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Pu Guo

Publications and source records attributed to Pu Guo.

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From LLM Inference to Agentic Workloads: Characterization and Implications for Serving Systems

Agentic applications are shifting AI serving from isolated model inference to long-running workloads in which LLMs coordinate tools, environments, and persistent state. However, the system behavior of these workloads---where latency, cost, and bottlenecks arise---remains poorly characterized, leaving serving systems to rely on assumptions built for conventional inference. We present AgentSysBench, a benchmark suite and measurement toolkit with ten representative agentic applications and unified systems-level instrumentation. Across controlled deployments and production traces, we identify six properties that distinguish agentic workloads from conventional LLM serving: (1) execution is heavyweight and stateful, with non-LLM components dominating latency in 5 of 10 applications and sandbox working-set memory peaking at 28 GB per session; (2) applications compose components with heterogeneous resource affinity---GPU-bound inference, memory-bound retrieval, CPU-bound sandboxes---whose task latencies diverge by up to 32x; (3) bottlenecks shift across requests, models, and deployments; (4) production sessions hold state idle for minutes to hours between active steps; (5) a control-plane tax---auxiliary LLM calls and context overhead from tool schemas and observations---crowds out productive compute and context; and (6) production traces from three applications reveal heavy cross-request redundancy in search queries and web fetches, exposing a large caching opportunity. Four design explorations demonstrate that these findings are actionable: task-aware serving reduces latency by 29--40%, communication-aware placement by up to 4.5x, state offloading reduces memory usage by 4.6x, and tool-result caching removes 35.2% of redundant search calls and saves 19.3% of aggregate search latency.

cs.OS

Nitsum: Serving Tiered LLM Requests with Adaptive Tensor Parallelism

LLM serving is increasingly multi-tenant: the same deployment must handle latency-critical interactive requests and more relaxed background workloads under a fixed GPU budget. This creates a tiered-SLO setting where maximizing overall goodput (requests that satisfy both TTFT and TPOT targets) is challenging because workload mix, request lengths, and load intensity vary over time. Existing systems mainly optimize request-level controls (e.g., queuing and batching) while keeping execution configuration largely static, which limits adaptation under multi-tier contention. We present Nitsum, a distributed LLM serving system that treats tensor parallelism (TP) as a first-class runtime control surface rather than a static deployment choice. Nitsum jointly optimizes TP level, prefill/decode GPU split, and request scheduling. To make frequent TP adaptation practical, Nitsum introduces TP-aware weight reuse and fast KV migration. Experiments on real traces and targeted microbenchmarks show that Nitsum improves SLO-compliant goodput over SoTA by up to 5.3 times.

cs.DC

Theoretical study of kinetics of proton coupled electron transfer in photocatalysis

Photocatalysis induced by sunlight is one of the most promising approach to environmental protection, solar energy conversion and sustainable production of fuels. The computational modeling of photocatalysis is a rapidly expending field which requires to adapt and further develop the available theoretical tools. The coupled transfer of proton and electron is an important reaction during photocatalysis. In this work, we present the first step of our methodology development in which we apply existing kinetic theory of such coupled transfer to a model system, namely, methanol photo-dissociation on rutile TiO$_2$(110) surface, with the help of high-level first-principles calculations. Moreover, we adapt the Stuchebrukhov-Hammes-Schiffer kinetic theory, where we use the Georgievskii-Stuchebrukhova vibronic coupling, to calculate the rate constant of the proton coupled electron transfer reaction for a particular pathway. In particular, we propose a modified expression to calculate the rate constant which enforces the near-resonance condition for the vibrational wavefunction during proton tunneling.

cond-mat.mtrl-sci