Judd-Ofelt analysis of holmium-doped alumino-silicate optical glass prepared by MCVD combined with nanoparticle doping
We present a detailed Judd--Ofelt (JO) analysis of Ho$^{3+}$-doped alumino-silicate optical fiber preforms in a wide range of compositions and prepared by both the standard solution doping method as well as the more advanced nanoparticle doping. The absorption spectra were measured, the absorption cross sections were calculated for each observed transition, and the Judd--Ofelt analysis was conducted. The preforms exhibited the values of JO parameters of $Ω_2 = (7.2--10.6) \times 10^{-20}\,\mathrm{cm}^2$, depending on the Al$_2$O$_3$ content, and $Ω_4$ and $Ω_6$ around $2.5$ and $1.2 \times 10^{-20}\,\mathrm{cm}^2$, respectively. The radiative transition parameters, such as transition probabilities, branching ratios, and radiative lifetimes, were calculated. The radiative lifetime of the ${}^5I_7 \rightarrow {}^5I_8$ transition, in the $16.1--17.2\,\mathrm{ms}$ range, combined with a measured value in the $0.9--1.9\,\mathrm{ms}$ range, was used to calculate the quantum efficiency, which was in the $5--11\,\%$ range. The preforms prepared by nanoparticle doping containing high Al$_2$O$_3$ contents above $8\,\mathrm{mol.}\,\%$ exhibited superior values of measured lifetime (above $1.5\,\mathrm{ms}$) and quantum efficiency (above $8\,\%$) compared to the standard solution-doped samples. To the best of our knowledge, this work is the first comprehensive report on the JO analysis of Ho$^{3+}$-doped alumino-silicate glass. The calculated parameters may be used in various calculations, simulations, and modelling of holmium-doped fiber lasers and other devices.