arXiv subjects

Pierre-Olivier Chapuis

Publications and source records attributed to Pierre-Olivier Chapuis.

At least 19 recordsLinked to original sources

arXiv2026

Influence of electrical properties on thermal boundary conductance at metal/semiconductor interface

Recent experimental investigations have demonstrated that doping a semiconductor is a route to increase the thermal boundary conductance at metal/semiconductor interfaces. In this work, the influence of the electrical properties on heat transfer across metal/doped semiconductor junctions is investigated. Specifically, thermal boundary conductance at the interfaces between p- and n-doped silicon and titanium is measured by employing frequency-domain photothermal radiometry under varying external conditions. The influence of the doping level of the semiconductor, the barrier height, and the space charge area is analyzed. In particular, a 40% increase in the interface thermal conductance with the application of a current at n-doped silicon/titanium interfaces is reported. The enhancement of the thermal boundary conductance is explained by the shrinking of the surface charga area induced by the electric current. This study opens the way to modulating interfacial heat transfer at metal/semiconductor interfaces through fine tuning of electrical effects.

cond-mat.mes-hall↗

arXiv2025

Far- and near-field photon noise limits to the detectivity of nanometer-thick thermal detectors

Thermal-radiation detectors such as bolometers -- often found as thin, suspended films -- are intrinsically limited by their optical absorption properties and by their intrinsic thermal conductive and radiative losses. We analyze the impact of the photon energy exchange between the film and a substrate located close to each other, noticing that the associated near-field exchange has been overlooked and could reduce the detectivity. In addition, we study how the nanometric thickness of the suspended film and its material impact the detectivity of such sensors. It is found that the blackbody-related photon noise limit of the detectivity can be surpassed with thin films. These results emphasize pathways for improvements of thermal-radiation detectors.

physics.optics↗

arXiv2025

Performances of far and near-field thermophotonic refrigeration devices from the detailed-balance approach

We study a near-field thermophotonic (NF-TPX) refrigerating device, consisting of a lightemitting diode and a photovoltaic cell in close proximity. Calculations are performed in the frame of the detailed-balance approach. We study how thermal radiation, separation distance and LED temperature can affect both cooling power and coefficient of performance. More specifically, we assess the impact of bandgap energy and external quantum efficiency for an artificial material on those cooling performances. For a particular device made of GaAs and/or AlGaAs we show that, in the near-field regime, the cooling power can be increased by one order of magnitude compared to far field. However, a 10% reduction of the external quantum efficiency can lead to a decrease of the cooling power by two orders of magnitude. Finally, we compare existing literature data on electroluminescent, TPX and thermoelectric cooling with our detailed balance prediction, which highlights design-rule requirements for NF-TPX cooling devices.

physics.app-ph↗

arXiv2025

Operating conditions and thermodynamic bounds of dual radiative heat engines

We propose a unified description of dual radiative heat engines (RHEs), consisting of two facing optoelectronic components (diodes) and capable of generating electrical power from heat. They can operate in three regimes depending on the applied biases, namely in thermoradiative-negative electroluminescent (TRNEL), thermoradiative-photovoltaic (TRPV) or thermophotonic regimes (TPX, consisting of a light-emitting diode and a PV cell). They have access to operating conditions that are unachievable by single RHEs such as thermophotovoltaic systems: at the radiative limit, TRNEL devices can reach the Carnot efficiency for any bandgap, while TPX devices achieve large power outputs by means of electroluminescent enhancement. Expressions of the maximum power output and related efficiency achieved by dual engines are derived analytically, and reveal that the power output of TPX engines is not bounded. A comparison to usual efficiency bounds also highlights the impact of thermalisation losses, and the subsequent interest of spectral filtering to extend the operating region. The influence of nonradiative recombinations is also investigated. This work provides common framework and guidelines for the study of RHEs, which represent a promising solution for reliable and scalable energy conversion.

physics.app-ph↗

arXiv2023

Thermal Radiation at the Nanoscale and Applications

There has been a paradigm shift from the well-known laws of thermal radiation derived over a century ago, valid only when the length scales involved are much larger than the thermal wavelength (around 10 $μ$m at room temperature), to a general framework known as fluctuational electrodynamics that allows calculations of radiative heat transfer for arbitrary sizes and length scales. Near-field radiative heat transfer and thermal emission in systems of sub-wavelength size can exhibit super-Planckian behaviour, i.e. flux rates several orders of magnitude larger than that predicted by the Stefan-Boltzmann (or blackbody) limit. These effects can be combined with novel materials, e.g. low-dimensional or topological systems, to yield even larger modifications and spectral and/or directional selectivity. We introduce briefly the context and the main steps that have led to the current boom of ideas and applications. We then discuss the original and impactful works gathered in the associated Special Topic collection, which provides an overview of the flourishing field of nanoscale thermal radiation.

