arXiv subjects

R. J. Stancliffe

Publications and source records attributed to R. J. Stancliffe.

At least 19 recordsLinked to original sources

arXiv2025

Modeling the progenitors of low-mass post-accretion binaries

About half of the mass of all heavy elements with mass number A > 90 is formed through the slow neutron capture process (s-process), occurring in evolved asymptotic giant branch (AGB) stars with masses ~1-6 $\rm{M_{\odot}}$. The s-process can be studied by modeling the accretion of material from AGB stars onto binary barium (Ba), CH, and carbon-enhanced metal-poor (CEMP)-s stars. Comparing observationally derived surface parameters and 1D-LTE abundance patterns of s-process elements to theoretical binary accretion models, we aim to understand the formation of post-accretion systems. We explore the extent of dilution of the accreted material and describe the impact of convective mixing on the observed surface abundances. We compute a new grid of 2700 accretion models for low-mass post-accretion systems. A maximum-likelihood comparison determines the best fit models for observational samples of Ba, CH, and CEMP-s stars. We find consistent AGB donor masses in the mass range of 2-3 $\rm{M_{\odot}}$ across our sample of post-accretion binaries. We find the formation scenario for weak Ba stars is an AGB star transferring a moderate amount of mass ($\leq$0.5 $\rm{M_{\odot}}$) resulting in a ~2.0-2.5 $\rm{M_{\odot}}$ star. The strong Ba stars are best fit with lower final masses ~1.0-2.0 $\rm{M_{\odot}}$, and significant accreted mass ($\geq$0.5 $\rm{M_{\odot}}$). The CH and CEMP-s stars display lower final masses (~1.0 $\rm{M_{\odot}}$) and small amounts of transferred material (~0.1 $\rm{M_{\odot}}$). We find that Ba stars generally accrete more material than CEMP-s and CH stars. We also find that strong Ba stars must accrete more than 0.50 $\rm{M_{\odot}}$ to explain their abundance patterns, and in this limit we are unable to reproduce the observed mass distribution of strong Ba stars. The mass distributions of the weak Ba stars, CEMP-s, and CH stars are well reproduced in our modeling.

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arXiv2024

S-Process Nucleosynthesis in Chemically Peculiar Binaries

Around half of the heavy elements in the universe are formed through the slow neutron capture (s-) process, which takes place in thermally pulsing asymptotic giant branch (AGB) stars with masses $1-6\;M_{\odot}$. The nucleosynthetic imprint of the s-process can be studied by observing the material on the surface of binary barium, carbon, CH, and CEMP stars. We study the s-process by observing the luminous components of binary systems polluted by a previous AGB companion. Our radial velocity (RV) monitoring program establishes a collection of binary stars exhibiting enrichment in s-process material for the study of elemental abundances, production of s-process material, and binary mass transfer. From high resolution optical spectra, we measure RVs for 350 stars and derive stellar parameters for 150 stars using ATHOS. For a sub-sample of 24 stars we refine our atmospheric parameters using the Xiru program. We use the MOOG code to compute 1D-LTE abundances of C, Mg, s-process elements Sr, Y, Zr, Mo, Ba, La, Ce, Nd, Pb, and Eu to investigate neutron capture events and stellar chemical composition. We estimate dynamical masses by optimising orbits with MCMC techniques in the ELC program, and we compare our results with low-mass AGB models in the FRUITY database. We find enhancements in s-process material in spectroscopic binaries, a signature of AGB mass transfer. We add Mo to the abundance patterns, and for 12 stars we add Pb detections or upper limits. Computed abundances are in general agreement with the literature. Comparing our abundances to the FRUITY yields, we find correlations in s-process enrichment and AGB mass, and agreements in theoretical and dynamically modelled masses. From our high-resolution observations we expand heavy element abundance patterns and highlight binarity in our chemically interesting systems. We investigate evolutionary stages for a small sub-set of our stars.

