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Peter Sollich

Publications and source records attributed to Peter Sollich.

At least 127 records · Page 7Linked to original sources
arXiv2012

High--order jamming crossovers and density anomalies

We demonstrate the existence of high--order jamming crossovers in systems of particles with repulsive contact interactions, which originate from the collapse of successive coordination shells. At zero temperature, these crossovers induce an anomalous behavior of the bulk modulus, which varies non--monotonically with the density, while at finite temperature they induce density anomalies consisting in an increased diffusivity upon isothermal compression and in a negative thermal expansion coefficient. We rationalize the dependence of these crossovers on the softness of the interaction potential, and relate the jamming crossovers and the anomalous diffusivity through the investigation of the vibrational spectrum.

cond-mat.soft↗
arXiv2012

A Monte Carlo method for chemical potential determination in single and multiple occupancy crystals

We describe a Monte Carlo scheme which, in a single simulation, yields a measurement of the chemical potential of a crystalline solid. Within the isobaric ensemble, this immediately provides an estimate of the system free energy, with statistical uncertainties that are determined precisely and transparently. An extension to multiple occupancy ("cluster") solids permits the direct determination of the cluster chemical potential and hence the equilibrium conditions. We apply the method to a model exhibiting cluster crystalline phases, where we find evidence for an infinite cascade of critical points terminating coexistence between crystals of differing site occupancies.

cond-mat.stat-mech↗
arXiv2012

Unified study of glass and jamming rheology in soft particle systems

We explore numerically the shear rheology of soft repulsive particles at large volume fraction. The interplay between viscous dissipation and thermal motion results in multiple rheological regimes encompassing Newtonian, shear-thinning and yield stress regimes near the `colloidal' glass transition when thermal fluctuations are important, crossing over to qualitatively similar regimes near the `jamming' transition when dissipation dominates. In the crossover regime, glass and jamming sectors coexist and give complex flow curves. Although glass and jamming limits are characterized by similar macroscopic flow curves, we show that they occur over distinct time and stress scales and correspond to distinct microscopic dynamics. We propose a simple rheological model describing the glass to jamming crossover in the flow curves, and discuss the experimental implications of our results.

cond-mat.soft↗
arXiv2012

Notes on the polynomial identities in random overlap structures

In these notes we review first in some detail the concept of random overlap structure (ROSt) applied to fully connected and diluted spin glasses. We then sketch how to write down the general term of the expansion of the energy part from the Boltzmann ROSt (for the Sherrington-Kirkpatrick model) and the corresponding term from the RaMOSt, which is the diluted extension suitable for the Viana-Bray model. From the ROSt energy term, a set of polynomial identities (often known as Aizenman-Contucci or AC relations) is shown to hold rigorously at every order because of a recursive structure of these polynomials that we prove. We show also, however, that this set is smaller than the full set of AC identities that is already known. Furthermore, when investigating the RaMOSt energy for the diluted counterpart, at higher orders, combinations of such AC identities appear, ultimately suggesting a crucial role for the entropy in generating these constraints in spin glasses.

cond-mat.dis-nn↗
arXiv2012

Thermodynamic Interpretation of Soft Glassy Rheology Models

Mesoscopic models play an important role in our understanding of the deformation and flow of amorphous materials. One such description, based on the Shear Transformation Zone (STZ) theory, has recently been re-formulated within a non-equilibrium thermodynamics framework, and found to be consistent with it. We show here that a similar interpretation can be made for the Soft Glassy Rheology (SGR) model. Conceptually this means that the "noise temperature" x, proposed phenomenologically in the SGR model to control the dynamics of a set of slow mesoscopic degrees of freedom, can consistently be interpreted as their actual thermodynamic temperature. (Because such modes are slow to equilibrate, this generally does not coincide with the temperature of the fast degrees of freedom and/or heat bath.) If one chooses to make this interpretation, the thermodynamic framework significantly constrains extensions of the SGR approach to models in which x is a dynamical variable. We assess in this light some such extensions recently proposed in the context of shear banding.