physics.app-ph↗

arXiv2023

Overcoming non-radiative losses with AlGaAs PIN junctions for near-field thermophotonic energy harvesting

In a thermophotonic device used in an energy-harvesting configuration, a hot light-emitting diode (LED) is coupled to a photovoltaic (PV) cell by means of electroluminescent radiation in order to produce electrical power. Using fluctuational electrodynamics and the drift-diffusion equations, we optimise a device made of an AlGaAs PIN LED and a GaAs PIN PV cell with matched bandgaps. We find that the LED can work as an efficient heat pump only in the near field, where radiative heat transfer is increased by wave tunnelling. A key reason is that non-radiative recombination rates are reduced compared to radiative ones in this regime. At 10 nm gap distance and for 100 cm.s --1 effective surface recombination velocity, the power output can reach 2.2 W.cm --2 for a 600 K LED, which highlights the potential for low-grade energy harvesting.

physics.class-ph↗

arXiv2022

Thermal boundary conductance of CVD-grown MoS$_2$ monolayer-on-silica substrate determined by scanning thermal microscopy

We characterize heat dissipation of supported molybdenum disulfide (MoS$_2$) monolayers grown by chemical vapor deposition by means of ambient-condition scanning thermal microscopy (SThM). We find that the thermal boundary conductance of the MoS$_2$ monolayers in contact with 300 nm of SiO$_2$ is around 4.6 $\pm$ 2 MW m$^{-2}$ K$^{-1}$. This value is in the low range of the values determined for exfoliated flakes with other techniques such as Raman thermometry, which span an order of magnitude (0.44-50 MW m$^{-2}$ K$^{-1}$), and underlines the dispersion of measurements. The sensitivity to the in-plane thermal conductivity of supported MoS$_2$ is very low, highlighting that the thermal boundary conductance is the key driver of heat dissipation for the MoS$_2$ monolayer when it is not suspended. In addition, this work also demonstrates that SThM calibration using different thicknesses of SiO$_2$, initially aimed at being used with bulk materials can be extended to 2D materials.

physics.app-ph↗

arXiv2022

GaAs-Based Near-Field Thermophotonic Devices: Approaching The Idealized Case With One-Dimensional PN Junctions

Thermophotonics (TPX) is a technology close to thermophotovoltaics (TPV), where a heated light-emitting diode (LED) is used as the active thermal emitter of the system. It allows to tune the heat flux, by means of electroluminescence, to a spectral range matching better the gap of a photovoltaic cell. The concept is extended to near-field thermophotonics (NF-TPX), where enhanced energy conversion is due to both electric control and wave tunneling. We perform a thorough numerical analysis of a GaAs-based NF-TPX device, by coupling a near-field radiative heat transfer solver based on fluctuational electrodynamics with an algorithm based on a simplified version of the drift-diffusion equations in 1D. This allows for the investigation of the emission and absorption profiles in the LED and the photovoltaic (PV) cell, and for the scrutiny of the impact of key parameters. We also demonstrate that the performance obtained with this algorithm can approach idealized cases for improved devices. For the considered simplified architecture and 300 K temperature difference, we find a power density output of 1 W.cm--2 , underlining the potential for waste heat harvesting close to ambient temperature.

physics.app-ph↗

arXiv2021

Temperature dependence of near-field radiative heat transfer above room temperature

Stefan-Boltzmann's law indicates that far-field blackbody radiation scales at the fourth power of temperature. The temperature dependence of radiative heat transfer in the near field is expected to be very different due to the contribution of evanescent waves. In this work, we experimentally observe such deviation on the radiative thermal conductance by bringing a hot micrometric sphere in the nearfield of a room-temperature planar substrate, down to a separation distance of few tens of nanometers. The influence of materials is assessed by using either SiO2 or graphite spheres, and SiO2, graphite and InSb substrates. Temperature differences as large as 900 K are imposed. A maximum near-field radiative thermal conductance of about 70 nW.K-1 is found for a graphite-graphite configuration. The experimental results demonstrate that the temperature exponent weakens in the near field, ranging from 2.2 to 4.1, depending on the gap distance and the materials. These results have broad consequences, in particular on the design of high-temperature nanoscale radiative energy devices.

