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R. J. Cava

Publications and source records attributed to R. J. Cava.

At least 55 records · Page 3Linked to original sources

Interacting multi-channel topological boundary modes in a quantum Hall valley system

Symmetry and topology play key roles in the identification of phases of matter and their properties. Both concepts are central to understanding quantum Hall ferromagnets (QHFMs), two-dimensional electronic phases with spontaneously broken spin or pseudospin symmetry whose wavefunctions also have topological properties. Domain walls between distinct broken symmetry QHFM phases are predicted to host gapless one-dimensional (1D) modes that emerge due to a topological change of the underlying electronic wavefunctions at such interfaces. Although a variety of QHFMs have been identified in different materials, probing interacting electronic modes at these domain walls has not yet been accomplished. Here we use a scanning tunneling microscope (STM) to directly visualize the spontaneous formation of boundary modes, within a sign-changing topological gap, at domain walls between different valley-polarized quantum Hall phases on the surface of bismuth. By changing the valley occupation and the corresponding number of modes at the domain wall, we can realize different regimes where the valley-polarized channels are either metallic or develop a spectroscopic gap. This behavior is a consequence of Coulomb interactions constrained by the symmetry-breaking valley flavor, which determines whether electrons in the topological modes can backscatter, making these channels a unique class of interacting Luttinger liquids.

cond-mat.mes-hall↗

A gap-protected zero-Hall effect state in the quantum limit of the nonsymmorphic metal KHgSb

A recurring theme in topological matter is the protection of unusual electronic states by symmetry, for example, protection of the surface states in Z2 topological insulators by time reversal symmetry [1-3]. Recently interest has turned to unusual surface states in the large class of nonsymmorphic materials [4-11]. In particular KHgSb is predicted to exhibit double quantum spin Hall (QSH) states [10]. Here we report observation of a novel feature of the Hall conductivity in KHgSb in strong magnetic field B. In the quantum limit, the Hall conductivity is observed to fall exponentially to zero, but the diagonal conductivity is finite. A large gap protects this unusual zero-Hall state. We propose that, in this limit, the chemical potential drops into the bulk gap, intersecting equal numbers of right and left-moving QSH surface modes to produce the zero-Hall state.

cond-mat.str-el↗

Electronic properties of type-II Weyl semimetal WTe$_2$. A review perspective

Currently, there is a flurry of research interest on materials with an unconventional electronic structure, and we have already seen significant progress in their understanding and engineering towards real-life applications. The interest erupted with the discovery of graphene and topological insulators in the previous decade. The electrons in graphene simulate massless Dirac Fermions with a linearly dispersing Dirac cone in their band structure, while in topological insulators, the electronic bands wind non-trivially in momentum space giving rise to gapless surface states and bulk bandgap. Weyl semimetals in condensed matter systems are the latest addition to this growing family of topological materials. Weyl Fermions are known in the context of high energy physics since almost the beginning of quantum mechanics. They apparently violate charge conservation rules, displaying the "chiral anomaly", with such remarkable properties recently theoretically predicted and experimentally verified to exist as low energy quasiparticle states in certain condensed matter systems. Not only are these new materials extremely important for our fundamental understanding of quantum phenomena, but also they exhibit completely different transport phenomena. For example, massless Fermions are susceptible to scattering from non-magnetic impurities. Dirac semimetals exhibit non-saturating extremely large magnetoresistance as a consequence of their robust electronic bands being protected by time reversal symmetry. These open up whole new possibilities for materials engineering and applications including quantum computing. In this review, we recapitulate some of the outstanding properties of WTe$_2$, namely, its non-saturating titanic magnetoresistance due to perfect electron and hole carrier balance up to a very high magnetic field observed for the very first time. (Continued. Please see the main article).

cond-mat.mtrl-sci↗

VI3 - a new layered ferromagnetic semiconductor

Two-dimensional (2D) materials are promising candidates for next-generation electronic devices. In this regime, insulating 2D ferromagnets, which remain rare, are of special importance due to their potential for enabling new device architectures. Here we report the discovery of ferromagnetism in a layered van der Waals semiconductor, VI3, which is based on honeycomb vanadium layers separated by an iodine-iodine van der Waals gap. It has a BiI3-type structure (R-3, No.148) at room temperature, and our experimental evidence suggests that it may undergo a subtle structural phase transition at 78 K. VI3 becomes ferromagnetic at 49 K, below which magneto-optical Kerr effect imaging clearly shows ferromagnetic domains, which can be manipulated by the applied external magnetic field. The optical band gap determined by reflectance measurements is 0.6 eV, and the material is highly resistive.

