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Paul S. Julienne

Publications and source records attributed to Paul S. Julienne.

At least 37 records · Page 2Linked to original sources

Weakly bound molecules as sensors of new gravitylike forces

Several extensions to the Standard Model of particle physics, including light dark matter candidates and unification theories, predict deviations from Newton's law of gravitation. For macroscopic distances, the inverse-square law of gravitation is well confirmed by astrophysical observations and laboratory experiments. At micrometer and shorter length scales, however, even the state-of-the-art constraints on deviations from gravitational interaction, whether provided by neutron scattering or precise measurements of forces between macroscopic bodies, are currently many orders of magnitude larger than gravity itself. Here we show that precision spectroscopy of weakly bound molecules can be used to constrain non-Newtonian interactions between atoms. A proof-of-principle demonstration using recent data from photoassociation spectroscopy of weakly bound Yb$_2$ molecules yields constraints on these new interactions that are already close to state-of-the-art neutron scattering experiments. At the same time, with the development of the recently proposed optical molecular clocks, the neutron scattering constraints could be surpassed by at least two orders of magnitude.

physics.atom-ph↗

Single-atom transistor as a precise magnetic field sensor

Feshbach resonances, which allow for tuning the interactions of ultracold atoms with an external magnetic field, have been widely used to control the properties of quantum gases. We propose a~scheme for using scattering resonances as a probe for external fields, showing that by carefully tuning the parameters it is possible to reach a $10^{-5}$G (or nT) level of precision with a single pair of atoms. We show that for our collisional setup it is possible to saturate the quantum precision bound with a simple measurement protocol.

quant-ph↗

Rydberg optical Feshbach resonances in cold gases

We propose a novel scheme to efficiently tune the scattering length of two colliding ground-state atoms by off-resonantly coupling the scattering-state to an excited Rydberg-molecular state using laser light. For the s-wave scattering of two colliding ${^{87}}\mathrm{Rb}$ atoms, we demonstrate that the effective optical length and pole strength of this Rydberg optical Feshbach resonance can be tuned over several orders of magnitude, while incoherent processes and losses are minimised. Given the ubiquity of Rydberg molecular states, this technique should be generally applicable to homo-nuclear atomic pairs as well as to atomic mixtures with s-wave (or even p-wave) scattering.

cond-mat.quant-gas↗

State-to-state chemistry at ultra-low temperature

Fully understanding a chemical reaction on the quantum level is a long-standing goal in physics and chemistry. Experimental investigation of such state-to-state chemistry requires both the preparation of the reactants and the detection of the products in a quantum state resolved way, which has been a long term challenge. Using the high level control in the ultracold domain, we prepare a few-body quantum state of reactants and demonstrate state-to-state chemistry with unprecedented resolution. We present measurements and accompanying theoretical analysis for the recombination of three spin-polarized ultracold Rb atoms forming a weakly bound Rb$_2$ dimer. Detailed insights of the reaction process are obtained that suggest propensity rules for the distribution of reaction products. The scheme can readily be adapted to other species and opens a door to detailed investigations of inelastic or reactive processes in domains never before accessible.

cond-mat.quant-gas↗

Observation of interspecies Feshbach resonances in an ultracold $^{39}$K-$^{133}$Cs mixture and refinement of interaction potentials

We observe interspecies Feshbach resonances due to s-wave bound states in ultracold $^{39}$K-$^{133}$Cs scattering for three different spin mixtures. The resonances are observed as joint atom loss and heating of the K sample. We perform least-squares fits to obtain improved K-Cs interaction potentials that reproduce the observed resonances, and carry out coupled-channel calculations to characterize the scattering and bound-state properties for $^{39}$K-Cs, $^{40}$K-Cs and $^{41}$K-Cs. Our results open up the possibilities of tuning interactions in K-Cs atomic mixtures and of producing ultracold KCs molecules.

cond-mat.quant-gas↗

Ultracold atoms in quasi-1D traps: a step beyond the Lieb-Liniger model

Ultracold atoms placed in a tight cigar-shaped trap are usually described in terms of the Lieb-Liniger model. We study the extensions of this model which arise when van der Waals interaction between atoms is taken into account. We find that the corrections induced by the finite range of interactions can become especially important in the vicinity of narrow Feshbach resonances and suggest realistic schemes of their experimental detection. The interplay of confinement and interactions can lead to effective transparency where the one-dimensional interactions are weak in a wide range of parameters.

