SearcharxivSearch

arXiv subjects

R. Aladro

Publications and source records attributed to R. Aladro.

At least 19 recordsLinked to original sources

First detection of a deuterated molecule in a starburst environment within NGC 253

Deuterium was primarily created during the Big Bang Nucleosynthesis (BBN). This fact, alongside its fractionation reactions resulting in enhanced abundances of deuterated molecules, means that these abundances can be used to better understand many processes within the interstellar medium (ISM), as well as its history. Previously, observations of deuterated molecules have been limited to the Galaxy, the Magellanic Clouds and (with respect to HD) to quasar absorption spectra. We present the first robust detection of a deuterated molecule in a starburst environment and, besides HD, the first one detected outside the Local Group. We therefore can constrain the deuterium fractionation, as observed by DCN. We observed the CMZ of the nearby starburst galaxy NGC 253 covering multiple Giant Molecular Clouds (GMC) with cloud scale observations ($\sim 30$ pc) using ALMA. Via the use of the \texttt{MADCUBA} package we were able to perform LTE analysis in order to obtain deuterium fractionation estimates. We detect DCN in the nuclear region of the starburst galaxy NGC 253 and estimate the deuterium fractionation (D/H ratio) of DCN within the GMCs of the CMZ of NGC 253. We find a range of $5 \times 10^{-4}$ to $10 \times 10^{-4}$, relatively similar to the values observed in warm Galactic star-forming regions. We also determine an upper limit of D/H of $8 \times 10^{-5}$ from DCO\plus within one region, closer to the cosmic value of D/H. Our observations of deuterated molecules within NGC 253 appear to be consistent with previous galactic studies of star forming regions. This implies that warmer gas temperatures increase the abundance of DCN relative to other deuterated species. This study also further expands the regions, particularly in the extragalactic domain, in which deuterated species have been detected.

astro-ph.GA

Reconstructing the shock history in the CMZ of NGC 253 with ALCHEMI

HNCO and SiO are well known shock tracers and have been observed in nearby galaxies, including the nearby (D=3.5 Mpc) starburst galaxy NGC 253. The simultaneous detection of these two species in regions where the star formation rate is high may be used to study the shock history of the gas. We perform a multi-line molecular study using these two shock tracers (SiO and HNCO) with the aim of characterizing the gas properties. We also explore the possibility of reconstructing the shock history in NGC 253's Central Molecular Zone (CMZ). Six SiO transitions and eleven HNCO transitions were imaged at high resolution $1''.6$ (28 pc) with the Atacama Large Millimeter/submillimeter Array (ALMA) as part of the ALCHEMI Large Programme. Both non-LTE radiative transfer analysis and chemical modelling were performed in order to characterize the gas properties, and to investigate the chemical origin of the emission. The non-LTE radiative transfer analysis coupled with Bayesian inference shows clear evidence that the gas traced by SiO has different densities and temperatures than that traced by HNCO, with an indication that shocks are needed to produce both species. Chemical modelling further confirms such a scenario and suggests that fast and slow shocks are responsible for SiO and HNCO production, respectively, in most GMCs. We are also able to infer the physical characteristics of the shocks traced by SiO and HNCO for each GMC. Radiative transfer and chemical analysis of the SiO and HNCO in the CMZ of NGC 253 reveal a complex picture whereby most of the GMCs are subjected to shocks. We speculate on the possible shock scenarios responsible for the observed emission and provide potential history and timescales for each shock scenario. Higher spatial resolution observations of these two species are required in order to quantitatively differentiate between scenarios.

astro-ph.GA

Phosphine in the Venusian Atmosphere: A Strict Upper Limit from SOFIA GREAT Observations

