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Pierre Nazé

Publications and source records attributed to Pierre Nazé.

At least 19 recordsLinked to original sources

Jarzynski equality for counterwork under reversed memory-filtered driving

We introduce a counterwork functional generated by a sign-inverting memory-filtered effective protocol. Given an imposed protocol $λ(t)$, the effective protocol $Λ(t)$ is obtained by applying an active protocol-memory kernel to $\dotλ(t)$, rather than by invoking a passive bath response. The counterwork is then the ordinary Hamiltonian work associated with $H(Γ,Λ(t))$, so that Jarzynski's equality applies directly to it. When $Λ(t)$ reverses the endpoints of $λ(t)$, the corresponding free-energy difference satisfies $ΔF_C=-ΔF_W$, and the exponential average of the counterwork is the reciprocal of that of the original work. We derive the kernel normalization realizing this reversed displacement and show, by Jensen's inequality, that the product of the exponentials of the average work and counterwork is bounded by unity, implying $\langle C\rangle+\langle W\rangle\geq0$. Thus negative average counterwork is possible only when compensated by the average work of the original operation. We further discuss the counteroperation under incomplete thermodynamic information, showing that the robust strategy is to enforce endpoint reversal while minimizing dissipated counterwork.

cond-mat.stat-mech

Linear optimal protocol for physical constraints in weakly driven processes

The minimization of irreversible work in weakly driven systems within linear response under physical constraints on the protocol derivative is studied. The problem reduces to a shifted eigenvalue equation involving the relaxation function. Owing to its dependence on time differences and its evenness, the relaxation kernel is naturally defined over a symmetric interval, where a periodic representation arises as a consistent closure that restores continuous translational invariance. Also, it shows how the irreversible work is defined in practice. Within this framework, the operator becomes diagonal in a Fourier basis. The global optimal solution is the zero mode, yielding a constant driving speed and a linear protocol. The corresponding optimal work depends only on the integrated relaxation function. Numerical results obtained via genetic programming confirm the robustness of this solution across different kernels.

cond-mat.stat-mech

A self-consistent criterion for the range of validity of weakly driven processes

One of the longstanding open questions in linear response theory concerns its true range of validity. Determining when the linear approximation can be trusted typically requires knowledge of second-order corrections, which are often difficult to compute explicitly. In this letter, I propose a self-consistent criterion for the validity of linear response, formulated in terms of a typical length scale that emerges from the fluctuation-response inequality within the theory itself. The result applies to classical open systems. I illustrate the criterion with explicit examples of Brownian particles in harmonic traps, and classical open systems presenting Kibble-Zurek mechanism. Finally, I discuss the physical meaning of this typical length, providing both thermodynamic and information-theoretic interpretations.

cond-mat.stat-mech

Unifying Kibble-Zurek Mechanism in Weakly Driven Processes

A description of the Kibble-Zurek mechanism with linear response theory has been done previously, but ad hoc hypotheses were used, like the use of the rate-dependent impulse window via the Zurek equation in the context of no driving in the relaxation time. In this work, I present a new framework where such hypotheses are unnecessary, preserving all the characteristics of the phenomenon. The Kibble-Zurek scaling obtained for the excess work is close to 2/5, a result that holds for open and thermally isolated systems whose relaxation time diverges at the critical point and the first zero of the relaxation function is finite. I exemplify the results using four different but significant types of scaling functions.

cond-mat.stat-mech

Thermodynamic optimization equalities in weakly driven processes

Equalities are generally more suitable for experimental verification than inequalities. In this work, I derive valid equalities from the Euler-Lagrange equation for the optimization of macroscopic thermodynamic averages in weakly driven classical open systems. These equalities show that optimization occurs when work and heat become path-independent. I illustrate their applicability by employing them as a convergence criterion in the global optimization technique of genetic programming. Moreover, due to fluctuation-dissipation relations for internal energy, work, and heat, analogous results hold for their variances.

cond-mat.stat-mech

Minimal dissipation with viscoelastic baths in weakly driven processes

We investigate the thermodynamics of overdamped systems weakly driven by time-dependent protocols while interacting with viscoelastic heat baths. Using a generalized Langevin equation with memory, we derive the conditions under which the friction kernel ensures thermodynamic consistency, notably requiring the addition of a Dirac delta. Within linear response theory, we compute the relaxation function and relaxation time for two classes of protocols: moving and stiffening harmonic traps. Surprisingly, we find that viscoelastic memory does not always hinder relaxation; in certain cases, it accelerates it by reducing the effective relaxation time, leading to lower dissipation. We also derive optimal protocols that minimize the irreversible work and show how they are modified by the presence of the persistence time of the viscoelastic heat bath. Our results reveal that memory effects in the overdamped regime leave measurable thermodynamic signatures, depending on the protocol, with direct implications for controlling complex systems.