cond-mat.quant-gas↗

Photoassociation of spin polarized Chromium

We report the homonuclear photoassociation (PA) of ultracold ${}^{52}\mathrm{Cr}$ atoms in an optical dipole trap. This constitutes the first measurement of PA in an element with total electron spin $\tilde{S}>1$. Although Cr, with its ${}^{7}\mathrm{S}_{3}$ ground and ${}^{7}\mathrm{P}_{4,3,2}$ excited states, is expected to have a complicated PA spectrum we show that a spin polarized cloud exhibits a remarkably simple PA spectrum when circularly polarized light is applied. Over a scan range of 20 GHz below the ${}^{7}\mathrm{P}_{3}$ asymptote we observe two distinct vibrational series each following a LeRoy-Bernstein law for a $C_3 / R^{3}$ potential with excellent agreement. We determine the $C_3$ coefficients of the Hund's case c) relativistic adiabatic potentials to be -1.83$\pm$0.02 a.u. and -1.46$\pm$0.01a.u.. Theoretical non-rotating Movre-Pichler calculations enable a first assignment of the series to $Ω=6_u$ and $5_g$ potential energy curves. In a different set of experiments we disturb the selection rules by a transverse magnetic field which leads to additional PA series.

physics.atom-ph↗

Doublon dynamics and polar molecule production in an optical lattice

Ultracold polar molecules provide an excellent platform to study quantum many-body spin dynamics, which has become accessible in the recently realized low entropy quantum gas of polar molecules in an optical lattice. To obtain a detailed understanding for the molecular formation process in the lattice, we prepare a density distribution where lattice sites are either empty or occupied by a doublon composed of a bosonic atom interacting with a fermionic atom. By letting this disordered, out-of-equilibrium system evolve from a well-defined initial condition, we observe clear effects on pairing that arise from inter-species interactions, a higher partial wave Feshbach resonance, and excited Bloch-band population. When only the lighter fermions are allowed to tunnel in the three-dimensional (3D) lattice, the system dynamics can be well described by theory. However, in a regime where both fermions and bosons can tunnel, we encounter correlated dynamics that is beyond the current capability of numerical simulations. Furthermore, we show that we can probe the microscopic distribution of the atomic gases in the lattice by measuring the inelastic loss of doublons. These techniques realize tools that are generically applicable to heteronuclear diatomic systems in optical lattices and can shed light on molecule production as well as dynamics of a Bose-Fermi mixture.

cond-mat.quant-gas↗

Chaotic scattering in the presence of a dense set of overlapping Feshbach resonances

Complex quantum systems consisting of large numbers of strongly coupled states exhibit characteristic level repulsion, leading to a non-Poisson spacing distribution which can be described by Random Matrix Theory. Scattering resonances observed in ultracold atomic and molecular systems exhibit similar features as a consequence of their energy level structure. We study how the overlap between Feshbach resonances affects the distribution of resonance spacings. The spectrum of strongly overlapping resonances turns out to be non-Poisson even when the assumptions of Random Matrix Theory are not fulfilled, but the spectrum is also not completely chaotic and tends towards being semi-Poisson.

quant-ph↗

Reactive collisions in confined geometries

We consider low energy threshold reactive collisions of particles interacting via a van der Waals potential at long range in the presence of external confinement and give analytic formulas for the confinement modified scattering in such circumstances. The reaction process is described in terms of the short range reaction probability. Quantum defect theory is used to express elastic and inelastic or reaction collision rates analytically in terms of two dimensionless parameters representing phase and reactivity. We discuss the modifications to Wigner threshold laws for quasi-one-dimensional and quasi-two-dimensional geometries. Confinement-induced resonances are suppressed due to reactions and are completely absent in the universal limit where the short-range loss probability approaches unity.

