arXiv subjects

R. Cayrel

Publications and source records attributed to R. Cayrel.

At least 19 recordsLinked to original sources

arXiv2019

The $^6$Li/$^7$Li isotopic ratio in the metal-poor binary CS22876--032

We present high-resolution and high-quality UVES spectroscopic data of the metal-poor double-lined spectroscopic binary CS 22876--032 ([Fe/H] $\sim -3.7$ dex), with the goal to derive the $^6$Li/$^7$Li isotopic ratio by analysing the \ion{Li}{i} $\lambda$~670.8~nm doublet. We coadd all 28 useful spectra normalised and corrected for radial velocity to the rest frame of the primary star. We fit the Li profile with a grid of the 3D-NLTE synthetic spectra, to take into account the line profile asymmetries induced by stellar convection, and perform Monte Carlo simulations to evaluate the uncertainty of the fit of the Li line profile. We check that the veiling factor does not affect the derived isotopic ratio, $^6$Li/$^7$Li, and only modifies the Li abundance, A(Li), by about 0.15~dex. The best fit of the Li profile of the primary star provides A(Li)~$ = 2.17 \pm 0.01$~dex and $^6$Li/$^7$Li~$=8^{+2}_{-5}$\% at 68\% confidence level. In addition, we improve the Li abundance of the secondary star at A(Li)~$= 1.55 \pm 0.04$~dex, which is about 0.6~dex lower than that of the primary star. The analysis of the Li profile of the primary star is consistent with no detection of $^6$Li and provides an upper-limit to the isotopic ratio of $^6$Li/$^7$Li~$< 10$\% at this very low metallicity, about 0.5~dex lower in metallicity than previous attempts for detection of $^6$Li in extremely metal poor stars. These results do not solve or worsen the cosmological $^7$Li problem, nor support the need for non standard $^6$Li production in the early Universe.

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arXiv2018

TOPoS V: Abundance ratios in a sample of very metal-poor turn-off stars

Extremely metal-poor stars are keys to understand the early evolution of our Galaxy. The ESO large programme TOPoS has been tailored to analyse a new set of metal-poor turn-off stars, whereas most of the previously known extremely metal-poor stars are giant stars. Sixty five turn-off stars (preselected from SDSS spectra) have been observed with the X-Shooter spectrograph at the ESO VLT Unit Telescope 2, to derive accurate and detailed abundances of magnesium, silicon, calcium, iron, strontium and barium. We analysed medium-resolution spectra (R ~ 10 000) obtained with the ESO X-Shooter spectrograph and computed the abundances of several alpha and neutron-capture elements using standard one-dimensional local thermodynamic equilibrium (1D LTE) model atmospheres. Our results confirms the super-solar [Mg/Fe] and [Ca/Fe] ratios in metal-poor turn-off stars as observed in metal-poor giant stars. We found a significant spread of the [alpha/Fe] ratios with several stars showing sub-solar [Ca/Fe] ratios. We could measure the abundance of strontium in 12 stars of the sample, leading to abundance ratios [Sr/Fe] around the Solar value. We detected barium in two stars of the sample. One of the stars (SDSS J114424-004658) shows both very high [Ba/Fe] and [Sr/Fe] abundance ratios (>1 dex).

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arXiv2018

TOPoS: IV. Chemical abundances from high-resolution observations of seven EMP stars

Extremely metal-poor stars provide us with indirect information on the first generations of massive stars. The TOPoS survey has been designed to increase the census of these stars and to provide a chemical inventory that is as detailed as possible. Seven of the most iron-poor stars have been observed with the UVES spectrograph at the ESO VLT Kueyen 8.2m telescope to refine their chemical composition. We analysed the spectra based on 1D LTE model atmospheres, but also used 3D hydrodynamical simulations of stellar atmospheres. We measured carbon in six of the seven stars: all are carbon-enhanced and belong to the low-carbon band, defined in the TOPoS II paper. We measured lithium (A(Li)=1.9) in the most iron-poor star (SDSS J1035+0641, [Fe/H] < -5.2 ). We were also able to measure Li in three stars at [Fe/H]~ -4.0, two of which lie on the Spite plateau. We confirm that SDSS J1349+1407 is extremely rich in Mg, but not in Ca. It is also very rich in Na. Several of our stars are characterised by low alpha-to-iron ratios. The lack of high-carbon band stars at low metallicity can be understood in terms of evolutionary timescales of binary systems. The detection of Li in SDSS J1035+0641 places a strong constraint on theories that aim at solving the cosmological lithium problem. The Li abundance of the two warmer stars at [Fe/H]~ -4.0 places them on the Spite plateau, while the third, cooler star, lies below. We argue that this suggests that the temperature at which Li depletion begins increases with decreasing [Fe/H]. SDSS J1349+1407 may belong to a class of Mg-rich EMP stars. We cannot assess if there is a scatter in alpha-to-iron ratios among the EMP stars or if there are several discrete populations. However, the existence of stars with low alpha-to-iron ratios is supported by our observations.

