arXiv subjects

Pierre Gratier

Publications and source records attributed to Pierre Gratier.

At least 37 records · Page 2Linked to original sources

arXiv2019

New constraints on the initial parameters of low-mass star formation from chemical modeling

The complexity of physico-chemical models of star formation is increasing, with models that take into account new processes and more realistic setups. These models allow astrochemists to compute the evolution of chemical species throughout star formation. Hence, comparing the outputs of such models to observations allows to bring new constraints on star formation. The work presented in this paper is based on the recent public release of a database of radiation hydrodynamical low-mass star formation models. We used this database as physical parameters to compute the time dependent chemical composition of collapsing cores with a 3-phase gas-grain model. The results are analyzed to find chemical tracers of the initial physical parameters of collapse such as the mass, radius, temperature, density, and free-fall time. They are also compared to observed molecular abundances of Class 0 protostars. We find numerous tracers of the initial parameters of collapse, except for the initial mass. More particularly, we find that gas phase CH3CN, NS and OCS trace the initial temperature, while H2CS trace the initial density and free-fall time of the parent cloud. The comparison of our results with a sample of 12 Class 0 low mass protostars allows us to constrain the initial parameters of collapse of low-mass prestellar cores. We find that low-mass protostars are preferentially formed within large cores with radii greater than 20000 au, masses between 2 and 4 Msol, temperatures lower or equal to 15 K, and densities between 6e4 and 2.5e5 part.cm-3, corresponding to free-fall times between 100 and 200 kyrs.

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arXiv2019

A dynamically young, gravitationally stable network of filaments in Orion B

Filaments are a key step on the path that leads from molecular clouds to star formation. However, their characteristics are heavily debated, and the exact processes that lead to their formation and fragmentation into dense cores still remain to be fully understood. We aim at characterising the mass, kinematics, and stability against gravitational collapse of a statistically significant sample of filaments in the Orion B molecular cloud, which is renown for its very low star formation efficiency. We characterise the gas column densities and kinematics over a field of 1.9 deg$^2$, using C$^{18}$O(J=1-0) data from the IRAM-30m large programme ORION-B. Using two different Hessian-based filters, we extract and compare two filamentary networks, each containing over 100 filaments. Independent of the extraction method, the filaments have widths of 0.12$\pm$0.04 pc, and show a wide range of linear (1 - 100 $M_{\odot}$pc$^{-1}$) and volume densities (2.10$^3$ - 2.10$^5$ cm$^{-3}$). Compared to previous studies, the filament population is dominated by low-density, thermally sub-critical structures, suggesting that most of the identified filaments are not collapsing to form stars. In fact, only ~1% of the Orion B cloud mass covered by our observations can be found in super-critical, star-forming filaments, explaining the low star formation efficiency of the region. The velocity profiles observed across the filaments show quiescence in the centre, and coherency in the plane of the sky, despite being mostly supersonic. The filaments in Orion B apparently belong to a continuum which contains a few elements comparable to already studied star-forming filaments as well as many lower-density, gravitationally unbound structures. This comprehensive study of the Orion B filaments shows that the mass fraction in super-critical filaments is a key factor in determining star formation efficiency.

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arXiv2019

Oxygen fractionation in dense molecular clouds

We have developed the first gas-grain chemical model for oxygen fractionation (also including sulphur fractionation) in dense molecular clouds, demonstrating that gas-phase chemistry generates variable oxygen fractionation levels, with a particularly strong effect for NO, SO, O2, and SO2. This large effect is due to the efficiency of the neutral 18O + NO, 18O + SO, and 18O + O2 exchange reactions. The modeling results were compared to new and existing observed isotopic ratios in a selection of cold cores. The good agreement between model and observations requires that the gas-phase abundance of neutral oxygen atoms is large in the observed regions. The S16O/S18O ratio is predicted to vary substantially over time showing that it can be used as a sensitive chemical proxy for matter evolution in dense molecular clouds.

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arXiv2018

Methyl cyanide (CH3CN) and propyne (CH3CCH) in the low mass protostar IRAS 16293-2422

Methyl cyanide (CH3CN) and propyne (CH3CCH) are two molecules commonly used as gas thermometers for interstellar gas. They are detected in several astrophysical environments and in particular towards protostars. Using data of the low-mass protostar IRAS 16293-2422 obtained with the IRAM 30m single-dish telescope, we constrained the origin of these two molecules in the envelope of the source. The line shape comparison and the results of a radiative transfer analysis both indicate that the emission of CH3CN arises from a warmer and inner region of the envelope than the CH3CCH emission. We compare the observational results with the predictions of a gas-grain chemical model. Our model predicts a peak abundance of CH3CCH in the gas-phase in the outer part of the envelope, at around 2000 au from the central star, which is relatively close to the emission size derived from the observations. The predicted CH3CN abundance only rises at the radius where the grain mantle ices evaporate, with an abundance similar to the one derived from the observations.

