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Peter Woitke

Publications and source records attributed to Peter Woitke.

At least 37 records · Page 2Linked to original sources

Circumplanetary disk ices. I. Ice formation vs. viscous evolution and grain drift

The large icy moons of Jupiter formed in a circumplanetary disk (CPD). CPDs are fed by infalling circumstellar gas and dust which may be shock-heated upon accretion or sublimated while passing through an optically thin gap. Accreted material is then either incorporated into moons, falls into the planet, or is lost beyond the disk edge on relatively short timescales. If ices are sublimated during accretion onto the CPD we know there must be sufficient time for them to recondense or moons such as Ganymede or Callisto could not form. The chemical timescale to form sufficiently icy solids places a novel constraint on the dynamical behaviour and properties of CPDs. We use the radiation thermochemical code ProDiMo to analyze how the radial ice abundance evolves in CPDs. We consider different initial chemical conditions of the disk to explore the consequences of infalling material being inherited from the circumstellar disk or being reset to atomic conditions by shock-heating. We contrast the timescales of ice formation with those of viscous evolution and radial dust drift. Water ice can form very efficiently in the CPD from initially atomic conditions, as a significant fraction is efficiently re-deposited on dust grains within < 1 yr. Radial grain drift timescales are in general longer than those of ice formation on grains. Icy grains of size $a < 3$ mm retain their icy mantles while crossing an optically thin circumstellar disk gap at 5 au for $L_* < 10 $ L$_{\odot}$. Three-body reactions play an important role in water formation in the dense midplane condition of CPDs. The CPD midplane must be depleted in dust relative to the circumstellar disk by a factor 10-50 to produce solids with the ice to rock ratio of the icy Galilean satellites. The CPD snowline is not erased by radial grain drift, which is consistent with the compositional gradient of the Galilean satellites being primordial.

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Exoplanet weather and climate regimes with clouds and thermal ionospheres: A model grid study in support of large-scale observational campaigns

With observational efforts moving from the discovery into the characterisation mode, systematic campaigns that cover large ranges of global stellar and planetary parameters will be needed. We aim to uncover cloud formation trends and globally changing chemical regimes due to the host star's effect on the thermodynamic structure of their atmospheres. We aim to provide input for exoplanet missions like JWST, PLATO, and Ariel, as well as potential UV missions ARAGO, PolStar or POLLUX. Pre-calculated 3D GCMs for M, K, G, F host stars are the input for our kinetic cloud model. Gaseous exoplanets fall broadly into three classes: i) cool planets with homogeneous cloud coverage, ii) intermediate temperature planets with asymmetric dayside cloud coverage, and iii) ultra-hot planets without clouds on the dayside. In class ii),} the dayside cloud patterns are shaped by the wind flow and irradiation. Surface gravity and planetary rotation have little effect. Extended atmosphere profiles suggest the formation of mineral haze in form of metal-oxide clusters (e.g. (TiO2)_N). The dayside cloud coverage is the tell-tale sign for the different planetary regimes and their resulting weather and climate appearance. Class (i) is representative of planets with a very homogeneous cloud particle size and material compositions across the globe (e.g., HATS-6b, NGTS-1b), classes (ii, e.g., WASP-43b, HD\,209458b) and (iii, e.g., WASP-121b, WP0137b) have a large day/night divergence of the cloud properties. The C/O ratio is, hence, homogeneously affected in class (i), but asymmetrically in class (ii) and (iii). The atmospheres of class (i) and (ii) planets are little affected by thermal ionisation, but class (iii) planets exhibit a deep ionosphere on the dayside. Magnetic coupling will therefore affect different planets differently and will be more efficient on the more extended, cloud-free dayside.