The presence of phosphine (PH$_3$) in the atmosphere of Venus was reported by Greaves et al. (2021a), based on observations of the J=1-0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous-bearing gases. Here we present results from a search for PH$_3$ on Venus using the GREAT instrument aboard the SOFIA aircraft, over three flights conducted in November 2021. Multiple PH$_3$ transitions were targeted at frequencies centered on 533 GHz and 1067 GHz, but no evidence for atmospheric PH$_3$ was detected. Through radiative transfer modeling, we derived a disk-averaged upper limit on the PH$_3$ abundance of 0.8 ppb in the altitude range 75-110 km, which is more stringent than previous ground-based studies.

astro-ph.EP

The SOFIA FEEDBACK Legacy Survey: Dynamics and mass ejection in the bipolar HII region RCW 36

We present [CII] 158 $\mu$m and [OI] 63 $\mu$m observations of the bipolar HII region RCW 36 in the Vela C molecular cloud, obtained within the SOFIA legacy project FEEDBACK, which is complemented with APEX $^{12/13}$CO(3-2) and Chandra X-ray (0.5-7 keV) data. This shows that the molecular ring, forming the waist of the bipolar nebula, expands with a velocity of 1 - 1.9 km s$^{-1}$. We also observe an increased linewidth in the ring indicating that turbulence is driven by energy injection from the stellar feedback. The bipolar cavity hosts blue-shifted expanding [CII] shells at 5.2$\pm$0.5$\pm$0.5 km s$^{-1}$ (statistical and systematic uncertainty) which indicates that expansion out of the dense gas happens non-uniformly and that the observed bipolar phase might be relatively short ($\sim$0.2 Myr). The X-ray observations show diffuse emission that traces a hot plasma, created by stellar winds, in and around RCW 36. At least 50 \% of the stellar wind energy is missing in RCW 36. This is likely due to leakage which is clearing even larger cavities around the bipolar RCW 36 region. Lastly, the cavities host high-velocity wings in [CII] which indicates relatively high mass ejection rates ($\sim$5$\times$10$^{-4}$ M$_{\odot}$ yr$^{-1}$). This could be driven by stellar winds and/or radiation pressure, but remains difficult to constrain. This local mass ejection, which can remove all mass within 1 pc of RCW 36 in 1-2 Myr, and the large-scale clearing of ambient gas in the Vela C cloud indicates that stellar feedback plays a significant role in suppressing the star formation efficiency (SFE).

astro-ph.GA

Methanol masers in NGC 253 with ALCHEMI

Context: Methanol masers of Class I (collisionally-pumped) and Class II (radiatively-pumped) have been studied in great detail in our Galaxy in a variety of astrophysical environments such as shocks and star-forming regions and are helpful to analyze the properties of the dense interstellar medium. However, the study of methanol masers in external galaxies is still in its infancy. Aims: Our main goal is to search for methanol masers in the central molecular zone (CMZ; inner 500 pc) of the nearby starburst galaxy NGC 253. Methods: Covering a frequency range between 84 and 373 GHz ($\lambda$ = 3.6 to 0.8 mm) at high angular (1.6"$\sim$27 pc) and spectral ($\sim$8--9 km s$^{-1}$) resolution with the ALMA large program ALCHEMI, we have probed different regions across the CMZ of NGC 253. In order to look for methanol maser candidates, we employed the rotation diagram method and a set of radiative transfer models. Results: We detect for the first time masers above 84 GHz in NGC 253, covering an ample portion of the $J_{-1}\rightarrow(J-$ 1)$_{0}-E$ line series (at 84, 132, 229, and 278 GHz) and the $J_{0}\rightarrow(J-$ 1)$_{1}-A$ series (at 95, 146, and 198 GHz). This confirms the presence of the Class I maser line at 84 GHz, already reported but now being detected in more than one location. For the $J_{-1}\rightarrow(J-$ 1)$_{0}-E$ line series, we observe a lack of Class I maser candidates in the central star-forming disk. Conclusions: The physical conditions for maser excitation in the $J_{-1}\rightarrow(J-$ 1)$_{0}-E$ line series can be weak shocks and cloud-cloud collisions as suggested by shock tracers (SiO and HNCO) in bi-symmetric shock/active regions located in the outskirts of the CMZ. On the other hand, the presence of photodissociation regions due to a high star-formation rate would be needed to explain the lack of Class I masers in the very central regions.