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arXiv2018

Statistical study of uncertainties in the diffusion rate of species on interstellar ice and its impact on chemical model predictions

Context: Diffusion of species on the dust surface is a key process for determining the chemical composition of interstellar ices. On the dust surface, adsorbed species diffuse from one potential well to another and react with other adsorbed reactants, resulting in the formation of simple and complex molecules. Aims: We study the impact on the abundances of the species simulated by the chemical codes by considering the uncertainties in the diffusion energy of adsorbed species. We aim to limit the uncertainties in the abundances as calculated by chemical codes by identifying the surface species that result in a larger error because of the uncertainties in their diffusion energy. Methods: We ran various cases with 2000 to 10000 simulations in each case and varied the diffusion energies of some or all surface species randomly. We calculated Pearson correlation coefficients between the abundances and the ratio of diffusion to binding energy of adsorbed species. We identified the species that introduce maximum uncertainty in the ice and gas-phase abundances. With these species we ran three sets, with 2000 simulations in each, to quantify the uncertainties they introduce. Results: We present the abundances of various molecules in the gas phase and also on the dust surface at different time intervals during the simulation. We show which species produce a large uncertainty in the abundances. We sorted species into different groups in accordance with their importance in propagating uncertainty in the chemical network. Conclusions: We show that CO, H$_2$, O, N, and CH$_3$ are the key species for uncertainties in the abundances, while CH$_2$, HCO, S and O$_2$ come next, followed by NO, HS, and CH. We also show that by limiting the uncertainties in the ratio of diffusion to binding energy of these species, we can eliminate the uncertainties in the gas-phase abundances of almost all the species.

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arXiv2018

Detection of HOCO+ in the protostar IRAS 16293-2422

The protonated form of CO2, HOCO+, is assumed to be an indirect tracer of CO2 in the millimeter/submillimeter regime since CO2 lacks a permanent dipole moment. Here, we report the detection of two rotational emission lines (4 0,4-3 0,3) and (5 0,5-4 0,4) of HOCO+ in IRAS 16293-2422. For our observations, we have used EMIR heterodyne 3 mm receiver of the IRAM 30m telescope. The observed abundance of HOCO+ is compared with the simulations using the 3-phase NAUTILUS chemical model. Implications of the measured abundances of HOCO+ to study the chemistry of CO2 ices using JWST-MIRI and NIRSpec are discussed as well.

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arXiv2018

Triggering the formation of the supergiant H II region NGC 604 in M33

Formation mechanism of a supergiant H II region NGC 604 is discussed in terms of collision of H I clouds in M33. An analysis of the archival H I data obtained with the Very Large Array (VLA) reveals complex velocity distributions around NGC 604. The H I clouds are composed of two velocity components separated by ~ 20 km s^-1 for an extent of ~ 700 pc, beyond the size of the the H II region. Although the H I clouds are not easily separated in velocity with some mixed component represented by merged line profiles, the atomic gas mass amounts to 6 x 10^6 M_Sol and 9 x 10^6 M_Sol for each component. These characteristics of H I gas and the distributions of dense molecular gas in the overlapping regions of the two velocity components suggest that the formation of giant molecular clouds and the following massive cluster formation have been induced by the collision of H I clouds with different velocities. Referring to the existence of gas bridging feature connecting M33 with M31 reported by large-scale HI surveys, the disturbed atomic gas possibly represent the result of past tidal interaction between the two galaxies, which is analogous to the formation of the R136 cluster in the LMC.

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arXiv2018

Properties and rotation of molecular clouds in M 33

The sample of 566 molecular clouds identified in the CO(2--1) IRAM survey covering the disk of M~33 is explored in detail.The clouds were found using CPROPS and were subsequently catalogued in terms of their star-forming properties as non-star-forming (A), with embedded star formation (B), or with exposed star formation C.We find that the size-linewidth relation among the M~33 clouds is quite weak but, when comparing with clouds in other nearby galaxies, the linewidth scales with average metallicity.The linewidth and particularly the line brightness decrease with galactocentric distance.The large number of clouds makes it possible to calculate well-sampled cloud mass spectra and mass spectra of subsamples.As noted earlier, but considerably better defined here, the mass spectrum steepens (i.e. higher fraction of small clouds) with galactocentric distance.A new finding is that the mass spectrum of A clouds is much steeper than that of the star-forming clouds.Further dividing the sample, this difference is strong at both large and small galactocentric distances and the A vs C difference is a stronger effect than the inner/outer disk difference in mass spectra.Velocity gradients are identified in the clouds using standard techniques.The gradients are weak and are dominated by prograde rotation; the effect is stronger for the high signal-to-noise clouds.A discussion of the uncertainties is presented.The angular momenta are low but compatible with at least some simulations.The cloud and galactic gradients are similar; the cloud rotation periods are much longer than cloud lifetimes and comparable to the galactic rotation period.The rotational kinetic energy is 1-2\% of the gravitational potential energy and the cloud edge velocity is well below the escape velocity, such that cloud-scale rotation probably has little influence on the evolution of molecular clouds.