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The Atmospheres of Rocky Exoplanets II. Influence of surface composition on the diversity of cloud condensates

Clouds are an integral part of planetary atmospheres, with most planets hosting clouds. The understanding of not only the formation, but also the composition of clouds is crucial to the understanding of future observations. As observations of the planet's surface will remain very difficult, it is essential to link the observable high atmosphere gas and cloud composition to the surface conditions. We present a fast and simple chemical equilibrium (eq.) model for the troposphere of rocky exoplanets, which is in chemical and phase eq. with the crust. The hydrostatic eq. atmosphere is built from bottom to top. In each atmospheric layer chemical eq. is solved and all thermally stable condensates are removed, depleting the atmosphere above in the effected elements. These removed condensates build an upper limit for cloud formation and can be separated into high and low temperature condensates. The most important cloud condensates for 1000K>T>400K are KCl, NaCl, FeS, FeS2, FeO, Fe2O3, Fe3O4. For T<400K H2O, C, NH3, NH4Cl, NH4SH are thermally stable. For even lower temperatures of T<150K CO2, CH4, NH3, H2S become stable. The inclusion of clouds with trace abundances results in the thermal stability of a total of 72 condensates for atmospheres with the different surface conditions (300K<T<1000K and p=1bar,100bar). The different cloud condensates are not independent of each other, but follow sequences of condensation, which are robust against changes in crust composition, surface pressure, and surface temperature. Independent of the existence of water as a crust condensate H2O is a thermally stable cloud condensate for all investigated elemental abundances. However, the water cloud base depends on the hydration level of the crust. Therefore, the detection of water condensates alone does not necessarily imply stable water on the surface, even if the temperature could allow water condensation.

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Hydroxide salts in the clouds of Venus: their effect on the sulfur cycle and cloud droplet pH

The depletion of SO$_2$ and H$_2$O in and above the clouds of Venus (45 -- 65 km) cannot be explained by known gas-phase chemistry and the observed composition of the atmosphere. We apply a full-atmosphere model of Venus to investigate three potential explanations for the SO$_2$ and H$_2$O depletion: (1) varying the below-cloud water vapor (H$_2$O), (2) varying the below-cloud sulfur dioxide (SO$_2$), and (3) the incorporation of chemical reactions inside the sulfuric acid cloud droplets. We find that increasing the below-cloud H$_2$O to explain the SO$_2$ depletion results in a cloud top that is 20 km too high, above-cloud O$_2$ three orders of magnitude greater than observational upper limits and no SO above 80 km. The SO$_2$ depletion can be explained by decreasing the below-cloud SO$_2$ to $20\,{\rm ppm}$. The depletion of SO$_2$ in the clouds can also be explained by the SO$_2$ dissolving into the clouds, if the droplets contain hydroxide salts. These salts buffer the cloud pH. The amount of salts sufficient to explain the SO$_2$ depletion entail a droplet pH of $\sim 1$ at 50 km. Since sulfuric acid is constantly condensing out into the cloud droplets, there must be a continuous and pervasive flux of salts of $\approx 10^{-13} \, {\rm mol \, cm^{-2} \, s^{-1}}$ driving the cloud droplet chemistry. An atmospheric probe can test both of these explanations by measuring the pH of the cloud droplets and the concentrations of gas-phase SO$_2$ below the clouds.

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The Atmospheres of Rocky Exoplanets I. Outgassing of Common Rock and the Stability of Liquid Water

Little is known about the interaction between atmospheres and crusts of exoplanets so far, but future space missions and ground-based instruments are expected to detect molecular features in the spectra of hot rocky exoplanets. We aim to understand the composition of the gas in an exoplanet atmosphere which is in equilibrium with a planetary crust. Methods. The molecular composition of the gas above a surface made of a mixture of solid and liquid materials is determined by assuming phase equilibrium for given pressure, temperature and element abundances. We study total element abundances that represent different parts of the Earth's crust (Continental Crust, Bulk Silicate Earth, Mid Oceanic Ridge Basalt), CI chondrites and abundances measured in polluted white dwarfs. For temperatures between 600K and 3500K, the near-crust atmospheres of all considered total element abundances are mainly composed of H2O, CO2, SO2 and in some cases of O2 and H2. For temperatures 500K, only N2-rich or CH4-rich atmospheres remain. For 3500K, the atmospheric gas is mainly composed of atoms (O, Na, Mg, Fe), metal oxides (SiO, NaO, MgO, CaO, AlO, FeO) and some metal hydroxides (KOH, NaOH). The inclusion of phyllosilicates as potential condensed species is crucial for lower temperatures, as they can remove water from the gas phase below about 700K and inhibit the presence of liquid water. Measurements of the atmospheric composition could, in principle, characterise the rock composition of exoplanet crusts. H2O, O2 and CH4 are natural products from the outgassing of different kinds of rocks that had time to equilibrate. These are discussed as biomarkers, but do emerge naturally as result of the thermodynamic interaction between crust and atmosphere. Only the simultaneous detection of all three molecules might be a sufficient biosignature, as it is inconsistent with chemical equilibrium.

