arXiv subjects

Pierre Gaspard

Publications and source records attributed to Pierre Gaspard.

At least 73 records · Page 4Linked to original sources

arXiv2012

Fluctuation relations for equilibrium states with broken discrete symmetries

Relationships are obtained expressing the breaking of spin-reversal symmetry by an external magnetic field in Gibbsian canonical equilibrium states of spin systems under specific assumptions. These relationships include an exact fluctuation relation for the probability distribution of the magnetization, as well as a relation between the standard thermodynamic entropy, an associated spin-reversed entropy or coentropy, and the product of the average magnetization with the external field, as a non-negative Kullback-Leibler divergence. These symmetry relations are applied to the model of noninteracting spins, the 1D and 2D Ising models, and the Curie-Weiss model, all in an external magnetic field. The results are drawn by analogy with similar relations obtained in the context of nonequilibrium physics.

cond-mat.stat-mech↗

arXiv2012

Broken Z2 symmetries and fluctuations in statistical mechanics

An analogy is developed between the breaking of space-inversion symmetry in equilibrium statistical mechanics and the breaking of time-reversal symmetry in nonequilibrium statistical mechanics. In this way, similar relationships characterizing fluctuations are obtained in both contexts.

cond-mat.stat-mech↗

arXiv2012

Time-reversal symmetry relation for nonequilibrium flows ruled by the fluctuating Boltzmann equation

A time-reversal symmetry relation is established for out-of-equilibrium dilute or rarefied gases described by the fluctuating Boltzmann equation. The relation is obtained from the associated coarse-grained master equation ruling the random numbers of particles in cells of given position and velocity in the single-particle phase space. The symmetry relation concerns the fluctuating particle and energy currents of the gas flowing between reservoirs or thermalizing surfaces at given particle densities or temperatures.

cond-mat.stat-mech↗

arXiv2012

Time-reversal symmetry relations for currents in quantum and stochastic nonequilibrium systems

An overview is given of recent advances in the nonequilibrium statistical mechanics of quantum systems and, especially, of time-reversal symmetry relations that have been discovered in this context. The systems considered are driven out of equilibrium by time-dependent forces or by coupling to large reservoirs of particles and energy. The symmetry relations are established for the exchange of energy and particles between the subsystem and its environment. These results have important consequences. In particular, generalizations of the Kubo formula and the Casimir-Onsager reciprocity relations can be deduced beyond linear response properties. Applications to electron quantum transport in mesoscopic semiconducting circuits are discussed.

cond-mat.mes-hall↗

arXiv2012

Self-Organization at the Nanoscale Scale in Far-From-Equilibrium Surface Reactions and Copolymerizations

An overview is given of theoretical progress on self-organization at the nanoscale in reactive systems of heterogeneous catalysis observed by field emission microscopy techniques and at the molecular scale in copolymerization processes. The results are presented in the perspective of recent advances in nonequilibrium thermodynamics and statistical mechanics, allowing us to understand how nanosystems driven away from equilibrium can manifest directionality and dynamical order.

cond-mat.stat-mech↗

arXiv2011

A two-stage approach to relaxation in billiard systems of locally confined hard spheres

We consider the three-dimensional dynamics of systems of many interacting hard spheres, each individually confined to a dispersive environment, and show that the macroscopic limit of such systems is characterized by a coefficient of heat conduction whose value reduces to a dimensional formula in the limit of vanishingly small rate of interaction. It is argued that this limit arises from an effective loss of memory. Similarities with the diffusion of a tagged particle in binary mixtures are emphasized.

cond-mat.stat-mech↗

arXiv2011

On the effectiveness of mixing in violent relaxation

Relaxation processes in collisionless dynamics lead to peculiar behavior in systems with long-range interactions such as self-gravitating systems, non-neutral plasmas and wave-particle systems. These systems, adequately described by the Vlasov equation, present quasi-stationary states (QSS), i.e. long lasting intermediate stages of the dynamics that occur after a short significant evolution called "violent relaxation". The nature of the relaxation, in the absence of collisions, is not yet fully understood. We demonstrate in this article the occurrence of stretching and folding behavior in numerical simulations of the Vlasov equation, providing a plausible relaxation mechanism that brings the system from its initial condition into the QSS regime. Area-preserving discrete-time maps with a mean-field coupling term are found to display a similar behaviour in phase space as the Vlasov system.