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arXiv2017

First detection of interstellar S2H

We present the first detection of gas phase S2H in the Horsehead, a moderately UV-irradiated nebula. This confirms the presence of doubly sulfuretted species in the interstellar medium and opens a new challenge for sulfur chemistry. The observed S2H abundance is ~5x10$^{-11}$, only a factor 4-6 lower than that of the widespread H2S molecule. H2S and S2H are efficiently formed on the UV-irradiated icy grain mantles. We performed ice irradiation experiments to determine the H2S and S2H photodesorption yields. The obtained values are ~1.2x10$^{-3}$ and <1x10$^{-5}$ molecules per incident photon for H2S and S2H, respectively. Our upper limit to the S2H photodesorption yield suggests that photo-desorption is not a competitive mechanism to release the S2H molecules to the gas phase. Other desorption mechanisms such as chemical desorption, cosmic-ray desorption and grain shattering can increase the gaseous S2H abundance to some extent. Alternatively, S2H can be formed via gas phase reactions involving gaseous H2S and the abundant ions S+ and SH+. The detection of S2H in this nebula could be therefore the result of the coexistence of an active grain surface chemistry and gaseous photo-chemistry.

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arXiv2017

Clustering the Orion B giant molecular cloud based on its molecular emission

Previous attempts at segmenting molecular line maps of molecular clouds have focused on using position-position-velocity data cubes of a single line to separate the spatial components of the cloud. In contrast, wide field spectral imaging with large spectral bandwidth in the (sub)mm domain now allows to combine multiple molecular tracers to understand the different physical and chemical phases that constitute giant molecular clouds. We aim at using multiple tracers (sensitive to different physical processes) to segment a molecular cloud into physically/chemically similar regions (rather than spatially connected components). We use a machine learning clustering method (the Meanshift algorithm) to cluster pixels with similar molecular emission, ignoring spatial information. Simple radiative transfer models are used to interpret the astrophysical information uncovered by the clustering. A clustering analysis based only on the J=1-0 lines of 12CO, 13CO and C18O reveals distinct density/column density regimes (nH~100, 500, and >1000 cm-3), closely related to the usual definitions of diffuse, translucent and high-column-density regions. Adding two UV-sensitive tracers, the (1-0) lines of HCO+ and CN, allows us to distinguish two clearly distinct chemical regimes, characteristic of UV-illuminated and UV-shielded gas. The UV-illuminated regime shows overbright HCO+ and CN emission, which we relate to photochemical enrichment. We also find a tail of high CN/HCO+ intensity ratio in UV-illuminated regions. Finer distinctions in density classes (nH~7E3, and 4E4 cm-3) for the densest regions are also identified, likely related to the higher critical density of the CN and HCO+ (1-0) lines. The association of simultaneous multi-line, wide-field mapping and powerful machine learning methods such as the Meanshift algorithm reveals how to decode the complex information available in molecular tracers.

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arXiv2017

Methyl isocyanate CH3NCO: An important missing organic in current astrochemical networks

Methyl isocyanate (CH3NCO) is one of the important complex organic molecules detected on the comet 67P/Churyumov-Gerasimenko by Rosetta's Philae lander. It was also detected in hot cores around high-mass protostars along with a recent detection in the solar-type protostar IRAS 16293-2422. We propose here a gas-grain chemical model to form CH3NCO after reviewing various formation pathways with quantum chemical computations. We have used NAUTILUS 3-phase gas-grain chemical model to compare observed abundances in the IRAS 16293-2422. Our chemical model clearly indicates the ice phase origin of CH3NCO.