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Understanding the atmospheric properties and chemical composition of the ultra-hot Jupiter HAT-P-7b II. Mapping the effects of gas kinetics

The atmospheres of ultra-hot Jupiters are commonly considered to be at thermochemical equilibrium. We aim to provide disequilibrium chemistry maps for a global understanding of the chemistry in HAT-P-7b's atmosphere and assess the importance of disequilibrium chemistry on UHJs. We apply a hierarchical modelling approach utilising 97 1D atmospheric profiles from 3D GCM of HAT-P-7b. For each 1D profile, we evaluate our kinetic cloud formation model consistently with the local gas-phase composition in chemical equilibrium. We then evaluate quenching results from a zeroth-order approximation in comparison to a kinetic gas-phase approach. We find that the zeroth-order approach of estimating quenching points agrees well with the full gas-kinetic modeling results. Chemical disequilibrium has the greatest effect on the nightside and morning abundance of species such as H, H$_2$O, CH$_4$, CO$_2$, HCN, and all C$_n$H$_m$ molecules; heavier C$_n$H$_m$ molecules are more affected by disequilibrium processes. CO abundance, however, is affected only marginally. While dayside abundances also notably change, those around the evening terminator of HAT-P-7b are the least affected by disequilibrium processes. The latter finding may partially explain the consistency of observed transmission spectra of UHJs with atmospheres in thermochemical equilibrium. Photochemistry only negligibly affects molecular abundances and quenching levels. In general, the quenching points of HAT-P-7b's atmosphere are at much lower pressures in comparison to the cooler hot-jupiters. We propose several avenues to look for the effect of disequilibrium processes on UHJs that are, in general, based on abundance and opacity measurements at different local times. It remains a challenge to completely disentangle this from the chemical effects of clouds and that of a primordial non-solar abundance.

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Dust in brown dwarfs and extra-solar planets. VII. Cloud formation in diffusive atmospheres

The precipitation of cloud particles in brown dwarf and exoplanet atmospheres establishes an ongoing downward flux of condensable elements. To understand the efficiency of cloud formation, it is therefore crucial to quantify the replenishment mechanism that is able to compensate for the element losses in the upper atmosphere, to keep the extrasolar weather cycle running. In this paper, we introduce a new cloud formation model by combining the cloud particle moment method of Helling & Woitke with a diffusive mixing approach, taking into account turbulent mixing and gas-kinetic diffusion for both gas and cloud particles. The equations are of diffusion-reaction type and are solved time-dependently for a prescribed 1D atmospheric structure, until the model has relaxed toward a time-independent solution. In comparison to our previous models, the new hot Jupiter model results (Teff=2000K, log g=3) show fewer but larger cloud particles which are more concentrated towards the cloud base. The abundances of condensable elements in the gas phase are featured by a steep decline above the cloud base, followed by a shallower, monotonous decrease towards a plateau, the level of which depends on temperature. The chemical composition of the cloud particles also differs significantly from our previous models. Due to the condensation of specific condensates like Mg2SiO4[s] in deeper layers, certain elements, such as Mg, are almost entirely removed from the gas phase early. This leads to unusual (and non-solar) element ratios in higher atmospheric layers, which then favours the formation of SiO[s] and SiO2[s], for example, rather than MgSiO3[s]. Such condensates are not expected in phase-equilibrium models that start from solar abundances. Above the main silicate cloud layer, which is enriched with iron and metal oxides, we find a second cloud layer made of Na2S[s] particles in cooler models (Teff<1500K).

