arXiv subjects

Peter Talkner

Publications and source records attributed to Peter Talkner.

At least 55 records · Page 3Linked to original sources

arXiv2011

Influence of measurements on the statistics of work performed on a quantum system

The recently demonstrated robustness of fluctuation theorems against measurements [M. Campisi \emph{et al.}, Phys. Rev. Lett. \textbf{105} 140601 (2010)] does not imply that the probability distributions of nonequilibrium quantities, such as heat and work, remain unaffected. We determine the impact of measurements that are performed during a running force protocol on the characteristic function of work. The results are illustrated by means of the Landau-Zener(-Stückelberg-Majorana) model. In the limit of continuous measurements the quantum Zeno effect suppresses any unitary dynamics. It is demonstrated that the characteristic function of work is the same as for an adiabatic protocol when the continuously measured quantity coincides with the Hamiltonian governing the unitary dynamics of the system in the absence of measurements.

cond-mat.stat-mech↗

arXiv2010

Brownian motion from molecular dynamics

Brownian motion of single particles with various masses M and diameters D is studied by molecular dynamics simulations. Besides the momentum auto-correlation function of the Brownian particle the memory function and the fluctuating force which enter the generalized Langevin equation of the Brownian particle are determined and their dependence on mass and diameter are investigated for two different fluid densities. Deviations of the fluctuating force distribution from a Gaussian form are observed for small particle diameters. For heavy particles the deviations of the fluctuating force from the total force acting on the Brownian particle decrease linearly with the mass ratio m/M where m denotes the mass of a fluid particle.

physics.chem-ph↗

arXiv2010

Thermodynamic anomalies in open quantum systems: Strong coupling effects in the isotropic XY model

The exactly solvable model of a one dimensional isotropic XY spin chain is employed to study the thermodynamics of open systems. For this purpose the chain is subdivided into two parts, one part is considered as the system while the rest as the environment or bath. The equilibrium properties of the system display several anomalous aspects such as negative entropies, negative specific heat, negative susceptibilities in dependence of temperature and coupling strength between system and bath. The statistical mechanics of this system is studied in terms of a reduced density matrix. At zero temperature and for a certain parameter values we observe a change of the ground state, a situation akin to a quantum phase transition.

cond-mat.stat-mech↗

arXiv2010

Fluctuation theorems for continuously monitored quantum fluxes

It is shown that quantum fluctuation theorems remain unaffected if measurements of any kind and number of observables are performed during the action of a force protocol. That is, although the backward and forward probabilities entering the fluctuation theorems are both altered by these measurements, their ratio remains unchanged. This observation allows to describe the measurement of fluxes through interfaces and, in this way, to bridge the gap between the current theory, based on only two measurements performed at the beginning and end of the protocol, and experiments that are based on continuous monitoring.

cond-mat.stat-mech↗

arXiv2010

Quantum Bochkov-Kuzovlev Work Fluctuation Theorems

The quantum version of the Bochkov-Kuzovlev identity is derived on the basis of the appropriate definition of work as the difference of the measured internal energies of a quantum system at the beginning and at the end of an external action on the system given by a prescribed protocol. According to the spirit of the original Bochkov-Kuzovlev approach, we adopt the "exclusive" viewpoint, meaning that the coupling to the external work-source is {\it not} counted as part of the internal energy. The corresponding canonical and microcanonical quantum fluctuation theorems are derived as well, and are compared to the respective theorems obtained within the "inclusive" approach. The relations between the quantum inclusive-work $w$, the exclusive-work $w_0$ and the dissipated-work $w_{dis}$, are discussed and clarified. We show by an explicit example that $w_0$ and $w_{dis}$ are distinct stochastic quantities obeying different statistics.

cond-mat.stat-mech↗

arXiv2010

Markovian embedding of non-Markovian superdiffusion

We consider different Markovian embedding schemes of non-Markovian stochastic processes that are described by generalized Langevin equations (GLE) and obey thermal detailed balance under equilibrium conditions. At thermal equilibrium superdiffusive behavior can emerge if the total integral of the memory kernel vanishes. Such a situation of vanishing static friction is caused by a super-Ohmic thermal bath. One of the simplest models of ballistic superdiffusion is determined by a bi-exponential memory kernel that was proposed by Bao [J.-D. Bao, J. Stat. Phys. 114, 503 (2004)]. We show that this non-Markovian model has infinitely many different 4-dimensional Markovian embeddings. Implementing numerically the simplest one, we demonstrate that (i) the presence of a periodic potential with arbitrarily low barriers changes the asymptotic large time behavior from free ballistic superdiffusion into normal diffusion; (ii) an additional biasing force renders the asymptotic dynamics superdiffusive again. The development of transients that display a qualitatively different behavior compared to the true large-time asymptotics presents a general feature of this non-Markovian dynamics. These transients though may be extremely long. As a consequence, they can be even mistaken as the true asymptotics. We find that such intermediate asymptotics exhibit a giant enhancement of superdiffusion in tilted washboard potentials and it is accompanied by a giant transient superballistic current growing proportional to $t^{α_{\rm eff}}$ with an exponent $α_{\rm eff}$ that can exceed the ballistic value of two.