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arXiv2017

The interstellar chemistry of C3H and C3H2 isomers

We report the detection of linear and cyclic isomers of C3H and C3H2 towards various starless cores and review the corresponding chemical pathways involving neutral (C3Hx with x=1,2) and ionic (C3Hx+ with x = 1,2,3) isomers. We highlight the role of the branching ratio of electronic Dissociative Recombination (DR) reactions of C3H2+ and C3H3+ isomers showing that the statistical treatment of the relaxation of C3H* and C3H2* produced in these DR reactions may explain the relative c,l-C3H and c,l-C3H2 abundances. We have also introduced in the model the third isomer of C3H2 (HCCCH). The observed cyclic-to-linear C3H2 ratio vary from 110 + or - 30 for molecular clouds with a total density around 1e4 molecules.cm-3 to 30 + or - 10 for molecular clouds with a total density around 4e5 molecules.cm-3, a trend well reproduced with our updated model. The higher ratio for low molecular cloud densities is mainly determined by the importance of the H + l-C3H2 -> H + c-C3H2 and H + t-C3H2 -> H + c-C3H2 isomerization reactions.

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arXiv2017

A new study of the chemical structure of the Horsehead nebula: the influence of grain-surface chemistry

A wide variety of molecules have recently been detected in the Horsehead nebula photodissociation region (PDR) suggesting that: (i) gas-phase and grain chemistries should both contribute to the formation of organic molecules, and (ii) far-ultraviolet (FUV) photodesorption may explain the release into the gas phase of grain surface species. In order to tackle these specific problems and more generally in order to better constrain the chemical structure of these types of environments we present a study of the Horsehead nebula gas-grain chemistry. To do so we used the 1D astrochemical gas-grain code Nautilus with an appropriate physical structure computed with the Meudon PDR Code and compared our modeled outcomes with published observations and with previously modeled results when available. The use of a large set of chemical reactions coupled with the time-dependent code Nautilus allows us to reproduce most of the observations well, including those of the first detections in a PDR of the organic molecules HCOOH, CH2CO, CH3CHO and CH3CCH, which are mostly associated with hot cores. We also provide some abundance predictions for other molecules of interest. Understanding the chemistry behind the detection of these organic molecules is crucial to better constrain the environments these molecules can probe.

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arXiv2017

On the reservoir of sulphur in dark clouds : chemistry and elemental abundance reconciled

Sulphur-bearing species are often used to probe the physical structure of star forming regions of the interstellar medium, but the chemistry of sulphur in these regions is still poorly understood. In dark clouds, sulphur is supposed to be depleted under a form which is still unknown despite numerous observations and chemical modeling studies that have been performed. In order to improve the modeling of sulphur chemistry, we propose an enhancement of the sulphur chemical network using experimental and theoretical literature. We test the effect of the updated network on the outputs of a three phases gas-grain chemical model for dark cloud conditions using different elemental sulphur abundances. More particularly, we focus our study on the main sulphur reservoirs as well as on the agreement between model predictions and the abundances observed in the dark cloud TMC-1 (CP). Our results show that depending on the age of the observed cloud, the reservoir of sulphur could either be atomic sulphur in the gas-phase or HS and H2S in icy grain bulks. We also report the first chemical model able to reproduce the abundances of observed S-bearing species in TMC-1 (CP) using as elemental abundance of sulphur its cosmic value.

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arXiv2017

From molecules to Young Stellar Clusters: the star formation cycle across the M33 disk

To shed light on the time evolution of local star formation episodes in M33, we study the association between 566 Giant Molecular Clouds (GMCs), identified through the CO (J=2-1) IRAM-all-disk survey, and 630 Young Stellar Cluster Candidates (YSCCs), selected via Spitzer-24~$μ$m emission. The spatial correlation between YSCCs and GMCs is extremely strong, with a typical separation of 17~pc, less than half the CO(2--1) beamsize, illustrating the remarkable physical link between the two populations. GMCs and YSCCs follow the HI filaments, except in the outermost regions where the survey finds fewer GMCs than YSCCs, likely due to undetected, low CO-luminosity clouds. The GMCs have masses between 2$\times 10^4$ and 2$\times 10^6$ M$_\odot$ and are classified according to different cloud evolutionary stages: inactive clouds are 32$\%$ of the total, classified clouds with embedded and exposed star formation are 16$\%$ and 52$\%$ of the total respectively. Across the regular southern spiral arm, inactive clouds are preferentially located in the inner part of the arm, possibly suggesting a triggering of star formation as the cloud crosses the arm. Some YSCCs are embedded star-forming sites while the majority have GALEX-UV and H$α$ counterparts with estimated cluster masses and ages. The distribution of the non-embedded YSCC ages peaks around 5~Myrs with only a few being as old as 8--10~Myrs. These age estimates together with the number of GMCs in the various evolutionary stages lead us to conclude that 14~Myrs is a typical lifetime of a GMC in M33, prior to cloud dispersal. The inactive and embedded phases are short, lasting about 4 and 2~Myrs respectively. This underlines that embedded YSCCs rapidly break out from the clouds and become partially visible in H$α$ or UV long before cloud dispersal.