cond-mat.stat-mech↗

arXiv2011

Fluctuation theorems for capacitively coupled electronic currents

The counting statistics of electron transport is theoretically studied in a system with two capacitively coupled parallel transport channels. Each channel is composed of a quantum dot connected by tunneling to two reservoirs. The nonequilibrium steady state of the system is controlled by two affinities or thermodynamic forces, each one determined by the two reservoirs of each channel. The status of a single-current fluctuation theorem is investigated starting from the fundamental two-current fluctuation theorem, which is a consequence of microreversibility. We show that the single-current fluctuation theorem holds in the limit of a large Coulomb repulsion between the two parallel quantum dots, as well as in the limit of a large current ratio between the parallel channels. In this latter limit, the symmetry relation of the single-current fluctuation theorem is satisfied with respect to an effective affinity that is much lower than the affinity determined by the reservoirs. This back-action effect is quantitatively characterized.

cond-mat.mes-hall↗

arXiv2011

Nonlinear transport effects in mass separation by effusion

Generalizations of Onsager reciprocity relations are established for the nonlinear response coefficients of ballistic transport in the effusion of gaseous mixtures. These generalizations, which have been established on the basis of the fluctuation theorem for the currents, are here considered for mass separation by effusion. In this kinetic process, the mean values of the currents depend nonlinearly on the affinities or thermodynamic forces controlling the nonequilibrium constraints. These nonlinear transport effects are shown to play an important role in the process of mass separation. In particular, the entropy efficiency turns out to be significantly larger than it would be the case if the currents were supposed to depend linearly on the affinities.

cond-mat.stat-mech↗

arXiv2010

Stochastic approach and fluctuation theorem for ion transport

We present a stochastic approach for ion transport at the mesoscopic level. The description takes into account the self-consistent electric field generated by the fixed and mobile charges as well as the discrete nature of these latter. As an application we study the noise in the ion transport process, including the effect of the displacement current generated by the fluctuating electric field. The fluctuation theorem is shown to hold for the electric current with and without the displacement current.

cond-mat.stat-mech↗

arXiv2009

Noise-induced escape from bifurcating attractors: Symplectic approach in the weak-noise limit

The effect of noise is studied in one-dimensional maps undergoing transcritical, tangent, and pitchfork bifurcations. The attractors of the noiseless map become metastable states in the presence of noise. In the weak-noise limit, a symplectic two-dimensional map is associated with the original one-dimensional map. The consequences of their noninvertibility on the phase-space structures are discussed. Heteroclinic orbits are identified which play a key role in the determination of the escape rates from the metastable states. Near bifurcations, the critical slowing down justifies the use of a continuous-time approximation replacing maps by flows, which allows the analytic calculation of the escape rates. This method provides the universal scaling behavior of the escape rates at the bifurcations.

cond-mat.stat-mech↗

arXiv2009

Heat transport in stochastic energy exchange models of locally confined hard spheres

We study heat transport in a class of stochastic energy exchange systems that characterize the interactions of networks of locally trapped hard spheres under the assumption that neighbouring particles undergo rare binary collisions. Our results provide an extension to three-dimensional dynamics of previous ones applying to the dynamics of confined two-dimensional hard disks [Gaspard P & Gilbert T On the derivation of Fourier's law in stochastic energy exchange systems J Stat Mech (2008) P11021]. It is remarkable that the heat conductivity is here again given by the frequency of energy exchanges. Moreover the expression of the stochastic kernel which specifies the energy exchange dynamics is simpler in this case and therefore allows for faster and more extensive numerical computations.

cond-mat.stat-mech↗

arXiv2009

Fractality of the non-equilibrium stationary states of open volume-preserving systems: I. Tagged particle diffusion