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arXiv2017

Using the CIFIST grid of CO5BOLD 3D model atmospheres to study the effects of stellar granulation on photometric colours. I. Grids of 3D corrections in the UBVRI, 2MASS, Hipparcos, Gaia, and SDSS systems

The atmospheres of cool stars are temporally and spatially inhomogeneous due to the effects of convection.The influence of this inhomogeneity, referred to as granulation, on colours has never been investigated over a large range of effective temperatures and gravities. We aim to study, in a quantitative way, the impact of granulation on colours. We use the CIFIST grid of CO5BOLD hydrodynamical models to compute emerging fluxes. These in turn are used to compute theoretical colours in the UBVRI,2MASS,Hipparcos,Gaia and SDSS systems. Every CO5BOLD model has a corresponding one dimensional (1D) plane-parallel LHD model computed for the same atmospheric parameters, which we used to define a "3D correction" that can be applied to colours computed from fluxes computed from any 1D model atmosphere code. The 3D corrections on colours are generally small, of the order of a few hundredths of a magnitude, yet they are far from negligible. We find that ignoring granulation effects can lead to underestimation of Teff by up to 200K and overestimation of gravity by up to 0.5dex, when using colours as diagnostics. We have identified a major shortcoming in how scattering is treated in the current version of the CIFIST grid, which could lead to offsets of the order 0.01mag, especially for colours involving blue and UV bands.We have investigated the Gaia and Hipparcos photometric systems and found that the (G-H_p),(BP-RP) diagram is immune to the effects of granulation. In addition, we point to the potential of the RVS photometry as a metallicity diagnostic. Our investigation shows that the effects of granulation should not be neglected if one wants to use colours as diagnostics of the stellar parameters of F,G,K stars. A limitation is that scattering is treated as true absorption in our current computations, thus our 3D corrections are likely an upper limit to the true effect. (Abridged)

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arXiv2016

TOPoS: III. An ultra iron-poor multiple CEMP system

One of the primary objectives of the TOPoS survey is to search for the most metal-poor stars. Our search has led to the discovery of one of the most iron-poor objects known, SDSS\,J092912.32+023817.0. This object is a multiple system, in which two components are clearly detected in the spectrum. We have analysed 16 high-resolution spectra obtained using the UVES spectrograph at the ESO 8.2m VLT telescope to measure radial velocities and determine the chemical composition of the system. Cross correlation of the spectra with a synthetic template yields a double-peaked cross-correlation function (CCF) for eight spectra, and in one case there is evidence for the presence of a third peak. Chemical analysis of the spectrum obtained by averaging all the spectra for which the CCF showed a single peak found that the iron abundance is [Fe/H]=-4.97. The system is also carbon enhanced with [C/Fe]=+3.91 (A(C)=7.44). From the permitted oxygen triplet we determined an upper limit for oxygen of [O/Fe]<+3.52 such that C/O>1.3. We are also able to provide more stringent upper limits on the Sr and Ba abundances ([Sr/Fe]<+0.70, and [Ba/Fe]<+1.46, respectively).