cond-mat.stat-mech↗

arXiv2009

Finite Bath Fluctuation Theorem

We demonstrate that a Finite Bath Fluctuation Theorem of the Crooks type holds for systems that have been thermalized via weakly coupling it to a bath with energy independent finite specific heat. We show that this theorem reduces to the known canonical and microcanonical fluctuation theorems in the two respective limiting cases of infinite and vanishing specific heat of the bath. The result is elucidated by applying it to a 2D hard disk colliding elastically with few other hard disks in a rectangular box with perfectly reflecting walls.

cond-mat.stat-mech↗

arXiv2009

Rate description of Fokker-Planck processes with time-periodic parameters

The large time dynamics of a periodically driven Fokker-Planck process possessing several metastable states is investigated. At weak noise transitions between the metastable states are rare. Their dynamics then represent a discrete Markovian process characterized by time dependent rates. Apart from the occupation probabilities, so-called specific probability densities and localizing functions can be associated to each metastable state. Together, these three sets of functions uniquely characterize the large time dynamics of the conditional probability density of the original process. Exact equations of motion are formulated for these three sets of functions and strategies are discussed how to solve them. These methods are illustrated and their usefulness is demonstrated by means of the example of a bistable Brownian oscillator within a large range of driving frequencies from the slow semiadiabatic to the fast driving regime.

cond-mat.stat-mech↗

arXiv2009

Thermodynamics and Fluctuation Theorems for a Strongly Coupled Open Quantum System: An Exactly Solvable Case

We illustrate recent results concerning the validity of the work fluctuation theorem in open quantum systems [M. Campisi, P. Talkner, and P. Hänggi, Phys. Rev. Lett. {\bf 102}, 210401 (2009)], by applying them to a solvable model of an open quantum system. The central role played by the thermodynamic partition function of the open quantum system, -- a two level fluctuator with a strong quantum nondemolition coupling to a harmonic oscillator --, is elucidated. The corresponding quantum Hamiltonian of mean force is evaluated explicitly. We study the thermodynamic entropy and the corresponding specific heat of this open system as a function of temperature and coupling strength and show that both may assume negative values at nonzero low temperatures.

cond-mat.stat-mech↗

arXiv2009

Specific heat anomalies of open quantum systems

The evaluation of the specific heat of an open, damped quantum system is a subtle issue. One possible route is based on the thermodynamic partition function which is the ratio of the partition functions of system plus bath and of the bath alone. For the free damped particle it has been shown, however, that the ensuing specific heat may become negative for appropriately chosen environments. Being an open system this quantity then naturally must be interpreted as the change of the specific heat obtained as the difference between the specific heat of the heat bath coupled to the system degrees of freedom and the specific heat of the bath alone. While this difference may become negative, the involved specific heats themselves are always positive; thus, the known thermodynamic stability criteria are perfectly guaranteed. For a damped quantum harmonic oscillator, instead of negative values, under appropriate conditions one can observe a dip in the difference of specific heats as a function of temperature. Stylized minimal models containing a single oscillator heat bath are employed to elucidate the occurrence of the anomalous temperature dependence of the corresponding specific heat values. Moreover, we comment on the consequences for the interpretation of the density of states based on the thermal partitionfunction.

quant-ph↗

arXiv2009

Fluctuation Theorem for Arbitrary Open Quantum Systems

Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare environment, the validity of the Crooks theorem and of the Jarzynski equality is extended to open quantum systems. No restrictions on the nature of the environment or on the strength of the coupling between system and environment need to be imposed. This free energy entering the Crooks theorem and the Jarzynski equality is closely related to the Hamiltonian of mean force that generalizes the classical statistical mechanical concept of the potential of mean force.

cond-mat.stat-mech↗

arXiv2008

Fluctuation theorems in driven open quantum systems

The characteristic function for the joint measurement of the changes of two commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work of a quantum system that {\it weakly} couples to its environment is determined in terms of the energy changes of the system and the environment due to the action of a classical, external force on the system. If the system and environment initially are in a canonical equilibrium, the work performed on the system is shown to satisfy the Tasaki-Crooks theorem and the Jarzynski equality.

