arXiv subjects

Qing Huang

Publications and source records attributed to Qing Huang.

At least 37 records · Page 2Linked to original sources

arXiv2026

Cross-sectional helium irradiation reveals interface-controlled bubble evolution in Cr/CrAlSiN multilayer coatings on zirconium alloys

The irradiation stability of Cr based protective coatings on zirconium alloys is critical for the development of accident-tolerant fuel claddings. However, conventional surface irradiation often produces shallow, nonuniform damage, obscuring interfacial behavior. In this study, we perform cross-sectional He irradiation to directly examine the interfacial response and He bubble evolution across Cr monolayer and Cr and CrAlSiN multilayer coatings on Zr substrates. Irradiation was carried out at 500 C and 750 C to doses of 2 and 3 dpa, enabling a direct comparison of temperature-dependent microstructural evolution. In the Cr monolayer, He implantation produced a homogeneous distribution of nanoscale bubbles throughout the damaged region and large cavities at the Cr and Zr interface, indicating severe Kirkendall-type voiding and interfacial decohesion at elevated temperature. In contrast, the Cr/CrAlSiN multilayer exhibited a periodically modulated bubble distribution, with bubble fragmentation and transformation into nanoscale platelets at CrAlSiN interfaces. A N-enriched Zr(N) interlayer formed spontaneously at the CrAlSiN and Zr interface, effectively suppressing bubble accumulation and interdiffusion. The nanochannel interfaces acted as He sinks and diffusion barriers, enhancing interfacial bonding and mitigating swelling. This work demonstrates that cross-sectional ion irradiation is a powerful approach for probing interfacial stability in multilayer systems, offering new insights into He-defect interactions and radiation tolerance engineering at buried interfaces. The findings highlight the potential of Cr and CrAlSiN multilayers as advanced coating architectures for high-temperature nuclear environments.

cond-mat.mtrl-sci↗

arXiv2025

Seeing to Act, Prompting to Specify: A Bayesian Factorization of Vision Language Action Policy

The pursuit of out-of-distribution generalization in Vision-Language-Action (VLA) models is often hindered by catastrophic forgetting of the Vision-Language Model (VLM) backbone during fine-tuning. While co-training with external reasoning data helps, it requires experienced tuning and data-related overhead. Beyond such external dependencies, we identify an intrinsic cause within VLA datasets: modality imbalance, where language diversity is much lower than visual and action diversity. This imbalance biases the model toward visual shortcuts and language forgetting. To address this, we introduce BayesVLA, a Bayesian factorization that decomposes the policy into a visual-action prior, supporting seeing-to-act, and a language-conditioned likelihood, enabling prompt-to-specify. This inherently preserves generalization and promotes instruction following. We further incorporate pre- and post-contact phases to better leverage pre-trained foundation models. Information-theoretic analysis formally validates our effectiveness in mitigating shortcut learning. Extensive experiments show superior generalization to unseen instructions, objects, and environments compared to existing methods. Project page is available at: https://xukechun.github.io/papers/BayesVLA.

cs.RO↗

arXiv2025

Domain-constrained Synthesis of Inconsistent Key Aspects in Textual Vulnerability Descriptions

Textual Vulnerability Descriptions (TVDs) are crucial for security analysts to understand and address software vulnerabilities. However, the key aspect inconsistencies in TVDs from different repositories pose challenges for achieving a comprehensive understanding of vulnerabilities. Existing approaches aim to mitigate inconsistencies by aligning TVDs with external knowledge bases, but they often discard valuable information and fail to synthesize comprehensive representations. In this paper, we propose a domain-constrained LLM-based synthesis framework for unifying key aspects of TVDs. Our framework consists of three stages: 1) Extraction, guided by rule-based templates to ensure all critical details are captured; 2) Self-evaluation, using domain-specific anchor words to assess semantic variability across sources; and 3) Fusion, leveraging information entropy to reconcile inconsistencies and prioritize relevant details. This framework improves synthesis performance, increasing the F1 score for key aspect augmentation from 0.82 to 0.87, while enhancing comprehension and efficiency by over 30\%. We further develop Digest Labels, a practical tool for visualizing TVDs, which human evaluations show significantly boosts usability.

