arXiv subjects

Pierre Hily-Blant

Publications and source records attributed to Pierre Hily-Blant.

At least 19 recordsLinked to original sources

arXiv2026

Chemistry and ro-vibrational excitation of CH$^+$ in the planetary nebula NGC 7027

Small carbon hydride cations, such as the methylidyne ion (CH$^+$), play an important role in the chemistry of the interstellar medium (ISM). They participate in gas-phase reaction networks leading to the formation of hydrocarbon species that act as precursors to more complex organic molecules. CH$^+$ is a highly reactive ion that is rapidly destroyed by H, H$_2$, and free electrons, making its excitation challenging to model. Its level populations depend not only on radiative and inelastic processes but also on chemical formation and destruction rates, a mechanism known as chemical pumping. We investigate this effect using a new set of ab initio state-resolved ro-vibrational (reactive and inelastic) collision data to model the observed CH$^+$ emission. Multiple rotational and ro-vibrational transitions of CH$^+$ detected toward the planetary nebula NGC 7027 are analyzed. The chemical structure of CH$^+$ is modeled with the CLOUDY code using updated reaction rates, providing the temperature and density structure across the nebula. A non-local thermodynamic equilibrium (NLTE) analysis is performed using CLOUDY and the single-zone RADEX code with a comprehensive set of spectroscopic and collisional data. In addition, chemical formation and destruction processes are implemented in RADEX and explored via Markov Chain Monte Carlo sampling. The CLOUDY model reproduces the observed CH$^+$ line fluxes within a factor of 1.3 on average. It indicates that rotational and ro-vibrational lines arise from physically distinct regions, primarily differing in temperature. RADEX models show that chemical pumping significantly enhances populations above ($\upsilon = 0, J = 1$), strongly increasing ro-vibrational emission, especially in the $\upsilon =2 \to 1$ band. Single-zone models remain limited, highlighting the need for full 1D modeling including all excitation processes.

astro-ph.GA↗

arXiv2025

Probing the Molecular Hearts of Extreme Bipolar Planetary Nebulae with ALMA

We present results from a program of Atacama Large Millimeter Array (ALMA) 1.3 mm (Band 6) molecular line mapping of a sample of nearby, bipolar/pinched-waist, molecule-rich PNe (NGC 6302, Hubble 5, NGC 2440, NGC 6445, NGC 2899, and NGC 2818). Maps of $^{12}$CO(2$-$1) and $^{13}$CO(2$-$1) emission as well as emission lines of HCN, HNC, HCO$^+$, CN, and CS $-$ many of these detected in these PNe for the first time $-$ reveal the molecular mass distributions, compositions, and velocity fields of the equatorial and, in some cases, polar regions of the sample PNe. In each case, the bulk of the molecular gas traces an expanding equatorial torus, with torus expansion velocities ranging from $\sim$15 to $\sim$50 km s$^{-1}$ and molecular masses from $\sim$0.002 to $\sim$0.1 $M_\odot$. The inferred molecular torus dynamical ages, which span the range $\sim$500 yr (Hb 5) to $\sim$11000 yr (NGC 2818), provide support for a model wherein molecular torus ejection precedes bipolar lobe formation. Collectively, these ALMA survey results provide insight into the rapid structural evolution as well as the zones of irradiated molecular gas within bipolar PNe that are descended from relatively massive progenitors, likely residing in interacting binary systems, over $\sim$10 kyr of the post-AGB evolution of such systems.

astro-ph.GA↗

arXiv2025

Chemistry and ro-vibrational excitation of HeH$^+$ in the Planetary Nebula NGC 7027

