arXiv subjects

Philipp Strasberg

Publications and source records attributed to Philipp Strasberg.

At least 37 records · Page 2Linked to original sources

arXiv2021

First and Second Law of Quantum Thermodynamics: A Consistent Derivation Based on a Microscopic Definition of Entropy

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of states and processes. The consistency with previous results is demonstrated. The framework applies to multiple baths including particle transport and accounts for processes with, e.g., a changing temperature of the bath, which is determined microscopically. An integral fluctuation theorem for entropy production is satisfied. In summary, this tutorial introduces a consistent and versatile framework to understand and apply the laws of thermodynamics in the quantum regime and beyond.

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arXiv2021

Clausius Inequality for Finite Baths Reveals Universal Efficiency Improvements

We study entropy production in nanoscale devices, which are coupled to finite heat baths. This situation is of growing experimental relevance, but most theoretical approaches rely on a formulation of the second law valid only for infinite baths. We fix this problem by pointing out that already Clausius' paper from 1865 contains an adequate formulation of the second law for finite heat baths, which can be also rigorously derived from a microscopic quantum description. This Clausius' inequality shows that nonequilibrium processes are less irreversible than previously thought. We use it to correctly extend Landauer's principle to finite baths and we demonstrate that any heat engine in contact with finite baths has a higher efficiency than previously thought. Importantly, our results are easy to study, requiring only the knowledge of the average bath energy.

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arXiv2021

Autonomous implementation of thermodynamic cycles at the nanoscale

There are two paradigms to study nanoscale engines in stochastic and quantum thermodynamics. Autonomous models, which do not rely on any external time-dependence, and models that make use of time-dependent control fields, often combined with dividing the control protocol into idealized strokes of a thermodynamic cycle. While the latter paradigm offers theoretical simplifications, its utility in practice has been questioned due to the involved approximations. Here, we bridge the two paradigms by constructing an autonomous model, which implements a thermodynamic cycle in a certain parameter regime. This effect is made possible by self-oscillations, realized in our model by the well studied electron shuttling mechanism. Based on experimentally realistic values, we find that a thermodynamic cycle analysis for a single-electron working fluid is {\it not} justified, but a few-electron working fluid could suffice to justify it. Furthermore, additional open challenges remain to autonomously implement the more studied Carnot and Otto cycles.

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arXiv2021

Reply to "Comment on `Measurability of nonequilibrium thermodynamics in terms of the Hamiltonian of mean force'"

We refute the criticism expressed in a comment by P. Talkner and P. Hänggi [Phys. Rev. E 102, 066101 (2020)] on our paper Phys. Rev. E 101, 050101(R) (2020). We first make clear that our paper is free of any technical mistakes. We then defend the statements of our manuscript which were claimed to be taken out of context. Finally, we give clear arguments showing that the basic concepts we rely on are meaningful and have a deep rational.

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arXiv2020

Quantum systems correlated with a finite bath: nonequilibrium dynamics and thermodynamics

Describing open quantum systems far from equilibrium is challenging, in particular when the environment is mesoscopic, when it develops nonequilibrium features during the evolution, or when the memory effects cannot be disregarded. Here, we derive a master equation that explicitly accounts for system-bath correlations and includes, at a coarse-grained level, a dynamically evolving bath. Such a master equation applies to a wide variety of physical systems including those described by Random Matrix Theory or the Eigenstate Thermalization Hypothesis. We obtain a local detailed balance condition which, interestingly, does not forbid the emergence of stable negative temperature states in unison with the definition of temperature through the Boltzmann entropy. We benchmark the master equation against the exact evolution and observe a very good agreement in a situation where the conventional Born-Markov-secular master equation breaks down. Interestingly, the present description of the dynamics is robust and it remains accurate even if some of the assumptions are relaxed. Even though our master equation describes a dynamically evolving bath not described by a Gibbs state, we provide a consistent nonequilibrium thermodynamic framework and derive the first and second law as well as the Clausius inequality. Our work paves the way for studying a variety of nanoscale quantum technologies including engines, refrigerators, or heat pumps beyond the conventionally employed assumption of a static thermal bath.

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arXiv2020

Entropy production as change in observational entropy

The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a large class of initial states. Using the recently introduced notion of observational entropy, shortcomings of previous approaches are overcome. I apologize that the actual abstract of the manuscript is longer than the arXiv guidelines allow and therefore not displayed here.

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arXiv2020

Measurability of nonequilibrium thermodynamics in terms of the Hamiltonian of mean force

The nonequilibrium thermodynamics of an open (classical or quantum) system in strong contact with a single heat bath can be conveniently described in terms of the Hamiltonian of mean force. However, the conventional formulation is limited by the necessity to measure differences in equilibrium properties of the system-bath composite. We make use of the freedom involved in defining thermodynamic quantities, which leaves the thermodynamics unchanged, to show that the Hamiltonian of mean force can be inferred from measurements on the system alone, up to that irrelevant freedom. In doing so, we refute a key criticism expressed in Phys. Rev. E 94, 022143 and arXiv:1911.11660. We also discuss the remaining part of the criticism.