cs.SE↗

arXiv2025

Dissociative Mechanism from NH3 and CH4 on Ni-Doped Graphene: Tuning Electronic and Optical Properties

In this study, we employ a multi-scale computational modeling approach, combining density functional theory (DFT) and self-consistent charge density functional tight binding (SCC-DFTB), to investigate hydrogen (H2) production and dissociation mechanisms from ammonia (NH3) and methane (CH4) on pristine and nickel-doped graphene. These two-dimensional materials hold significant potential for applications in advanced gas sensing and catalysis. Our analysis reveals that Ni-doped graphene, validated through work function calculations, is a promising material for gas separation and hydrogen production. The samples with adsorbed molecules are characterized by calculating chemical potential, chemical hardness, electronegativity, electrophilicity, vibrational frequencies, adsorbtion and Gibbs energies by DFT calculations. Methane molecules preferentially adsorb at the hexagonal ring centers of graphene, while ammonia inter-acts more strongly with carbon atoms, highlighting distinct molecular doping mechanisms for CH4 and NH3. Dynamic simulations show that CH4 splits into CH3+H, with Ni-doped graphene facilitating enhanced hydrogen transmission, while NH3 dissociates into NH2+H, which may lead to N2H4 formation. Our non-equilibrium Green's function (NEGF) simulations demonstrate increased H-atom transmission on Ni-doped graphene during gas interactions. These findings suggest that Ni-doped graphene is superior to pristine graphene for applications in gas separation, hydrogen production, and high-sensitivity sensors.

cond-mat.mtrl-sci↗

arXiv2025

CoNi-MOF laccase-like nanozymes prepared by dielectric barrier discharge plasma for treatment of antibiotic pollution

Laccase is a natural green catalyst and utilized in pollution treatment. Nevertheless, its practical application is constrained by limitations including high cost, poor stability, and difficulties in recovery. Herein, with inspiration from catalytic mechanism of natural laccase, we designed and prepared a bimetallic metal-organic framework, namely, CoNi-MOF, using low-temperature plasma (LTP) technology. We employed dielectric barrier discharge (DBD) plasma to prepare CoNi-MOF, and by precisely modulating the N2/O2 gas ratio, we could modulate the distribution concentration of oxygen vacancies in CoNi-MOF. Experimental investigations and density functional theory (DFT) calculations elucidated that the critical role of the oxygen vacancies in enhancing the laccase-like activity, which promoted the activation of molecular oxygen (O2) for generation of reactive oxygen species (ROS). Compared to natural laccase, CoNi-MOF exhibited superior catalytic performance in the degradation of antibiotic tetracycline (TC), along with enhanced resistance to harsh environmental conditions, improved stability, and low biotoxicity. Notably, aeration increased the dissolved oxygen (DO) content, further improving the TC degradation efficiency. As such, this study not only proposes a facile and efficient low-temperature plasma technology for synthesizing high-performance laccase-like nanozymes but also provides a promising and environmentally friendly strategy for the remediation of antibiotic contamination in the environment.

cond-mat.mtrl-sci↗

arXiv2025

Facet Specific Electron Conduction in Pentavalent (W5+) WO3 Drives Superior Photocatalytic CO 2 Reduction in (002) Plane

This article reports a concept of heat-induced topological modifications of non-layered WO 3 followed by successful synthesis of oxygen-vacant more-porous nanosheets with exposed active (002) facet. Experimental measurements and Density Functional Theory (DFT) calculations have revealed that the photoexcited electrons are found to accumulate preferentially on (002) facet to yield enhanced electron conduction, and consequently, strengthen the reduction potential as active catalytic sites for photocatalytic CO2 reduction. Owing to these beneficial properties, the more-porous nanosheets of WO 3 with (002) facet have exhibited superior performance than that of less-porous nanosheets of WO3 with (220) facet and bulk WO3 with (205) facet. This study therefore provides a new understanding of regulating physical, optical, and electronic properties through intricate atomic structure modulation of WO3, and may find widespread application in optoelectronics, sensors, and energy conversion.