HeH$^+$ belongs to the class of "reactive" ions that can be destroyed so quickly that chemical formation and destruction rates may compete with inelastic rates and should be considered when solving the statistical equilibrium equations. This so-called chemical "pumping" or "excitation" effect is investigated here for the first time in HeH$^+$. The chemical evolution of HeH$^+$ in NGC 7027 is modeled with the CLOUDY photoionization code using updated reaction rate coefficients. The non-LTE analysis of the three observed HeH$^+$ emission lines is then performed with the CLOUDY and RADEX codes using an extensive set of spectroscopic and inelastic collisional data suitable for the specific high-temperature environment of NGC 7027. In a second approach, chemical formation and destruction rates of HeH$^+$ are implemented in RADEX. This code is combined with MCMC sampling (performed on the RADEX-parameters space) to extract the best-fit HeH$^+$ column density and physical conditions from the observed line fluxes. The CLOUDY and RADEX non-LTE results are found to be in good agreement, and the $\upsilon=1-0 \ P(2)/P(1)$ line ratio is better than 20%. Agreement to better than a factor of 2.3 is obtained when including the reaction between He($2^3S$) and H as an additional source of HeH$^+$. The RADEX/MCMC model with chemical pumping is found to reproduce both the observed line fluxes and the line ratio to 20%. Our results suggest that additional HeH$^+$ lines must be detected in NGC 7027 to better constrain the physical conditions via non-LTE models. Uncertainties in collisional (reactive and inelastic) data of HeH$^+$ have been largely reduced in this work. The three observed lines are not sensitive to chemical pumping while excited "short-lived" levels are significantly overpopulated with respect to a non-LTE model neglecting chemical excitation.

astro-ph.GA↗

arXiv2024

Fate and detectability of rare gas hydride ions in nova ejecta: A case study with nova templates

HeH$^+$ was the first heteronuclear molecule to form in the metal-free Universe after the Big Bang. The molecule gained significant attention following its first circumstellar detection in the young and dense planetary nebula NGC 7027. We target some hydride ions associated with the noble gases (HeH$^+$, ArH$^+$, and NeH$^+$) to investigate their formation in harsh environments like the nova outburst region. We use a photoionization modeling (based on previously published best-fit physical parameters) of the moderately fast ONe type nova, QU Vulpeculae 1984, and the CO type novae, RS Ophiuchi and V1716 Scorpii. Our steady-state modeling reveals a convincing amount of HeH$^+$, especially in the dense clump of RS Ophiuchi and V1716 Scorpii. The calculated upper limit on the surface brightness of HeH$^+$ transitions suggests that the James Webb Space Telescope (JWST) could detect some of them, particularly in sources like RS Ophiuchi and V1716 Scorpii, which have similar physical and chemical conditions and evolution. It must be clearly noted that the sources studied are used as templates, and not as targets for observations. The detection of these lines could be useful for determining the physical conditions in similar types of systems and for validating our predictions based on new electron-impact ro-vibrational collisional data at temperatures of up to 20,000 K.

astro-ph.GA↗

arXiv2024

ALMA Observations of Molecular Line Emission from High-excitation Bipolar Planetary Nebulae

We present early results from our program of ALMA Band 6 (1.3mm) molecular line mapping of a sample of nearby, well-studied examples of high-excitation, bipolar/pinched-waist and molecule-rich planetary nebulae (Hubble 5 and NGC 2440, 2818, 2899, 6302, and 6445). We have mapped these planetary nebulae (PNe) in isotopologues of CO as well as various molecular line tracers of high-energy irradiation, such as HCN, CN, HNC, and HCO+, with the complementary goals of establishing nebular kinematics as well as the zones of UV-heated and X-ray-ionized molecular gas within each nebula. The resulting high-resolution ALMA molecular emission-line maps reveal the regions of high-excitation bipolar PNe in which molecular gas, presumably ejected during asymptotic giant branch stages of the PN progenitor stars, survives and evolves chemically. We present a summary of molecular species detected to date in the sample nebulae, and we use example results for one PN (NGC 6455) to demonstrate the power of the ALMA data in revealing the structures, kinematics, and compositions of the equatorial molecular tori that are a common feature of the sample objects.

astro-ph.SR↗

arXiv2023

Identification of Ammonium Salts on Comet 67P/C-G Surface from Infrared VIRTIS/Rosetta Data Based on Laboratory Experiments. Implications and Perspectives

The nucleus of comet 67P/Churyumov-Gerasimenko exhibits a broad spectral reflectance feature around 3.2 $μ$m, which is omnipresent in all spectra of the surface, and whose attribution has remained elusive since its discovery. Based on laboratory experiments, we have shown that most of this absorption feature is due to ammonium (NH4+) salts mixed with the dark surface material. The depth of the band is compatible with semi-volatile ammonium salts being a major reservoir of nitrogen in the comet, which could dominate over refractory organic matter and volatile species. These salts may thus represent the long-sought reservoir of nitrogen in comets, possibly bringing their nitrogen-to-carbon ratio in agreement with the solar value. Moreover, the reflectance spectra of several asteroids are compatible with the presence of NH4+ salts at their surfaces. The presence of such salts, and other NH4+-bearing compounds on asteroids, comets, and possibly in proto-stellar environments, suggests that NH4+ may be a tracer of the incorporation and transformation of nitrogen in ices, minerals and organics, at different phases of the formation of the Solar System.