cond-mat.quant-gas↗

Cold atomic and molecular collisions: approaching the universal loss regime

We investigate the behaviour of single-channel theoretical models of cold and ultracold collisions that take account of inelastic and reactive processes using a single parameter to represent short-range loss. We present plots of the resulting energy-dependence of elastic and inelastic or reactive cross sections over the full parameter space of loss parameters and short-range phase shifts. We then test the single-channel model by comparing it with the results of coupled-channel calculations of rotationally inelastic collisions between LiH molecules and Li atoms. We find that the range of cross sections predicted by the single-channel model becomes increasingly accurate as the initial LiH rotational quantum number increases, with a corresponding increase in the number of open loss channels. The results suggest that coupled-channel calculations at very low energy (in the s-wave regime) could in some cases be used to estimate a loss parameter and then to predict the range of possible loss rates at higher energy, without the need for explicit coupled-channel calculations for higher partial waves.

physics.atom-ph↗

Quantum defect model of a reactive collision at finite temperature

We consider a general problem of inelastic collision of particles interacting with power-law potentials. Using quantum defect theory we derive an analytical formula for the energy-dependent complex scattering length, valid for arbitrary collision energy, and use it to analyze the elastic and reactive collision rates. Our theory is applicable for both universal and non-universal collisions. The former corresponds to the unit reaction probability at short range, while in the latter case the reaction probability is smaller than one. In the high-energy limit we present a method that allows to incorporate quantum corrections to the classical reaction rate due to the shape resonances and the quantum tunneling.

physics.atom-ph↗

Polar molecule reactive collisions in quasi-1D systems

We study polar molecule scattering in quasi-one-dimensional geometries. Elastic and reactive collision rates are computed as a function of collision energy and electric dipole moment for different confinement strengths. The numerical results are interpreted in terms of first order scattering and of adiabatic models. Universal dipolar scattering is also discussed. Our results are relevant to experiments where control of the collision dynamics through one dimensional confinement and an applied electric field is envisioned.

cond-mat.quant-gas↗

Mass scaling and non-adiabatic effects in photoassociation spectroscopy of ultracold strontium atoms

We report photoassociation spectroscopy of ultracold $^{86}$Sr atoms near the intercombination line and provide theoretical models to describe the obtained bound state energies. We show that using only the molecular states correlating with the $^1S_0$$+$$^3P_1$ asymptote is insufficient to provide a mass scaled theoretical model that would reproduce the bound state energies for all isotopes investigated to date: $^{84}$Sr, $^{86}$Sr and $^{88}$Sr. We attribute that to the recently discovered avoided crossing between the $^1S_0$$+$$^3P_1$ $0_u^+$ ($^3Π_u$) and $^1S_0$$+$$^1D_2$ $0_u^+$ ($^1Σ^+_u$) potential curves at short range and we build a mass scaled interaction model that quantitatively reproduces the available $0_u^+$ and $1_u$ bound state energies for the three stable bosonic isotopes. We also provide isotope-specific two-channel models that incorporate the rotational (Coriolis) mixing between the $0_u^+$ and $1_u$ curves which, while not mass scaled, are capable of quantitatively describing the vibrational splittings observed in experiment. We find that the use of state-of-the-art ab initio potential curves significantly improves the quantitative description of the Coriolis mixing between the two -8 GHz bound states in $^{88}$Sr over the previously used model potentials. We show that one of the recently reported energy levels in $^{84}$Sr does not follow the long range bound state series and theorize on the possible causes. Finally, we give the Coriolis mixing angles and linear Zeeman coefficients for all of the photoassociation lines. The long range van der Waals coefficients $C_6(0_u^+)=3868(50)$~a.u. and $C_6(1_u)=4085(50)$~a.u. are reported.

physics.atom-ph↗

Contrasting the wide Feshbach resonances in $^6$Li and $^7$Li

We compare and contrast the wide Fehbach resonances and the corresponding weakly bound states in the lowest scattering channels of ultracold $^6$Li and $^7$Li. We use high-precision measurements of binding energies and scattering properties to determine new interaction potentials, incorporating non-Born-Oppenheimer terms to account for the failure of mass scaling between $^6$Li and $^7$Li. Correction terms are needed for both the singlet and the triplet potential curves. The universal formula relating binding energy to scattering length is not accurate for either system. The $^6$Li resonance is open-channel-dominated and the van der Waals formula of Gao [J. Phys. B 37, 4273 (2004)] gives accurate results for the binding energies across much of the resonance width. The $^7$Li resonance, by contrast, is weakly closed-channel-dominated and a coupled-channels treatment of the binding energies is required. Plotting the binding energies in universal van der Waals form helps illustrate subtle differences between the experimental results and different theoretical forms near the resonance pole.