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On water delivery in the inner solar nebula: Monte Carlo simulations of forsterite hydration

Endogenous or exogenous, dry or wet, various scenarios have been so far depicted for the origin of water on our Solar Systems rocky bodies. Hydrated silicates found in meteorites and in interplanetary dust particles together with observations of abundant water reservoirs in the habitable zone of protoplanetary disks are evidences that support aqueous alteration of silicate dust grains by water vapor condensation in a nebular setting. We investigate the thermodynamics (temperature and pressure dependencies) and kinetics (adsorption rates and energies, surface diffusion and cluster formation) of water adsorption on surfaces of forsterite grains. (abbreviated) The protoplanetary disk model (ProDiMo) code is tuned to simulate the thermochemical disk structure of the early solar nebula at three evolutionary stages. Pressure, temperature and water vapor abundance within 1 au from the protosun were extracted and used as input for a Monte Carlo code to model water associative adsorption using adsorption energies that resemble the forsterite [100] crystal lattice. Hydration of forsterite surfaces by water vapor adsorption could have occurred within the nebula lifetime already at a density of 1e8 cm-3, with increasing surface coverage for higher water vapor densities. Full surface coverage is attained for temperatures lower than 500 K, while for hotter grain surfaces water cluster formation plays a crucial role. (abbreviated) This work shows that water cluster formation enhances the water surface coverage and enables a stable water layer to form at high temperature and low water vapor density conditions. Finally, surface diffusion of physisorbed water molecules shortens the timescale for reaching steady state, enabling phyllosilicate formation within the solar nebula timescale.

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Consistent dust and gas models for protoplanetary disks: II. Chemical networks and rates

Aims. We define a small and large chemical network which can be used for the quantitative simultaneous analysis of molecular emission from the near-IR to the submm. We revise reactions of excited molecular hydrogen, which are not included in UMIST, to provide a homogeneous database for future applications. Methods. We use the thermo-chemical disk modeling code ProDiMo and a standard T Tauri disk model to evaluate the impact of various chemical networks, reaction rate databases and sets of adsorption energies on a large sample of chemical species and emerging line fluxes from the near-IR to the submm wavelength range. Results. We find large differences in the masses and radial distribution of ice reservoirs when considering freeze-out on bare or polar ice coated grains. Most strongly the ammonia ice mass and the location of the snow line (water) change. As a consequence molecules associated to the ice lines such as N2H+ change their emitting region; none of the line fluxes in the sample considered here changes by more than 25% except CO isotopologues, CN and N2H+ lines. The three-body reaction N+H2+M plays a key role in the formation of water in the outer disk. Besides that, differences between the UMIST 2006 and 2012 database change line fluxes in the sample considered here by less than a factor 2 (a subset of low excitation CO and fine structure lines stays even within 25%); exceptions are OH, CN, HCN, HCO+ and N2H+ lines. However, different networks such as OSU and KIDA 2011 lead to pronounced differences in the chemistry inside 100 au and thus affect emission lines from high excitation CO, OH and CN lines. H2 is easily excited at the disk surface and state-to-state reactions enhance the abundance of CH+ and to a lesser extent HCO+. For sub-mm lines of HCN, N2H+ and HCO+, a more complex larger network is recommended. ABBREVIATED

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Grand challenges in protoplanetary disc modelling

The Protoplanetary Discussions conference --- held in Edinburgh, UK, from 7th --11th March 2016 --- included several open sessions led by participants. This paper reports on the discussions collectively concerned with the multiphysics modelling of protoplanetary discs, including the self-consistent calculation of gas and dust dynamics, radiative transfer and chemistry. After a short introduction to each of these disciplines in isolation, we identify a series of burning questions and grand challenges associated with their continuing development and integration. We then discuss potential pathways towards solving these challenges, grouped by strategical, technical and collaborative developments. This paper is not intended to be a review, but rather to motivate and direct future research and collaboration across typically distinct fields based on \textit{community driven input}, to encourage further progress in our understanding of circumstellar and protoplanetary discs.

