arXiv subjects

Ping-Yuan Lo

Publications and source records attributed to Ping-Yuan Lo.

17 recordsLinked to original sources

arXiv2024

Signatures of valley drift in the diversified band dispersions of bright, gray, and dark excitons in MoS2 monolayers under uni-axial strains

We present a comprehensive theoretical investigation of the strain-modulated excitonic properties of uni-axially strained transition-metal dichalcogenide monolayers (TMD-MLs) by solving the Bethe-Salpeter equation (BSE) established on the basis of first principles. We show that imposing an uni-axial strain onto a MoS_$2$ monolayers leads to the diversified band dispersions of the bright exciton (BX), gray exciton (GX), and dark exciton (DX) states, as a consequence of the competitive interplay between strain-induced valley drift (VD) and momentum-dependent electron-hole exchange interaction (EHEI). While the band dispersions of BX doublet in the light-accessible small reciprocal area remain almost unchanged against strain, the band dispersion of DX is reshaped by an increasing uni-axial strain from a parabola to a Mexican-hat-like profile, featured with unusual sign-reversal of the heavy effective mass and strain-activated brightness. In contrast, the effective mass of GX is drastically lightened by uni-axial strain and remains always positive. We show that the strain-diversified exciton band dispersions leads to the distinct exciton diffusivities and angle-resolved optical patterns of BX, GX, and DX in a strained TMD-ML, suggesting the feasibility of {\it spatially} resolving spinallowed and -forbidden excitons in exciton transport experiments and angle-resolved optical spectroscopies.

physics.app-ph↗

arXiv2024

Efficient light upconversion via resonant exciton-exciton annihilation of dark excitons in few-layer transition metal dichalcogenides

In this work, we report a pronounced light upconversion in few-layer transition metal dichalcogenides. Our joint theory-experiment study attributes the upconversion photoluminescence to a resonant exciton-exciton annihilation involving a pair of dark excitons with opposite momenta, followed by the spontaneous emission of upconverted bright excitons, which can have a high upconversion efficiency. Additionally, the upconversion photoluminescence is generic in MoS2, MoSe2, WS2, and WSe2, showing a high tuneability from green to ultraviolet light.

cond-mat.mtrl-sci↗

arXiv2023

Unveiling the nonclassicality within quasi-distribution representations through deep learning

To unequivocally distinguish genuine quantumness from classicality, a widely adopted approach focuses on the negative values of a quasi-distribution representation as compelling evidence of nonclassicality. Prominent examples include the dynamical process nonclassicality characterized by the canonical Hamiltonian ensemble representation (CHER) and the nonclassicality of quantum states characterized by the Wigner function. However, to construct a multivariate joint quasi-distribution function with negative values from experimental data is typically highly cumbersome. Here we propose a computational approach utilizing a deep generative model, processing three marginals, to construct the bivariate joint quasi-distribution functions. We first apply our model to tackle the challenging problem of the CHERs, which lacks universal solutions, rendering the problem ground-truth (GT) deficient. To overcome the GT deficiency of the CHER problem, we design optimal synthetic datasets to train our model. While trained with synthetic data, the physics-informed optimization enables our model to capture the detrimental effect of the thermal fluctuations on nonclassicality, which cannot be obtained from any analytical solutions. This underscores the reliability of our approach. This approach also allows us to predict the Wigner functions subject to thermal noises. Our model predicts the Wigner functions with a prominent accuracy by processing three marginals of probability distributions. Our approach also provides a significant reduction of the experimental efforts of constructing the Wigner functions of quantum states, giving rise to an efficient alternative way to realize the quantum state tomography.

quant-ph↗

arXiv2023

The key role of non-local screening in the environment-insensitive exciton fine structures of transition-metal dichalcogenide monolayers

In this work, we present a comprehensive theoretical and computational investigation of exciton fine structures of WSe$_2$-monolayers, one of the best known two-dimensional (2D) transition-metal dichalcogenides (TMD's), in various dielectric-layer environments by solving the first-principles-based Bethe-Salpeter equation. While the physical and electronic properties of atomically thin nano-materials are normally sensitive to the variation of surrounding environment, our studies reveal that the influence of dielectric environment on the exciton fine structures of TMD-ML's is surprisingly limited. We point out that the non-locality of Coulomb screening plays a key role to suppress the factor of dielectric environment and drastically shrink the fine structure splittings between bright exciton (BX) states and various dark exciton (DX) states of TMD-ML's. The intriguing non-locality of screening in 2D materials can be manifested by the measurable {\it non-linear} correlation between the BX-DX splittings and exciton binding energies with varying the surrounding dielectric environments. The revealed environment-insensitive exciton fine structures of TMD-ML's suggest the robustness of prospective dark-exciton-based opto-electronics against the inevitable variation of inhomogeneous dielectric environment.

