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Qilin Han

Publications and source records attributed to Qilin Han.

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Symmetry Origins of the Field-Free Superconducting Diode Effect in the Kagome Superconductor CsV$_3$Sb$_5$

Field-free superconducting diode effects require both inversion-symmetry breaking and an internal time-reversal-symmetry (TRS) breaking field, making them sensitive probes of hidden order in superconductors. In centrosymmetric kagome AV$_3$Sb$_5$, the inversion symmetry generally should generally preclude the observation of the superconducting diode effect. Furthermore, though TRS breaking has been reported in the superconducting regime of CsV$_3$Sb$_5$, whether it is generated by superconductivity or inherited from charge-density-wave (CDW) order remains unresolved. Here we show that pristine CsV$_3$Sb$_5$ devices exhibit no intrinsic field-free superconducting diode effect, whereas surface oxidation or asymmetric etching activates a large nonreciprocal supercurrent. Moreover, the response is stochastic, with sweep-dependent polarity and magnitude, indicating metastable TRS-breaking domain configurations. Small out-of-plane magnetic fields stabilize the superconducting diode response, consistent with field selection of such domains. Finally, when long-range CDW order is suppressed by Ti doping, the SDE disappears. Our results establish the symmetry requirements for the field-free SDE in CsV$_3$Sb$_5$, reveal its stochastic domain-controlled character, and link superconducting-state TRS breaking to CDW-related order.

cond-mat.supr-con

Large Field-Free Superconducting Diode Effect with Nonmonotonic Polarity Reversals in NbSe$_2$/CrBr$_3$ Heterostructures

The superconducting diode effect (SDE), characterized by nonreciprocal dissipationless supercurrent, offers a promising route toward ultralow-power superconducting electronics. Yet most realizations require an external magnetic field, and achieving a large, controllable SDE at zero field remains challenging. Here we report a field-free SDE with an efficiency reaching 35.7% in a van der Waals NbSe$_2$/CrBr$_3$ heterostructure, whose polarity is programmable by magnetic-field history. Unlike conventional mechanisms based on finite-momentum pairing, the SDE originates from the leading symmetry-allowed cubic term odd in Cooper-pair momentum, which yields unequal critical currents while leaving the equilibrium condensate at zero momentum. Remarkably, upon sweeping a perpendicular magnetic field, the diode polarity undergoes nonmonotonic and hysteretic reversals that cannot be explained by Meissner screening or conventional ferromagnetic proximity. Combining transport measurements, micromagnetic simulations, and a generalized Ginzbur-Landau theory, we attribute these unconventional behaviors to layered ferrimagnetism in CrBr$_3$, where coexisting ferromagnetic and antiferromagnetic interlayer couplings produce a history-dependent interfacial exchange field acting on NbSe$_2$. Our results reveal a distinct mechanism for nonreciprocal superconductivity and establish layered van der Waals magnetism as a versatile platform for high-efficiency, programmable, field-free superconducting diodes.

cond-mat.supr-con