physics.class-ph↗

arXiv2021

Impact of roughness on heat conduction involving nanocontacts

The impact of surface roughness on conductive heat transfer across nanoscale contacts is investigated by means of scanning thermal microscopy. Silicon surfaces with out-of-plane rms roughness of ~0, 0.5, 4, 7 and 11 nm are scanned both under air and vacuum conditions. Three types of resistive SThM probes spanning curvature radii over orders of magnitude are used. A correlation between thermal conductance and adhesion force is highlighted. In comparison with a flat surface, the contact thermal conductance can decrease as much as 90% for a microprobe and by about 50% for probes with curvature radius lower than 50 nm. The effects of multi-contact and ballistic heat conduction are discussed. Limits of contact techniques for thermal conductivity characterization are also discussed.

physics.app-ph↗

arXiv2021

Radiative heat transfer at nanoscale: experimental trends and challenges

Energy transport theories are being revisited at the nanoscale, as macroscopic laws known since a century are broken at dimensions smaller than those associated with energy carriers. For thermal radiation, where the typical dimension is provided by Wien's wavelength, Planck's law and associated concepts describing surface-to-surface radiative transfer have to be replaced by a full electromagnetic framework capturing near-field radiative heat transfer (photon tunnelling between close bodies), interference effects and sub-wavelength thermal emission (emitting body of small size). It is only during the last decade that nanotechnology has allowed for many experimental verifications-with a recent boom-of the large increase of radiative heat transfer at nanoscale. In this minireview, we highlight the parameter space that has been investigated until now, showing that it is limited in terms of inter-body distance, temperature and object size, and provide clues about possible thermal-energy harvesting, sensing and management applications. We also provide an outlook on open topics, underlining some difficulties in applying single-wavelength approaches to broadband thermal emitters while acknowledging the promises of thermal nanophotonics and observing that molecular/chemical viewpoints have been hardly addressed. Context: revisiting thermal radiative energy transport and conversion at the nanoscale

physics.chem-ph↗

arXiv2018

Microfabricated sensor platform with through-glass vias for bidirectional 3-omega thermal characterization of solid and liquid samples

A novel microfabricated, all-electrical measurement platform is presented for a direct, accurate and rapid determination of the thermal conductivity and diffusivity of liquid and solid materials. The measurement approach is based on the bidirectional 3-omega method. The platform is composed of glass substrates on which sensor structures and a very thin dielectric nanolaminate passivation layer are fabricated. Using through-glass vias for contacting the sensors from the chip back side leaves the top side of the platform free for deposition, manipulation and optical inspection of the sample during 3-omega measurements. The thin passivation layer, which is deposited by atomic layer deposition on the platform surface, provides superior chemical resistance and allows for the measurement of electrically conductive samples, while maintaining the conditions for a simple thermal analysis. We demonstrate the measurement of thermal conductivities of borosilicate glass, pure water, glycerol, 2-propanol, PDMS, cured epoxy, and heat-sink compounds. The results compare well with both literature values and values obtained with the steady-state divided bar method. Small sample volumes (~0.02 mm$^2$) suffice for accurate measurements using the platform, allowing rapid temperature-dependent measurements of thermal properties, which can be useful for the development, optimization and quality testing of many materials, such as liquids, gels, pastes and solids.

physics.ins-det↗

arXiv2015

Impacts of propagating, frustrated and surface modes on radiative, electrical and thermal losses in nanoscale-gap thermophotovoltaic power generators

The impacts of radiative, electrical and thermal losses on the power output enhancement of nanoscale-gap thermophotovoltaic (nano-TPV) power generators consisting of a gallium antimonide cell paired with a broadband tungsten and a radiatively-optimized Drude radiator are analyzed. Results reveal that surface mode mediated nano-TPV power generation with the Drude radiator outperforms the tungsten emitter, dominated by frustrated modes, only for a vacuum gap thickness of 10 nm and if both electrical and thermal losses are neglected. The key limiting factors for the Drude and tungsten-based devices are respectively the recombination of electron-hole pairs at the cell surface and thermalization of radiation with energy larger than the absorption bandgap. In a nano-TPV power generator cooled by convection with a fluid at 293 K and a heat transfer coefficient of 10^4 Wm^-2K^-1, power output enhancements of 4.69 and 1.89 are obtained for the tungsten and Drude radiators, respectively, when a realistic vacuum gap thickness of 100 nm is considered. A design guideline is also proposed where a high energy cutoff above which radiation has a net negative effect on nano-TPV power output is determined. This work demonstrates that design and optimization of nano-TPV devices must account for radiative, electrical and thermal losses.

