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Pratik Deshmukh

Publications and source records attributed to Pratik Deshmukh.

8 recordsLinked to original sources

Veriphi: Attack-Guided Neural Network Verification with Dataset-Dependent Training Methods

We present Veriphi, a GPU-accelerated neural network verification system that combines fast adversarial attacks with formal bound certification using alpha,beta-CROWN methods. Through systematic experiments on MNIST and CIFAR-10 using three training methodologies (standard, adversarial, certified), we demonstrate that training method effectiveness is fundamentally dataset-dependent. Interval Bound Propagation (IBP) achieves 78% certified accuracy on simple MNIST (784 dimensions) but provides negligible certification performance on the more complex CIFAR-10 dataset, where PGD adversarial training dominates with 94% certification at small perturbations. We achieve 5x verification speedup through attack-guided falsification and scale our approach to production-size models (105.8M parameters) for real-world aerospace logistics optimization. Our results challenge the assumption that certified training universally outperforms adversarial training, showing context matters critically for verification strategy selection.

cs.LG

Near-Infrared-Triggered Photodynamic Antibacterial Therapy Using Rose Bengal-Coated Upconverting Nanoparticles

Antimicrobial photodynamic therapy (aPDT) is a promising modality for inactivation of antibiotic resistant bacteria, relying on the activation of a photosensitizer (PS) by light of a specific wavelength. This process results in the formation of reactive oxygen species, which ultimately induce cell death. However, aPDT in its conventional form, is limited by the shallow penetration of visible light, restricting its effectiveness for treatment of soft tissue and orthopaedic tissues. To overcome this limitation, near-infrared (NIR) absorbing PS can be used. However, poor stability in vivo after injection, ineffective microbial targeting due to hydrophilic nature and off-site tissue damage are the issues with use of NIR absorbing bare PSs. This issue can be mitigated by combining NIR light with a upconverting nanoparticles (UCNPs), which mediate in conversion of NIR into visible light for effective PS activation. In this study, LaF$_3$:Er$^{3+}$,Yb$^{3+}$ nanoparticles were synthesized using a hydrothermal method and coated with Rose Bengal (RB), a promising hydrophilic PS for aPDT, to evaluate the potential for NIR-triggered aPDT. Characterization of the synthesized UCNPs confirmed the crystalline structure, size distribution and successful RB functionalization. Photophysical studies demonstrated efficient energy transfer between UCNPs and RB, leading to singlet oxygen ($^1$O$_2$) generation in vitro. Antibacterial studies against Methicilin resistant Staphylococcus aureus (MRSA), a superbug of implicated soft tissue and orthopaedic infections, revealed significant photo-bactericidal efficacy upon NIR irradiation, indicating the potential of RB-coated UCNPs for aPDT applications.

cond-mat.mtrl-sci

On Semantic Loss Fine-Tuning Approach for Preventing Model Collapse in Causal Reasoning

Standard fine-tuning of transformer models on causal reasoning tasks leads to catastrophic model collapse, where models learn trivial solutions such as always predicting "Yes" or "No" regardless of input structure. We demonstrate that fine-tuning Gemma 270M on transitivity and d-separation tasks without semantic loss results in 100% collapse rate, with models achieving misleadingly high accuracy (73.9%) while learning no causal reasoning. We propose a semantic loss function with graph-based logical constraints and dynamic lambda scheduling that prevents this collapse. Our approach achieves 70.4% accuracy on transitivity tasks and 68.6% on d-separation tasks with stable, context-dependent predictions, representing a 42.7% improvement over collapsed baselines. Adversarial evaluation on 1,000 structural reasoning samples shows semantic models achieve 67-70% accuracy while collapsed models fail catastrophically at 43-71%. We validate our findings through comprehensive benchmarking on 200,000+ evaluation samples across five model variants, demonstrating that semantic loss is essential and not optional, for stable causal reasoning in transformers.

cs.LG

Correlation between spin-phonon coupling and magneto-electric effects in CoFe2O4/PMN-PT nanocomposite: Raman Spectroscopy and XMCD study

We have investigated the coupling of lattice with spin via strain interactions in the CoFe2O4/PMN-PT composite system. X-ray diffraction and Raman spectroscopic studies illustrate a remarkable modification in CoFe2O4lattice across Curie temperature (450 K) of PMN-PT. Subsequently, CoFe2O4/PMN-PT composite reveals a sudden drop in magnetic moment across Tc of PMN-PT (450 K). However,theindependent CoFe2O4phasedisplaystypical ferromagnetic behaviour across this temperature. These findings establish spin-lattice coupling owing to th interfacial strain transfer between CoFe2O4 and PMN-PT in composite. The strain intractions leads to magneto-electric coupling, evidenced by measuring magentization and magneto-electric coefficient for the electric field poled and unploed CoFe2O4/PMN-PT composite samples. X-ray magnetic circular dichroism (XMCD) analysis establishes that the cation (Fe3+/Co2+) redistribution occurs on tetrahedral and octahedral site in the electrically poled CoFe2O4/PMN-PT composite, confirming the coupling between magnetic and electric ordering in the composite. The magneto-electric coupling coefficient alpha vs dc magnetic field curves revealed hysteretic behavior and enhanced α values after electric poling, which originates from the strain induced modifications in the magnetic domains configuration of composite in the poled samples. These findings suggest that the existence of spin lattice coupling may leads to the mechanism of strong magneto-electric effects via strain interactions in CoFe2O4/PMN-PT composite.