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arXiv2015

The photospheric solar oxygen project: IV. 3D-NLTE investigation of the 777 nm triplet lines

The solar photospheric oxygen abundance is still widely debated. Adopting the solar chemical composition based on the "low" oxygen abundance, as determined with the use of three-dimensional (3D) hydrodynamical model atmospheres, results in a well-known mismatch between theoretical solar models and helioseismic measurements that is so far unresolved. We carry out an independent redetermination of the solar oxygen abundance by investigating the center-to-limb variation of the OI IR triplet lines at 777 nm in different sets of spectra with the help of detailed synthetic line profiles based on 3D hydrodynamical CO5BOLD model atmospheres and 3D non-LTE line formation calculations with NLTETD. The idea is to simultaneously derive the oxygen abundance,A(O), and the scaling factor SH that describes the cross-sections for inelastic collisions with neutral hydrogen relative the classical Drawin formula. The best fit of the center-to-limb variation of the triplet lines achieved with the CO5BOLD 3D solar model is clearly of superior quality compared to the line profile fits obtained with standard 1D model atmospheres. Our best estimate of the 3D non-LTE solar oxygen abundance is A(O) = 8.76 +/- 0.02, with the scaling factor SH in the range between 1.2 and 1.8. All 1D non-LTE models give much lower oxygen abundances, by up to -0.15 dex. This is mainly a consequence of the assumption of a $μ$-independent microturbulence.

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arXiv2015

TOPoS: II. On the bimodality of carbon abundance in CEMP stars. Implications on the early chemical evolution of galaxies

In the course of the TOPoS (Turn Off Primordial Stars) survey, aimed at discovering the lowest metallicity stars, we have found several carbon-enhanced metal-poor (CEMP) stars. We here present our analysis of six CEMP stars. Calcium and carbon are the only elements that can be measured in all six stars. The range is -5.0<=[Ca/H]< -2.1 and 7.12<=A(C)<=8.65. For star SDSS J1742+2531 we were able to detect three FeI lines from which we deduced [Fe/H]=-4.80, from four CaII lines we derived [Ca/H]=-4.56, and from synthesis of the G-band we derived A(C)=7.26. For SDSS J1035+0641 we were not able to detect any iron lines, yet we could place a robust (3sigma) upper limit of [Fe/H]< -5.0 and measure the Ca abundance, with [Ca/H]=-5.0, and carbon, A(C)=6.90. No lithium is detected in the spectrum of SDSS J1742+2531 or SDSS J1035+0641, which implies a robust upper limit of A(Li)<1.8 for both stars. Our measured carbon abundances confirm the bimodal distribution of carbon in CEMP stars, identifying a high-carbon band and a low-carbon band. We propose an interpretation of this bimodality according to which the stars on the high-carbon band are the result of mass transfer from an AGB companion, while the stars on the low-carbon band are genuine fossil records of a gas cloud that has also been enriched by a faint supernova (SN) providing carbon and the lighter elements. (Abridged)

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arXiv2014

High-resolution abundance analysis of very metal-poor r-I stars

Moderately r-process-enriched stars (r-I) are at least four times as common as those that are greatly enriched in r-process elements (r-II), and the abundances in their atmospheres are important tools for obtaining a better understanding of the nucleosynthesis processes responsible for the origin of the elements beyond the iron peak. The main aim of this work is to derive abundances for a sample of seven metal-poor stars with classified as r-I stars, to understand the role of these stars for constraining the astrophysical nucleosynthesis event(s) that is(are) responsible for the production of the r-process, and to investigate whether they differ, in any significant way, from the r-II stars. We carried out a detailed abundance analysis based on high-resolution spectra obtained with the VLT/UVES spectrograph. The OSMARCS LTE 1D model atmosphere grid was employed, along with the spectrum synthesis code Turbospectrum. We have derived abundances of light elements Li, C, and N, alpha-elements, odd-Z elements, iron-peak elements, and the trans-iron elements from the first peak, the second peak, the third peak, and the actinides regions. The results are compared with values for these elements for r-II and normal very and extremely metal-poor stars reported in the literature, ages based on radioactive chronometry are explored using different models, and a number of conclusions about the r-process and the r-I stars are presented. Hydrodynamical models were used for some elements, and general behaviors for the 3D corrections were presented.