cond-mat.mes-hall↗

arXiv2022

Precession-induced nonclassicality of the free induction decay of NV centers by a dynamical polarized nuclear spin bath

The ongoing exploration of the ambiguous boundary between the quantum and the classical worlds has spurred substantial developments in quantum science and technology. Recently, the nonclassicality of dynamical processes has been proposed from a quantum-information-theoretic perspective, in terms of witnessing nonclassical correlations with Hamiltonian ensemble simulations. To acquire insights into the quantum-dynamical mechanism of the process nonclassicality, here we propose to investigate the nonclassicality of the electron spin free-induction-decay process associated with an NV$^-$ center. By controlling the nuclear spin precession dynamics via an external magnetic field and nuclear spin polarization, it is possible to manipulate the dynamical behavior of the electron spin, showing a transition between classicality and nonclassicality. We propose an explanation of the classicality-nonclassicality transition in terms of the nuclear spin precession axis orientation and dynamics. We have also performed a series of numerical simulations supporting our findings. Consequently, we can attribute the nonclassical trait of the electron spin dynamics to the behavior of nuclear spin precession dynamics.

quant-ph↗

arXiv2022

Twisted-light-induced exciton wave packets in transition-metal dichalcogenide monolayers

We present a comprehensive theoretical investigation of the photo-generated excitons in transition-metal dichalcogenide monolayers (TMD-ML's) by Laguerre-Gaussian beams, a celebrated kind of twisted lights (TL's) carrying quantized orbital angular momenta (OAM). We show that the photo-excitation of TL incident to a TMD-ML leads to the formation of spatially localized exciton wave packets, constituted by the superposition of finite-momentum exciton states determined by the intriguing interplay between the multiple degrees of freedom of the optical and excitonic subsystems. Consequently, the TL-induced exciton wave packets yield profound directional photo-luminescences whose polar-angle-dependences are encoded by the transferred optical OAM and azimuthal angle part, despite OAM-irrelevant, optically resolves the exchange-split longitudinal and transverse exciton bands. Interestingly, the application of linearly polarized TL onto a valley-excitonic system mimics an exciton multiplexer allowing for selectively detecting the individual valley-mixed exciton bands, which are normally hardly measured spectrally.

cond-mat.mes-hall↗

arXiv2021

Inherently high valley polarizations of momentum-forbidden dark excitons in transition-metal dichalcogenide monolayers

High degree of valley polarization of optically active excitons in transition-metal dichalcogenide monolayers (TMD-MLs) is vital in valley-based photonic applications but known to be likely spoiled by the intrinsic electron-hole exchange interactions. In this study, we present a theoretical investigation of the valley and optical properties of finite-momentum dark excitons in WSe$_2$-MLs by solving the density-functional-theory(DFT)-based Bethe-Salpeter equation (BSE) under the guidance of symmetry analysis. %We reveal that, in general, finite-momentum excitons are actually well immune from the exchange-induced valley depolarization, except for those with specific exciton momenta coincident with the $3σ_v$ and $3C_2'$ symmetries in the $D_{3h}$ point group of TMD-MLs. We reveal that, unlike the bright exciton inevitably subjected to electron-hole exchange interaction, inter-valley finite-momentum dark excitons in WSe$_2$-MLs are well immune from the exchange-induced valley depolarization and inherently highly valley-polarized under the enforcement of the crystal symmetries. More importantly, the superior valley polarizations of the inter-valley dark excitons in WSe$_2$-MLs are shown almost fully transferable to the optical polarization in the phonon-assisted photo-luminescences because of the native suppression of exchange-induced depolarization in the second-order optical processes. The analysis of phonon-assisted photo-luminescences accounts for the recently observed brightness, high degree of optical polarization and long lifetime of the inter-valley dark exciton states in tungsten-based TMD-MLs.

cond-mat.mes-hall↗

arXiv2020

Symmetry governed valley-pseudospin textures of the full-zone excitonic bands of transition-metal dichalcogenide monolayers

