Filamentation of Mid-IR pulses in ambient air in the vicinity of molecular resonances
Properties of filaments ignited by multi-millijoule, 90-fs mid-IR pulses centered at 3.9 μm are examined experimentally by monitoring plasma density and losses as well as spectral dynamics and beam profile evolution at different focusing strengths. By softening the focusing from strong (f=0.25 m) to loose (f=7 m) we observe a shift from plasma assisted filamentation to filaments with low plasma density. In the latter case, filamentation manifests itself by beam self-symmetrization and spatial self-channeling. Spectral dynamics in the case of loose focusing is dominated by the non-linear Raman frequency downshift, which leads to the overlap with the CO2 resonance in the vicinity of 4.2 μm. The dynamic CO2 absorption in the case of 3.9-μm filaments with their low plasma content is the main mechanism of energy losses and either alone or together with other nonlinear processes contributes to the arrest of intensity.