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arXiv2013

TOPoS: I. Survey design and analysis of the first sample

The metal-weak tail of the metallicity distribution function (MDF) of the Galactic Halo stars contains crucial information on the formation mode of the first generation of stars. To determine this observationally, it is necessary to observe large numbers of extremely metal-poor stars. We present here the Turn-Off Primordial Stars survey (TOPoS) that is conducted as an ESO Large Programme at the VLT. This project has {four} main goals: (i) to understand the formation of low-mass stars in a low-metallicity gas: determine the metal-weak tail of the halo MDF below [M/H]=-3.5. In particular, we aim at determining the critical metallicity, that is the lowest metallicity sufficient for the formation of low-mass stars; (ii) to determine the relative abundance of the elements in extremely metal-poor stars, which are the signature of the massive first stars; (iii) to determine the trend of the lithium abundance at the time when the Galaxy formed; and (iv) to derive the fraction of C-enhanced extremely metal-poor stars with respect to normal extremely metal-poor stars. The large number of stars observed in the SDSS provides a good sample of candidates of stars at extremely low metallicity. Candidates with turn-off colours down to magnitude g=20 were selected from the low-resolution spectra of SDSS by means of an automated procedure. X-Shooter has the potential of performing the necessary follow-up spectroscopy, providing accurate metallicities and abundance ratios for several key elements for these stars. We here present the stellar parameters of the first set of stars. The nineteen stars range in iron abundance between -4.1 and -2.9 dex relative to the Sun. Two stars have a high radial velocity and, according to our estimate of their kinematics, appear to be marginally bound to the Galaxy and are possibly accreted from another galaxy.

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arXiv2013

X-Shooter GTO: evidence for a population of extremely metal-poor, alpha-poor stars

The extremely metal-poor stars are the direct descendants of the first generation stars. They carry the chemical signature of the pristine Universe at the time they formed, shortly after the Big Bang. We aim to derive information about extremely metal-poor stars from their observed spectra. Four extremely metal-poor stars were selected from the Sloan Digital Sky Survey (SDSS) and observed during the guaranteed observing time of X-Shooter. The X-Shooter spectra were analysed using an automatic code, MyGIsFOS, which is based on a traditional analysis method. It makes use of a synthetic grid computed from one-dimensional, plane-parallel, hydrostatic model atmospheres. The low metallicity derived from the SDSS spectra is confirmed here. Two kinds of stars are found. Two stars are confirmed to be extremely metal-poor, with no evidence of any enhancement in carbon. The two other stars are strongly enhanced in carbon. We could not derive iron abundance for one of them, while [Ca/H] is below -4.5. Two of the stars are members of the rare population of extremely metal-poor stars low in alpha elements.

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arXiv2013

Oxygen spectral line synthesis: 3D non-LTE with CO5BOLD hydrodynamical model atmospheres

In this work we present first results of our current project aimed at combining the 3D hydrodynamical stellar atmosphere approach with non-LTE (NLTE) spectral line synthesis for a number of key chemical species. We carried out a full 3D-NLTE spectrum synthesis of the oxygen IR 777 nm triplet, using a modified and improved version of our NLTE3D package to calculate departure coefficients for the atomic levels of oxygen in a CO5BOLD 3D hydrodynamical solar model atmosphere. Spectral line synthesis was subsequently performed with the Linfor 3D code. In agreement with previous studies, we find that the lines of the oxygen triplet produce deeper cores under NLTE conditions, due to the diminished line source function in the line forming region. This means that the solar oxygen IR 777 nm lines should be stronger in NLTE, leading to negative 3D NLTE-LTE abundance corrections. Qualitatively this result would support previous claims for a relatively low solar oxygen abundance. Finally, we outline several further steps that need to be taken in order to improve the physical realism and numerical accuracy of our current 3D-NLTE calculations.

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arXiv2012

First stars XVI. STIS/HST abundances of heavy-elements in the uranium-rich star CS 31082-001

Detailed abundances of the elements produced by r-process nucleosynthesis in various circumstances are our best observational clues to their origin, since the site(s) of r-element production is(are) still not known with certainty. A small fraction of extremely metal-poor (EMP) stars exhibit excesses of heavy neutron-capture elements produced in the r-process, and CS 31082-001 is among the 4 well-known r-process-enhanced EMP stars. Observations with HST/STIS provide abundances for elements observable only from the UV region. Here we aim to supplement the optical data with abundances from near-UV spectroscopy of the first and second peak of the r-elements, which are crucial to giving insight into the nucleosynthesis of the elements beyond iron. The UVES spectrum provided additional measurements, thereby improving the previous results. The spectra were analyzed with the OSMARCS LTE model atmosphere and with a consistent approach based on the spectrum synthesis code Turbospectrum to derive abundances of heavy elements in CS 31082-001, using updated oscillator strengths from the recent literature. We computed synthetic spectra for all lines of the elements of interest, checking for proper intensities and possible blends. We combined the abundances of heavy elements derived in previous works with the derivation of abundances from all reliable new list of lines, for the first and second peaks of r-elements. We were able to derive new abundances for 23 n-elements, 6 of them - Ge, Mo, Lu, Ta, W, and Re - were not available in previous works, making this star the most complete r-II object studied, with a total of 37 detections of n-capture elements. We also present the first NLTE+3D lead abundance in this star. The results provide improved constraints on the nature of the r-process.