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arXiv2020

Thermodynamics of Quantum Causal Models: An Inclusive, Hamiltonian Approach

Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory is defined solely in terms of experimentally accessible measurement results, which serve as the basis to define the corresponding thermodynamic quantities. In contrast to this observer-dependent point of view, a `black box', which evolves unitarily and can simulate a quantum causal model, is constructed here. The quantum thermodynamics of this big isolated system can then be studied using widely accepted arguments from statistical mechanics. It is shown that the resulting definitions of internal energy, heat, work, and entropy have a natural extension to the trajectory level. The canonical choice of them coincides with the proclaimed definitions of operational quantum stochastic thermodynamics, thereby providing strong support in favour of that novel framework. However, a few remaining ambiguities in the definition of stochastic work and heat are also discovered and in light of these findings some other proposals are reconsidered. Finally, it is demonstrated that the first and second law hold for an even wider range of scenarios than previously thought, covering a large class of quantum causal models based solely on a single assumption about the initial system-bath state.

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arXiv2019

Repeated interactions and quantum stochastic thermodynamics at strong coupling

The thermodynamic framework of repeated interactions is generalized to an arbitrary open quantum system in contact with a heat bath. Based on these findings the theory is then extended to arbitrary measurements performed on the system. This constitutes a direct experimentally testable framework in strong coupling quantum thermodynamics. By construction, it provides many quantum stochastic processes and quantum causal models with a consistent thermodynamic interpretation. The setting can be further used, for instance, to rigorously investigate the interplay between non-Markovianity and nonequilibrium thermodynamics.

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arXiv2019

An operational approach to quantum stochastic thermodynamics

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from the repeated interaction framework, we define internal energy, heat, work and entropy at the trajectory level. The validity of the first law (at the trajectory level) and the second law (on average) is established. The theory naturally allows to treat incomplete information and it is able to smoothly interpolate between a trajectory based and ensemble level description. We use our theory to compute the thermodynamic efficiency of recent experiments reporting on the stabilization of photon number states using real-time quantum feedback control. Special attention is also payed to limiting cases of our general theory, where we recover or contrast it with previous results. We point out various interesting problems, which the theory is able to address rigorously, such as the detection of quantum effects in thermodynamics.

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arXiv2019

Classical quantum stochastic processes

We investigate the role of coherence and Markovianity in finding an answer to the question whether the outcomes of a projectively measured quantum stochastic process are compatible with a classical stochastic process. For this purpose we put forward an operationally motivated definition of incoherent dynamics applicable to any open system's dynamics. For non-degenerate observables described by rank-1 projective measurements we show that classicality always implies incoherent dynamics, whereas the converse is only true for invertible Markovian (but not necessarily time-homogeneous) dynamics. For degenerate observables the picture is somewhat reversed as classicality does no longer suffice to imply incoherent dynamics (even in the invertible Markovian case), while an incoherent, invertible Markovian dynamics still implies classicality.

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arXiv2019

Stochastic thermodynamics with arbitrary interventions

We extend the theory of stochastic thermodynamics in three directions: (i) instead of a continuously monitored system we consider measurements only at an arbitrary set of discrete times, (ii) we allow for imperfect measurements and incomplete information in the description, and (iii) we treat arbitrary manipulations (e.g. feedback control operations) which are allowed to depend on the entire measurement record. For this purpose we define for a driven system in contact with a single heat bath the four key thermodynamic quantities: internal energy, heat, work and entropy along a single `trajectory' for a causal model. The first law at the trajectory level and the second law on average is verified. We highlight the special case of Bayesian or `bare' measurements (incomplete information, but no average disturbance) which allows us to compare our theory with the literature and to derive a general inequality for the estimated free energy difference in Jarzynksi-type experiments. An analysis of a recent Maxwell demon experiment using real-time feedback control is also given. As a mathematical tool, we prove a classical version of Stinespring's dilation theorem, which might be of independent interest.

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arXiv2018

Non-Markovianity and negative entropy production rates

Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovian dynamics. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovian dynamics and when it does not. This is established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a system in contact with a single heat bath described by a Markovian master equation and (ii) the classical Hamiltonian dynamics of a driven system, which is coupled arbitrary strongly to a single heat bath. The quantum version of the latter result is shown not to hold despite the fact that the integrated thermodynamic description is formally equivalent to the classical case. The instantaneous steady state of a non-Markovian dynamics plays an important element in our study. Our key contribution is to provide a consistent theoretical framework to study the finite-time thermodynamics of a large class of dynamics with a precise link to its non-Markovianity.