cond-mat.mtrl-sci↗

The trimer-based spin liquid candidate Ba4NbIr3O12

Ba4NbIr3O12, a previously unreported material with a triangular planar geometry of Ir3O12 trimers, is described. Magnetic susceptibility measurements show no magnetic ordering down to 1.8 K despite the Curie-Weiss temperature of -13 K. The material has a very low effective magnetic moment of 0.80 μB/f.u. To look at the lower temperature behavior, the specific heat (Cp) was measured down to 0.35 K; it shows no indication of magnetic ordering and fitting a power law to Cp vs. T below 2 K yields the power α = 3/4. Comparison to the previously unreported trimer compound made with the 4d element Rh in place of the 5d element Ir, Ba4NbRh3O12, is presented. The analysis suggests that Ba4NbIr3O12 is a candidate spin liquid material.

cond-mat.str-el↗

A Spin Glass State in Ba3TiRu2O9

The magnetic properties of Ba3TiRu2O9 , whose crystal structure is based on stacked triangular planar lattices of MO6 dimers and single MO6 octahedra, are reported. The system is magnetically disturbed by a substantial amount of Ti/Ru chemical disorder. The Weiss temperature and effective magnetic moment were found to be -29.5 K and 1.82 μB/f.u. respectively, and a bifurcation in the zero field cooled and field cooled magnetic susceptibility is observed below 4.7 K, suggesting that this is a compositionally-disordered spin-glass system. The material is a semiconductor with an activation energy for charge transport of approximately 0.14 eV.

cond-mat.str-el↗

Role of matrix elements in the time-resolved photoemission signal

Time- and angle-resolved photoemission spectroscopy accesses the ultrafast evolution of quasiparticles and many-body interactions in solid-state systems. However, the momentum- and energy-resolved transient photoemission intensity may not be unambiguously related to the intrinsic relaxation dynamics of photoexcited electrons. In fact, interpretation of the time-dependent photoemission signal can be affected by the transient evolution of both the one-electron removal spectral function as well as the photoemission dipole matrix elements. Here we investigate the topological insulator Bi$_{1.1}$Sb$_{0.9}$Te$_2$S to demonstrate, by means of a careful probe-polarization study, the transient contribution of matrix elements to the time-resolved photoemission signal.

cond-mat.mtrl-sci↗

Trimers of MnO6 octahedra and ferrimagnetism of Ba4NbMn3O12

Ba4NbMn3O12 is reported, synthesized by a solid state method in air. The crystal structure, determined by performing refinements on room temperature powder X-ray diffraction data by the Rietveld method, consists of Mn3O12 trimers in the configuration of three face-sharing MnO6 octahedra, with the trimers arranged in triangular planes. An effective moment of 4.82 μB/f.u is observed and competing antiferromagnetic and ferromagnetic interactions between Mn ions are inferred from the Weiss temperature of -4 K and the ferrimagnetic ordering transition of approximately 42 K. Ba4NbMn3O12 is a semiconductor with a transport activation energy of 0.37 eV.

cond-mat.str-el↗

Crystal Field Levels and Magnetic Anisotropy in the Kagome Compounds $\rm{Nd_3Sb_3Mg_2O_{14}}$, $\rm{Nd_3Sb_3Zn_2O_{14}}$, and $\rm{Pr_3Sb_3Mg_2O_{14}}$

We report the crystal field levels of several newly-discovered rare-earth kagome compounds: $\rm{Nd_3Sb_3Mg_2O_{14}}$, $\rm{Nd_3Sb_3Zn_2O_{14}}$, and $\rm{Pr_3Sb_3Mg_2O_{14}}$. We determine the CEF Hamiltonian by fitting to neutron scattering data using a point-charge Hamiltonian as an intermediate fitting step. The fitted Hamiltonians accurately reproduce bulk susceptibility measurements, and the results indicate easy-axis ground state doublets for $\rm{Nd_3Sb_3Mg_2O_{14}}$ and $\rm{Nd_3Sb_3Zn_2O_{14}}$, and a singlet ground state for $\rm{Pr_3Sb_3Mg_2O_{14}}$. These results provide the groundwork for future investigations of these compounds and a template for CEF analysis of other low-symmetry materials.