astro-ph.EP↗

arXiv2022

Mapping NGC 7027 in New Light: CO$^+$ and HCO$^+$ Emission Reveal Its Photon- and X-ray-Dominated Regions

The young and well-studied planetary nebula NGC 7027 harbors significant molecular gas that is irradiated by luminous, point-like UV (central star) and diffuse (shocked nebular) X-ray emission. This nebula represents an excellent subject to investigate the molecular chemistry and physical conditions within photon- and X-ray-dominated regions (PDRs and XDRs). As yet, the exact formation routes of CO$^+$ and HCO$^+$ in PN environments remain uncertain. Here, we present $\sim$2$"$ resolution maps of NGC 7027 in the irradiation tracers CO$^+$ and HCO$^+$, obtained with the IRAM NOEMA interferometer, along with SMA CO and HST 2.12~$μ$m H$_2$ data for context. The CO$^+$ map constitutes the first interferometric map of this molecular ion in any PN. Comparison of CO$^+$ and HCO$^+$ maps reveal strikingly different emission morphologies, as well as a systematic spatial displacement between the two molecules; the regions of brightest HCO$^+$, found along the central waist of the nebula, are radially offset by $\sim$1$"$ ($\sim$900 au) outside the corresponding CO$^+$ emission peaks. The CO$^+$ emission furthermore precisely traces the inner boundaries of the nebula's PDR (as delineated by near-IR H$_2$ emission), suggesting that central star UV emission drives CO$^+$ formation. The displacement of HCO$^+$ radially outward with respect to CO$^+$ is indicative that dust-penetrating soft X-rays are responsible for enhancing the HCO$^+$ abundance in the surrounding molecular envelope, forming an XDR. These interferometric CO$^+$ and HCO$^+$ observations of NGC 7027 thus clearly establish the spatial distinction between the PDR and XDR formed (respectively) by intense UV and X-ray irradiation of molecular gas.

astro-ph.GA↗

arXiv2021

Sampling Molecular Gas in the Helix Planetary Nebula: Variation in HNC/HCN with UV Flux

Observations of molecular clouds, prestellar cores, and protoplanetary disks have established that the HNC/HCN ratio may be a potent diagnostic of molecular gas physical conditions. The processes that govern the relative abundances of these molecules nevertheless remain poorly understood. We seek to exploit the wide range of UV irradiation strengths within the 1 pc diameter Helix planetary nebula to explore the potential role of UV radiation in driving HNC/HCN. We performed IRAM 30 m and APEX 12 m radio line observations across six positions within the Helix Nebula, making use of radiative transfer and photodissociation modeling codes to interpret the results for line intensities and line ratios in terms of the molecular gas properties. We have obtained the first detections of the plasma-embedded Helix molecular knots (globules) in HCN, HNC, HCO+, and other trace molecules. Analysis of the HNC/HCN integrated line intensity ratio reveals an increase with radial distance from the Helix central star. In the context of molecular line ratios of other planetary nebulae from the literature, the HNC/HCN ratio appears to be anticorrelated with UV emission over four orders of magnitude in incident flux. Models of the photodissociation regions within the Helix using the RADEX and Meudon codes reveal strong constraints on column density of the molecular gas, as well as pressure and temperature. Analysis of the molecular ion HCO+ across the Helix indicates that X-ray irradiation is likely driving HCO+ production in the outer regions of planetary nebulae, where photodissociation is limited, yet cold gas and ionized molecules are abundant. Although the observational results clearly indicate that UV irradiation is important in determining the HNC/HCN ratio, our PDR modeling indicates that the UV flux gradient alone cannot reproduce the observed variation of HNC/HCN across the Helix.

astro-ph.GA↗

arXiv2021

Rotational excitation of H$_3$O$^+$ cations by para-H$_2$: improved collisional data at low temperatures

