere's bulk carbon and oxygen abundance. From chemical considerations we expected that the TiO abundance would depend on the bulk nitrogen, however found that any change to N/H did not result in changes to the resulting TiO. We apply our method to a set of known exoplanets that have been observed in the relevant optical wavelengths and find good agreement between low resolution observations and our model for WASP-121b, marginally good agreement with WASP-79b, WASP-76b, and WASP-19b, and poorer agreement with HD 209458b. Our method can be particularly helpful for indirect studies of the bulk abundances of carbon and oxygen.

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Equatorial anti-rotating day side wind flow in WASP-43b elicited by deep wind jets?

We present WASP-43b climate simulations with deep wind jets (down to 700~bar) that are linked to retrograde (westward) flow at the equatorial day side for $p<0.1$~bar. Retrograde flow inhibits efficient eastward heat transport and naturally explains the small hotspot shift and large day-night-side gradient of WASP-43b ($P_{\text{orb}}=P_{\text{rot}}=0.8135$~days) observed with Spitzer. We find that deep wind jets are mainly associated with very fast rotations ($P_{\text{rot}}=P_{\text{orb}}\leq 1.5$~days) which correspond to the Rhines length smaller than $2$ planetary radii. We also diagnose wave activity that likely gives rise to deviations from superrotation. Further, we show that we can achieve full steady state in our climate simulations by imposing a deep forcing regime for $p>10$~bar: convergence time scale $τ_{\text{conv}}=10^6-10^8$~s to a common adiabat, as well as linear drag at depth ($p\geq 200$~bar), which mimics to first order magnetic drag. Lower boundary stability and the deep forcing assumptions were also tested with climate simulations for HD~209458b ($P_{\text{orb}}=P_{\text{rot}}=3.5$~days). HD~209458b simulations always show shallow wind jets (never deeper than 100~bar) and unperturbed superrotation. If we impose a fast rotation ($P_{\text{orb}}=P_{\text{rot}}=0.8135$~days), also the HD~209458b-like simulation shows equatorial retrograde flow at the day side. We conclude that the placement of the lower boundary at $p=200$~bar is justified for slow rotators like HD~209458b, but we suggest that it has to be placed deeper for fast-rotating, dense hot Jupiters ($P_{\text{orb}}\leq 1.5$~days) like WASP-43b. Our study highlights that the deep atmosphere may have a strong influence on the observable atmospheric flow in some hot Jupiters.

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Tentative Evidence for Water Vapor in the Atmosphere of the Neptune-Size Exoplanet HD 106315 c

We present a transmission spectrum for the Neptune-size exoplanet HD 106315 c from optical to infrared wavelengths based on transit observations from the Hubble Space Telescope/Wide Field Camera 3, K2, and Spitzer. The spectrum shows tentative evidence for a water absorption feature in the $1.1 - 1.7μ$m wavelength range with a small amplitude of 30 ppm (corresponding to just $0.8 \pm 0.04$ atmospheric scale heights). Based on an atmospheric retrieval analysis, the presence of water vapor is tentatively favored with a Bayes factor of 1.7 - 2.6 (depending on prior assumptions). The spectrum is most consistent with either enhanced metallicity, high altitude condensates, or both. Cloud-free solar composition atmospheres are ruled out at $>5σ$ confidence. We compare the spectrum to grids of cloudy and hazy forward models and find that the spectrum is fit well by models with moderate cloud lofting or haze formation efficiency, over a wide range of metallicities ($1 - 100\times$ solar). We combine the constraints on the envelope composition with an interior structure model and estimate that the core mass fraction is $\gtrsim0.3$. With a bulk composition reminiscent of that of Neptune and an orbital distance of 0.15 AU, HD 106315 c hints that planets may form out of broadly similar material and arrive at vastly different orbits later in their evolution.

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Atmospheric compositions and observability of nitrogen dominated ultra-short period super-Earths

