arXiv subjects

Petar Jurcevic

Publications and source records attributed to Petar Jurcevic.

At least 19 recordsLinked to original sources

arXiv2026

Observation of Improved Accuracy over Classical Sparse Ground-State Solvers using a Quantum Computer

Demonstrating quantum advantage over classical algorithms for ground state energy problems is an outstanding open problem in quantum computation. We experimentally demonstrate that a quantum algorithm can outperform classical selected configuration interaction (SCI) methods, a key family of techniques used in computational chemistry and condensed matter physics. We construct a class of local Hamiltonian problems with sparse ground states, and show that SCI fails to find the ground state of a 49-qubit instance. We then show that sample-based Krylov quantum diagonalization, run on an IBM Heron R3 processor, succeeds at the same task. While the problem is solvable classically using iterative solvers designed to target our Hamiltonian construction, this work resolves the question of whether a sample-based quantum diagonalization algorithm can outperform standard SCI heuristics.

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arXiv2025

Closed-loop calculations of electronic structure on a quantum processor and a classical supercomputer at full scale

Quantum computers must operate in concert with classical computers to deliver on the promise of quantum advantage for practical problems. To achieve that, it is important to understand how quantum and classical computing can interact together, and how one can characterize the scalability and efficiency of hybrid quantum-classical workflows. So far, early experiments with quantum-centric supercomputing workflows have been limited in scale and complexity. Here, we use a Heron quantum processor deployed on premises with the entire supercomputer Fugaku to perform the largest computation of electronic structure involving quantum and classical high-performance computing. We design a closed-loop workflow between the quantum processors and 152,064 classical nodes of Fugaku, to approximate the electronic structure of chemistry models beyond the reach of exact diagonalization, with accuracy comparable to some all-classical approximation methods. Our work pushes the limits of the integration of quantum and classical high-performance computing, showcasing computational resource orchestration at the largest scale possible for current classical supercomputers.

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arXiv2025

Quantum-Centric Algorithm for Sample-Based Krylov Diagonalization

Approximating the ground state of many-body systems is a key computational bottleneck underlying important applications in physics and chemistry. The most widely known quantum algorithm for ground state approximation, quantum phase estimation, is out of reach of current quantum processors due to its high circuit-depths. Subspace-based quantum diagonalization methods offer a viable alternative for pre- and early-fault-tolerant quantum computers. Here, we introduce a quantum diagonalization algorithm which combines two key ideas on quantum subspaces: a classical diagonalization based on quantum samples, and subspaces constructed with quantum Krylov states. We prove that our algorithm converges in polynomial time under the working assumptions of Krylov quantum diagonalization and sparseness of the ground state. We then demonstrate the scalability of our approach by performing the largest ground-state quantum simulation of impurity models using a Heron quantum processors and the Frontier supercomputer. We consider both the single-impurity Anderson model with 41 bath sites, and a system with 4 impurities and 7 bath sites per impurity. Our results are in excellent agreement with Density Matrix Renormalization Group calculations.

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arXiv2025

Chemistry Beyond the Scale of Exact Diagonalization on a Quantum-Centric Supercomputer

A universal quantum computer can simulate diverse quantum systems, with electronic structure for chemistry offering challenging problems for practical use cases around the hundred-qubit mark. While current quantum processors have reached this size, deep circuits and large number of measurements lead to prohibitive runtimes for quantum computers in isolation. Here, we demonstrate the use of classical distributed computing to offload all but an intrinsically quantum component of a workflow for electronic structure simulations. Using a Heron superconducting processor and the supercomputer Fugaku, we simulate the ground-state dissociation of N$_2$ and the [2Fe-2S] and [4Fe-4S] clusters, with circuits up to 77 qubits and 10,570 gates. The proposed algorithm processes quantum samples to produce upper bounds for the ground-state energy and sparse approximations to the ground-state wavefunctions. Our results suggest that, for current error rates, a quantum-centric supercomputing architecture can tackle challenging chemistry problems beyond sizes amenable to exact diagonalization.