cond-mat.mtrl-sci↗

arXiv2025

AvatarShield: Visual Reinforcement Learning for Human-Centric Synthetic Video Detection

Recent advances in Artificial Intelligence Generated Content have led to highly realistic synthetic videos, particularly in human-centric scenarios involving speech, gestures, and full-body motion, posing serious threats to information authenticity and public trust. Unlike DeepFake techniques that focus on localized facial manipulation, human-centric video generation methods can synthesize entire human bodies with controllable movements, enabling complex interactions with environments, objects, and even other people. However, existing detection methods largely overlook the growing risks posed by such full-body synthetic content. Meanwhile, a growing body of research has explored leveraging LLMs for interpretable fake detection, aiming to explain decisions in natural language. Yet these approaches heavily depend on supervised fine-tuning, which introduces limitations such as annotation bias, hallucinated supervision, and weakened generalization. To address these challenges, we propose AvatarShield, a novel multimodal human-centric synthetic video detection framework that eliminates the need for dense textual supervision by adopting Group Relative Policy Optimization, enabling LLMs to develop reasoning capabilities from simple binary labels. Our architecture combines a discrete vision tower for high-level semantic inconsistencies and a residual extractor for fine-grained artifact analysis. We further introduce FakeHumanVid, a large-scale benchmark containing 15K real and synthetic videos across nine state-of-the-art human generation methods driven by text, pose, or audio. Extensive experiments demonstrate that AvatarShield outperforms existing methods in both in-domain and cross-domain settings.

cs.CV↗

arXiv2025

Si-Substituted MAX Phases and In-Situ Formation of Si-coated MXene Composites via Chlorosilane Etching

Silicon-based MAX phases are a promising class of layered ceramics with superior thermal and chemical stability. However, their synthesis remains challenging due to inherent thermodynamic instability at high temperatures. Herein, we develop a general top-down strategy to synthesize a broad family of Si-substituted MAX phases (M = Ti, V, Nb, Ta, Cr; X = C, N) by reacting Al-based MAX precursors with SiCl4 vapor. This approach not only circumvents traditional high-temperature limitations but also enables precise A-site defect engineering, resulting in phases with controlled vacancy concentrations (e.g., Nb2Si3/4C and Nb2Si1/2C). Furthermore, we introduce a redox potential-based model that rationalizes the reaction pathway. Using Tin+1AlXn etched with SiCl4 as an example, the process simultaneously forms Cl-terminated MXene (Mn+1XnCl2) and amorphous nano-Si, enabling the one-step synthesis of Si-coated MXene composites. This methodology provides new avenues for designing advanced MAX phases and MXene-based hybrids with tailored functionalities for applications in energy storage and catalysis.

cond-mat.mtrl-sci↗

arXiv2025

Rethinking Reasoning Quality in Large Language Models through Enhanced Chain-of-Thought via RL

Reinforcement learning (RL) has recently become the dominant paradigm for strengthening the reasoning abilities of large language models (LLMs). Yet the rule-based reward functions commonly used on mathematical or programming benchmarks assess only answer format and correctness, providing no signal as to whether the induced Chain-of-Thought (CoT) actually improves the answer. Furthermore, such task-specific training offers limited control over logical depth and therefore may fail to reveal a model's genuine reasoning capacity. We propose Dynamic Reasoning Efficiency Reward (DRER) -- a plug-and-play RL reward framework that reshapes both reward and advantage signals. (i) A Reasoning Quality Reward assigns fine-grained credit to those reasoning chains that demonstrably raise the likelihood of the correct answer, directly incentivising the trajectories with beneficial CoT tokens. (ii) A Dynamic Length Advantage decays the advantage of responses whose length deviates from a validation-derived threshold, stabilising training. To facilitate rigorous assessment, we also release Logictree, a dynamically constructed deductive reasoning dataset that functions both as RL training data and as a comprehensive benchmark. Experiments confirm the effectiveness of DRER: our 7B model attains GPT-o3-mini level performance on Logictree with 400 trianing steps, while the average confidence of CoT-augmented answers rises by 30%. The model further exhibits generalisation across diverse logical-reasoning datasets, and the mathematical benchmark AIME24. These results illuminate how RL shapes CoT behaviour and chart a practical path toward enhancing formal-reasoning skills in large language models. All code and data are available in repository https://github.com/Henryhe09/DRER.

