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Peter Gispert

Publications and source records attributed to Peter Gispert.

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Fluctuation-induced and quantum effects in nanofluidic transport

The hydrodynamic wall has traditionally been considered a featureless object, whose only role is to provide a boundary for fluid flow. Yet, there is now ample evidence that at nanometer scales, liquid flows are sensitive to the wall's internal -- in particular, electronic -- degrees of freedom. Here, after reviewing the experimental evidence for nanoscale liquid-electron couplings, we present the theoretical advances that have allowed for their quantitative understanding. We discuss how a quantum description of the liquid-solid interface reveals the influence of electron dynamics on classical fluid transport, in the form of the fluctuation-induced quantum friction effect. Quantum friction is at the root of liquid-electron coupled transport phenomena, that may be combined into a hydro-electronic transport matrix. We present analytical formulas for the hydro-electronic transport coefficients, that allow for their quantitative estimation in practical cases; we further outline the potential consequences of coupled liquid-electron transport for the water-energy nexus. Fluctuation-induced and quantum effects at liquid-solid interfaces represent an emerging interface between fluid dynamics and condensed-matter physics, and a largely uncharted territory for both theory and experiment.

physics.flu-dyn

Active Transport as a Mechanism of Microphase Selection in Biomolecular Condensates

The size and organization of biomolecular condensates formed by liquid-liquid phase separation (LLPS) are set by multiple cellular mechanisms that are not yet fully understood. Here we identify a transport-driven mechanism: stochastic binding of phase-separating proteins to cytoskeletal motor proteins, followed by active redistribution along filament networks, generates an effective long-range repulsion that arrests coarsening and selects a finite condensate size. A minimal diffusion-transport model, analyzed by linear stability theory and three-dimensional simulations, reveals a transition from macroscopic to microphase separation at remarkably low binding/release fractions, corresponding to minute motor-bound populations. Tuning motor binding rates $b$ or transport velocities enables sublinear control of condensate sizes ($L \sim b^{-1/4}$) from a few hundred nanometres up to the micron scale. The selected length scale is robust to the intrinsic shot noise of the binding--release reactions. In anisotropic cytoskeletal environments, transport asymmetry drives morphological transitions from spherical to cylindrical condensates, independently of the thermodynamic parameters. This mechanism provides a versatile, spatiotemporally programmable route to condensate organization and informs the design of synthetic active emulsions with tunable architectures.

physics.bio-ph

Electrostatic Screening in Nanotubes: A Tubular Response Function Framework

The structure and transport of electrolytes in nanoscale channels are known to be affected by the electronic properties of the confining walls. This influence is particularly pronounced in quasi-one-dimensional nanotubes, where the high surface-to-volume ratio makes the wall the dominant source of electrostatic screening. For instance, ideal metallic tubes suppress long-range Coulomb interactions between ions exponentially. Yet, there exists no generic framework for evaluating electrostatic interactions in tubular confinement. Here, we introduce tubular response functions - a generalisation of surface response functions that captures how nanotubes with arbitrary electronic properties screen Coulomb interactions. Using this framework, we evaluate the interaction potential of ions confined in a metallic carbon nanotube, treating its long-range electronic properties exactly within a Luttinger liquid model. We demonstrate that the screening characteristic of metallic armchair carbon nanotubes is almost identical to that of an ideal metal, regardless of electron density. We trace the origin of such strong screening to the quantum confinement of electrons around the tube circumference and to the suppression of Friedel oscillations. Our framework opens the way for quantitative descriptions of ionic correlations and charge storage in nanotube-based electrodes, and can be further extended to address confined ion dynamics.

cond-mat.mes-hall