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Peter Hänggi

Publications and source records attributed to Peter Hänggi.

At least 19 recordsLinked to original sources

Diffusion coefficient of a Brownian particle in equilibrium and nonequilibrium: Einstein model and beyond

Diffusion of small particles is omnipresent in a plentiful number of processes occurring in Nature. As such, it is widely studied and exerted in almost all branches of sciences. It constitutes such a broad and often rather complex subject of exploration that we opt here to narrow down our survey for the case of the diffusion coefficient for a Brownian particle which can be modeled in the framework of Langevin dynamics. Our main focus will center on the temperature dependence of the diffusion coefficient for several fundamental models of diverse physical systems. Starting out with diffusion in equilibrium for which the Einstein theory holds we consider a number of physical situations away from free Brownian motion and end with surveying nonequilibrium diffusion for a time-periodically driven Brownian particle dwelling randomly in a periodic potential. For this latter situation the diffusion coefficient exhibits an intriguingly non-monotonic dependence on temperature.

cond-mat.stat-mech

Velocity multistability vs ergodicity breaking in a biased periodic potential

Multistability, i.e. the coexistence of several attractors for a given set of system parameters is one of the most important phenomena occurring in dynamical systems. We consider it in velocity dynamics of a Brownian particle driven by thermal fluctuations and moving in a biased periodic potential. In doing so we focus on the impact of ergodicity - a concept which lies at the core of statistical mechanics. The latter implies that a single trajectory of the system is representative for the whole ensemble and as a consequence the initial conditions of the dynamics are fully forgotten. The ergodicity of the deterministic counterpart is strongly broken and we discuss how the velocity multistability depends on the starting position and velocity of the particle. While for non-zero temperature the ergodicity is in principle restored, in the low temperature regime the velocity dynamics is still affected by initial conditions due to weak ergodicity breaking. For moderate and high temperature the multistability is robust with respect to the choice of the starting position and velocity of the particle.

cond-mat.stat-mech

Quasi-stationary states of game-driven systems: a dynamical approach

Evolutionary game theory is a framework to formalize the evolution of collectives ("populations") of competing agents that are playing a game and, after every round, update their strategies to maximize individual payoffs. There are two complementary approaches to modeling evolution of player populations. The first addresses essentially finite populations by implementing the apparatus of Markov chains. The second assumes that the populations are infinite and operates with a system of mean-field deterministic differential equations. By using a model of two antagonistic populations, which are playing a game with stationary or periodically varying payoffs, we demonstrate that it exhibits metastable dynamics that is reducible neither to an immediate transition to a fixation (extinction of all but one strategy in a finite-size population) nor to the mean-field picture. In the case of stationary payoffs, this dynamics can be captured with a system of stochastic differential equations and interpreted as a stochastic Hopf bifurcation. In the case of varying payoffs, the metastable dynamics is much more complex than the dynamics of the means.

nlin.AO

Comment on "Measurability of nonequilibrium thermodynamics in terms of the Hamiltonian of mean force"

In a recent paper [P. Strasberg and M. Esposito, Phys. Rev. E {\bf 101}, 050101(R) (2020)] an attempt is presented to formulate the nonequilibrium thermodynamics of an open system in terms of the Hamiltonian of mean force. The purpose of the present comment is to clarify severe restrictions of this approach and also to stress that recently noted ambiguities [P. Talkner and P. Hänggi, Phys. Rev. E {\bf 94}, 022143 (2016)] of fluctuating thermodynamic potentials cannot be removed in the suggested way.

cond-mat.stat-mech

{\it Colloquium:} Statistical Mechanics and Thermodynamics at Strong Coupling: Quantum and Classical

The statistical mechanical description of small systems staying in thermal equilibrium with an environment can be achieved by means of the Hamiltonian of mean force. In contrast to the reduced density matrix of an open quantum system, or the reduced phase-space probability density function of a classical open system, the Hamiltonian of mean force not only characterizes the reduced state but also contains full information about the thermodynamics of the considered open system. The resulting thermodynamic potentials all assume the form as the difference of the potentials for the total system and the bare environment in the absence of the system. In contrast to work as a mechanical notion, one faces several problems with the definition of heat which turns out to be largely ambiguous in the case of strong coupling between system and environment. The general theory of the thermodynamics of open systems, in particular, in view of strong coupling, is reviewed and illustrated with several examples. The vagueness of heat is discussed in the context of the ambiguities in the definitions of a fluctuating internal energy and other fluctuating thermodynamic potentials.