We explore the chemistry and observability of nitrogen dominated atmospheres for ultra-short-period super-Earths. We base the assumption, that super-Earths could have nitrogen filled atmospheres, on observations of 55 Cnc e that favour a scenario with a high-mean-molecular-weight atmosphere. We take Titan's elemental budget as our starting point and using chemical kinetics compute a large range of possible compositions for a hot super-Earth. We use analytical temperature profiles and explore a parameter space spanning orders of magnitude in C/O \& N/O ratios, while always keeping nitrogen the dominant component. We generate synthetic transmission and emission spectra and assess their potential observability with the future James Webb Space Telescope and ARIEL. Our results suggest that HCN is a strong indicator of a high C/O ratio, which is similar to what is found for H-dominated atmospheres. We find that these worlds are likely to possess C/O > 1.0, and that HCN, CN, CO should be the primary molecules to be searched for in thermal emission. For lower temperatures (T < 1500 K), we additionally find NH3 in high N/O ratio cases, and C2H4, CH4 in low N/O ratio cases to be strong absorbers. Depletion of hydrogen in such atmospheres would make CN, CO and NO exceptionally prominent molecules to look for in the 0.6 - 5.0 $μ$m range. Our models show that the upcoming JWST and ARIEL missions will be able to distinguish atmospheric compositions of ultra-short period super-Earths with unprecedented confidence.

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MIRACLES: atmospheric characterization of directly imaged planets and substellar companions at 4-5 $μ$m. I. Photometric analysis of $β$ Pic b, HIP 65426 b, PZ Tel B and HD 206893 B

Directly imaged planets and substellar companions are key targets for the characterization of self-luminous atmospheres. Their photometric appearance at 4-5 $μ$m is sensitive to the chemical composition and cloud content of their atmosphere. We aim at systematically characterizing the atmospheres of directly imaged low-mass companions at 4-5 $μ$m. We want to homogeneously process the data and compile a photometric library at thermal wavelengths of these mostly young, low-gravity objects. In this way, we want to find trends related to their spectral type and surface gravity by comparing with isolated brown dwarfs and predictions from atmospheric models. We have used the high-resolution, high-contrast capabilities of NACO at the VLT to directly image the companions of HIP 65426, PZ Tel, and HD 206893 in the NB4.05 and/or $M'$ filters. For the same targets, and additionally $β$ Pic, we have also analyzed six archival VLT/NACO datasets which were taken with the NB3.74, $L'$, NB4.05, and $M'$ filters. The $L'$-NB4.05 and $L'$-$M'$ colors of the studied sample are all red while the NB4.05-$M'$ color is blue for $β$ Pic b, gray for PZ Tel B, and red for HIP 65426 b and HD 206893 B (although typically with low significance). The absolute NB4.05 and $M'$ fluxes of our sample are all larger than those of field dwarfs with similar spectral types. Finally, the surface gravity of $β$ Pic b has been constrained to $\log{g} = 4.17_{-0.13}^{+0.10}$ dex from its photometry and dynamical mass. A red color at 3-4 $μ$m and a blue color at 4-5 $μ$m might be (partially) caused by H$_2$O and CO absorption, respectively. The red characteristics of $β$ Pic b, HIP 65426 b, and HD 206893 B at 3-5$μ$m, as well as their higher fluxes in NB4.05 and $M'$ compared to field dwarfs, indicate that cloud densities are enhanced close to the photosphere as a result of their low surface gravity.

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From cold to hot irradiated gaseous exoplanets: Fingerprints of chemical disequilibrium in atmospheric spectra

Almost all planetary atmospheres are affected by disequilibrium chemical processes. In this paper we introduce our recently developed Chemical Kinetic Model (\texttt{ChemKM}). We show that the results of our HD189733b model are in good agreement with previously published results, except at $μ$bar regime, where molecular diffusion and photochemistry are the dominant processes. We thus recommend careful consideration of these processes when abundances at the top of the atmosphere are desired. We also propose a new metric for a quantitative measure of quenching levels. By applying this metric, we find that quenching pressure decreases with the effective temperature of planets, but it also varies significantly with other atmospheric parameters such as [Fe/H], log(g), and C/O. In addition, we find that the "Methane Valley", a region between 800 and 1500K where above a certain C/O threshold value a greater chance of CH$_4$ detection is expected, still exists after including the vertical mixing. The first robust CH$_4$ detection on an irradiated planet (HD102195b) places this object within this region; supporting our prediction. We also investigate the detectability of disequilibrium spectral fingerprints by JWST, and suggest focusing on the targets with T$_{eff}$ between 1000 and 1800K, orbiting around M-dwarfs, having low surface gravity but high metallicity and a C/O ratio value around unity. Finally, constructing Spitzer color-maps suggests that the main two color-populations are largely insensitive to the vertical mixing. Therefore any deviation of observational points from these populations are likely due to the presence of clouds and not disequilibrium processes. However, some cold planets (T$_{eff}<$900K) with very low C/O ratios ($<$0.25) show significant deviations; making these planets interesting cases for further investigation.

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