astro-ph.GA

The chemical footprint of AGN feedback in the outflowing circumnuclear disk of NGC 1068

In the nearby (D=14 Mpc) AGN-starburst composite galaxy NGC 1068, it has been found that the molecular gas in the Circum-nuclear Disk (CND) is outflowing, which is a manifestation of ongoing AGN feedback. The outflowing gas has a large spread of velocities, which likely drive different shock chemistry signatures at different locations in the CND. We perform a multi-line molecular study using two shock tracers, SiO and HNCO, with the aim to determine the gas properties traced by these two species, and explore the possibility of reconstructing the shock history in the CND. Five SiO transitions and three HNCO transitions were imaged at high resolution $0''.5-0''.8$ with the Atacama Large Millimeter/submillimeter Array (ALMA). We performed both LTE and non-LTE radiative transfer analysis coupled with Bayesian inference process in order to characterize the gas properties, such as molecular gas density and gas temperature. We found clear evidence of chemical differentiation between SiO and HNCO, with the SiO/HNCO ratio ranging from greater than one on the east of CND to lower than one on the west side. The non-LTE radiative transfer analysis coupled with Bayesian inference confirms that the gas traced by SiO has different densities - and possibly temperatures - than that traced by HNCO. We find that SiO traces gas affected by fast shocks while the gas traced by HNCO is either just affected by slow shocks or not shocked at all. A distinct differentiation between SiO and HNCO has been revealed in our observations and the further analysis of the gas properties traced by both species, which confirms the results from previous chemical modelings.

astro-ph.GA

First extragalactic detection of a phosphorus-bearing molecule with ALCHEMI: phosphorus nitride (PN)

Phosphorus (P) is a crucial element for life given its central role in several biomolecules. P-bearing molecules have been discovered in different regions of the Milky Way, but not yet towards an extragalactic environment. We have searched for P-bearing molecules towards the nearby starburst Galaxy NGC 253. Using observations from the ALMA Comprehensive High-resolution Extragalactic Molecular Inventory (ALCHEMI) project, we used the MADCUBA package to model the emission of P-bearing molecules assuming Local Thermodynamic Equilibrium (LTE) conditions. We have also performed a non-LTE analysis using SpectralRadex. We report the detection of a P-bearing molecule, phosphorus nitride (PN), for the first time in an extragalactic environment, towards two giant molecular clouds (GMCs) of NGC 253. The LTE analysis yields total PN beam-averaged column densities $N$=(1.20$\pm$0.09)$\times$10$^{13}$ cm$^{-2}$ and $N$=(6.5$\pm$1.6)$\times$10$^{12}$ cm$^{-2}$, which translate into abundances with respect to H$_2$ of $\chi$=(8.0$\pm$1.0)$\times$10$^{-12}$ and $\chi$=(4.4$\pm$1.2)$\times$10$^{-12}$. We derived a low excitation temperature of $T_{\rm ex}$=(4.4$\pm$1.3) K towards the GMC with the brightest PN emission, which indicates that PN is sub-thermally excited. The non-LTE analysis results in column densities consistent with the LTE values. We have also searched for other P-bearing molecules (PO, PH$_{3}$, CP and CCP), and upper limits were derived. The derived PO/PN ratios are $<$1.3 and $<$1.7. The abundance ratio between PN and the shock-tracer SiO derived towards NGC 253 follows the same trend previously found towards Galactic sources. Comparison of the observations with chemical models indicates that the derived molecular abundances of PN in NGC 253 can be explained by shock-driven chemistry followed by cosmic-ray-driven photochemistry.

astro-ph.GA

ALCHEMI: an ALMA Comprehensive High-resolution Extragalactic Molecular Inventory. Survey presentation and first results from the ACA array