cond-mat.stat-mech

Analytical solution for optimal protocols of weak drivings

One of the main objectives of science is the recognition of a general pattern in a particular phenomenon in some particular regime. In this work, this is achieved with the analytical expression for the optimal protocol that minimizes the thermodynamic work and its variance for finite-time, isothermal, and weak processes. The method that solves the Euler-Lagrange integral equation is quite general and depends only on the time-reversal symmetry of the optimal protocol, which is proven generically for the regime considered. The solution is composed of a straight line with jumps at the boundaries and impulse-like terms. Already known results are deduced, and many new examples are solved corroborating this pattern. Slowly-varying and sudden cases are deduced in their appropriate asymptotic limits. Comparison with numerical procedures is limited by the nonavailability of the present methods of the literature to produce solutions in the space of distributions.

cond-mat.stat-mech

Fluctuation theorem for time-averaged work

There is evidence that taking the time average of the work performed by a thermally isolated system effectively "transforms" the adiabatic process into an isothermal one. This approach allows inherent quantities of adiabatic processes to be accessed through the definitions of isothermal processes. A fluctuation theorem is then established, linking the time-averaged work to the quasistatic work. Numerical evidence supporting this equality is provided for a classical harmonic oscillator with a driven linear equilibrium position parameter. Furthermore, the strong inequality for the averaged work is derived from the deduced fluctuation theorem using optimality arguments.

cond-mat.stat-mech

Analytical shortcuts to adiabaticity of weakly driven processes

The analytical expression for shortcuts to adiabaticity for any switching time and any thermally isolated system performing a finite-time and weakly driven process is presented. It is based on the analytical solution of the optimal protocols of weak processes for open systems. The extension to adiabatic processes was made by employing the concept of waiting time. The shortcuts to adiabaticity are proven by showing that the excess power is null in all instants, indicating that no nonequilibrium excitation occurs along the driving. Two examples are solved to verify the validity of such shortcuts: the typical case of oscillatory relaxation function and the transverse-field quantum Ising chain. In this last case, it is shown that non-quenching process outperforms the quenching one by suppressing the non-equilibrium excitations until the critical point is not achieved.

quant-ph

Work probability distribution of weakly driven process in overdamped dynamics

Analytical work probability distributions for open classical systems are scarce; they can only be calculated in a few examples. In this work, I present a new method to derive such quantities for weakly driven processes in the overdamped regime for any switching time. The white noise Brownian motion in a harmonic linear stiffening trap illustrates the result. The work probability distribution is non-tabulated, with positive, semi-finite support, diverging at the minimal value, and non-Gaussian. An analysis of the range of validity of linear response is made by using the self-consistent criterion of the fluctuation-dissipation relation. The first, second, third, and fourth moments are correctly calculated for small perturbations.

cond-mat.stat-mech

Fluctuation theorems for quasistatic work

When a thermally isolated system performs a driving process in the quasistatic regime, its variation of average energy is equal to its quasistatic work. Even though presenting this simple definition, few attempts have been made to describe such quantity from the fluctuation theorem point of view. In this work, based on Jarzynski's equality, four forms of such equality are deduced. To corroborate the result, a relation with the strong inequality $\langle W\rangle\ge \langle W_{\rm qs}\rangle$ is pursued. It is concluded in the end that any of the fluctuation theorems deduced cannot derive such a postulate. Also, no contradiction is observed if the strong inequality breaks down.

cond-mat.stat-mech

Kibble-Zurek mechanism in driven underdamped Brownian motion

Kibble-Zurek mechanism is widely known to appear in the transverse-field quantum Ising chain in the thermodynamic limit at zero temperature, having notorious characteristics, like the divergence of its relaxation time. In this work, I present the same effect in a simple system, the driven underdamped Brownian motion. Using linear response theory, I show the appropriate limits where the Kibble-Zurek mechanism happens. The divergence of the relaxation time, the high-temperature condition in the initial thermal equilibrium state, a new Kibble-Zurek scaling at sudden processes, and the pausing effect in the optimal protocol are presented as consequences.