cond-mat.stat-mech

Asymptotic Floquet states of open quantum systems: The role of interaction

We investigate the asymptotic state of a periodically driven many-body quantum system which is weakly coupled to an environment. The combined action of the modulations and the environment steers the system towards a state being characterized by a time-periodic density operator. To resolve this asymptotic non-equilibrium state at stroboscopic instants of time, we introduce the dissipative Floquet map, evaluate the stroboscopic density operator as its eigen-element and elucidate how particle interactions affect properties of the density operator. We illustrate the idea with a periodically modulated Bose-Hubbard dimer and discuss the relations between the interaction-induced bifurcations in a mean-field dynamics and changes in the characteristics of the genuine quantum many-body state. We argue that Floquet maps provide insight into the system relaxation towards its asymptotic state and may help to understand whether it is possible (or not) to construct a stroboscopic time-independent generator mimicking the action of the original time-dependent one.

cond-mat.quant-gas

Diffusion of Colloidal Rods in Corrugated Channels

In many natural and artificial devices diffusive transport takes place in confined geometries with corrugated boundaries. Such boundaries cause both entropic and hydrodynamic effects, which have been studied only for the case of spherical particles. Here we experimentally investigate diffusion of particles of elongated shape confined into a corrugated quasi-two-dimensional channel. Elongated shape causes complex excluded-volume interactions between particle and channel walls which reduce the accessible configuration space and lead to novel entropic free energy effects. The extra rotational degree of freedom also gives rise to a complex diffusivity matrix that depends on both the particle location and its orientation. We further show how to extend the standard Fick-Jacobs theory to incorporate combined hydrodynamic and entropic effects, so as, for instance, to accurately predict experimentally measured mean first passage times along the channel. Our approach can be used as a generic method to describe translational diffusion of anisotropic particles in corrugated channels.

cond-mat.soft

Tunable mass separation via negative mobility

A prerequisite for isolating diseased cells requires a mechanism for effective mass-based separation. This objective, however, is generally rather challenging because typically no valid correlation exists between the size of the particles and their mass value. We consider an inertial Brownian particle moving in a symmetric periodic potential and subjected to an externally applied unbiased harmonic driving in combination with a constant applied bias. In doing so we identify a most efficient separation scheme which is based on the anomalous transport feature of negative mobility, meaning that the immersed particles move in the direction opposite to the acting bias. This work is first of its kind in demonstrating a tunable separation mechanism in which the particle mass targeted for isolation is effectively controlled over a regime of nearly two orders of mass-magnitude upon changing solely the frequency of the external harmonic driving. This approach may provide mass selectivity required in present and future separation of a diversity of nano and micro-sized particles of either biological or synthetic origin.

cond-mat.stat-mech

Single atom energy-conversion device with a quantum load

This work reports the functioning of a single atom energy-conversion device, operating either as a quantum engine or a refrigerator, coupled to a quantum load. The "working fluid" is comprised of two optical levels of a single ion, and the load is one vibrational mode of the same ion cooled down to the quantum regime. The energy scales of these two modes differ by 9 orders of magnitude. We realize cyclic energy transfers between the working fluid and the quantum load, either increasing or decreasing the population of the vibrational mode. This is achieved albeit the interaction between the load and the working fluid leads to a significant population redistribution and quantum correlations between them. The performance of the engine cycles as a function of several parameters is examined, and found to be in agreement with theory. We specifically look at the ergotropy of the load, which indicates the amount of energy stored in the load that can be extracted with a unitary process. We show that ergotropy rises with the number of engine cycles despite an increase in the entropy of the load. Our experiment represents the first fully quantum 4-stroke energy-conversion device operating with a generic coupling to a quantum load.

quant-ph

Asymptotic Floquet states of non-Markovian systems

We propose a method to find asymptotic states of a class of periodically modulated open systems which are outside the range of validity of the Floquet theory due to the presence of memory effects. The method is based on a Floquet treatment of the time-local, memoryless dynamics taking place in a minimally enlarged state space where the original system is coupled to auxiliary -- typically non-physical -- variables. A projection of the Floquet solution into the physical subspace returns the sought asymptotic state of the system. The spectral gap of the Floquet propagator acting in the enlarged state space can be used to estimate the relaxation time. We illustrate the method with a modulated version of quantum random walk model.

cond-mat.stat-mech

Hydrodynamic and entropic effects on colloidal diffusion in corrugated channels

In the absence of advection, confined diffusion characterizes transport in many natural and artificial devices, such as ionic channels, zeolites, and nanopores. While extensive theoretical and numerical studies on this subject have produced many important predictions, experimental verifications of the predictions are rare. Here, we experimentally measure colloidal diffusion times in microchannels with periodically varying width and contrast results with predictions from the Fick-Jacobs theory and Brownian dynamics simulation. While the theory and simulation correctly predict the entropic effect of the varying channel width, they fail to account for hydrodynamic effects, which include both an overall decrease and a spatial variation of diffusivity in channels. Neglecting such hydrodynamic effects, the theory and simulation underestimate the mean and standard deviation of first passage times by 40\% in channels with a neck width twice the particle diameter. We further show that the validity of the Fick-Jakobs theory can be restored by reformulating it in terms of the experimentally measured diffusivity. Our work thus demonstrates that hydrodynamic effects play a key role in diffusive transport through narrow channels and should be included in theoretical and numerical models.