We used the Atacama Large Millimeter/submillimeter Array (ALMA), covering a nearly contiguous 289 GHz frequency range between 84.2 and 373.2 GHz, to image the continuum and spectral line emission at 1.6\arcsec ($\sim 28$ pc) resolution down to a sensitivity of $30-50$ mK. This article describes the ALMA Comprehensive High-resolution Extragalactic Molecular Inventory (ALCHEMI) Large Program. We focus on the analysis of the spectra extracted from the $15''$ ($\sim255$ pc) resolution ALMA Compact Array data. We model the molecular emission assuming local thermodynamic equilibrium with 78 species detected. Additionally, multiple hydrogen and helium recombination lines are identified. Spectral lines contribute 5 to 36\% of the total emission in frequency bins of 50 GHz. We report the first extragalactic detections of C$_2$H$_5$OH, HOCN, HC$_3$HO, and several rare isotopologues. Isotopic ratios of carbon, oxygen, sulfur, nitrogen and silicon were measure with multiple species. Infrared pumped vibrationaly excited HCN, HNC, and HC$_3$N emission, originating in massive star formation locations, is clearly detected at low resolution, while we do not detect it for HCO$^+$. We suggest high temperature conditions in these regions driving a seemingly "carbon-rich" chemistry which may also explain the observed high abundance of organic species close to those in Galactic hot cores. The $L_{vib}/L_{IR}$ ratio is used as a proxy to estimate a $3\%$ contribution from proto super star cluster to the global infrared emission. Measured isotopic ratios with high dipole moment species agree with those within the central kiloparsec of the Galaxy, while those derived from $\rm^{13}C^{18}O$ are a factor of 5 larger, confirming the existence of multiple ISM components within NGC 253 with different degrees of nucleosynthesis enrichment. ALCHEMI provides a template for early Universe galaxies.

astro-ph.GA

The Distribution and Origin of C$_2$H in NGC 253 from ALCHEMI

Observations of chemical species can provide an insight into the physical conditions of the emitting gas but it is important to understand how their abundances and excitation vary within different heating environments. C$_2$H is a molecule typically found in PDR regions of our own Galaxy but there is evidence to suggest it also traces other regions undergoing energetic processing in extragalactic environments. As part of the ALCHEMI ALMA large program, the emission of C$_2$H in the central molecular zone of the nearby starburst galaxy NGC 253 was mapped at 1.6 " (28 pc) resolution and characterized to understand its chemical origins. Spectral modelling of the N=1-0 through N=4-3 rotational transitions of C$_2$H was used to derive the C$_2$H column densities towards the dense clouds in NGC 253. Chemical modelling, including PDR, dense cloud, and shock models were then used to investigate the chemical processes and physical conditions that are producing the molecular emission. We find high C$_2$H column densities of $\sim 10^{15} cm^{-3}$ detected towards the dense regions of NGC 253. We further find that these column densities cannot be reproduced by assuming that the emission arises from the PDR regions at the edge of the clouds. Instead, we find that the C$_2$H abundance remains high even in the high visual extinction interior of these clouds and that this is most likely caused by a high cosmic-ray ionization rate.

astro-ph.GA

Observation and calibration strategies for large-scale multi-beam velocity-resolved mapping of the [CII] emission in the Orion molecular cloud

Context. The [CII] 158micron far-infrared fine-structure line is one of the dominant cooling lines of the star-forming interstellar medium (ISM). Hence [CII] emission originates in and thus can be used to trace a range of ISM processes. Velocity-resolved large-scale mapping of [CII] in star-forming regions provides a unique perspective of the kinematics of these regions and their interactions with the exciting source of radiation. Aims. We explore the scientific applications of large-scale mapping of velocity-resolved [CII] observations. With the [CII] observations, we investigate the effect of stellar feedback on the ISM. We present the details of observation, calibration, and data reduction using a heterodyne array receiver mounted on an airborne observatory. Results. A square-degree [CII] map with a spectral resolution of 0.3 km/s is presented. The scientific potential of this data is summarized with discussion of mechanical and radiative stellar feedback, filament tracing using [CII], [CII] opacity effects, [CII] and carbon recombination lines, and [CII] interaction with the large molecular cloud. The data quality and calibration is discussed in detail, and new techniques are presented to mitigate the effects of unavoidable instrument deficiencies (e.g. baseline stability) and thus to improve the data quality. A comparison with a smaller [CII] map taken with the Herschel/Heterodyne Instrument for the Far-Infrared (HIFI) spectrometer is presented.

