arXiv subjects

Paul Quinn

Publications and source records attributed to Paul Quinn.

4 recordsLinked to original sources

arXiv2026

Reducing acquisition time and radiation damage: data-driven subsampling for spectro-microscopy

Spectro-microscopy is an experimental technique which can be used to observe spatial variations in chemical state and changes in chemical state over time or under experimental conditions. As a result it has broad applications across areas such as energy materials, catalysis, environmental science and biological samples. However, the technique is often limited by factors such as long acquisition times and radiation damage. We present two measurement strategies that allow for significantly shorter experiment times and total doses applied. The strategies are based on taking only a small subset of all the measurements (e.g. sparse acquisition or subsampling), and then computationally reconstructing all unobserved measurements using mathematical techniques. The methods are data-driven, using spectral and spatial importance subsampling distributions to identify important measurements. As a result, taking as little as 4-6\% of the measurements is sufficient to capture the same information as in a conventional scan.

physics.med-ph↗

arXiv2025

Autonomous battery research: Principles of heuristic operando experimentation

Unravelling the complex processes governing battery degradation is critical to the energy transition, yet the efficacy of operando characterisation is severely constrained by a lack of Reliability, Representativeness, and Reproducibility (the 3Rs). Current methods rely on bespoke hardware and passive, pre-programmed methodologies that are ill-equipped to capture stochastic failure events. Here, using the Rutherford Appleton Laboratory's multi-modal toolkit as a case study, we expose the systemic inability of conventional experiments to capture transient phenomena like dendrite initiation. To address this, we propose Heuristic Operando experiments: a framework where an AI pilot leverages physics-based digital twins to actively steer the beamline to predict and deterministically capture these rare events. Distinct from uncertainty-driven active learning, this proactive search anticipates failure precursors, redefining experimental efficiency via an entropy-based metric that prioritises scientific insight per photon, neutron, or muon. By focusing measurements only on mechanistically decisive moments, this framework simultaneously mitigates beam damage and drastically reduces data redundancy. When integrated with FAIR data principles, this approach serves as a blueprint for the trusted autonomous battery laboratories of the future.

physics.ins-det↗

arXiv2023

Undersampling Raster Scans in Spectromicroscopy for reduced dose and faster measurements

Combinations of spectroscopic analysis and microscopic techniques are used across many disciplines of scientific research, including material science, chemistry and biology. X-ray spectromicroscopy, in particular, is a powerful tool used for studying chemical state distributions at the micro and nano scales. With the beam fixed, a specimen is typically rastered through the probe with continuous motion and a range of multimodal data is collected at fixed time intervals. The application of this technique is limited in some areas due to: long scanning times to collect the data, either because of the area/volume under study or the compositional properties of the specimen; and material degradation due to the dose absorbed during the measurement. In this work, we propose a novel approach for reducing the dose and scanning times by undersampling the raster data. This is achieved by skipping rows within scans and reconstructing the x-ray spectromicroscopic measurements using low-rank matrix completion. The new method is robust and allows for x 5-6 reduction in sampling. Experimental results obtained on real data are illustrated.

physics.med-ph↗

arXiv2019

Data Protection by Design for Cybersecurity Systems in a Smart Home Environment

The present paper deals with the elucidation and implementation of the Data Protection by Design (DPbD) principle as recently introduced in the European Union data protection law, specifically with regards to cybersecurity systems in a Smart Home environment, both from a legal and a technical perspective. Starting point constitutes the research conducted in the Cyber-Trust project, which endeavours the development of an innovative and customisable cybersecurity platform for cyber-threat intelligence gathering, detection and mitigation within the Internet of Things ecosystem. During the course of the paper, the requirements of DPbD with regards to the conceptualisation, design and actual development of the system are presented as prescribed in law. These requirements are then translated into technical solutions, as envisaged in the Cyber-Trust system. For trade-offs are not foreign to the DPbD context, technical limitations and legal challenges are also discussed in this interdisciplinary dialogue.

cs.CR↗