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arXiv2023

Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CH$_3$NHCH$_3$, and searches for it in space

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunneling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to $J = 61$ and $K_a = 21$, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array toward the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693$-$0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report nondetections of dimethylamine toward the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693$-$0.027 which imply that dimethylamine is at least 14, 4.5 and 39 times less abundant than methylamine toward these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modeled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

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arXiv2019

Reduction of the maximum mass-loss rate of OH/IR stars due to unnoticed binary interaction

In 1981, the idea of a superwind that ends the life of cool giant stars was proposed. Extreme OH/IR-stars develop superwinds with the highest mass-loss rates known so far, up to a few 10^(-4) Msun/yr, informing our understanding of the maximum mass-loss rate achieved during the Asymptotic Giant Branch (AGB) phase. A condundrum arises whereby the observationally determined duration of the superwind phase is too short for these stars to become white dwarfs. Here, we report on the detection of spiral structures around two cornerstone extreme OH/IR-stars, OH26.5+0.6 and OH30.1-0.7, identifying them as wide binary systems. Hydrodynamical simulations show that the companion's gravitational attraction creates an equatorial density enhancement mimicking a short extreme superwind phase, thereby solving the decades-old conundrum. This discovery restricts the maximum mass-loss rate of AGB stars around the single-scattering radiation-pressure limit of a few 10^(-5) Msun/yr. This brings about crucial implications for nucleosynthetic yields, planet survival, and the wind-driving mechanism.

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arXiv2018

Unusual neutron-capture nucleosynthesis in a carbon-rich Galactic bulge star

Metal-poor stars in the Galactic halo often show strong enhancements in carbon and/or neutron-capture elements. However, the Galactic bulge is notable for its paucity of carbon-enhanced metal-poor (CEMP) and/or CH-stars, with only two such objects known to date. This begs the question whether the processes that produced their abundance distribution were governed by a comparable nucleosynthesis in similar stellar sites as for their more numerous counterparts in the halo. Recently, two contenders of such stars were discovered in the bulge, at [Fe/H] = $-1.5$ and $-$2.5 dex, both of which show enhancements in [C/Fe] of 0.4 and 1.4 dex, [Ba/Fe] in excess of 1.3 dex, and also elevated nitrogen. The more metal-poor of the stars is matched by standard $s$-process nucleosynthesis in low-mass Asymptotic Giant Branch (AGB) polluters. The other star shows an abnormally high [Rb/Fe] ratio. Here, we investigate the origin of the abundance peculiarities in the Rb-rich star by new, detailed measurements of heavy element abundances and by comparing the chemical element ratios of 36 species to models of neutron-capture nucleosynthesis. The $i$-process with intermediate neutron densities between those of the $s$- and $r$-processes has been previously found to provide good matches of CEMP stars with enhancements in both $r$- and $s$-process elements, rather than invoking a superposition of yields from the respective individual processes. However, the peculiar bulge star is incompatible with a pure $i$-process from a single ingestion event. Instead, it can, statistically, be better reproduced by models accounting for two proton ingestion events, or by an $i$-process component in combination with $s$-process nucleosynthesis in low-to-intermediate mass AGB stars, indicating multiple polluters. [abridged]

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arXiv2018

The interaction of core-collapse supernova ejecta with a stellar companion

The progenitors of many core-collapse supernovae (CCSNe) are expected to be in binary systems. By performing a series of three-dimensional hydrodynamical simulations, we investigate how CCSN explosions affect their binary companion. We find that the amount of removed stellar mass, the resulting impact velocity, and the chemical contamination of the companion that results from the impact of the SN ejecta, strongly increases with decreasing binary separation and increasing explosion energy. Also, it is foud that the impact effects of CCSN ejecta on the structure of main-sequence (MS) companions, and thus their long term post-explosion evolution, is in general not be dramatic.

