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R. J. Fleming

Publications and source records attributed to R. J. Fleming.

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An improved perturbation approach to the 2D Edwards polymer -- corrections to scaling

We present the results of a new perturbation calculation in polymer statistics which starts from a ground state that already correctly predicts the long chain length behaviour of the mean square end--to--end distance $\langle R_N^2 \rangle\ $, namely the solution to the 2~dimensional~(2D) Edwards model. The $\langle R_N^2 \rangle$ thus calculated is shown to be convergent in $N$, the number of steps in the chain, in contrast to previous methods which start from the free random walk solution. This allows us to calculate a new value for the leading correction--to--scaling exponent~$Δ$. Writing $\langle R_N^2 \rangle = AN^{2ν}(1+BN^{-Δ} + CN^{-1}+...)$, where $ν= 3/4$ in 2D, our result shows that $Δ= 1/2$. This value is also supported by an analysis of 2D self--avoiding walks on the {\em continuum}.

cond-mat

Corrections to scaling in 2--dimensional polymer statistics

Writing $ = AN^{2ν}(1+BN^{-Δ_1}+CN^{-1}+ ...)$ for the mean square end--to--end length $ $ of a self--avoiding polymer chain of $N$ links, we have calculated $Δ_1$ for the two--dimensional {\em continuum} case from a new {\em finite} perturbation method based on the ground state of Edwards self consistent solution which predicts the (exact) $ν=3/4$ exponent. This calculation yields $Δ_1=1/2$. A finite size scaling analysis of data generated for the continuum using a biased sampling Monte Carlo algorithm supports this value, as does a re--analysis of exact data for two--dimensional lattices.

cond-mat