cond-mat.stat-mech

Performance of near-optimal protocols in weak processes

A natural criticism of the optimal protocol of the irreversible work found for weakly driven processes is its experimental difficulty in being implementable due to its singular part. In this work, I explore the possibility of taking its continuous linear part as an acceptable near-optimal protocol. First, I prove that such a solution is the optimal protocol for non-singular admissible functions. I corroborate this result by observing successful comparisons with test protocols on six reasonable examples. Also, extending such analysis, I conclude that the error committed on this near-optimal protocol is considerable compared to the first-order singular approximation solution, except for sudden and slowly-varying processes. A conjecture is made about a general structure of a near-optimal protocol for systems under arbitrarily strong perturbations.

cond-mat.stat-mech

Hamilton's equations for relaxation function

The relaxation function is the cornerstone to perform calculations in weakly driven processes. Properties that such a function should obey are already established, but the difficulty in its calculation is still an issue to be overcome. In this work, I proposed a new method to determine such a function for thermally isolated systems, based on a Hamilton's equations approach. Observing that the microscopic relaxation function can be turned into a canonical variable, one can choose the initial conditions of the solutions of Hamilton's equations to avoid the calculation of the average in the initial canonical ensemble. The unbearable example of the quartic oscillator is solved to corroborate the method. Extensions to the quantum realm and stochastic thermodynamics are mandatory.

cond-mat.stat-mech

Fluctuation-optimization theorem

A fluctuation theorem relating the work to its optimal average work is presented. The function mediating the relation is increasing and convex, and depends on the switching time $τ$, driving strength $δλ/λ_0$, and protocol $g(t)$. The result is corroborated by an example of an overdamped white noise Brownian motion subjected to a moving laser harmonic trap. Observing also that the fluctuation-optimization theorem is an Euler-Lagrange equation, I conclude that the function minimizing $\langle h(-βW)\rangle$ obeys the relation proposed. The optimal work can now be calculated with numerical methods without knowing the optimal protocol, using only a work distribution of an arbitrary protocol.

cond-mat.stat-mech

Casimir-Onsager matrix for weakly driven processes

Modeling of physical systems must be based on their suitability to unavoidable physical laws. In this work, in the context of classical, isothermal, finite-time, and weak drivings, I demonstrate that physical systems, driven simultaneously at the same rate in two or more external parameters, must have the Fourier transform of their relaxation functions composing a positive-definite matrix to satisfy the Second Law of Thermodynamics. By evaluating them in the limit of near-to-equilibrium processes, I identify that such coefficients are the Casimir-Onsager ones. The result is verified in paradigmatic models of the overdamped and underdamped white noise Brownian motions. Finally, an extension to thermally isolated systems is made by using the time-averaged Casimir-Onsager matrix, in which the example of the harmonic oscillator is presented.

cond-mat.stat-mech

Quantum Ising chain with time-averaged work in linear response theory

For systems performing a weakly isothermal process, the decorrelation time dictates how fast the relaxation function decorrelates. However, like many other thermally isolated systems, the transverse-field quantum Ising chain presents an ill-defined decorrelation time. On the other hand, the Kibble-Zurek mechanism uses a heuristic relaxation time to achieve its famous scaling. The problem however of having a well-defined decorrelation time, derived from first principles, agreeing with the Kibble-Zurek mechanism is still open. Such a solution is proposed here by measuring the work using the time-averaged relaxation function of the system, which offers a new and well-defined decorrelation time for thermally isolated systems. I recover with this the Kibble-Zurek mechanism in the finite-time and weak driving regime, and new features in the slowly-varying one. The gain in control over the system in such a distinction is desirable for potential applications.

cond-mat.stat-mech

Optimal work fluctuations for finite-time and weak processes

The optimal protocols for the irreversible work achieve their maximum usefulness if their work fluctuations are the smallest ones. In this work, for classical and isothermal processes subjected to finite-time and weak drivings, I show that the optimal protocol for the irreversible work is the same for the variance of work. This conclusion is based on the fluctuation-dissipation relation $\overline{W}=ΔF+βσ_W^2/2$, extended now to finite-time and weak drivings. To illustrate it, I analyze a white noise overdamped Brownian motion subjected to an anharmonic stiffening trap for fast processes. By contrast with the already known results in the literature for classical systems, the linear-response theory approach of the work probabilistic distribution is not a Gaussian reduction.

cond-mat.stat-mech