The hydronium cation plays a crucial role in interstellar oxygen and water chemistry. While its spectroscopy was extensively investigated earlier, the collisional excitation of H$_3$O$^+$ is not well studied yet. In this work we present state-to-state collisional data for rotational de-excitation of both ortho- and para-H$_3$O$^+$ due to para-H$_2$ impact. The cross sections are calculated within the close-coupling formalism using our recent, highly accurate rigid-rotor potential energy surface for this collision system. The corresponding thermal rate coefficients are calculated up to 100 K. For para-H$_3$O$^+$ the lowest 20 rotation-inversion states were considered in the calculations, while for ortho-H$_3$O$^+$ the lowest 11 states are involved (up to $j\leq5$), so all levels with rotational energy below 420 K (292 cm$^{-1}$) are studied. In order to analyse the impact of the new collisional rates on the excitation of H$_3$O$^+$ in astrophysical environments radiative transfer calculations are also provided. The most relevant emission lines from an astrophysical point of view are studied, taking into account the transitions at 307, 365, 389 and 396 GHz. We show that our new collisional data have a non-negligible impact (from a few percents up to about a factor of 3) on the brightness and excitation temperatures of H$_3$O$^+$, justifying the revision of the physical conditions in the appropriate astrophysical observations. The calculated rate coefficients allow one to recalculate the column density of hydronium in interstellar clouds, which can lead to a better understanding of interstellar water and oxygen chemistry.

physics.chem-ph↗

arXiv2020

Efficient methanol production on the dark side of a prestellar core

We present ALMA maps of the starless molecular cloud core Ophiuchus/H-MM1 in the lines of deuterated ammonia (ortho-NH2D), methanol (CH3OH), and sulphur monoxide (SO). The dense core is seen in NH2D emission, whereas the CH3OH and SO distributions form a halo surrounding the core. Because methanol is formed on grain surfaces, its emission highlights regions where desorption from grains is particularly efficient. Methanol and sulphur monoxide are most abundant in a narrow zone that follows the eastern side of the core. This side is sheltered from the stronger external radiation field coming from the west. We show that photodissociation on the illuminated side can give rise to an asymmetric methanol distribution, but that the stark contrast observed in H-MM1 is hard to explain without assuming enhanced desorption on the shaded side. The region of the brightest emission has a wavy structure that rolls up at one end. This is the signature of Kelvin-Helmholtz instability occurring in sheared flows. We suggest that in this zone, methanol and sulphur are released as a result of grain-grain collisions induced by shear vorticity.

astro-ph.GA↗

arXiv2019

Multiple nitrogen reservoirs in a protoplanetary disk at the epoch of comet and giant planet formation

The isotopic ratio of nitrogen measured in primitive Solar System bodies shows a broad range of values, the origin of which remains unknown. One key question is whether these isotopic reservoirs of nitrogen predate the comet formation stage or are posterior to it. Another central question is elucidating the processes that can produce the observed variations in the 14N/15N isotopic ratio. Disks that orbit pre-main-sequence stars provide unique opportunities for observing the chemical content of analogs of the protosolar nebula and therefore for building a comprehensive scenario for the origin of nitrogen in the Solar System and in planet-forming disks. We present spectrally and spatially resolved observations of the hyperfine structure of the 4-3 rotational transition of HCN and its main isotopologs H13CN and HC15N in the disk orbiting the 8 Myr old TTauri star TW Hya. The spatially averaged HCN/H13CN and HCN/HC15N abundance ratios are 86+/-4 and 223+/-21, respectively. The latter value is significantly lower than the CN:C15N ratio 323+/-30 in this disk and thus provides the first evidence that two isotopic reservoirs of nitrogen are present in a disk at the stage of giant planet and comet formation. Furthermore, we find clear evidence for an increase in the ratio of HCN to HC15N with radius. The ratio in the outer disk is 339+/-28, in excellent agreement with direct measurements in the local interstellar medium, and with the bulk nitrogen isotopic ratio predicted from galactic evolution calculations. In the comet formation region at r=20 au, the ratio is a factor ~3 lower, 121+/-11. This radial increase qualitatively agrees with the scenario in which selective photodissociation of N 2 is the dominant fractionation process. However, our isotopic ratios and kinetic temperature of the HCN-emitting layers quantitatively disagree with models of nitrogen chemistry in disks.