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arXiv2025

Unifying non-Markovian characterisation with an efficient and self-consistent framework

Noise on quantum devices is much more complex than it is commonly given credit. Far from usual models of decoherence, nearly all quantum devices are plagued both by a continuum of environments and temporal instabilities. These induce noisy quantum and classical correlations at the level of the circuit. The relevant spatiotemporal effects are difficult enough to understand, let alone combat. There is presently a lack of either scalable or complete methods to address the phenomena responsible for scrambling and loss of quantum information. Here, we make deep strides to remedy this problem. We establish a theoretical framework that uniformly incorporates and classifies all non-Markovian phenomena. Our framework is universal, assumes no parameters values, and is written entirely in terms of experimentally accessible circuit-level quantities. We formulate an efficient reconstruction using tensor network learning, allowing also for easy modularisation and simplification based on the expected physics of the system. This is then demonstrated through both extensive numerical studies and implementations on IBM Quantum devices, estimating a comprehensive set of spacetime correlations. Finally, we conclude our analysis with applications thereof to the efficacy of control techniques to counteract these effects -- including noise-aware circuit compilation and optimised dynamical decoupling. We find significant improvements are possible in the diamond norm and average gate fidelity of arbitrary $SU(4)$ operations, as well as related decoupling improvements in contrast to off-the-shelf schemes.

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arXiv2024

Diagonalization of large many-body Hamiltonians on a quantum processor

The estimation of low energies of many-body systems is a cornerstone of computational quantum sciences. Variational quantum algorithms can be used to prepare ground states on pre-fault-tolerant quantum processors, but their lack of convergence guarantees and impractical number of cost function estimations prevent systematic scaling of experiments to large systems. Alternatives to variational approaches are needed for large-scale experiments on pre-fault-tolerant devices. Here, we use a superconducting quantum processor to compute eigenenergies of quantum many-body systems on two-dimensional lattices of up to 56 sites, using the Krylov quantum diagonalization algorithm, an analog of the well-known classical diagonalization technique. We construct subspaces of the many-body Hilbert space using Trotterized unitary evolutions executed on the quantum processor, and classically diagonalize many-body interacting Hamiltonians within those subspaces. These experiments show that quantum diagonalization algorithms are poised to complement their classical counterpart at the foundation of computational methods for quantum systems.

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arXiv2024

Quantum-centric Supercomputing for Materials Science: A Perspective on Challenges and Future Directions

Computational models are an essential tool for the design, characterization, and discovery of novel materials. Hard computational tasks in materials science stretch the limits of existing high-performance supercomputing centers, consuming much of their simulation, analysis, and data resources. Quantum computing, on the other hand, is an emerging technology with the potential to accelerate many of the computational tasks needed for materials science. In order to do that, the quantum technology must interact with conventional high-performance computing in several ways: approximate results validation, identification of hard problems, and synergies in quantum-centric supercomputing. In this paper, we provide a perspective on how quantum-centric supercomputing can help address critical computational problems in materials science, the challenges to face in order to solve representative use cases, and new suggested directions.

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arXiv2024

Suppressing Correlated Noise in Quantum Computers via Context-Aware Compiling

Coherent errors, and especially those that occur in correlation among a set of qubits, are detrimental for large-scale quantum computing. Correlations in noise can occur as a result of spatial and temporal configurations of instructions executing on the quantum processor. In this paper, we perform a detailed experimental characterization of many of these error sources, and theoretically connect them to the physics of superconducting qubits and gate operations. Equipped with this knowledge, we devise compiler strategies to suppress these errors using dynamical decoupling or error compensation into the rest of the circuit. Importantly, these strategies are successful when the context at each layer of computation is taken into account: how qubits are connected, what crosstalk terms exist on the device, and what gates or idle periods occur in that layer. Our context-aware compiler thus suppresses some dominant sources of error, making further error mitigation or error correction substantially less expensive. For example, our experiments show an increase of 18.5\% in layer fidelity for a candidate 10-qubit circuit layer compared to context-unaware suppression. Owing to the exponential nature of error mitigation, these improvements due to error suppression translate to several orders of magnitude reduction of sampling overhead for a circuit consisting of a moderate number of layers.