cond-mat.soft↗
arXiv2012

Spectra of Empirical Auto-Covariance Matrices

We compute spectra of sample auto-covariance matrices of second order stationary stochastic processes. We look at a limit in which both the matrix dimension $N$ and the sample size $M$ used to define empirical averages diverge, with their ratio $α=N/M$ kept fixed. We find a remarkable scaling relation which expresses the spectral density $ρ(λ)$ of sample auto-covariance matrices for processes with dynamical correlations as a continuous superposition of appropriately rescaled copies of the spectral density $ρ^{(0)}_α(λ)$ for a sequence of uncorrelated random variables. The rescaling factors are given by the Fourier transform $\hat C(q)$ of the auto-covariance function of the stochastic process. We also obtain a closed-form approximation for the scaling function $ρ^{(0)}_α(λ)$. This depends on the shape parameter $α$, but is otherwise universal: it is independent of the details of the underlying random variables, provided only they have finite variance. Our results are corroborated by numerical simulations using auto-regressive processes.

cond-mat.dis-nn↗
arXiv2011

Suppressed compressibility at large scale in jammed packings of size disperse spheres

We analyze the large scale structure and fluctuations of jammed packings of size disperse spheres, produced in a granular experiment as well as numerically. While the structure factor of the packings reveals no unusual behavior for small wavevectors, the compressibility displays an anomalous linear dependence at low wavectors and vanishes when q -> 0. We show that such behavior occurs because jammed packings of size disperse spheres have no bulk fluctuations of the volume fraction and are thus hyperuniform, a property not observed experimentally before. Our results apply to arbitrary particle size distributions. For continuous distributions, we derive a perturbative expression for the compressibility that is accurate for polydispersity up to about 30%.

cond-mat.stat-mech↗
arXiv2011

Polydispersity induced solid-solid transitions in model colloids

Specialized Monte Carlo simulation techniques and moment free energy method calculations, capable of treating fractionation exactly, are deployed to study the crystalline phase behaviour of an assembly of spherical particles described by a top-hat "parent" distribution of particle sizes. An increase in either the overall density or the degree of polydispersity is shown to generate a succession of phase transitions in which the system demixes into an ever greater number of face-centred cubic "daughter" phases. Each of these phases is strongly fractionated: it contains a much narrower distribution of particle sizes than is present in the system overall. Certain of the demixing transitions are found to be nearly continuous, accompanied by fluctuations in local particle size correlated over many lattice spacings. We explore possible factors controlling the stability of the phases and the character of the demixing transitions.

cond-mat.stat-mech↗
arXiv2010

Kinetically Constrained Models

In this chapter we summarize recent developments in the study of kinetically constrained models (KCMs) as models for glass formers. After recalling the definition of the KCMs which we cover we study the possible occurrence of ergodicity breaking transitions and discuss in some detail how, before any such transition occurs, relaxation timescales depend on the relevant control parameter (density or temperature). Then we turn to the main issue: the prediction of KCMs for dynamical heterogeneities. We focus in particular on multipoint correlation functions and susceptibilities, and decoupling in the transport coefficients. Finally we discuss the recent view of KCMs as being at first order coexistence between an active and an inactive space-time phase.

cond-mat.stat-mech↗
arXiv2010

Phase behaviour of polydisperse spheres: simulation strategies and an application to the freezing transition

The statistical mechanics of phase transitions in dense systems of polydisperse particles presents distinctive challenges to computer simulation and analytical theory alike. The core difficulty, namely dealing correctly with particle size fractionation between coexisting phases, is set out in the context of a critique of previous simulation work on such systems. Specialized Monte Carlo simulation techniques and moment free energy method calculations, capable of treating fractionation exactly, are then described and deployed to study the fluid-solid transition of an assembly of repulsive spherical particles described by a top-hat "parent" distribution of particle sizes. The cloud curve delineating the solid-fluid coexistence region is mapped as a function of the degree of polydispersity $δ$, and the properties of the incipient "shadow" phases are presented. The coexistence region is found to shift to higher densities as $δ$ increases, but does not exhibit the sharp narrowing predicted by many theories and some simulations.

cond-mat.soft↗
arXiv2010

Duality symmetries in driven one-dimensional hopping models

We consider some duality relations for models of non-interacting particles hopping on disordered one-dimensional chains. In particular, we discuss symmetries of bulk-driven barrier and trap models, and relations between boundary-driven and equilibrium models with related energy landscapes. We discuss the relationships between these duality relations and similar results for interacting many-body systems.

cond-mat.stat-mech↗
arXiv2010

Large deviations and ensembles of trajectories in stochastic models

We consider ensembles of trajectories associated with large deviations of time-integrated quantities in stochastic models. Motivated by proposals that these ensembles are relevant for physical processes such as shearing and glassy relaxation, we show how they can be generated directly using auxiliary stochastic processes. We illustrate our results using the Glauber-Ising chain, for which biased ensembles of trajectories can exhibit ferromagnetic ordering. We discuss the relation between such biased ensembles and quantum phase transitions.