astro-ph.IM

Observed CN and HCN intensity ratios exhibit subtle variations in extreme galaxy environments

We use both new and archival ALMA data of three energy lines each of CN and HCN to explore intensity ratios in dense gas in NGC 3256, NGC 7469, and IRAS 13120-5453. The HCN (3-2)/HCN (1-0) intensity ratio varies in NGC 3256 and NGC 7469, with superlinear trends of 1.53$\pm$0.07 and 1.55$\pm$0.05, respectively. We find an offset to higher HCN (3-2)/HCN (1-0) intensity ratios (~0.8) in IRAS 13120-5453 compared to NGC 3256 (~0.3-0.4) and NGC 7469 (~0.3-0.5). The HCN (4-3)/HCN (3-2) intensity ratio in NGC 7469 has a slope of 1.34$\pm$0.05. We attribute the variation within NGC 3256 to excitation associated with the northern and southern nuclei. In NGC 7469, the variations are localized to the region surrounding the active galactic nucleus. At our resolution (~700 pc), IRAS 13120-5453 shows little variation in the HCN intensity ratios. Individual galaxies show nearly constant CN (2-1)/CN (1-0) intensity ratios. We find an offset to lower CN (2-1)/CN (1-0) intensity ratios (~0.5) in NGC 3256 compared to the other two galaxies (~0.8). For the CN (3-2)/CN (2-1) intensity ratio, NGC 7469 has a superlinear trend of 1.55$\pm$0.04, with the peak localized toward the active galactic nucleus. We find high (~1.7) CN (1-0)/HCN (1-0) intensity ratios in IRAS 13120-5453 and in the northern nucleus of NGC 3256, compared to a more constant ratio (~1.1) in NGC 7469 and non-starbursting regions of NGC 3256.

astro-ph.GA

The PDR structure and kinematics around the compact HII regions S235A and S235C with [CII], [13CII], [OI] and HCO+ line profiles

The aim of the present work is to study structure and gas kinematics in the photodissociation regions (PDRs) around the compact HII regions S235A and S235C. We observe the [CII], [13CII] and [OI] line emission, using SOFIA/upGREAT and complement them by data of HCO+ and CO. We use the [13CII] line to measure the optical depth of the [CII] emission, and find that the [CII] line profiles are influenced by self-absorption, while the [13CII] line remains unaffected by these effects. Hence, for dense PDRs, [13CII] emission is a better tracer of gas kinematics. The optical depth of the [CII] line is up to 10 in S235A. We find an expanding motion of the [CII]-emitting layer of the PDRs into the front molecular layer in both regions. Comparison of the gas and dust columns shows that gas components visible neither in the [CII] nor in low-J CO lines may contribute to the total column across S235A. We test whether the observed properties of the PDRs match the predictions of spherical models of expanding HII region + PDR + molecular cloud. Integrated intensities of the [13CII], [CII] and [OI] lines are well-represented by the model, but the models do not reproduce the double-peaked [CII] line profiles due to an insufficient column density of C+. The model predicts that the [OI] line could be a more reliable tracer of gas kinematics, but the foreground self-absorbing material does not allow using it in the considered regions.

