arXiv subjects

Pierpaolo Belardinelli

Publications and source records attributed to Pierpaolo Belardinelli.

4 recordsLinked to original sources

arXiv2025

Sparse identification of quasipotentials via a combined data-driven method

The quasipotential function allows for comprehension and prediction of the escape mechanisms from metastable states in nonlinear dynamical systems. This function acts as a natural extension of the potential function for non-gradient systems and it unveils important properties such as the maximum likelihood transition paths, transition rates and expected exit times of the system. Here, we demonstrate how to discover parsimonious equations for the quasipotential directly from data. Leveraging machine learning, we combine two existing data-driven techniques, namely a neural network and a sparse regression algorithm, specifically designed to symbolically describe multistable energy landscapes. First, we employ a vanilla neural network enhanced with a renormalization and rescaling procedure to achieve an orthogonal decomposition of the vector field. Next, we apply symbolic regression to extract the downhill and circulatory components of the decomposition, ensuring consistency with the underlying dynamics. This symbolic reconstruction involves a simultaneous regression that imposes constraints on both the orthogonality condition and the vector field. We implement and benchmark our approach using an archetypal model with a known exact quasipotential, as well as a nanomechanical resonator system. We further demonstrate its applicability to noisy data and to a four-dimensional system. Our model-unbiased analytical forms of the quasipotential is of interest to a wide range of applications aimed at assessing metastability and energy landscapes, serving to parametrically capture the distinctive fingerprint of the fluctuating dynamics.

math.DS↗

arXiv2022

Sensitivity of viscoelastic characterization in multi-harmonic atomic force microscopy

Quantifying the nanomechanical properties of soft-matter using multi-frequency atomic force microscopy (AFM) is crucial for studying the performance of polymers, ultra-thin coatings, and biological systems. Such characterization processes often make use of cantilever's spectral components to discern nanomechanical properties within a multi-parameter optimization problem. This could inadvertently lead to an over-determined parameter estimation with no clear relation between the identified parameters and their influence on the experimental data. In this work, we explore the sensitivity of viscoelastic characterization in polymeric samples to the experimental observables of multi-frequency intermodulation AFM. By performing simulations and experiments we show that surface viscoelasticity has negligible effect on the experimental data and can lead to inconsistent and often non-physical identified parameters. Our analysis reveals that this lack of influence of the surface parameters relates to a vanishing gradient and non-convexity while minimizing the objective function. By removing the surface dependency from the model, we show that the characterization of bulk properties can be achieved with ease and without any ambiguity. Our work sheds light on the sensitivity issues that can be faced when optimizing for a large number of parameters and observables in AFM operation, and calls for the development of new viscoelastic models at the nanoscale and improved computational methodologies for nanoscale mapping of viscoelasticity using AFM.

cond-mat.soft↗

arXiv2018

High-frequency stochastic switching of graphene resonators near room temperature

Stochastic switching between the two bistable states of a strongly driven mechanical resonator enables detection of weak signals based on probability distributions, in a manner that mimics biological systems. However, conventional silicon resonators at the microscale require a large amount of fluctuation power to achieve a switching rate in the order of a few Hertz. Here, we employ graphene membrane resonators of atomic thickness to achieve a stochastic switching rate of 7.8 kHz, which is 200 times faster than current state-of-the-art. The (effective) temperature of the fluctuations is approximately 400 K, which is 3000 times lower than the state-of-the-art. This shows that these membranes are potentially useful to transduce weak signals in the audible frequency domain. Furthermore, we perform numerical simulations to understand the transition dynamics of the resonator and derive simple analytical expressions to investigate the relevant scaling parameters that allow high-frequency, low-temperature stochastic switching to be achieved in mechanical resonators.

cond-mat.mes-hall↗

arXiv2018

Modal analysis for determining the size-and temperature-dependent bending rigidity of graphene

The bending rigidity of two-dimensional (2D) materials is a key parameter for understanding the mechanics of 2D NEMS devices. The apparent bending rigidity of graphene membranes at macroscopic scale differs from theoretical predictions at micro-scale. This difference is believed to originate from thermally induced dynamic ripples in the atomically thin membrane. In this paper, we perform modal analysis to estimate the effective macroscopic bending rigidity of graphene membranes from the frequency spectrum of their Brownian motion. Our method is based on fitting the resonance frequencies obtained from the Brownian motion in molecular dynamics simulations, to those obtained from a continuum mechanics model, with bending rigidity and pretension as the fit parameters. In this way, the effective bending rigidity of the membrane and its temperature and size dependence, are extracted, while including the effects of dynamic ripples and thermal fluctuations. The proposed method provides a framework for estimating the macroscopic mechanical properties at high frequencies in other two-dimensional nano-structures at finite temperatures.

physics.app-ph↗