cond-mat.str-el↗

$μ$SR study of spin freezing and persistent spin dynamics in NaCaNi$_2$F$_7$

A new pyrochlore compound, NaCaNi$_2$F$_7$, was recently synthesized and has a single magnetic site with spin-1 Ni$^{2+}$. We present zero field (ZF) and longitudinal field (LF) muon spin rotation ($μ$SR) measurements on this pyrochlore. Density functional theory (DFT) calculations show that the most likely muon site is located between two fluorine ions, but off-centre. A characteristic F-$μ$-F muon spin polarization function is observed at high temperatures where Ni spin fluctuations are sufficiently rapid. The Ni$^{2+}$ spins undergo spin freezing into a disordered ground state below 4~K, with a characteristic internal field strength of 140~G. Persistent Ni spin dynamics are present to our lowest temperatures (75~mK), a feature characteristic of many geometrically frustrated magnetic systems.

cond-mat.str-el↗

Magnetic Properties of Lithium-Containing Rare Earth Garnets Li3RE3Te2O12 (RE = Y, Pr, Nd, Sm-Lu)

The synthesis, structural description, temperature dependent magnetic susceptibilities and field dependent magnetizations of a series of rare earth garnets of the form Li3RE3Te2O12 (RE = Y, La, Pr, Nd, Sm-Lu) are reported. The structure of Li3Dy3Te2O12 is refined from powder X-ray diffraction data. The field dependent magnetizations saturate for some of the members by 9 Tesla at 2 K. Of particular interest for further study in this family is the behavior of the Pr, Tb, Dy and Yb garnets.

cond-mat.mtrl-sci↗

Experimental tests of the chiral anomaly magnetoresistance in the Dirac-Weyl semimetals Na$_3$Bi and GdPtBi

In the Dirac/Weyl semimetal, the chiral anomaly appears as an "axial" current arising from charge-pumping between the lowest (chiral) Landau levels of the Weyl nodes, when an electric field is applied parallel to a magnetic field $\bf B$. Evidence for the chiral anomaly was obtained from the longitudinal magnetoresistance (LMR) in Na$_3$Bi and GdPtBi. However, current jetting effects (focussing of the current density $\bf J$) have raised general concerns about LMR experiments. Here we implement a litmus test that allows the intrinsic LMR in Na$_3$Bi and GdPtBi to be sharply distinguished from pure current jetting effects (in pure Bi). Current jetting enhances $J$ along the mid-ridge (spine) of the sample while decreasing it at the edge. We measure the distortion by comparing the local voltage drop at the spine (expressed as the resistance $R_{spine}$) with that at the edge ($R_{edge}$). In Bi, $R_{spine}$ sharply increases with $B$ but $R_{edge}$ decreases (jetting effects are dominant). However, in Na$_3$Bi and GdPtBi, both $R_{spine}$ and $R_{edge}$ decrease (jetting effects are subdominant). A numerical simulation allows the jetting distortions to be removed entirely. We find that the intrinsic longitudinal resistivity $ρ_{xx}(B)$ in Na$_3$Bi decreases by a factor of 10.9 between $B$ = 0 and 10 T. A second litmus test is obtained from the parametric plot of the planar angular magnetoresistance. These results strenghthen considerably the evidence for the intrinsic nature of the chiral-anomaly induced LMR. We briefly discuss how the squeeze test may be extended to test ZrTe$_5$.

cond-mat.str-el↗

Magneto-elastic induced vibronic bound state in the spin ice pyrochlore Ho$_2$Ti$_2$O$_7$

The single ion physics of Ho$_2$Ti$_2$O$_7$ is well-understood to produce strong Ising anisotropy, which is an essential ingredient to its low-temperature spin ice state. We present inelastic neutron scattering measurements on Ho$_2$Ti$_2$O$_7$ that reveal a clear inconsistency with its established single ion Hamiltonian. Specifically, we show that a crystal field doublet near 60~meV is split by approximately 3~meV. Furthermore, this crystal field splitting is not isolated to Ho$_2$Ti$_2$O$_7$ but can also be found in its chemical pressure analogs, Ho$_2$Ge$_2$O$_7$ and Ho$_2$Sn$_2$O$_7$. We demonstrate that the origin of this effect is a vibronic bound state, resulting from the entanglement of a phonon and crystal field excitation. We derive the microscopic Hamiltonian that describes the magneto-elastic coupling and provides a quantitative description of the inelastic neutron spectra.

cond-mat.str-el↗

Stabilizing the Tb-based 214 cuprate by partial Pd substitution

Previously known to form only under high pressure synthetic conditions, here we report that the T'-type 214-structure cuprate based on the rare earth atom Tb is stabilized for ambient pressure synthesis through partial substitution of Pd for Cu. The new material is obtained in purest form for mixtures of nominal composition $Tb_{1.96}Cu_{0.80}Pd_{0.20}O_{4}$. The refined formula, in orthorhombic space group Pbca, with a = 5.5117(1) Å, b = 5.5088(1) Å, and c = 11.8818(1) Å, is $Tb_{2}Cu_{0.83}Pd_{0.17}O_{4}$. An incommensurate structural modulation is seen along the a axis by electron diffraction and high resolution imaging. Magnetic susceptibility measurements reveal long range antiferromagnetic ordering at 7.9 K, with a less pronounced feature at 95 K; a magnetic moment reorientation transition is observed to onset at a field of approximately 1.1 Tesla at 3 K. The material is an n-type semiconductor.