cond-mat.mtrl-sci↗

arXiv2013

Strong tip-sample coupling in thermal radiation scanning tunneling microscopy

We analyze how a probing particle modifies the infrared electromagnetic near field of a sample. The particle, described by electric and magnetic polarizabilities, represents the tip of an apertureless scanning optical near-field microscope (SNOM). We show that the interaction with the sample can be accounted for by ascribing to the particle dressed polarizabilities that combine the effects of image dipoles with retardation. When calculated from these polarizabilities, the SNOM signal depends only on the fields without the perturbing tip. If the studied surface is not illuminated by an external source but heated instead, the signal is closely related to the projected electromagnetic local density of states (EM-LDOS). Our calculations provide the link between the measured far-field spectra and the sample's optical properties.We also analyze the case where the probing particle is hotter than the sample and evaluate the impact of the dressed polarizabilities on near-field radiative heat transfer. We show that such a heated probe above a surface performs a surface spectroscopy, in the sense that the spectrum of the heat current is closely related to the local electromagnetic density of states. The calculations agree well with available experimental data.

physics.optics↗

arXiv2012

Tip-sample electromagnetic interaction in the infrared: Effective polarizabilities, retarded image dipole model and near-field thermal radiation detection

We analyse how a probing particle modifies infrared electromagnetic near fields. The particle, assimilated to both electric and magnetic dipoles, represents the tip of an apertureless scanning optical near-field microscope (SNOM). We show that the interaction can be accounted for by ascribing to the particle effective dipole polarizabilities that add the effect of retardation to the one of the image dipole. Apart from these polarizabilities, the SNOM signal expression depends only on the fields without tip perturbation, shown to be closely related to the electromagnetic density of states (EM-LDOS) and essentially linked to the sample's optical properties, so that measuring local spectra of heated samples is equivalent to performing a local surface spectroscopy. We also analyse the case where the probing particle is hotter. We evaluate in this case the impact of the effective polarizabilities on the tip-sample near-field radiative heat transfer. We also show that such an heated probe above a surface also performs a surface spectroscopy. The calculations agree well with available experimental data.

physics.optics↗

arXiv2008

Radiative heat transfer between metallic nanoparticles

In this letter, we study the radiative heat transfer between two nanoparticles in the near field and in the far field. We find that the heat transfer is dominated by the electric dipole-dipole interaction for dielectric particles and by the magnetic dipole-dipole interaction for metallic nanoparticles. We introduce polarizabilities formulas valid for arbitrary values of the skin depth. While the heat transfer mechanism is different for metallic and dielectric nanoparticles, we show that the distance dependence is the same. However, the dependence of the heat flux on the particle radius is different.

physics.optics↗

arXiv2008

Nanoscale heat transfer at contact between a hot tip and a substrate

Hot tips are used either for characterizing nanostructures by using scanning thermal microscopes or for local heating to assist data writing. The tip-sample thermal interaction involves conduction at solid-solid contact as well as conduction through the ambient gas and through the water meniscus. We analyze those three heat transfer modes with experimental data and modeling. We conclude that the three modes contribute in a similar manner to the thermal contact conductance but they have distinct contact radii ranging from 30 nm to 1 micron. We also show that any scanning thermal microscope has a 1-3 microns resolution when used in ambient air.

cond-mat.mtrl-sci↗

arXiv2008

Heat transfer between a nano-tip and a surface

We study quasi-ballistic heat transfer through air between a hot nanometer-scale tip and a sample. The hot tip/surface configuration is widely used to perform nonintrusive confined heating. Using a Monte-Carlo simulation, we find that the thermal conductance reaches 0.8 MW.m-2K-1 on the surface under the tip and show the shape of the heat flux density distribution (nanometer-scale thermal spot). These results show that a surface can be efficiently heated locally without contact. The temporal resolution of the heat transfer is a few tens of picoseconds.

cond-mat.mtrl-sci↗