astro-ph.GA↗

arXiv2018

Abundance of HCN and its C and N isotopologues in L1498

The isotopic ratio of nitrogen in nearby protoplanetary disks, recently measured in CN and HCN, indicates that a fractionated reservoir of nitrogen is available at the stage of comet formation. This reservoir presents a 3:1 enrichment in 15N relative to the elemental ratio of 330, identical to that between comets and the sun, suggesting that similar processes are responsible for the fractionation in the protosolar nebula (PSN) and in PSN analogs. However, how the fractionation of nitrogen takes place is an open question. Previously obtained HCN/HC15N abundance ratios suggest that HCN may be enriched in 15N in prestellar cores, although doubts remain on these measurements, which rely on the double-isotopologue method. Here we present direct measurements of the HCN/H13CN and HCN/HC15N abundance ratios in the L1498 prestellar core based on spatially resolved spectra of HCN(1-0), (3-2), H13CN(1-0), and HC15N(1-0). We use state-of-the-art radiative transfer calculations using ALICO, a 1D radiative transfer code capable of treating hyperfine (hf) overlaps. From an analysis of dust emission maps of L1498, we derive a new physical structure. We also use new, high-accuracy HCN-H2 hf collisional rates, which enable us to quantitatively reproduce all the features of the HCN(1-0) and HCN(3-2) spectra, especially the anomalous hf line ratios. Special attention is devoted to derive meaningful uncertainties on the abundance ratios. The obtained values, HCN/H13CN=45(3) and HCN/HC15N=338(28), indicate that carbon is fractionated in HCN, but nitrogen is not. For the HCN/HC15N abundance ratio, our study validates to some extent analyses based on the single excitation temperature assumption. Comparisons with other measurements suggest significant core-to-core variability. Furthermore, the 13C enrichment we found in HCN could explain the superfractionation of nitrogen measured in solar system chondrites.

astro-ph.GA↗

arXiv2018

Seeds of Life in Space (SOLIS). III. Zooming into the methanol peak of the pre-stellar core L1544

Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH$_3$OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2~km~s$^{-1}$ and the velocity dispersion increases from subsonic to transonic towards the central zone of the core, where the velocity field also shows complex structure. This could be indication of gentle accretion of material onto the core or interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH$_3$OH column density, $N_{tot}({\rm CH_3OH})$, profile has been derived with non-LTE radiative transfer modelling and compared with chemical models of a static core. The measured $N_{tot}({\rm CH_3OH})$ profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunnelling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance.

astro-ph.GA↗

arXiv2017

Direct evidence of multiple reservoirs of volatile nitrogen in a protosolar nebula analogue

Isotopic ratios are keys to understanding the origin and early evolution of the solar system in the context of Galactic nucleosynthesis. The large range of measured $^{14}$N/$^{15}$N isotopic ratios in the solar system reflects distinct reservoirs of nitrogen whose origins remain to be determined. We have directly measured a C$^{14}$N/C$^{15}$N abundance ratio of 323$\pm$30 in the disk orbiting the nearby young star TW Hya. This value, which is in good agreement with nitrogen isotopic ratios measured for prestellar cores, likely reflects the primary present-day reservoir of nitrogen in the solar neighbourhood. These results support models invoking novae as primary $^{15}$N sources as well as outward migration of the Sun over its lifetime, and suggest that comets sampled a secondary, $^{15}$N-rich reservoir during solar system formation.

astro-ph.GA↗

arXiv2017

Detection of the HC$_3$NH$^+$ and HCNH$^+$ ions in the L1544 pre-stellar core

The L1544 pre-stellar core was observed as part of the ASAI (Astrochemical Surveys At IRAM) Large Program. We report the first detection in a pre-stellar core of the HCNH$^+$ and HC$_3$NH$^+$ ions. The high spectral resolution of the observations allows to resolve the hyperfine structure of HCNH$^+$. Local thermodynamic equilibrium analysis leads to derive a column density equal to (2.0$\pm$0.2)$\times$10$^{13}$cm$^{-2}$ for HCNH$^+$ and (1.5$\pm$0.5)$\times$10$^{11}$cm$^{-2}$ for HC$_3$NH$^+$. We also present non-LTE analysis of five transitions of HC$_3$N, three transitions of H$^{13}$CN and one transition of HN$^{13}$C, all of them linked to the chemistry of HCNH$^+$ and HC$_3$NH$^+$. We computed for HC$_3$N, HCN, and HNC a column density of (2.0$\pm$0.4)$\times$10$^{13}$cm$^{-2}$, (3.6$\pm$0.9)$\times10^{14}$cm$^{-2}$, and (3.0$\pm$1.0)$\times$10$^{14}$cm$^{-2}$, respectively. We used the gas-grain chemical code Nautilus to predict the abundances all these species across the pre-stellar core. Comparison of the observations with the model predictions suggests that the emission from HCNH$^+$ and HC$_3$NH$^+$ originates in the external layer where non-thermal desorption of other species was previously observed. The observed abundance of both ionic species ([HCNH$^+$]$\,\simeq3\times10^{-10}$ and [HC$_3$NH$^+$]$\,\simeq[1.5-3.0]\times10^{-12}$, with respect to H$_2$) cannot be reproduced at the same time by the chemical modelling, within the error bars of the observations only. We discuss the possible reasons for the discrepancy and suggest that the current chemical models are not fully accurate or complete. However, the modelled abundances are within a factor of three consistent with the observations, considering a late stage of the evolution of the pre-stellar core, compatible with previous observations.