Deterministic diffusive systems such as the periodic Lorentz gas, multi-baker map, as well as spatially periodic systems of interacting particles, have non-equilibrium stationary states with fractal properties when put in contact with particle reservoirs at their boundaries. We study the macroscopic limits of these systems and establish a correspondence between the thermodynamics of the macroscopic diffusion process and the fractality of the stationary states that characterize the phase-space statistics. In particular the entropy production rate is recovered from first principles using a formalism due to Gaspard [J. Stat. Phys. 88, 1215 (1997)]. This article is the first of two; the second article considers the influence of a uniform external field on such systems.

cond-mat.stat-mech↗

arXiv2009

Fractality of the non-equilibrium stationary states of open volume-preserving systems: II. Galton boards

Galton boards are models of deterministic diffusion in a uniform external field, akin to driven periodic Lorentz gases, here considered in the absence of dissipation mechanism. Assuming a cylindrical geometry with axis along the direction of the external field, the two-dimensional board becomes a model for one-dimensional mass transport along the direction of the external field. This is a purely diffusive process which admits fractal non-equilibrium stationary states under flux boundary conditions. Analytical results are obtained for the statistics of multi-baker maps modeling such a non-uniform diffusion process. A correspondence is established between the local phase-space statistics and their macroscopic counter-parts. The fractality of the invariant state is shown to be responsible for the positiveness of the entropy production rate.

cond-mat.stat-mech↗

arXiv2008

Fluctuation theorem for currents in open quantum systems

A quantum-mechanical framework is set up to describe the full counting statistics of particles flowing between reservoirs in an open system under time-dependent driving. A symmetry relation is obtained which is the consequence of microreversibility for the probability of the nonequilibrium work and the transfer of particles and energy between the reservoirs. In some appropriate long-time limit, the symmetry relation leads to a steady-state quantum fluctuation theorem for the currents between the reservoirs. On this basis, relationships are deduced which extend the Onsager-Casimir reciprocity relations to the nonlinear response coefficients.

cond-mat.stat-mech↗

arXiv2008

On the derivation of Fourier's law in stochastic energy exchange systems

We present a detailed derivation of Fourier's law in a class of stochastic energy exchange systems that naturally characterize two-dimensional mechanical systems of locally confined particles in interaction. The stochastic systems consist of an array of energy variables which can be partially exchanged among nearest neighbours at variable rates. We provide two independent derivations of the thermal conductivity and prove this quantity is identical to the frequency of energy exchanges. The first derivation relies on the diffusion of the Helfand moment, which is determined solely by static averages. The second approach relies on a gradient expansion of the probability measure around a non-equilibrium stationary state. The linear part of the heat current is determined by local thermal equilibrium distributions which solve a Boltzmann-like equation. A numerical scheme is presented with computations of the conductivity along our two methods. The results are in excellent agreement with our theory.

cond-mat.stat-mech↗

arXiv2008

Heat conduction and Fourier's law in a class of many particle dispersing billiards

We consider the motion of many confined billiard balls in interaction and discuss their transport and chaotic properties. In spite of the absence of mass transport, due to confinement, energy transport can take place through binary collisions between neighbouring particles. We explore the conditions under which relaxation to local equilibrium occurs on time scales much shorter than that of binary collisions, which characterize the transport of energy, and subsequent relaxation to local thermal equilibrium. Starting from the pseudo-Liouville equation for the time evolution of phase-space distributions, we derive a master equation which governs the energy exchange between the system constituents. We thus obtain analytical results relating the transport coefficient of thermal conductivity to the frequency of collision events and compute these quantities. We also provide estimates of the Lyapunov exponents and Kolmogorov-Sinai entropy under the assumption of scale separation. The validity of our results is confirmed by extensive numerical studies.

nlin.CD↗

arXiv2008

Heat conduction and Fourier's law by consecutive local mixing and thermalization

We present a first-principles study of heat conduction in a class of models which exhibit a new multi-step local thermalization mechanism which gives rise to Fourier's law. Local thermalization in our models occurs as the result of binary collisions among locally confined gas particles. We explore the conditions under which relaxation to local equilibrium, which involves no energy exchange, takes place on time scales shorter than that of the binary collisions which induce local thermalization. The role of this mechanism in multi-phase material systems such as aerogels is discussed.

cond-mat.stat-mech↗