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The protoplanetary disk of FT Tauri: multi-wavelength data analysis and modeling

Investigating the evolution of protoplanetary disks is crucial for our understanding of star and planet formation. Several theoretical and observational studies have been performed in the last decades to advance this knowledge. FT Tauri is a young star in the Taurus star forming region that was included in a number of spectroscopic and photometric surveys. We investigate the properties of the star, the circumstellar disk, and the accretion and ejection processes and propose a consistent gas and dust model also as a reference for future observational studies. We performed a multi-wavelength data analysis to derive the basic stellar and disk properties, as well as mass accretion/outflow rate from TNG-Dolores, WHT-Liris, NOT-Notcam, Keck-Nirspec, and Herschel-Pacs spectra. From the literature, we compiled a complete Spectral Energy Distribution. We then performed detailed disk modeling using the MCFOST and ProDiMo codes. Multi-wavelengths spectroscopic and photometric measurements were compared with the reddened predictions of the codes in order to constrain the disk properties. This object can serve as a benchmark for primordial disks with significant mass accretion rate, high gas content and typical size.

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Gas lines from the 5-Myr old optically thin disk around HD141569A. Herschel observations and modeling

At the distance of 99-116 pc, HD141569A is one of the nearest HerbigAe stars that is surrounded by a tenuous disk, probably in transition between a massive primordial disk and a debris disk. We observed the fine-structure lines of OI at 63 and 145 micron and the CII line at 157 micron with the PACS instrument onboard the Herschel Space Telescope as part of the open-time large programme GASPS. We complemented the atomic line observations with archival Spitzer spectroscopic and photometric continuum data, a ground-based VLT-VISIR image at 8.6 micron, and 12CO fundamental ro-vibrational and pure rotational J=3-2 observations. We simultaneously modeled the continuum emission and the line fluxes with the Monte Carlo radiative transfer code MCFOST and the thermo-chemical code ProDiMo to derive the disk gas- and dust properties assuming no dust settling. The models suggest that the oxygen lines are emitted from the inner disk around HD141569A, whereas the [CII] line emission is more extended. The CO submillimeter flux is emitted mostly by the outer disk. Simultaneous modeling of the photometric and line data using a realistic disk structure suggests a dust mass derived from grains with a radius smaller than 1 mm of 2.1E-7 MSun and from grains with a radius of up to 1 cm of 4.9E-6 MSun. We constrained the polycyclic aromatic hydrocarbons (PAH) mass to be between 2E-11 and 1..4E-10 MSun assuming circumcircumcoronene (C150H30) as the representative PAH. The associated PAH abundance relative to hydrogen is lower than those found in the interstellar medium (3E-7) by two to three orders of magnitude. The disk around HD141569A is less massive in gas (2.5 to 4.9E-4 MSun or 67 to 164 MEarth) and has a flat opening angle (<10%). [abridged]

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Tracing the Physical Conditions in Active Galactic Nuclei with Time-Dependent Chemistry

We present an extension of the code ProDiMo that allows for a modeling of processes pertinent to active galactic nuclei and to an ambient chemistry that is time dependent. We present a proof-of-concept and focus on a few astrophysically relevant species, e.g., H+, H2+ and H3+; C+ and N+; C and O; CO and H2O; OH+, H2O+ and H3O+; HCN and HCO+. We find that the freeze-out of water is strongly suppressed and that this affects the bulk of the oxygen and carbon chemistry occurring in AGN. The commonly used AGN tracer HCN/HCO+ is strongly time-dependent, with ratios that vary over orders of magnitude for times longer than 10^4 years. Through ALMA observations this ratio can be used to probe how the narrow-line region evolves under large fluctuations in the SMBH accretion rate. Strong evolutionary trends, on time scales of 10^4-10^8 years, are also found in species such as H3O+, CO, and H2O. These reflect, respectively, time dependent effects in the ionization balance, the transient nature of the production of molecular gas, and the freeze-out/sublimation of water.