cond-mat.mtrl-sci

Strain assisted magnetization switching in ordered nanomagnets of CoFe2O4/SrRuO3/PMNPT hetrostructures

We have explored the electric field controlled magnetization in the nanodot CoFe2O4/SrRuO3/PMN-PT heterostructures. Ordered ferromagnetic CFO nanodots (~300 nm lateral dimension) are developed on the PMN-PT substrate (ferroelectric as well as piezoelectric) using a nanostencil-mask pattering method during pulsed laser deposition. The nanostructures reveal electric field induced magnetization reversal in the single domain CFO nanodots through transfer of piezostrains from the piezoelectric PMN-PT substrate to the CFO. Further, electric field modulated spin structure of CFO nanomagnets is analysed by using X-ray magnetic circular dichroism (XMCD). The XMCD analysis reveals cations (Fe3+/Co2+) redistribution on the octahedral and tetrahedral site in the electric field poled CoFe2O4 nanodots, establishing the strain induced magneto-electric coupling effects. The CoFe2O4/SrRuO3/PMN-PT nanodots structure demonstrate multilevel switching of ME coupling coefficient (α) by applying selective positive and negative electric fields in a non-volatile manner. The retention of two stable states of α is illustrated for ~106 seconds, which can be employed to store the digital data in non-volatile memory devices. Thus the voltage controlled magnetization in the nanodot structures leads a path towards the invention of energy efficient high-density memory devices.

cond-mat.mtrl-sci

Fabrication and characterization of Er,Ndcodoped Y2O3 Transparent Ceramic: A dual mode Photo-luminescence emitter

The transparent Er, Nd co-doped Yttria ceramics with transparency around 78 percentage (in 500 - 2000 nm range without Fresnels correction) were fabricated successfully. It involved nanoparticle synthesis by coprecipitation method and sintering of pellets under high vacuum condition. The crystalline phase, particle size and element composition were confirmed by X- ray diffraction, scanning electron microscope, energy dispersive X- ray fluorescence techniques, respectively. The upconversion luminescence mechanisms involving energy transfer and non-radiative relaxation were analyzed. It is expected that, the result evolved from this study will provide better understanding of upconversion mechanism involved in Er, Nd codoped host material. The emission at both 563 nm and 1064 nm on 822 nm excitation proves potential of the ceramic material for dual mode efficient emitter.

cond-mat.mtrl-sci

Effect of charge transfer band on luminescence properties of Yb doped Y2O3 nano particles for blue-far yellow emission

The photoluminescence properties of Yb doped Y2O3 nanoparticles are investigated in visible region. The presence of peaks at 335 nm and 370 nm in the excitation spectra of bulk as well as in nano Yb: Y2O3 and their absence in pure Y2O3 confirm its origin due to Yb3+ dopant. The Yb doping in nano Y2O3 not only modify the charge transfer bands (CTB) but also helps in transition of electron from these CTBs to ground 2F5/2 and 2F7/2 levels of Yb. This results in strong intense broad emission from ~400 to ~650 nm (white light emission range) for 335 nm excitation.

cond-mat.mtrl-sci

Effect of Mg substitution in Sr2SiO4:Eu2+ nanophosphors for blue and white emission at near UV excitation

Nanophosphors of (Sr0.98-xMgxEu0.02)2SiO4 (x=0, 0.18, 0.38, 0.58 and 0.78) were prepared through low temperature solution combustion method and their luminescence properties were studied. The emission peak for Eu2+ doped Sr2SiO4 nanophosphor is observed at ~490 nm and ~553 nm corresponding to two Sr2+ sites Sr(I) and Sr(II) respectively for 395 nm excitation but the addition of Mg2+ dopant in Sr2SiO4 leads to suppression of ~553 nm emission peak due to absence of energy levels of Sr (II) sites which results in a single broad emission at ~460nm. It was shown that the emission peak blue shifted with increase in Mg concentration which may be attributed to change in crystal field environment around Sr(I) sites. Therefore the (Mg0.78Sr0.20Eu0.02)2SiO4: Eu2+ nanophosphor can be used for blue emission and the Sr2SiO4:Eu0.042+ for green-yellow emission at 395 nm excitations. The CIE coordinates for mixed powders of (Mg0.78Sr0.20Eu0.02)2SiO4 and Sr2SiO4:Eu0.042+ (in 1: 1 ratio) falls in the white region demonstrating the possible use of the mixture in white light generation using near UV excitation source.

cond-mat.mtrl-sci