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arXiv2017

Rotational mixing in carbon-enhanced metal-poor stars with s-process enrichment

Carbon-enhanced metal-poor stars with s-process enrichment (CEMP-s) are believed to be the products of mass transfer from an AGB companion, which has long since become a white dwarf. The surface abundances of CEMP-s stars are thus commonly assumed to reflect the nucleosynthesis output of the first AGB stars. We have previously shown that, for this to be the case, some physical mechanism must counter atomic diffusion in these nearly fully radiative stars, which otherwise leads to surface abundance anomalies clearly inconsistent with observations. Here we take into account angular momentum accretion by these stars. We compute in detail the evolution of typical CEMP-s stars from the ZAMS, through the mass accretion, and up the RGB for a wide range of specific angular momentum of the accreted material, corresponding to rotation velocities between about 0.3 and 300 km/s. We find that only for specific angular momentum above 1e+17 cm2/s (rotation velocities above 20 km/s) angular momentum accretion directly causes chemical dilution of the accreted material. This could nevertheless be relevant to CEMP-s stars, which are observed to rotate more slowly, if they undergo continuous angular momentum loss akin to solar-like stars. In models with rotation velocities characteristic of CEMP-s stars, rotational mixing primarily serves to inhibit atomic diffusion, such that the maximal surface abundance variations (with respect to the composition of the accreted material) prior to first dredge-up remain within about 0.4 dex without thermohaline mixing or about 0.5-1.5 dex with thermohaline mixing. Even in models with the lowest rotation velocities (under a km/s), rotational mixing is able to severely inhibit atomic diffusion, compared to non-rotating models. We thus conclude that it offers a natural solution to the problem posed by atomic diffusion and cannot be neglected in models of CEMP-s stars.

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arXiv2017

How much mass and angular momentum can the progenitors of carbon-enriched stars accrete?

The chemically peculiar barium stars, CH stars, and most CEMP stars are all believed to be the products of mass transfer in binary systems from a now extinct AGB primary star. The mass of the AGB star and the orbital parameters of the system are the key factors usually considered when determining how much mass is transferred onto the lower-mass main-sequence companion. What is usually neglected, however, is the angular momentum of the accreted material, which should spin up the accreting star. If the star reaches critical rotation, further accretion should cease until the excess angular momentum is somehow dealt with. If the star cannot redistribute or lose the angular momentum while the primary is on the AGB, the amount of mass accreted could be much lower than otherwise expected. Here we present calculations, based on detailed stellar evolution models, of the mass that can be accreted by putative progenitors of Ba and CEMP stars before they reach critical rotation under the assumption that no angular momentum loss occurs during the mass transfer. We consider different accretion rates and values of specific angular momentum. The most stringent limits on the accreted masses result from considering accretion from a Keplerian accretion disk, which is likely present during the formation of most extrinsically-polluted carbon-enriched stars. Our calculations indicate that in this scenario only about 0.05 solar masses of material can be added to the accreting star before it reaches critical rotation, which is much too low to explain the chemical enrichment of many Ba and CEMP stars. Either the specific angular momentum of the accreted material has to effectively be lower by about a factor of ten than the Keplerian value, or significant angular momentum losses must occur for substantial accretion to take place.

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arXiv2017

Partial mixing and the formation of 13C pockets in AGB stars: effects on the s-process elements

The production of the elements heavier than iron via slow neutron captures (the s process) is a main feature of the contribution of asymptotic giant branch (AGB) stars of low mass (< 5 Msun) to the chemistry of the cosmos. However, our understanding of the main neutron source, the 13C(alpha,n)16O reaction, is still incomplete. It is commonly assumed that in AGB stars mixing beyond convective borders drives the formation of 13C pockets. However, there is no agreement on the nature of such mixing and free parameters are present. By means of a parametric model we investigate the impact of different mixing functions on the final s-process abundances in low-mass AGB models. Typically, changing the shape of the mixing function or the mass extent of the region affected by the mixing produce the same results. Variations in the relative abundance distribution of the three s-process peaks (Sr, Ba, and Pb) are generally within +/-0.2 dex, similar to the observational error bars. We conclude that other stellar uncertainties - the effect of rotation and of overshoot into the C-O core - play a more important role than the details of the mixing function. The exception is at low metallicity, where the Pb abundance is significantly affected. In relation to the composition observed in stardust SiC grains from AGB stars, the models are relatively close to the data only when assuming the most extreme variation in the mixing profile.

