arXiv subjects

Pralay K. Santra

Publications and source records attributed to Pralay K. Santra.

3 recordsLinked to original sources

arXiv2026

Time Resolved Study of Laser Induced Ultrafast Alloying Processes in Au/Pd Core Shell Nanorods

Femtosecond laser-induced alloying presents a novel approach to modifying bimetallic systems. Visualizing ultrafast processes during laser-induced alloying is essential to uncover fundamental mechanisms associated with phase transformations, which enables precise control over material composition and structure at the atomic level. In this study, we investigated the ultrafast dynamics of laser-induced alloying of Au/Pd core-shell nanorods using a time-resolved X-ray diffraction technique at an X-ray free-electron laser facility, capturing the structural evolution from picoseconds to microsecond timescales. We found that a laser fluence threshold of ~ 48 mJ/cm2 with 800 nm excitation is sufficient for melting and subsequent alloy formation. Above this threshold, the formation of Au1.51Pd0.49 was observed, and we found that alloying is not a single-step phenomenon; instead, it is a dynamic process involving interdiffusion.

cond-mat.mtrl-sci↗

arXiv2011

Re-entrant ordering of solute in a colloidal suspension during solvent evaporation

We study the phenomenon of self-assembly of silica micro-spheres on a glass plate during evaporation of the solvent from a colloidal suspension. Our experiments unveil an interesting competition between ordering and compaction in a strongly driven, out of equilibrium system arising from a slowing down of dynamics due to an impending glass transition. A suitable choice of experimental conditions minimizing the influence of many other competing phenomena that usually complicate probing of this underlying physics is crucial for our study. A re-entrant behavior in the order-disorder phase diagram as a function of particle density and drying time is established and the results are explained with the help of simulations and phenomenological theory.

cond-mat.soft↗

arXiv2007

Growth mechanism of nanocrystals in solution: ZnO, a case study

We investigate the mechanism of growth of nanocrystals from solution using the case of ZnO. Spanning a wide range of values of the parameters, such as the temperature and the reactant concentration, that control the growth, our results establish a qualitative departure from the widely accepted diffusion controlled coarsening (Ostwald ripening) process quantified in terms of the Lifshitz-Slyozov-Wagner theory. Further, we show that these experimental observations can be qualitatively and quantitatively understood within a growth mechanism that is intermediate between the two well-defined limits of diffusion control and kinetic control.

cond-mat.mtrl-sci↗