cs.AI↗

arXiv2025

When Prompt Engineering Meets Software Engineering: CNL-P as Natural and Robust "APIs'' for Human-AI Interaction

With the growing capabilities of large language models (LLMs), they are increasingly applied in areas like intelligent customer service, code generation, and knowledge management. Natural language (NL) prompts act as the ``APIs'' for human-LLM interaction. To improve prompt quality, best practices for prompt engineering (PE) have been developed, including writing guidelines and templates. Building on this, we propose Controlled NL for Prompt (CNL-P), which not only incorporates PE best practices but also draws on key principles from software engineering (SE). CNL-P introduces precise grammar structures and strict semantic norms, further eliminating NL's ambiguity, allowing for a declarative but structured and accurate expression of user intent. This helps LLMs better interpret and execute the prompts, leading to more consistent and higher-quality outputs. We also introduce an NL2CNL-P conversion tool based on LLMs, enabling users to write prompts in NL, which are then transformed into CNL-P format, thus lowering the learning curve of CNL-P. In particular, we develop a linting tool that checks CNL-P prompts for syntactic and semantic accuracy, applying static analysis techniques to NL for the first time. Extensive experiments demonstrate that CNL-P enhances the quality of LLM responses through the novel and organic synergy of PE and SE. We believe that CNL-P can bridge the gap between emerging PE and traditional SE, laying the foundation for a new programming paradigm centered around NL.

cs.SE↗

arXiv2025

FinMMR: Make Financial Numerical Reasoning More Multimodal, Comprehensive, and Challenging

We present FinMMR, a novel bilingual multimodal benchmark tailored to evaluate the reasoning capabilities of multimodal large language models (MLLMs) in financial numerical reasoning tasks. Compared to existing benchmarks, our work introduces three significant advancements. (1) Multimodality: We meticulously transform existing financial reasoning benchmarks, and construct novel questions from the latest Chinese financial research reports. FinMMR comprises 4.3K questions and 8.7K images spanning 14 categories, including tables, bar charts, and ownership structure charts. (2) Comprehensiveness: FinMMR encompasses 14 financial subdomains, including corporate finance, banking, and industry analysis, significantly exceeding existing benchmarks in financial domain knowledge breadth. (3) Challenge: Models are required to perform multi-step precise numerical reasoning by integrating financial knowledge with the understanding of complex financial images and text. The best-performing MLLM achieves only 53.0% accuracy on Hard problems. We believe that FinMMR will drive advancements in enhancing the reasoning capabilities of MLLMs in real-world scenarios.

cs.CV↗

arXiv2025

FinanceReasoning: Benchmarking Financial Numerical Reasoning More Credible, Comprehensive and Challenging