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arXiv2016

Nucleosynthesis in AGB stars traced by oxygen isotopic ratios. I - Determining the stellar initial mass by means of the $^{17}$O/$^{18}$O ratio

The aim of this paper is to investigate the $^{17}$O/$^{18}$O ratio for a sample of AGB stars, containing M-, S- and C-type stars. These ratios are evaluated in relation to fundamental stellar evolution parameters: the stellar initial mass and pulsation period. Circumstellar $^{13}$C$^{16}$O, $^{12}$C$^{17}$O and $^{12}$C$^{18}$O line observations were obtained for a sample of nine stars with various single-dish long-wavelength facilities. Line intensity ratios are shown to relate directly to the surface $^{17}$O/$^{18}$O abundance ratio. Stellar evolution models predict the $^{17}$O/$^{18}$O ratio to be a sensitive function of initial mass and to remain constant throughout the entire TP-AGB phase for stars initially less massive than 5\,$M_{\odot}$. This makes the measured ratio a probe of the initial stellar mass. Observed $^{17}$O/$^{18}$O ratios are found to be well in the range predicted by stellar evolution models that do not consider convective overshooting. From this, accurate initial mass estimates are calculated for seven sources. For the remaining two sources two mass solutions result, though with a larger probability that the low-mass solution is the correct one. Finally, hints at a possible separation between M/S- and C-type stars when comparing the $^{17}$O/$^{18}$O ratio to the stellar pulsation period are presented.

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arXiv2016

Radiative levitation in carbon-enhanced metal-poor stars with s-process enrichment

A significant fraction of all metal-poor stars are carbon-rich. Most of these carbon-enhanced metal-poor (CEMP) stars also show enhancement in elements produced mainly by the s-process (CEMP-s stars) and evidence suggests that the origin of these non-standard abundances can be traced to mass transfer from a binary asymptotic giant branch (AGB) companion. Thus, observations of CEMP-s stars are commonly used to infer the nucleosynthesis output of low-metallicity AGB stars. A crucial step in this exercise is understanding what happens to the accreted material after mass transfer ceases. Here we present models of the post-mass-transfer evolution of CEMP-s stars considering the physics of thermohaline mixing and atomic diffusion, including radiative levitation. We find that stars with typical CEMP-s star masses (M ~ 0.85 Msun) have very shallow convective envelopes (Menv < 1e-7 Msun). Hence, the surface abundance variations arising from the competition between gravitational settling and radiative levitation should be orders of magnitude larger than observed (e.g. [C/Fe]<-1 or [C/Fe]>+4). We are therefore unable to reproduce the spread in the observed abundances with these models and conclude that some other physical process must largely suppress atomic diffusion in the outer layers of CEMP-s stars. We demonstrate that this could be achieved by some additional (turbulent) mixing process operating at the base of the convective envelope, as found by other authors. Alternatively, mass-loss rates around 1e-13 Msun/yr could also negate most of the abundance variations by eroding the surface layers and forcing the base of the convective envelope to move inwards in mass. Since atomic diffusion cannot have a substantial effect on the surface abundances of CEMP-s stars, the dilution of the accreted material, while variable in degree from one star to the next, is most likely the same for all elements.