cond-mat.supr-con↗

Ferroelectric quantum Hall phase revealed by visualizing Landau level wavefunction interference

Novel broken symmetry states can spontaneously form due to Coulomb interactions in electronic systems with multiple internal degrees of freedom. Multi-valley materials offer an especially rich setting for the emergence of such states, which have potential electronic and optical applications. To date, identification of these broken symmetry phases has mostly relied on the examination of macroscopic transport or optical properties. Here we demonstrate a powerful direct approach by visualizing the wave functions of bismuth surface states with a scanning tunneling microscope. Strong spin-orbit coupling on the surface of bismuth leads to six degenerate teardrop-shaped hole pockets. Our spectroscopic measurements reveal that this degeneracy is fully lifted at high magnetic field as a result of exchange interactions, and we are able to determine the nature of valley ordering by imaging the broken symmetry Landau level (LL) wave functions. The remarkable spatial features of singly degenerate LL wave functions near isolated defects contain unique signatures of interference between spin-textured valleys, which identify the electronic ground state as a quantum Hall ferroelectric. Our observations confirm the recent prediction that interactions in strongly anisotropic valley systems favor the occupation of a single valley, giving rise to emergent ferroelectricity in the surface state of bismuth.

cond-mat.mes-hall↗

A Geometrically Frustrated Trimer-Based Mott Insulator

The crystal structure of Ba4NbRu3O12 is based on triangular planes of elongated Ru3O12 trimers oriented perpendicular to the plane. We report that it is semiconducting, that its Weiss temperature and effective magnetic moment are -155 K and 2.59 μB/f.u. respectively, and that magnetic susceptibility and specific heat data indicate that it exhibits magnetic ordering near 4 K. The presence of a high density of low energy states is evidenced by a substantial Sommerfeld-like T-linear term (gamma = 31(2) mJ/mole-K^2) in the specific heat. Electronic structure calculations reveal that the electronic states at the Fermi Energy reside on the Ru3O12 trimers and that the calculated density of electronic states is high and continuous around the Fermi Energy - in other words density functional theory calculates the material to be a metal. Our results imply that Ba4NbRu3O12 is a geometrically frustrated trimer-based Mott insulator.

cond-mat.str-el↗

Strong Electron-Phonon Coupling Superconductivity Induced by a Low-lying Phonon in IrGe

The physical properties of the previously reported superconductor IrGe and the Rh1-xIrxGe solid solution are investigated. IrGe has an exceptionally high superconducting transition temperature (Tc = 4.7 K) among the isostructural 1:1 late-metal germanides MGe (M = Rh, Pd, Ir and Pt). Specific-heat measurements reveal that IrGe has an anomalously low Debye temperature, originating from a low-lying phonon, compared to the other MGe phases. A large jump at Tc in the specific-heat data clearly indicates that IrGe is a strong coupling superconductor. In the Rh1-xIrxGe solid solution, a relationship between an anomalous change in lattice constants and the Debye temperature is observed. We conclude that the unusually high Tc for IrGe is likely due to strong electron-phonon coupling derived from the presence of a low-lying phonon.

cond-mat.supr-con↗

Non-uniform carrier density in Cd$_3$As$_2$ evidenced by optical spectroscopy

We report the detailed optical properties of Cd$_3$As$_2$ crystals in a wide parameter space: temperature, magnetic field, carrier concentration and crystal orientation. We investigate high-quality crystals synthesized by three different techniques. In all the studied samples, independently of how they were prepared and how they were treated before the optical experiments, our data indicate conspicuous fluctuations in the carrier density (up to 30%). These charge puddles have a characteristic scale of 100 $μ$m, they become more pronounced at low temperatures, and possibly, they become enhanced by the presence of crystal twinning. The Drude response is characterized by very small scattering rates ($\sim 1$ meV) for as-grown samples. Mechanical treatment, such as cutting or polishing, influences the optical properties of single crystals, by increasing the Drude scattering rate and also modifying the high frequency optical response. Magneto-reflectivity and Kerr rotation are consistent with electron-like charge carriers and a spatially non-uniform carrier density.

cond-mat.mtrl-sci↗