We introduce FinanceReasoning, a novel benchmark designed to evaluate the reasoning capabilities of large reasoning models (LRMs) in financial numerical reasoning problems. Compared to existing benchmarks, our work provides three key advancements. (1) Credibility: We update 15.6% of the questions from four public datasets, annotating 908 new questions with detailed Python solutions and rigorously refining evaluation standards. This enables an accurate assessment of the reasoning improvements of LRMs. (2) Comprehensiveness: FinanceReasoning covers 67.8% of financial concepts and formulas, significantly surpassing existing datasets. Additionally, we construct 3,133 Python-formatted functions, which enhances LRMs' financial reasoning capabilities through refined knowledge (e.g., 83.2% $\rightarrow$ 91.6% for GPT-4o). (3) Challenge: Models are required to apply multiple financial formulas for precise numerical reasoning on 238 Hard problems. The best-performing model (i.e., OpenAI o1 with PoT) achieves 89.1% accuracy, yet LRMs still face challenges in numerical precision. We demonstrate that combining Reasoner and Programmer models can effectively enhance LRMs' performance (e.g., 83.2% $\rightarrow$ 87.8% for DeepSeek-R1). Our work paves the way for future research on evaluating and improving LRMs in domain-specific complex reasoning tasks.

cs.CL↗

arXiv2025

MARS: Defending Unmanned Aerial Vehicles From Attacks on Inertial Sensors with Model-based Anomaly Detection and Recovery

Unmanned Aerial Vehicles (UAVs) rely on measurements from Inertial Measurement Units (IMUs) to maintain stable flight. However, IMUs are susceptible to physical attacks, including acoustic resonant and electromagnetic interference attacks, resulting in immediate UAV crashes. Consequently, we introduce a Model-based Anomaly detection and Recovery System (MARS) that enables UAVs to quickly detect adversarial attacks on inertial sensors and achieve dynamic flight recovery. MARS features an attack-resilient state estimator based on the Extended Kalman Filter, which incorporates position, velocity, heading, and rotor speed measurements to reconstruct accurate attitude and angular velocity information for UAV control. Moreover, a statistical anomaly detection system monitors IMU sensor data, raising a system-level alert if an attack is detected. Upon receiving the alert, a multi-stage dynamic flight recovery strategy suspends the ongoing mission, stabilizes the drone in a hovering condition, and then resumes tasks under the resilient control. Experimental results in PX4 software-in-the-loop environments as well as real-world MARS-PX4 autopilot-equipped drones demonstrate the superiority of our approach over existing IMU-defense frameworks, showcasing the ability of the UAVs to survive attacks and complete the missions.

eess.SY↗

arXiv2025

The 2D Materials Roadmap

Over the past two decades, 2D materials have rapidly evolved into a diverse and expanding family of material platforms. Many members of this materials class have demonstrated their potential to deliver transformative impact on fundamental research and technological applications across different fields. In this roadmap, we provide an overview of the key aspects of 2D material research and development, spanning synthesis, properties and commercial applications. We specifically present roadmaps for high impact 2D materials, including graphene and its derivatives, transition metal dichalcogenides, MXenes as well as their heterostructures and moiré systems. The discussions are organized into thematic sections covering emerging research areas (e.g., twisted electronics, moiré nano-optoelectronics, polaritronics, quantum photonics, and neuromorphic computing), breakthrough applications in key technologies (e.g., 2D transistors, energy storage, electrocatalysis, filtration and separation, thermal management, flexible electronics, sensing, electromagnetic interference shielding, and composites) and other important topics (computational discovery of novel materials, commercialization and standardization). This roadmap focuses on the current research landscape, future challenges and scientific and technological advances required to address, with the intent to provide useful references for promoting the development of 2D materials.

cond-mat.mtrl-sci↗

arXiv2025

Phase stabilization of In2Se3 by disordered Ni intercalation and its enhanced thermoelectrical performance

Van der Waals (vdW) layered materials have gained significant attention owing to their distinctive structure and unique properties. The weak interlayer bonding in vdW layered materials enables guest atom intercalation, allowing precise tuning of their physical and chemical properties. In this work, a ternary compound, NixIn2Se3 (x = 0-0.3), with Ni randomly occupying the interlayers of In2Se3, was synthesized via an intercalation route driven by electron injection. The intercalated Ni atoms act as anchor points within the interlayer of In2Se3, which effectively suppresses the phase transition of In2Se3 at elevated temperatures. Furthermore, the disordered Ni intercalation significantly enhanced the electrical conductivity of In2Se3 through electron injection, while reducing the thermal conductivity due to the interlayer phonon scattering, leading to an improved thermoelectric performance. For instance, the thermoelectric figure of merit (ZT) of Ni0.3In2Se3 increased by 86% (in-plane) and 222% (out-of-plane) compared to In2Se3 at 500 oC. These findings not only provide an effective strategy to enhance the performance of layered thermoelectric materials, but also demonstrate the potential of intercalation chemistry for expanding the application scope of van der Waals (vdW) layered materials.