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arXiv2024

Robust estimation of the Quantum Fisher Information on a quantum processor

We present the experimental measurement, on a quantum processor, of a series of polynomial lower bounds that converge to the quantum Fisher information (QFI), a fundamental quantity for certifying multipartite entanglement that is useful for metrological applications. We combine advanced methods of the randomized measurement toolbox to obtain estimators that are robust against drifting errors caused uniquely during the randomized measurement protocol. We estimate the QFI for Greenberg-Horne-Zeilinger states, observing genuine multipartite entanglement. Then, we prepare the ground state of the transverse field Ising model at the critical point using a variational circuit. We estimate its QFI and investigate the interplay between state optimization and noise induced by increasing the circuit depth.

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arXiv2023

Defining Standard Strategies for Quantum Benchmarks

As quantum computers grow in size and scope, a question of great importance is how best to benchmark performance. Here we define a set of characteristics that any benchmark should follow -- randomized, well-defined, holistic, device independent -- and make a distinction between benchmarks and diagnostics. We use Quantum Volume (QV) [1] as an example case for clear rules in benchmarking, illustrating the implications for using different success statistics, as in Ref. [2]. We discuss the issue of benchmark optimizations, detail when those optimizations are appropriate, and how they should be reported. Reporting the use of quantum error mitigation techniques is especially critical for interpreting benchmarking results, as their ability to yield highly accurate observables comes with exponential overhead, which is often omitted in performance evaluations. Finally, we use application-oriented and mirror benchmarking techniques to demonstrate some of the highlighted optimization principles, and introduce a scalable mirror quantum volume benchmark. We elucidate the importance of simple optimizations for improving benchmarking results, and note that such omissions can make a critical difference in comparisons. For example, when running mirror randomized benchmarking, we observe a reduction in error per qubit from 2% to 1% on a 26-qubit circuit with the inclusion of dynamic decoupling.

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arXiv2022

Single-shot error mitigation by coherent Pauli checks

Generating samples from the output distribution of a quantum circuit is a ubiquitous task used as a building block of many quantum algorithms. Here we show how to accomplish this task on a noisy quantum processor lacking full-blown error correction for a special class of quantum circuits dominated by Clifford gates. Our approach is based on Coherent Pauli Checks (CPCs) that detect errors in a Clifford circuit by verifying commutation rules between random Pauli-type check operators and the considered circuit. Our main contributions are as follows. First, we derive a simple formula for the probability that a Clifford circuit protected by CPCs contains a logical error. In the limit of a large number of checks, the logical error probability is shown to approach the value ${\approx}7εn/5$, where $n$ is the number of qubits and $ε$ is the depolarizing error rate. Our formula agrees nearly perfectly with the numerical simulation results. Second, we show that CPCs are well-suited for quantum processors with a limited qubit connectivity. For example, the difference between all-to-all and linear qubit connectivity is only a 3X increase in the number of CNOT gates required to implement CPCs. Third, we describe simplified one-sided CPCs which are well-suited for mitigating measurement errors in the single-shot settings. Finally, we report an experimental demonstration of CPCs with up to 10 logical qubits and more than 100 logical CNOT gates. Our experimental results show that CPCs provide a marked improvement in the logical error probability for the considered task of sampling the output distribution of quantum circuits.

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arXiv2022

Dynamics of superconducting qubit relaxation times

Superconducting qubits are a leading candidate for quantum computing but display temporal fluctuations in their energy relaxation times T1. This introduces instabilities in multi-qubit device performance. Furthermore, autocorrelation in these time fluctuations introduces challenges for obtaining representative measures of T1 for process optimization and device screening. These T1 fluctuations are often attributed to time varying coupling of the qubit to defects, putative two level systems (TLSs). In this work, we develop a technique to probe the spectral and temporal dynamics of T1 in single junction transmons by repeated T1 measurements in the frequency vicinity of the bare qubit transition, via the AC-Stark effect. Across 10 qubits, we observe strong correlations between the mean T1 averaged over approximately nine months and a snapshot of an equally weighted T1 average over the Stark shifted frequency range. These observations are suggestive of an ergodic-like spectral diffusion of TLSs dominating T1, and offer a promising path to more rapid T1 characterization for device screening and process optimization.