astro-ph.GA

ALMA view of the $^{12}$C/$^{13}$C isotopic ratio in starburst galaxies

We derive molecular-gas-phase $^{12}$C/$^{13}$C isotope ratios for the central few 100 pc of the three nearby starburst galaxies NGC 253, NGC 1068, and NGC 4945 making use of the $λ$ $\sim$ 3 mm $^{12}$CN and $^{13}$CN $N$ = 1--0 lines in the ALMA Band 3. The $^{12}$C/$^{13}$C isotopic ratios derived from the ratios of these lines range from 30 to 67 with an average of 41.6 $\pm$ 0.2 in NGC 253, from 24 to 62 with an average of 38.3 $\pm$ 0.4 in NGC 1068, and from 6 to 44 with an average of 16.9 $\pm$ 0.3 in NGC 4945. The highest $^{12}$C/$^{13}$C isotopic ratios are determined in some of the outskirts of the nuclear regions of the three starburst galaxies. The lowest ratios are associated with the northeastern and southwestern molecular peaks of NGC 253, the northeastern and southwestern edge of the mapped region in NGC 1068, and the very center of NGC 4945. In case of NGC 1068, the measured ratios suggest inflow from the outer part of NGC 1068 into the circum-nuclear disk through both the halo and the bar. Low $^{12}$C/$^{13}$C isotopic ratios in the central regions of these starburst galaxies indicate the presence of highly processed material.

astro-ph.GA

Spatially resolved carbon and oxygen isotopic ratios in NGC 253 using optically thin tracers

To trace chemical evolution in a prototypical starburst environment, we spatially resolve the carbon and oxygen isotope ratios across the central molecular zone (full size ~$\sim 600$ pc) in the nearby starburst galaxy NGC 253. We imaged the emission of the optically thin isotopologues $^{13}$CO, C$^{18}$O, C$^{17}$O, $^{13}$C$^{18}$O at a spatial resolution $\sim50$ pc, comparable to the typical size of giant molecular associations. Optical depth effects and contamination of $^{13}$C$^{18}$O by C$_4$H is discussed and accounted for to derive column densities. This is the first extragalactic detection of the double isotopologue $^{13}$C$^{18}$O. Derived isotopic ratios $^{12}$C/$^{13}$C$\sim21\pm6$, $^{16}$O/$^{18}$O$\sim130\pm40$, and $^{18}$O/$^{17}$O$\sim4.5\pm0.8$ differ from the generally adopted values in the nuclei of galaxies. The molecular clouds in the central region of NGC 253 show similar rare isotope enrichment to those within the central molecular zone of the Milky way. This enrichment is attributed to stellar nucleosynthesis. Measured isotopic ratios suggest an enhancement of $^{18}$O as compared to our Galactic center, which we attribute to an extra $^{18}$O injection from massive stars. Our observations show evidence for mixing of distinct gas components with different degrees of processing. We observe an extra molecular component of highly processed gas on top of the already proposed less processed gas being transported to the central region of NGC 253. Such multicomponent nature and optical depth effects may hinder the use of isotopic ratios based on spatially unresolved line to infer the star formation history and/or initial stellar mass function properties in the nuclei of galaxies.

astro-ph.GA

Hidden or missing outflows in highly obscured galaxy nuclei?

Understanding the nuclear growth and feedback processes in galaxies requires investigating their often obscured central regions. One way to do this is to use (sub)millimeter line emission from vibrationally excited HCN (HCN-vib). It has been suggested that the most intense HCN-vib emission from a galaxy is connected to a phase of nuclear growth that occurs before the nuclear feedback processes have been fully developed. We aim to investigate if there is a connection between the presence of strong HCN-vib emission and the development of feedback in (U)LIRGs. We collected literature and archival data to compare the luminosities of rotational lines of HCN-vib, normalized to the total infrared luminosity, to the median velocities of 119 μm OH absorption lines, potentially indicating outflows, in a total of 17 (U)LIRGs. The most HCN-vib luminous systems all lack signatures of significant molecular outflows in the far-infrared OH absorption lines. However, at least some of the systems with bright HCN-vib emission do have fast and collimated outflows that can be seen in spectral lines at longer wavelengths. We conclude that the galaxy nuclei with the highest L(HCN-vib)/L(IR) do not drive wide-angle outflows detectable using the median velocities of far-infrared OH absorption lines. It is possible that this is due to an orientation effect where sources which are oriented in such a way that their outflows are not along our line of sight also radiate a smaller proportion of their infrared luminosity in our direction. It could also be that massive wide-angle outflows destroy the deeply embedded regions responsible for bright HCN-vib emission, so that the two phenomena cannot coexist. This would strengthen the idea that vibrationally excited HCN traces a heavily obscured stage of evolution before nuclear feedback mechanisms are fully developed.