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arXiv2012

6Li detection in metal-poor stars: can 3D model atmospheres solve the second lithium problem?

The presence of 6Li in the atmospheres of metal-poor halo stars is usually inferred from the detection of a subtle extra depression in the red wing of the 7Li doublet line at 670.8 nm. However, the intrinsic line asymmetry caused by convective flows in the photospheres of cool stars is almost indistinguishable from the asymmetry produced by a weak 6Li blend on a (presumed) symmetric 7Li profile. Previous determinations of the 6Li/ 7Li isotopic ratio based on 1D model atmospheres, ignoring the convection-induced line asymmetry, must therefore be considered as upper limits. By comparing synthetic 1D LTE and 3D non-LTE line profiles of the Li 670.8 nm feature, we quantify the differential effect of the convective line asymmetry on the derived 6Li abundance as a function of effective temperature, gravity, and metallicity. As expected, we find that the asymmetry effect systematically reduces the resulting 6Li/7Li ratios. Depending on the stellar parameters, the 3D-1D offset in 6Li/7Li ranges between -0.005 and -0.020. When this purely theoretical correction is taken into account for the Asplund 2006 sample of stars, the number of significant 6Li detections decreases from 9 to 5 (2 sigma criterion), or from 5 to 2 (3 sigma criterion). We also present preliminary results of a re-analysis of high-resolution, high S/N spectra of individual metal-poor turn-off stars, to see whether the "second Lithium problem" actually disappears when accounting properly for convection and non-LTE line formation in 3D stellar atmospheres. Out of 8 stars, HD84937 seems to be the only significant (2 sigma) detection of 6Li. In view of our results, the existence of a 6Li plateau appears questionable.

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arXiv2012

An extremely primitive halo star

The early Universe had a chemical composition consisting of hydrogen, helium and traces of lithium1, almost all other elements were created in stars and supernovae. The mass fraction, Z, of elements more massive than helium, is called "metallicity". A number of very metal poor stars have been found some of which, while having a low iron abundance, are rich in carbon, nitrogen and oxygen. For theoretical reasons and because of an observed absence of stars with metallicities lower than Z=1.5E-5, it has been suggested that low mass stars (M<0.8M\odot, the ones that survive to the present day) cannot form until the interstellar medium has been enriched above a critical value, estimated to lie in the range 1.5E-8\leqZ\leq1.5E-6, although competing theories claiming the contrary do exist. Here we report the chemical composition of a star with a very low Z\leq6.9E-7 (4.5E-5 of that of the Sun) and a chemical pattern typical of classical extremely metal poor stars, meaning without the enrichment of carbon, nitrogen and oxygen. This shows that low mass stars can be formed at very low metallicity. Lithium is not detected, suggesting a low metallicity extension of the previously observed trend in lithium depletion. Lithium depletion implies that the stellar material must have experienced temperatures above two million K in its history, which points to rather particular formation condition or internal mixing process, for low Z stars.

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arXiv2012

A primordial star in the heart of the Lion

Context: The discovery and chemical analysis of extremely metal-poor stars permit a better understanding of the star formation of the first generation of stars and of the Universe emerging from the Big Bang. aims: We report the study of a primordial star situated in the centre of the constellation Leo (SDSS J102915+172027). method: The star, selected from the low resolution-spectrum of the Sloan Digital Sky Survey, was observed at intermediate (with X-Shooter at VLT) and at high spectral resolution (with UVES at VLT). The stellar parameters were derived from the photometry. The standard spectroscopic analysis based on 1D ATLAS models was completed by applying 3D and non-LTE corrections. results: An iron abundance of [Fe/H]=--4.89 makes SDSS J102915+172927 one of the lowest [Fe/H] stars known. However, the absence of measurable C and N enhancements indicates that it has the lowest metallicity, Z<= 7.40x10^{-7} (metal-mass fraction), ever detected. No oxygen measurement was possible. conclusions: The discovery of SDSS J102915+172927 highlights that low-mass star formation occurred at metallicities lower than previously assumed. Even lower metallicity stars may yet be discovered, with a chemical composition closer to the composition of the primordial gas and of the first supernovae.