cond-mat.stat-mech↗

arXiv2008

Diffusion in confined geometries

Diffusive transport of particles or, more generally, small objects is a ubiquitous feature of physical and chemical reaction systems. In configurations containing confining walls or constrictions transport is controlled both by the fluctuation statistics of the jittering objects and the phase space available to their dynamics. Consequently, the study of transport at the macro- and nanoscales must address both Brownian motion and entropic effects. With this survey we report on recent advances in the theoretical and numerical investigation of stochastic transport occurring either in micro-sized geometries of varying cross section or in narrow channels wherein the diffusing particles are hindered from passing each other (single file diffusion). For particles undergoing biased diffusion in static suspension media enclosed by confining geometries, transport exhibits intriguing features such as (i) a decrease of nonlinear mobility with increasing temperature or, also, (ii) a broad excess peak of the effective diffusion above the free diffusion limit. These paradoxical aspects can be understood in terms of entropic contributions resulting from the restricted dynamics in phase space. If, in addition, the suspension medium is subjected to external, time-dependent forcing, rectification or segregation of the diffusing Brownian particles becomes possible. Likewise, the diffusion in very narrow, spatially modulated channels gets modified via contact particle-particle interactions, which induce anomalous sub-diffusion. The effective sub-diffusion constant for a driven single file also develops a resonance-like structure as a function of the confining coupling constant.

cond-mat.stat-mech↗

arXiv2008

Finite quantum dissipation: the challenge of obtaining specific heat

We consider a free particle coupled with finite strength to a bath and investigate the evaluation of its specific heat. A harmonic oscillator bath of Drude type with cutoff frequency omega_D is employed to model an ohmic friction force with dissipation strength gamma. Two scenarios for obtaining specific heat are presented. The first one uses the measurement of the kinetic energy of the free particle while the second one is based on the reduced partition function. Both descriptions yield results which are consistent with the Third Law of thermodynamics. Nevertheless, the two methods produce different results that disagree even in their leading quantum corrections at high temperatures. We also consider the regime where the cutoff frequency is smaller than the friction strength, i.e. omega_D 1.

quant-ph↗

arXiv2008

Microcanonical quantum fluctuation theorems

Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate spectra. In the particular case of microcanonical initial states explicit expressions for the characteristic function and the corresponding probability density of work are formulated. Their classical limit as well as their relations to the respective canonical expressions are discussed. A fluctuation theorem is derived that expresses the ratio of probabilities of work for a process and its time reversal to the ratio of densities of states of the microcanonical equilibrium systems with corresponding initial and final Hamiltonians.From this Crooks-type fluctuation theorem a relation between entropies of different systems can be derived which does not involve the time reversed process. This entropy-from-work theorem provides an experimentally accessible way to measure entropies.

cond-mat.stat-mech↗

arXiv2008

Negative conductance in driven Josephson junctions

We investigate an optimal regime of negative-valued conductance, emerging in a resistively and capacitively shunted Josephson junction, which is driven simultaneously by both, a time-periodic (ac) and a constant (dc) current. We analyze the current-voltage characteristics in the regime of absolute negative conductance. We additionally explore the stability of the negative response with respect to the ac-current frequency.

cond-mat.supr-con↗

arXiv2008

Statistics of work performed on a forced quantum oscillator

Various aspects of the statistics of work performed by an external classical force on a quantum mechanical system are elucidated for a driven harmonic oscillator. In this special case two parameters are introduced that are sufficient to completely characterize the force protocol. Explicit results for the characteristic function of work and the respective probability distribution are provided and discussed for three different types of initial states of the oscillator: microcanonical, canonical and coherent states. Depending on the choice of the initial state the probability distributions of the performed work may grossly differ. This result in particular holds also true for identical force protocols. General fluctuation and work theorems holding for microcanonical and canonical initial states are confirmed.

cond-mat.stat-mech↗

arXiv2007

Thermal equilibrium and statistical thermometers in special relativity

There is an intense debate in the recent literature about the correct generalization of Maxwell's velocity distribution in special relativity. The most frequently discussed candidate distributions include the Juettner function as well as modifications thereof. Here, we report results from fully relativistic one-dimensional (1D) molecular dynamics (MD) simulations that resolve the ambiguity. The numerical evidence unequivocally favors the Juettner distribution. Moreover, our simulations illustrate that the concept of 'thermal equilibrium' extends naturally to special relativity only if a many-particle system is spatially confined. They make evident that 'temperature' can be statistically defined and measured in an observer frame independent way.

cond-mat.stat-mech↗