astro-ph.GA

The upGREAT dual frequency heterodyne arrays for SOFIA

We present the performance of the upGREAT heterodyne array receivers on the SOFIA telescope after several years of operations. This instrument is a multi-pixel high resolution (R > 10^7) spectrometer for the Stratospheric Observatory for Far-Infrared Astronomy (SOFIA). The receivers use 7-pixel subarrays configured in a hexagonal layout around a central pixel. The low frequency array receiver (LFA) has 2x7 pixels (dual polarization), and presently covers the 1.83-2.06 THz frequency range, which allows to observe the [CII] and [OI] lines at 158 um and 145 um wavelengths. The high frequency array (HFA) covers the [OI] line at 63 um and is equipped with one polarization at the moment (7 pixels, which can be upgraded in the near future with a second polarization array). The 4.7 THz array has successfully flown using two separate quantum-cascade laser local oscillators from two different groups. NASA completed the development, integration and testing of a dual-channel closed-cycle cryocooler system, with two independently operable He compressors, aboard SOFIA in early 2017 and since then, both arrays can be operated in parallel using a frequency separating dichroic mirror. This configuration is now the prime GREAT configuration and has been added to SOFIA's instrument suite since observing cycle 6.

astro-ph.IM

Abundant Z-cyanomethanimine in the interstellar medium: paving the way to the synthesis of adenine

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes previously proposed (gas-phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130$-$210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.

astro-ph.GA

Molecular gas in the northern nucleus of Mrk273: Physical and chemical properties of the disk and its outflow

Aiming to characterise the properties of the molecular gas in the ultraluminous infrared galaxy Mrk273 and its outflow, we used the NOEMA interferometer to image the dense gas molecular tracers HCN, HCO+, HNC, HOC+ and HC3N at 86GHz and 256GHz with angular resolutions of 4.9x4.5 arcsec (3.7x3.4 kpc) and 0.61x0.55 arcsec (460x420 pc). We also modelled the flux of several H2O lines observed with Herschel using a radiative transfer code that includes excitation by collisions as well as by far-infrared photons. The disk of the Mrk273 north nucleus has two components with decoupled kinematics. The gas in the outer parts (1.5 kpc) rotates with a south-east to north-west direction, while in the inner disk (300 pc) follows a north-east to south-west rotation. The central 300 pc, which hosts a compact starburst region, is filled with dense and warm gas, contains a dynamical mass of (4-5)x10^9M_sun, a luminosity of L'_HCN=(3-4)x10^8 K km/s pc^2, and a dust temperature of 55 K. At the very centre, a compact core with R~50 pc has a luminosity of L_IR=4x10^11L_sun (30% of the total infrared luminosity), and a dust temperature of 95 K. The core is expanding at low velocities ~50-100 km/s, probably affected by the outflowing gas. We detect the blue-shifted component of the outflow, while the red-shifted counterpart remains undetected in our data. Its cold and dense phase reaches fast velocities up to ~1000 km/s, while the warm outflowing gas has more moderate maximum velocities of ~600 km/s. The outflow is detected as far as 460 pc from the centre in the northern direction, and has a mass of dense gas <8x10^8M_sun. The difference between the position angles of the inner disk (~70 degree) and the outflow (~10 degree) indicates that the outflow is likely powered by the AGN, and not by the starburst. Regarding the chemistry, we measure an extremely low HCO+/HOC+ ratio of 10+-5 in the inner disk of Mrk273.

astro-ph.GA