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Radiation thermo-chemical models of protoplanetary discs. IV Modelling CO ro-vibrational emission from Herbig Ae discs

The carbon monoxide rovibrational emission from discs around Herbig Ae stars and T Tauri stars with strong ultraviolet emissions suggests that fluorescence pumping from the ground X1 Sigma+ to the electronic A1 Pi state of CO should be taken into account in disc models. We implemented a CO model molecule that includes up to 50 rotational levels within nine vibrational levels for the ground and A excited states in the radiative photochemical code ProDiMo. We took CO collisions with hydrogen molecules, hydrogen atoms, helium, and electrons into account. We estimated the missing collision rates using standard scaling laws and discussed their limitations. UV fluorescence and IR pumping impact on the population of ro-vibrational v > 1 levels. The v = 1 rotational levels are populated at rotational temperatures between the radiation temperature around 4.6 micron and the gas kinetic temperature. The UV pumping efficiency increases with decreasing disc mass. The consequence is that the vibrational temperatures, which measure the relative populations between the vibrational levels, are higher than the disc gas kinetic temperatures (suprathermal population). Rotational temperatures from fundamental transitions derived using optically thick 12CO lines do not reflect the gas kinetic temperature. CO pure rotational levels with energies lower than 1000 K are populated in LTE but are sensitive to a number of vibrational levels included in the model. The 12CO pure rotational lines are highly optically thick for transition from levels up to Eupper=2000 K. (abridged)

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FUV and X-ray irradiated protoplanetary disks: a grid of models II - Gas diagnostic line emission

Most of the mass in protoplanetary disks is in the form of gas. The study of the gas and its diagnostics is of fundamental importance in order to achieve a detailed description of the thermal and chemical structure of the disk. The radiation from the central star (from optical to X-ray wavelengths) and viscous accretion are the main source of energy and dominates the disk physics and chemistry in its early stages. This is the environment in which the first phases of planet formation will proceed. We investigate how stellar and disk parameters impact the fine-structure cooling lines [NeII], [ArII], [OI], [CII] and H2O rotational lines in the disk. These lines are potentially powerful diagnostics of the disk structure and their modelling permits a thorough interpretation of the observations carried out with instrumental facilities such as Spitzer and Herschel. Following Aresu et al. (2011), we computed a grid of 240 disk models, in which the X-ray luminosity, UV-excess luminosity, minimum dust grain size, dust size distribution power law and surface density distribution power law, are systematically varied. We solve self-consistently for the disk vertical hydrostatic structure in every model and apply detailed line radiative transfer to calculate line fluxes and profiles for a series of well known mid- and far-infrared cooling lines. The [OI] 63 micron line flux increases with increasing FUV luminosity when Lx < 1e30 erg/s, and with increasing X-ray luminosity when LX > 1e30 erg/s. [CII] 157 micron is mainly driven by FUV luminosity via C+ production, X-rays affect the line flux to a lesser extent. [NeII] 12.8 micron correlates with X-rays; the line profile emitted from the disk atmosphere shows a double-peaked component, caused by emission in the static disk atmosphere, next to a high velocity double-peaked component, caused by emission in the very inner rim. (abridged)

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Radiation thermo-chemical models of protoplanetary discs. III. Impact of inner rims on Spectral Energy Distributions