physics.atom-ph↗

Effective-range approximations for resonant scattering of cold atoms

Studies of cold atom collisions and few-body interactions often require the energy dependence of the scattering phase shift, which is usually expressed in terms of an effective-range expansion. We use accurate coupled-channel calculations on $^{6}$Li, $^{39}$K and $^{133}$Cs to explore the behavior of the effective range in the vicinity of both broad and narrow Feshbach resonances. We show that commonly used expressions for the effective range break down dramatically for narrow resonances and near the zero-crossings of broad resonances. We present an alternative parametrization of the effective range that is accurate through both the pole and the zero-crossing for both broad and narrow resonances. However, the effective range expansion can still fail at quite low collision energies, particularly around narrow resonances. We demonstrate that an analytical form of an energy and magnetic field-dependent phase shift, based on multichannel quantum defect theory, gives accurate results for the energy-dependent scattering length.

cond-mat.quant-gas↗

Universal van der Waals Physics for Three Ultracold Atoms

Experimental studies with ultracold atoms have enabled major breakthroughs in understanding three-body physics, historically a fundamental yet challenging problem. This is because the interactions among ultracold atoms can be precisely varied using magnetically tunable scattering resonances known as Feshbach resonances. The collisions of ultracold atoms have been discovered to have many universal aspects near the unitarity limit. Away from this limit, many quantum states are expected to be active during a three-body collision, making the collisional observables practically unpredictable. Here we report a major development in predicting three-body ultracold scattering rates by properly building in the pairwise van der Waals interactions plus the multi-spin properties of a tunable Feshbach resonance state characterized by two known dimensionless two-body parameters. Numerical solution of the Schr{ö}dinger equation then predicts the three-atom collisional rates without adjustable fitting parameters needed to fit data. Our calculations show quantitative agreement in magnitude and feature position and shape across the full range of tuning of measured rate coefficients for three-body recombination and atom-dimer collisions involving ultracold Cs atoms.

physics.atom-ph↗

Scattering lengths in isotopologues of the RbYb system

We model the binding energies of rovibrational levels of the RbYb molecule using experimental data from two-color photoassociation spectroscopy in mixtures of ultracold $^{87}$Rb with various Yb isotopes. The model uses a theoretical potential based on state-of-the-art \emph{ab initio} potentials, further improved by least-squares fitting to the experimental data. We have fixed the number of bound states supported by the potential curve, so that the model is mass scaled, that is, it accurately describes the bound state energies for all measured isotopic combinations. Such a model enables an accurate prediction of the s-wave scattering lengths of all isotopic combinations of the RbYb system. The reduced mass range is broad enough to cover the full scattering lengths range from $-\infty$ to $+\infty$. For example, the $^{87}$Rb$^{174}$Yb system is characterized by a large positive scattering length of $+880(120)$~a.u., while $^{87}$Rb$^{173}$Yb has $a=-626(88)$~a.u.. On the other hand $^{87}$Rb$^{170}$Yb has a very small scattering length of $-14.5(1.8)$~a.u. confirmed by the pair's extremely low thermalization rate. For isotopic combinations including $^{85}$Rb the variation of the interspecies scattering lengths is much smoother ranging from $+39.0(1.6)$ a.u. for $^{85}$Rb$^{176}$Yb to $+230(10)$ a.u. in the case of $^{85}$Rb$^{168}$Yb. Hyperfine corrections to these scattering lengths are also given. We further complement the fitted potential with interaction parameters calculated from alternative methods. The recommended value of the van der Waals coefficient is $C_6$=2837(13)~a.u. and is in agreement and more precise than the current state-of-the-art theoretical predictions (S. G. Porsev, M. S. Safronova, A. Derevianko, and C.W. Clark, arXiv:1307.2654 (2013)).

physics.atom-ph↗