Preserving a high degree of valley polarization of excitons in photo-excited transition-metal dichalcogenide monolayers (TMD-MLs) is desirable for the valley-based photonic applications, but widely recognized as a hard task hindered by the intrinsic electron-hole exchange interaction. In this study, we present a comprehensive investigation of valley-polarized finite-momentum excitons in WSe$_2$-MLs over the entire Brillouin zone by solving the density-functional-theory(DFT)-based Bethe-Salpeter equation (BSE) under the guidance of symmetry analysis. We reveal that finite-momentum excitons are actually in general well immune from the exchange-induced valley depolarization, except for those with specific exciton momenta directionally coincide with the axes associated with the $3σ_v$ and $3C_2'$ symmetries in TMD-MLs. Governed by the symmetries, the valley pseudo-spin texture of the full-zone exciton band in the momentum space is locally featured by individual skyrmion-like structures where highly valley-polarized finite-momentum exciton states are centred. Remarkably, we show that the high degrees of valley polarizations of the finite-momentum exciton states are excellently well transferable to the optical polarizations in the resulting phonon-assisted photo-luminescences, suggesting the prospective usefulness of those inter-valley excitons in valley-based photonics.

cond-mat.mes-hall↗

arXiv2019

Quantifying the nonclassicality of pure dephasing

One of the central problems in quantum theory is to characterize, detect, and quantify quantumness in terms of classical strategies. Dephasing processes, caused by non-dissipative information exchange between quantum systems and environments, provides a natural platform for this purpose, as they control the quantum-to-classical transition. Recently, it has been shown that dephasing dynamics itself can exhibit (non)classical traits, depending on the nature of the system-environment correlations and the related (im)possibility to simulate these dynamics with Hamiltonian ensembles---the classical strategy. Here we establish the framework of detecting and quantifying the nonclassicality for pure dephasing dynamics. The uniqueness of the canonical representation of Hamiltonian ensembles is shown, and a constructive method to determine the latter is presented. We illustrate our method for qubit, qutrit, and qubit-pair pure dephasing and describe how to implement our approach with quantum process tomography experiments. Our work is readily applicable to present-day quantum experiments.

quant-ph↗

arXiv2019

Distinctive signatures of the spin- and momentum-forbidden dark exciton states in the photo-luminescences of strained WSe$_2$ monolayers under thermalization

With the both spin and valley degrees of freedom, the low-lying excitonic spectra of photo-excited transition-metal dichalcogenide monolayers (TMDC-MLs) are featured by rich fine structures, comprising the intra-valley bright exciton states as well as various intra- and inter-valley dark ones. The latter states can be classified as those of the spin- and momentum-forbidden dark excitons according to the violated optical selection rules. Because of the optical invisibility, the two types of the dark states are in general hardly observed and even distinguished in conventional spectroscopies although their impacts on the optical and dynamical properties of TMDC-MLs have been well noticed. In this Letter, we present a theoretical and computational investigation of the exciton fine structures and the temperature-dependent photo-luminescence spectra of strained tungsten diselenide monolayers (WSe$_2$-MLs) where the intra-valley spin-forbidden dark exciton lies in the lowest exciton states and other momentum-forbidden states are in the higher energies that are tunable by external stress. The numerical computations are carried out by solving the Bethe-Salpeter equation for an exciton in a WSe$_2$-ML under the stress-control in the tight-binding scheme established from the first principle computation in the density functional theory. According to the numerical computation and supportive model analysis, we reveal the distinctive signatures of the spin- and momentum-forbidden exciton states of strained WSe$_2$-MLs in the temperature-dependent photo-luminescences and present the guiding principle to infer the relative energetic locations of the two types of DX's.

cond-mat.mes-hall↗

arXiv2018

Simulating Open Quantum Systems with Hamiltonian Ensembles and the Nonclassicality of the Dynamics

The incoherent dynamical properties of open quantum systems are generically attributed to an ongoing correlation between the system and its environment. Here, we propose a novel way to assess the nature of these system-environment correlations by examining the system dynamics alone. Our approach is based on the possibility or impossibility to simulate open-system dynamics with Hamiltonian ensembles. As we show, such (im)possibility to simulate is closely linked to the system-environment correlations. We thus define the nonclassicality of open-system dynamics in terms of the nonexistence of a Hamiltonian-ensemble simulation. This classifies any nonunital open-system dynamics as nonclassical. We give examples for open-system dynamics that are unital and classical, as well as unital and nonclassical.

quant-ph↗

arXiv2015

The short-time and long-time behaviors of non-Markovianity measure using two-time correlation functions in open quantum systems