cond-mat.soft

Quantum resonant activation

Quantum resonant activation is investigated for the archetype setup of an externally driven two-state (spin-boson) system subjected to strong dissipation by means of both analytical and extensive numerical calculations. The phenomenon of resonant activation emerges in the presence of either randomly fluctuating or deterministic periodically varying driving fields. Addressing the incoherent regime, a characteristic minimum emerges in the mean first passage time to reach an absorbing neighboring state whenever the intrinsic time scale of the modulation matches the characteristic time scale of the system dynamics. For the case of deterministic periodic driving, the first passage time probability density function (pdf) displays a complex, multi-peaked behavior, which depends crucially on the details of initial phase, frequency, and strength of the driving. As an interesting feature we find that the mean first passage time enters the resonant activation regime at a critical frequency $ν^*$ which depends very weakly on the strength of the driving. Moreover, we provide the relation between the first passage time pdf and the statistics of residence times.

quant-ph

Taxis of Artificial Swimmers in a Spatio-Temporally Modulated Activation Medium

Contrary to microbial taxis, where a tactic response to external stimuli is controlled by complex chemical pathways acting like sensor-actuator loops, taxis of artificial microswimmers is a purely stochastic effect associated with a non-uniform activation of the particles' self-propulsion. We study the tactic response of such swimmers in a spatio-temporally modulated activating medium by means of both numerical and analytical techniques. In the opposite limits of very fast and very slow rotational particle dynamics, we obtain analytic approximations that closely reproduce the numerical description. A swimmer drifts on average either parallel or anti-parallel to the propagation direction of the activating pulses, depending on their speed and width. The drift in line with the pulses is solely determined by the finite persistence length of the active Brownian motion performed by the swimmer, whereas the drift in the opposite direction results from the combination of ballistic and diffusive properties of the swimmer's dynamics.

cond-mat.soft

Self-Polarizing Microswimmers in Active Density Waves

An artificial microswimmer drifts in response to spatio-temporal modulations of an activating suspension medium. We consider two competing mechanisms capable of influencing its tactic response: angular fluctuations, which help it explore its surroundings and thus diffuse faster toward more active regions, and self-polarization, a mechanism inherent to self-propulsion, which tends to orient the swimmer's velocity parallel or antiparallel to the local activation gradients. We investigate, both numerically and analytically, the combined action of such two mechanisms. By determining their relative magnitude, we characterize the selective transport of artificial microswimmers in inhomogeneous activating media.

cond-mat.soft

Non-monotonic temperature dependence of chaos-assisted diffusion in driven periodic systems

The spreading of a cloud of independent Brownian particles typically proceeds more effectively at higher temperatures, as it derives from the commonly known Sutherland-Einstein relation for systems in thermal equilibrium. Here, we report on a non-equilibrium situation in which the diffusion of a periodically driven Brownian particle moving in a periodic potential decreases with increasing temperature within a finite temperature window. We identify as the cause for this non-intuitive behaviour a dominant deterministic mechanism consisting of a few unstable periodic orbits embedded into a chaotic attractor together with thermal noise-induced dynamical changes upon varying temperature. The presented analysis is based on extensive numerical simulations of the corresponding Langevin equation describing the studied setup as well as on a simplified stochastic model formulated in terms of a three-state Markovian process. Because chaos exists in many natural as well as in artificial systems representing abundant areas of contemporary knowledge, the described mechanism may potentially be discovered in plentiful different contexts.

cond-mat.stat-mech

Open system trajectories specify fluctuating work but not heat

Based on the explicit knowledge of a Hamiltonian of mean force, the classical statistical mechanics and equilibrium thermodynamics of open systems in contact with a thermal environment at arbitrary interaction strength can be formulated. Even though the Hamiltonian of mean force uniquely determines the equilibrium phase space probability density of a strongly coupled open system the knowledge of this probability density alone is insufficient to determine the Hamiltonian of mean force, needed in constructing the underlying statistical mechanics and thermodynamics. We demonstrate that under the assumption that the Hamiltonian of mean force is known, an extension of thermodynamic structures from the level of averaged quantities to fluctuating objects (i.e. a stochastic thermodynamics) is possible. However, such a construction undesirably involves also a vast ambiguity. This situation is rooted in the eminent lack of a physical guiding principle allowing to distinguish a physically meaningful theory out of a multitude of other equally conceivable ones.

cond-mat.stat-mech

Occurrence of discontinuities in the performance of finite-time quantum Otto cycles

We study a quantum Otto cycle in which the strokes are performed in finite time. The cycle involves energy measurements at the end of each stroke to allow for the respective determination of work. We then optimize for the work and efficiency of the cycle by varying the time spent in the different strokes and find that the optimal value of the ratio of time spent on each stroke goes through sudden changes as the parameters of this cycle vary continuously. The position of these discontinuities depends on the optimized quantity under consideration such as the net work output or the efficiency.

cond-mat.stat-mech