cond-mat.mtrl-sci↗

arXiv2025

FakeShield: Explainable Image Forgery Detection and Localization via Multi-modal Large Language Models

The rapid development of generative AI is a double-edged sword, which not only facilitates content creation but also makes image manipulation easier and more difficult to detect. Although current image forgery detection and localization (IFDL) methods are generally effective, they tend to face two challenges: \textbf{1)} black-box nature with unknown detection principle, \textbf{2)} limited generalization across diverse tampering methods (e.g., Photoshop, DeepFake, AIGC-Editing). To address these issues, we propose the explainable IFDL task and design FakeShield, a multi-modal framework capable of evaluating image authenticity, generating tampered region masks, and providing a judgment basis based on pixel-level and image-level tampering clues. Additionally, we leverage GPT-4o to enhance existing IFDL datasets, creating the Multi-Modal Tamper Description dataSet (MMTD-Set) for training FakeShield's tampering analysis capabilities. Meanwhile, we incorporate a Domain Tag-guided Explainable Forgery Detection Module (DTE-FDM) and a Multi-modal Forgery Localization Module (MFLM) to address various types of tamper detection interpretation and achieve forgery localization guided by detailed textual descriptions. Extensive experiments demonstrate that FakeShield effectively detects and localizes various tampering techniques, offering an explainable and superior solution compared to previous IFDL methods. The code is available at https://github.com/zhipeixu/FakeShield.

cs.CV↗

arXiv2025

NMR study of supersolid phases in the triangular-lattice antiferromagnet Na2BaCo(PO4)2

We report ultra-low-temperature $^{23}$Na NMR measurements on the Ising triangular lattice antiferromagnet Na$_2$BaCo(PO$_4$)$_2$, which precisely resolve the phase diagram under magnetic field applied along the crystalline $c$ axis. With increasing field, the NMR spectra resolve three ordered phases with distinct spin configurations: the Y, up-up-down (UUD), and V phases. The spin-lattice relaxation rate $1/T_1$ data demonstrate gapless excitations in the Y and V phases, strongly supporting their supersolid nature. However, the phase transitions from the UUD phase to the two supersolid phases exhibit dramatically different behaviors upon cooling. Prior to entering the Y phase, $1/T_1$ identifies a gapless regime within the UUD phase, suggesting a Berezinskii-Kosterlitz-Thouless phase above a second-order phase transition. In contrast, the coexistence of the UUD and V phases observed in our experiments provides direct evidence of a first-order phase transition between these phases.

cond-mat.str-el↗

arXiv2025

Universal dynamics of a pair condensate

Pair condensates appear in multiple branches of physics, always introducing exotic phenomena. The pair condensate in quantum magnetism is the spin nematic, whose static (quadrupolar) order is difficult to access, favoring dynamical probes. Here, we perform high-resolution neutron spectroscopy to obtain direct evidence for the presence of two spin-nematic phases induced in the triangular-lattice antiferromagnet Na2BaNi(PO4)2 by controlling the applied magnetic field. By combining precise experiments with quantitative theoretical and numerical analysis, we identify universal dynamics arising from the pair condensate. We show explicitly how the gapless Goldstone mode influences the dispersion and induces Cherenkov-like velocity-selective decay of the gapped single-quasiparticle band. These common spectral features shed new light on spin-nematic dynamics and underline the universal phenomenology shared by pair condensates across different physical systems.

cond-mat.str-el↗