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arXiv2017

Dissecting the molecular structure of the Orion B cloud: Insight from Principal Component Analysis

Context. The combination of wideband receivers and spectrometers currently available in (sub-)millimeter observatories deliver wide- field hyperspectral imaging of the interstellar medium. Tens of spectral lines can be observed over degree wide fields in about fifty hours. This wealth of data calls for restating the physical questions about the interstellar medium in statistical terms. Aims. We aim at gaining information on the physical structure of the interstellar medium from a statistical analysis of many lines from different species over a large field of view, without requiring detailed radiative transfer or astrochemical modeling. Methods. We coupled a nonlinear rescaling of the data with one of the simplest multivariate analysis methods, namely the Principal Component Analysis, to decompose the observed signal into components that we interpret first qualitatively and then quantitatively based on our deep knowledge of the observed region and of the astrochemistry at play. Results. We identify 3 principal components, linear compositions of line brightness temperatures, that are correlated at various levels with the column density, the volume density and the UV radiation field. Conclusions. When sampling a sufficiently diverse mixture of physical parameters, it is possible to decompose the molecular emission in order to gain physical insight on the observed interstellar medium. This opens a new avenue for future studies of the interstellar medium.

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arXiv2017

Turbulence and star formation efficiency in molecular clouds: solenoidal versus compressive motions in Orion B

The nature of turbulence in molecular clouds is one of the key parameters that control star formation efficiency: compressive motions, as opposed to solenoidal motions, can trigger the collapse of cores, or mark the expansion of Hii regions. We try to observationally derive the fractions of momentum density ($ρv$) contained in the solenoidal and compressive modes of turbulence in the Orion B molecular cloud and relate these fractions to the star formation efficiency in the cloud. The implementation of a statistical method developed by Brunt & Federrath (2014), applied to a $^{13}$CO(J=1-0) datacube obtained with the IRAM-30m telescope, allows us to retrieve 3-dimensional quantities from the projected quantities provided by the observations, yielding an estimate of the compressive versus solenoidal ratio in various regions of the cloud. Despite the Orion B molecular cloud being highly supersonic (mean Mach number $\sim$ 6), the fractions of motion in each mode diverge significantly from equipartition. The cloud's motions are on average mostly solenoidal (excess > 8 % with respect to equipartition), which is consistent with its low star formation rate. On the other hand, the motions around the main star-forming regions (NGC 2023 and NGC 2024) prove to be strongly compressive. We have successfully applied to observational data a method that was so far only tested on simulations, and have shown that there can be a strong intra-cloud variability of the compressive and solenoidal fractions, these fractions being in turn related to the star formation efficiency. This opens a new possibility for star-formation diagnostics in galactic molecular clouds.

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arXiv2016

The anatomy of the Orion B Giant Molecular Cloud: A local template for studies of nearby galaxies

We aim to develop the Orion B Giant Molecular Cloud (GMC) as a local template for interpreting extra-galactic molecular line observations. We use the wide-band receiver at the IRAM-30m to spatially and spectrally resolve the Orion B GMC. The observations cover almost 1 square degree at 26" resolution with a bandwidth of 32 GHz from 84 to 116 GHz in only two tunings. Among the mapped spectral lines are the 12CO, 13CO, C18O, C17O, HCN, HNC, 12CN, CCH, HCO+, N2H+ (1-0), and 12CS, 32SO, SiO, c-C3H2, CH3OH (2-1) transitions. We introduce the molecular anatomy of the Orion B GMC, including relations between line intensities and gas column density or far-UV radiation fields, and correlations between selected line and line ratios. We also obtain a dust-traced gas mass that is less than about one third the CO-traced mass, using the standard Xco conversion factor. The presence of overluminous CO can be traced back to the dependence of the CO intensity on UV illumination. In fact, while most lines show some dependence on the UV radiation field, CN and CCH are the most sensitive. Moreover dense cloud cores are almost exclusively traced by N2H+. Other traditional high density tracers, such as HCN (1-0), are also easily detected in extended translucent regions at a typical density of about 500 H2 cm-3. In general, we find no straightforward relation between line critical density and the fraction of the line luminosity coming from dense gas regions. Our initial findings demonstrate that the relations between line (ratio) intensities and environment in GMCs are more complicated than often assumed. Sensitivity (i.e., the molecular column density), excitation, and above all chemistry contribute to the observed line intensity distributions. They must be considered together when developing the next generation of extra-galactic molecular line diagnostics of mass, density, temperature and radiation field.

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