We investigate non-Markovianity measure using two-time correlation functions for open quantum systems. We define non-Markovianity measure as the difference between the exact two-time correlation function and the one obtained in the Markov limit. Such non-Markovianity measure can easily be measured in experiments. We found that the non-Markovianity dynamics in different time scale crucially depends on the system-environment coupling strength and other physical parameters such as the initial temperature of the environment and the initial state of the system. In particular, we obtain the short-time and long-time behaviors of non-Markovianity for different spectral densities. We also find that the thermal fluctuation always reduce the non-Markovian memory effect. Also, the non-Markovianity measure shows non-trivial initial state dependence in different time scales.

quant-ph↗

arXiv2015

Reply to the Comment on "General Non-Markovian Dynamics of Open Quantum System"

This is the reply to the 2nd version of the comment, [arXiv.1312.5286v2], by McCutcheon {\it et al.} on our paper [PRL 109, 170402 (2012)]. Our letter presents three examples. For the steady-state solution of the first example, i.e., the dissipationless part of Eq.(12) in the PRL, the 2nd version of the Comment claimed that "this [dissipationless] regime exists if and only if the total Hamiltonian is unbounded from below, casting serious doubts on the usefulness of this result." In this reply, we show again that the 2nd version of the Comment is also incorrect.

quant-ph↗

arXiv2014

Exact decoherence dynamics of $1/f$ noise

In this paper, we investigate the exact decoherence dynamics of a superconducting resonator coupled to an electromagnetic reservoir characterized by the $1/f$ noise at finite temperature, where a full quantum description of the environment with $1/f^{x}$ noise (with $x \approx 1$) is presented. The exact master equation and the associated non-equilibrium Green's functions are solved exactly for such an open system. We show a clear signal of non-Markovian dynamics induced purely by $1/f$ noise. Our analysis is also applicable to another nano/micro mechanical oscillators. Finally, we demonstrate the non-Markovian decoherence dynamics of photon number superposition states using Wigner distribution that could be measured in experiments.

quant-ph↗

arXiv2013

Breakdown of Bose-Einstein distribution in photonic crystals

In the last two decades, considerable advances have been made in the investigation of nano-photonics in photonic crystals. Previous theoretical investigations of photon dynamics were carried out at zero temperature. Here, we investigate micro/nano cavity photonics in photonic crystals at finite temperature. Due to photonic-band-gap-induced non-Markovian dynamics, we discover that cavity photons in photonic crystals do not obey the standard Bose-Einstein statistical distribution. Within the photonic band gap and in the vicinity of the band edge, cavity photons combine nontrivial quantum dissipation with thermal fluctuations to form photon states that can memorize the initial cavity state information. As a result, Bose-Einstein distribution is completely broken down in these regimes, even if the thermal energy is larger than the photonic band gap.

quant-ph↗

arXiv2013

Non-Markovian Dynamics Impact on the Foundations of Statistical Mechanics

The foundations of statistical mechanics, namely how equilibrium hypothesis emerges microscopically from quantum theory, is explored through investigating the environment-induced quantum decoherence processes. Based on the recent results on non-Markovian dynamics [Phys. Rev. Lett. 109, 170402 (2012)], we find that decoherence of quantum states manifests unexpected complexities. Indeed, an arbitrary given initial quantum state, under the influence of different reservoirs, can evolve into four different steady states: thermal, thermal-like, quantum memory and oscillating quantum memory states. The first two steady states \textit{de facto} provided a rigorous proof how the system relaxes to thermal equilibrium with its environment. The latter two steady states, with strong non-Markovian effects, will maintain the initial state information and not reach thermal equilibrium, which is beyond the conventional wisdom of statistical mechanics.

quant-ph↗

arXiv2012

General non-Markovian dynamics of open quantum systems

We present a general theory of non-Markovian dynamics for open quantum systems. We explore the non-Markovian dynamics by connecting the exact master equations with the non-equilibirum Green functions. Environmental back-actions are fully taken into account. The non-Markovian dynamics consists of non-exponential decays and dissipationless oscillations. Non-exponential decays are induced by the discontinuity in the imaginary part of the self-energy corrections. Dissipationless oscillations arise from band gaps or the finite band structure of spectral densities. The exact analytic solutions for various non-Markovian environments show that the non-Markovian dynamics can be largely understood from the environmental-modified spectra of the open systems.

quant-ph↗