astro-ph.GA↗

arXiv2016

Deuteration of ammonia in the starless core Ophiuchus/H-MM1

Ammonia and its deuterated isotopologues probe physical conditions in dense molecular cloud cores. With the aim of testing the current understanding of the spin-state chemistry of these molecules, we observed spectral lines of NH3, NH2D, NHD2, ND3, and N2D+ towards a dense, starless core in Ophiuchus with the APEX, GBT, and IRAM 30-m telescopes. The observations were interpreted using a gas-grain chemistry model combined with radiative transfer calculations. The chemistry model distinguishes between the different nuclear spin states of light hydrogen molecules, ammonia, and their deuterated forms. High deuterium fractionation ratios with NH2D/NH3=0.4, NHD2/NH2D=0.2, and ND3/NHD2=0.06 were found in the core. The observed ortho/para ratios of NH2D and NHD2 are close to the corresponding nuclear spin statistical weights. The chemistry model can approximately reproduce the observed abundances, but predicts uniformly too low ortho/para-NH2D, and too large ortho/para-NHD2 ratios. The longevity of N2H+ and NH3 in dense gas, which is prerequisite to their strong deuteration, can be attributed to the chemical inertia of N2 on grain surfaces. The discrepancies between the chemistry model and the observations are likely to be caused by the fact that the model assumes complete scrambling in principal gas-phase deuteration reactions of ammonia, which means that all the nuclei are mixed in reactive collisions. If, instead, these reactions occur through proton hop/hydrogen abstraction processes, statistical spin ratios are to be expected. The present results suggest that while the deuteration of ammonia changes with physical conditions and time, the nuclear spin ratios of ammonia isotopologues do not probe the evolutionary stage of a cloud.

astro-ph.GA↗

arXiv2015

Hyperfine transitions of 13CN from pre-protostellar sources

Recent quantum mechanical calculations of rate coefficients for collisional transfer of population between the hyperfine states of 13CN enable their population densities to be determined. We have computed the relative populations of the hyperfine states of the N = 0, 1, 2 rotational states for kinetic temperatures 5 $\le$ T $\le$ 20 K and molecular hydrogen densities 1 $\le$ n(H2) $\le$10 10 cm --3. Spontaneous and induced radiative transitions were taken into account. Our calculations show that, if the lines are optically thin, the populations of the hyperfine states, F, within a given rotational manifold are proportional to their statistical weights, (2F + 1) -- i.e. in local thermodynamic equilibrium -- over the entire range of densities. We have re-analysed IRAM 30 m telescope observations of 13CN hyperfine transitions (N = 1 $\rightarrow$ 0) in four starless cores. A comparison of these observations with our calculations confirms that the hyperfine states are statistically populated in these sources.

astro-ph.GA↗

arXiv2015

A Ring of C2H in the Molecular Disk Orbiting TW Hya

We have used the Submillimeter Array to image, at ~1.5" resolution, C2H (3-2) emission from the circumstellar disk orbiting the nearby (D = 54 pc), ~8 Myr-old, ~0.8 Msun classical T Tauri star TW Hya. The SMA imaging reveals that the C2H emission exhibits a ring-like morphology. Based on a model in which the C2H column density follows a truncated radial power-law distribution, we find that the inner edge of the ring lies at ~45 AU, and that the ring extends to at least ~120 AU. Comparison with previous (single-dish) observations of C2H (4-3) emission indicates that the C2H molecules are subthermally excited and, hence, that the emission arises from the relatively warm, tenuous upper atmosphere of the disk. We propose that the C2H emission most likely traces particularly efficient photo-destruction of small grains and/or photodesorption and photodissociation of hydrocarbons derived from grain ice mantles in the surface layers of the outer disk. The presence of a C2H ring in the TW Hya disk hence likely serves as a marker of dust grain processing and radial and vertical grain size segregation within the disk.

astro-ph.SR↗