We study the hydrostatic density structure of the inner disc rim around HerbigAe stars using the thermo-chemical hydrostatic code ProDiMo. We compare the Spectral Energy Distributions (SEDs) and images from our hydrostatic disc models to that from prescribed density structure discs. The 2D continuum radiative transfer in ProDiMo includes isotropic scattering. The dust temperature is set by the condition of radiative equilibrium. In the thermal-decoupled case the gas temperature is governed by the balance between various heating and cooling processes. The gas and dust interact thermally via photoelectrons, radiatively, and via gas accommodation on grain surfaces. As a result, the gas is much hotter than in the thermo-coupled case, where the gas and dust temperatures are equal, reaching a few thousands K in the upper disc layers and making the inner rim higher. A physically motivated density drop at the inner radius ("soft-edge") results in rounded inner rims, which appear ring-like in near-infrared images. The combination of lower gravity pull and hot gas beyond ~1 AU results in a disc atmosphere that reaches a height over radius ratio z/r of 0.1 while this ratio is 0.2 only in the thermo-coupled case. This puffed-up disc atmosphere intercepts larger amount of stellar radiation, which translates into enhanced continuum emission in the 3- 30 micron wavelength region from hotter grains at ~500 K. We also consider the effect of disc mass and grain size distribution on the SEDs self-consistently feeding those quantities back into the gas temperature, chemistry, and hydrostatic equilibrium computation.

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Continuum and line modelling of discs around young stars. I. 300000 disc models for Herschel/GASPS

We have combined the thermo-chemical disc code ProDiMo with the Monte Carlo radiative transfer code MCFOST to calculate a grid of ~300000 circumstellar disc models, systematically varying 11 stellar, disc and dust parameters including the total disc mass, several disc shape parameters and the dust-to-gas ratio. For each model, dust continuum and line radiative transfer calculations are carried out for 29 far IR, sub-mm and mm lines of [OI], [CII], 12CO and o/p-H2O under 5 inclinations. The grid allows to study the influence of the input parameters on the observables, to make statistical predictions for different types of circumstellar discs, and to find systematic trends and correlations between the parameters, the continuum fluxes, and the line fluxes. The model grid, comprising the calculated disc temperatures and chemical structures, the computed SEDs, line fluxes and profiles, will be used in particular for the data interpretation of the Herschel open time key programme GASPS. The calculated line fluxes show a strong dependence on the assumed UV excess of the central star, and on the disc flaring. The fraction of models predicting [OI] and [CII] fine-structure lines fluxes above Herschel/PACS and Spica/SAFARI detection limits are calculated as function of disc mass. The possibility of deriving the disc gas mass from line observations is discussed.

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Warm gas phase chemistry as possible origin of high HDO/H2O ratios in hot and dense gases: application to inner protoplanetary discs

The origin of Earth oceans is controversial. Earth could have acquired its water either from hydrated silicates (wet Earth scenario) or from comets (dry Earth scenario). [HDO]/[H2O] ratios are used to discriminate between the scenarios. High [HDO]/[H2O] ratios are found in Earth oceans. These high ratios are often attributed to the release of deuterium enriched cometary water ice, which was formed at low gas and dust temperatures. Observations do not show high [HDO]/[H2O] in interstellar ices. We investigate the possible formation of high [HDO]/[H2O] ratios in dense (nH> 1E6 cm^{-3}) and warm gas (T=100-1000 K) by gas-phase photochemistry in the absence of grain surface chemistry. We derive analytical solutions, taking into account the major neutral-neutral reactions for gases at T>100 K. The chemical network is dominated by photodissociation and neutral-neutral reactions. Despite the high gas temperature, deuterium fractionation occurs because of the difference in activation energy between deuteration enrichment and the back reactions. The analytical solutions were confirmed by the time-dependent chemical results in a 1E-3 MSun disc around a typical TTauri star using the photochemical code ProDiMo. The ProDiMo code includes frequency-dependent 2D dust-continuum radiative transfer, detailed non-LTE gas heating and cooling, and hydrostatic calculation of the disc structure. Both analytical and time-dependent models predict high [HDO]/[H2O] ratios in the terrestrial planet forming region (< 3 AU) of circumstellar discs. Therefore the [HDO]/[H2O] ratio may not be an unique criterion to discriminate between the different origins of water on Earth.

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