cond-mat.stat-mech↗
arXiv2010

Crystalline phases of polydisperse spheres

We use specialized Monte Carlo simulation methods and moment free energy calculations to provide conclusive evidence that dense polydisperse spheres at equilibrium demix into coexisting fcc phases, with more phases appearing as the spread of diameters increases. We manage to track up to four coexisting phases. Each of these is fractionated: it contains a narrower distribution of particle sizes than is present in the system overall. We also demonstrate that, surprisingly, demixing transitions can be nearly continuous, accompanied by fluctuations in local particle size correlated over many lattice spacings.

cond-mat.stat-mech↗
arXiv2009

Fluid phase coexistence and critical behaviour from simulations in the restricted Gibbs ensemble

The symmetrical restricted Gibbs ensemble (RGE) is a version of the Gibbs ensemble in which particles are exchanged between two boxes of fixed equal volumes. It has recently come to prominence because -- when combined with specialized algorithms -- it provides for the study of near-coexistence density fluctuations in highly size-asymmetric binary mixtures. Hitherto, however, a detailed framework for extracting accurate estimates of critical point and coexistence curve parameters from RGE density fluctuations has been lacking. Here we address this problem by exploiting an exact link between the RGE density fluctuations and those of the grand canonical ensemble. In the sub-critical region we propose and test a simple method for obtaining accurate estimates of coexistence densities. In the critical region we identify an observable that serves as a finite system size estimator for the critical point parameters, and present a finite-size scaling theory that allows extrapolation to the thermodynamic limit.

cond-mat.stat-mech↗
arXiv2009

Duality symmetries and effective dynamics in disordered hopping models

We identify a duality transformation in one-dimensional hopping models that relates propagators in general disordered potentials linked by an up-down inversion of the energy landscape. This significantly generalises previous results for a duality between trap and barrier models. We use the resulting insights into the symmetries of these models to develop a real-space renormalisation scheme that can be implemented computationally and allows rather accurate prediction of propagation in these models. We also discuss the relation of this renormalisation scheme to earlier analytical treatments.

cond-mat.stat-mech↗
arXiv2009

Dynamic heterogeneities in critical coarsening: Exact results for correlation and response fluctuations in finite-sized spherical models

We study dynamic heterogeneities in the out-of-equilibrium coarsening dynamics of the spherical ferromagnet after a quench from infinite temperature to its critical point. A standard way of probing such heterogeneities is by monitoring the fluctuations of correlation and susceptibility, coarse-grained over mesoscopic regions. We discuss how to define fluctuating coarse-grained correlations (C) and susceptibilities (Chi) in models where no quenched disorder is present. Our focus for the spherical model is on coarse-graining over the whole volume of $N$ spins, which requires accounting for N^{-1/2} non-Gaussian fluctuations of the spin. The latter are treated as a perturbation about the leading order Gaussian statistics. We obtain exact results for these quantities, which enable us to characterise the joint distribution of C and Chi fluctuations. We find that this distribution is qualitatively different, even for equilibrium above criticality, from the spin-glass scenario where C and Chi fluctuations are linked in a manner akin to the fluctuation-dissipation relation between the average C and Chi. Our results show that coarsening at criticality is clearly heterogeneous for d>4 and suggest that, as in other glassy systems, there is a well-defined timescale on which fluctuations across thermal histories are largest. Surprisingly, however, neither this timescale nor the amplitude of the heterogeneities increase with the age of the system, as would be expected from the growing correlation length. For d<4, the strength of the fluctuations varies on a timescale proportional to the age of the system; the corresponding amplitude also grows with age, but does not scale with the correlation volume as might have been expected naively.

cond-mat.dis-nn↗
arXiv2008

Subdiffusive motion in kinetically constrained models

We discuss a kinetically constrained model in which real-valued local densities fluctuate in time, as introduced recently by Bertin, Bouchaud and Lequeux. We show how the phenomenology of this model can be reproduced by an effective theory of mobility excitations propagating in a disordered environment. Both excitations and probe particles have subdiffusive motion, characterised by different exponents and operating on different time scales. We derive these exponents, showing that they depend continuously on one of the parameters of the model.

cond-mat.stat-mech↗