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arXiv2022

Effective qubit dephasing induced by spectator-qubit relaxation

In many leading architectures for quantum computing, it remains to be understood if we can equate single-qubit coherence times measured in isolation, to that of coherence times measured in multi-qubit devices. On a multi-qubit superconducting circuit platform we show an increase in the dephasing rate of a control qubit due to the spontaneous relaxation of spectator qubits coupled to the control qubit. We attribute this increased dephasing to random in time Z-phase kicks on the control qubit due to the interplay between spectator relaxation and the control-spectator ZZ- interaction. We measure the magnitude of this extra dephasing using Ramsey decay experiments, show how it can be corrected via dynamical decoupling pulse sequences, and demonstrate that randomized benchmarking is insensitive to the effect. Our experimental results are supported by a robust theoretical model that captures an arbitrary number of spectator qubits, and gives a simple, intuitive picture for the mechanism behind the enhanced dephasing.

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arXiv2021

Quality, Speed, and Scale: three key attributes to measure the performance of near-term quantum computers

Defining the right metrics to properly represent the performance of a quantum computer is critical to both users and developers of a computing system. In this white paper, we identify three key attributes for quantum computing performance: quality, speed, and scale. Quality and scale are measured by quantum volume and number of qubits, respectively. We propose a speed benchmark, using an update to the quantum volume experiments that allows the measurement of Circuit Layer Operations Per Second (CLOPS) and identify how both classical and quantum components play a role in improving performance. We prescribe a procedure for measuring CLOPS and use it to characterize the performance of some IBM Quantum systems.

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arXiv2021

Optimal qubit assignment and routing via integer programming

We consider the problem of mapping a logical quantum circuit onto a given hardware with limited two-qubit connectivity. We model this problem as an integer linear program, using a network flow formulation with binary variables that includes the initial allocation of qubits and their routing. We consider several cost functions: an approximation of the fidelity of the circuit, its total depth, and a measure of cross-talk, all of which can be incorporated in the model. Numerical experiments on synthetic data and different hardware topologies indicate that the error rate and depth can be optimized simultaneously without significant loss. We test our algorithm on a large number of quantum volume circuits, optimizing for error rate and depth; our algorithm significantly reduces the number of CNOTs compared to Qiskit's default transpiler SABRE, and produces circuits that, when executed on hardware, exhibit higher fidelity.

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arXiv2020

Demonstration of quantum volume 64 on a superconducting quantum computing system

We improve the quality of quantum circuits on superconducting quantum computing systems, as measured by the quantum volume, with a combination of dynamical decoupling, compiler optimizations, shorter two-qubit gates, and excited state promoted readout. This result shows that the path to larger quantum volume systems requires the simultaneous increase of coherence, control gate fidelities, measurement fidelities, and smarter software which takes into account hardware details, thereby demonstrating the need to continue to co-design the software and hardware stack for the foreseeable future.

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arXiv2020

Reducing unitary and spectator errors in cross resonance with optimized rotary echoes

We present an improvement to the cross resonance gate realized with the addition of resonant, target rotary pulses. These pulses, applied directly to the target qubit, are simultaneous to and in phase with the echoed cross resonance pulses. Using specialized Hamiltonian error amplifying tomography, we confirm a reduction of error terms with target rotary -- directly translating to improved two-qubit gate fidelity. Beyond improvement in the control-target subspace, the target rotary reduces entanglement between target and target spectators caused by residual quantum interactions. We further characterize multi-qubit performance improvement enabled by target rotary pulsing using unitarity benchmarking and quantum volume measurements, achieving a new record quantum volume for a superconducting qubit system.

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arXiv2019

Self-Verifying Variational Quantum Simulation of the Lattice Schwinger Model

Hybrid classical-quantum algorithms aim at variationally solving optimisation problems, using a feedback loop between a classical computer and a quantum co-processor, while benefitting from quantum resources. Here we present experiments demonstrating self-verifying, hybrid, variational quantum simulation of lattice models in condensed matter and high-energy physics. Contrary to analog quantum simulation, this approach forgoes the requirement of realising the targeted Hamiltonian directly in the laboratory, thus allowing the study of a wide variety of previously intractable target models. Here, we focus on the Lattice Schwinger model, a gauge theory of 1D quantum electrodynamics. Our quantum co-processor is a programmable, trapped-ion analog quantum simulator with up to 20 qubits, capable of generating families of entangled trial states respecting symmetries of the target Hamiltonian. We determine ground states, energy gaps and, by measuring variances of the Schwinger Hamiltonian, we provide algorithmic error bars for energies, thus addressing the long-standing challenge of verifying quantum simulation.

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