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arXiv2011

X-Shooter GTO: Chemical analysis of a sample of EMP candidates

Context: Extremely metal-poor stars (EMP) are very rare objects that hold in their atmospheres the fossil record of the chemical composition of the early phases of Galactic evolution. Finding these objects and determining their chemical composition provides important constraints on these early phases. Aims: Using a carefully designed selection method, we chose a sample of candidate EMP stars from the low resolution spectra of the Sloan Digital Sky Survey and observed them with X-Shooter at the VLT to confirm their metallicities and determine abundances for as many elements as possible. Method: The X-Shooter spectra are analysed by means of one-dimensional, plane-parallel, hydrostatic model atmospheres. Corrections for the granulation effects are computed using CO5BOLD hydrodynamical simulations. Results: All the candidates are confirmed to be EMP stars, proving the efficiency of our selection method within about 0.5 dex. The chemical composition of this sample is compatible with those of brighter samples, suggesting that the stars in the Galactic halo are well mixed. Conclusions These observations show that it is feasible to observe, in a limited amount of time, a large sample of about one hundred stars among EMP candidates selected from the SDSS. Such a size of sample will allow us, in particular, to confirm or refute the existence of a vertical drop in the Galactic Halo metallicity distribution function around [Fe/H] ~ -3.5.

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arXiv2011

NLTE strontium abundance in a sample of extremely metal poor stars and the Sr/Ba ratio in the early Galaxy

Heavy element abundances in extremely metal-poor stars provide strong constraints on the processes of forming these elements in the first stars. We attempt to determine precise abundances of strontium in a homogeneous sample of extremely metal-poor stars. The abundances of strontium in 54 very or extremely metal-poor stars, was redetermined by abandoning the local thermodynamic equilibrium (LTE) hypothesis, and fitting non-LTE (NLTE) profiles to the observed spectral lines. The corrected Sr abundances and previously obtained NLTE Ba abundances are compared to the predictions of several hypothetical formation processes for the lighter neutron-capture elements. Our NLTE abundances confirm the previously determined huge scatter of the strontium abundance in low metallicity stars. This scatter is also found (and is even larger) at very low metallicities (i. e. early in the chemical evolution). The Sr abundance in the extremely metal-poor (EMP) stars is compatible with the main r-process involved in other processes (or by variations of the r-process), as we briefly discuss.

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arXiv2011

First stars XIII. Two extremely metal-poor RR Lyrae stars?

The chemical composition of extremely metal-poor stars (EMP stars; [Fe/H]<~ -3) is a unique tracer of early nucleosynthesis in the Galaxy. As such stars are rare, we wish to find classes of luminous stars which can be studied at high resolution. We aim to determine the detailed chemical composition of the two EMP stars CS30317-056 and CS22881-039, originally thought to be red horizontal-branch (RHB) stars, and compare it to earlier results for EMP stars as well as to nucleosynthesis yields from various supernova (SN) models. In the analysis, we discovered that our targets are in fact the two most metal-poor RR Lyrae stars known. Our detailed abundance analysis, taking into account the variability of the stars, is based on VLT/UVES spectra (R~ 43000) and 1D LTE OSMARCS model atmospheres and synthetic spectra. For comparison with SN models we also estimate NLTE corrections for a number of elements. We derive LTE abundances for the 16 elements O, Na, Mg, Al, Si, S, Ca, Sc, Ti, Cr, Mn, Fe, Co, Ni, Sr and Ba, in good agreement with earlier values for EMP dwarf, giant and RHB stars. Li and C are not detected in either star. NLTE abundance corrections are newly calculated for O and Mg and taken from the literature for other elements. The resulting abundance pattern is best matched by model yields for supernova explosions with high energy and/or significant asphericity effects. Our results indicate that, except for Li and C, the surface composition of EMP RR Lyr stars is not significantly affected by mass loss, mixing or diffusion processes; hence, EMP RR Lyr stars should also be useful tracers of the chemical evolution of the early Galactic halo. The observed abundance ratios indicate that these stars were born from an ISM polluted by energetic, massive (25 - 40M*) and/or aspherical supernovae, but the NLTE corrections for Sc and certain other elements do play a role in the choice of model.

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