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arXiv2018

Response functions as quantifiers of non-Markovianity

Quantum non-Markovianity is crucially related to the study of dynamical maps, which are usually derived for initially factorized system-bath states. We here demonstrate that linear response theory also provides a way to derive dynamical maps, but for initially correlated (and in general entangled) states. Importantly, these maps are always time-translational invariant and allow for a much simpler quantification of non-Markovianity compared to previous approaches. We apply our theory to the Caldeira-Leggett model, for which our quantifier is valid beyond linear response and can be expressed analytically. We find that a classical Brownian particle coupled to an Ohmic bath can already exhibit non-Markovian behaviour, a phenomenon related to the initial state preparation procedure. Furthermore, for a peaked spectral density we demonstrate that there is no monotonic relation between our quantifier and the system-bath coupling strength, the sharpness of the peak or the resonance frequency in the bath.

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arXiv2018

From quantum heat engines to laser cooling: Floquet theory beyond the Born-Markov approximation

We combine the formalisms of Floquet theory and full counting statistics with a Markovian embedding strategy to access the dynamics and thermodynamics of a periodically driven thermal machine beyond the conventional Born-Markov approximation. The working medium is a two-level system and we drive the tunneling as well as the coupling to one bath with the same period. We identify four different operating regimes of our machine which include a heat engine and a refrigerator. As the coupling strength with one bath is increased, the refrigerator regime disappears, the heat engine regime narrows and their efficiency and coefficient of performance decrease. Furthermore, our model can reproduce the setup of laser cooling of trapped ions in a specific parameter limit.

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arXiv2018

An electronic Maxwell demon in the coherent strong-coupling regime

We consider a feedback control loop rectifying particle transport through a single quantum dot that is coupled to two electronic leads. While monitoring the occupation of the dot, we apply conditional control operations by changing the tunneling rates between the dots and its reservoirs, which can be interpreted as the action of a Maxwell demon opening or closing a shutter. This can generate a current at equilibrium or even against a potential bias, producing electric power from information. While this interpretation is well-explored in the weak-coupling limit, we can address the strong-coupling regime with a fermionic reaction-coordinate mapping, which maps the system into a serial triple quantum dot coupled to two leads. There, we find that a continuous projective measurement of the central dot would lead to a complete suppression of electronic transport due to the quantum Zeno effect. In contrast, a microscopic model for the quantum point contact detector implements a weak measurement, which allows for closure of the control loop without inducing transport blockade. In the weak-coupling regime between the central dot and its leads, the energy flows associated with the feedback loop are negligible, and the information gained in the measurement induces a bound for the generated electric power. In contrast, in the strong coupling limit, the protocol may require more energy for opening and closing the shutter than electric power produced, such that the device is no longer information-dominated and can thus not be interpreted as a Maxwell demon.

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arXiv2018

Fermionic reaction coordinates and their application to an autonomous Maxwell demon in the strong coupling regime

We establish a theoretical method which goes beyond the weak coupling and Markovian approximations while remaining intuitive, using a quantum master equation in a larger Hilbert space. The method is applicable to all impurity Hamiltonians tunnel-coupled to one (or multiple) baths of free fermions. The accuracy of the method is in principle not limited by the system-bath coupling strength, but rather by the shape of the spectral density and it is especially suited to study situations far away from the wide-band limit. In analogy to the bosonic case, we call it the fermionic reaction coordinate mapping. As an application we consider a thermoelectric device made of two Coulomb-coupled quantum dots. We pay particular attention to the regime where this device operates as an autonomous Maxwell demon shoveling electrons against the voltage bias thanks to information. Contrary to previous studies we do not rely on a Markovian weak coupling description. Our numerical findings reveal that in the regime of strong coupling and non-Markovianity, the Maxwell demon is often doomed to disappear except in a narrow parameter regime of small power output.

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arXiv2017

Stochastic thermodynamics in the strong coupling regime: An unambiguous approach based on coarse-graining

We consider a classical and possibly driven composite system $X \otimes Y$ weakly coupled to a Markovian thermal reservoir $R$ so that an unambiguous stochastic thermodynamics ensues for $X \otimes Y$. This setup can be equivalently seen as a system $X$ strongly coupled to a non-Markovian reservoir $Y \otimes R$. We demonstrate that only in the limit where the dynamics of $Y$ is much faster then $X$, our unambiguous expressions for thermodynamic quantities such as heat, entropy or internal energy, are equivalent to the strong coupling expressions recently obtained in the literature using the Hamiltonian of mean force. By doing so, we also significantly extend these results by formulating them at the level of instantaneous rates and by allowing for time-dependent couplings between $X$ and its environment. Away from the limit where $Y$ evolves much faster than $X$, previous approaches fail to reproduce the correct results from the original unambiguous formulation, as we illustrate numerically for an underdamped Brownian particle coupled strongly to a non-Markovian reservoir.

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