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arXiv2016

Confronting uncertainties in stellar physics II. exploring differences in main-sequence stellar evolution tracks

We assess the systematic uncertainties in stellar evolutionary calculations for low- to intermediate-mass, main-sequence stars. We compare published stellar tracks from several different evolution codes with our own tracks computed using the stellar codes STARS and MESA. In particular, we focus on tracks of 1 and 3 solar masses at solar metallicity. We find that the spread in the available 1 solar mass tracks (computed before the recent solar composition revision by Asplund et al.) can be covered by tracks between 0.97-1.01 solar masses computed with the STARS code. We assess some possible causes of the origin of this uncertainty, including how the choice of input physics and the solar constraints used to perform the solar calibration affect the tracks. We find that for a 1 solar mass track, uncertainties of around 10% in the initial hydrogen abundance and initial metallicity produce around a 2% error in mass. For the 3 solar mass tracks, there is very little difference between the tracks from the various different stellar codes. The main difference comes in the extent of the main sequence, which we believe results from the different choices of the implementation of convective overshooting in the core. Uncertainties in the initial abundances lead to a 1-2% error in the mass determination. These uncertainties cover only part of the total error budget, which should also include uncertainties in the input physics (e.g., reaction rates, opacities, convective models) and any missing physics (e.g., radiative levitation, rotation, magnetic fields). Uncertainties in stellar surface properties such as luminosity and effective temperature will further reduce the accuracy of any potential mass determinations.

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arXiv2015

Did the progenitor of SN2011dh have a binary companion?

We present late-time Hubble Space Telescope (HST) ultraviolet (UV) and optical observations of the site of SN 2011dh in the galaxy M51, ~1164 days post-explosion. At the SN location, we observe a point source that is visible at all wavelengths, that is significantly fainter than the spectral energy distribution (SED) of the Yellow Supergiant progenitor observed prior to explosion. The previously reported photometry of the progenitor is, therefore, completely unaffected by any sources that may persist at the SN location after explosion. In comparison with the previously reported late-time photometric evolution of SN 2011dh, we find that the light curve has plateaued at all wavelengths. The SED of the late-time source is clearly inconsistent with a SED of stellar origin. Although the SED is bright at UV wavelengths, there is no strong evidence that the late-time luminosity originates solely from a stellar source corresponding to the binary companion, although a partial contribution to the observed UV flux from a companion star can not be ruled out.

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arXiv2015

Modelling the observed properties of carbon-enhanced metal-poor stars using binary population synthesis

The stellar population in the Galactic halo is characterised by a large fraction of CEMP stars. Most CEMP stars are enriched in $s$-elements (CEMP-$s$ stars), and some of these are also enriched in $r$-elements (CEMP-$s/r$ stars). One formation scenario proposed for CEMP stars invokes wind mass transfer in the past from a TP-AGB primary star to a less massive companion star which is presently observed. We generate low-metallicity populations of binary stars to reproduce the observed CEMP-star fraction. In addition, we aim to constrain our wind mass-transfer model and investigate under which conditions our synthetic populations reproduce observed abundance distributions. We compare the CEMP fractions and the abundance distributions determined from our synthetic populations with observations. Several physical parameters of the binary stellar population of the halo are uncertain, e.g. the initial mass function, the mass-ratio and orbital-period distributions, and the binary fraction. We vary the assumptions in our model about these parameters, as well as the wind mass-transfer process, and study the consequent variations of our synthetic CEMP population. The CEMP fractions calculated in our synthetic populations vary between 7% and 17%, a range consistent with the CEMP fractions among very metal-poor stars recently derived from the SDSS/SEGUE data sample. The results of our comparison between the modelled and observed abundance distributions are different for CEMP-$s/r$ stars and for CEMP-$s$ stars. For the latter, our simulations qualitatively reproduce the observed distributions of C, Na, Sr, Ba, Eu, and Pb. Contrarily, for CEMP-$s/r$ stars our model cannot reproduce the large abundances of neutron-rich elements such as Ba, Eu, and Pb. This result is consistent with previous studies, and suggests that CEMP-$s/r$ stars experienced a different nucleosynthesis history to CEMP-$s$ stars.

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arXiv2013

The effect of including molecular opacities of variable composition on the evolution of intermediate-mass AGB stars

Calculations from stellar evolutionary models of low- and intermediate-mass asymptotic giant branch (AGB) stars provide predictions of elemental abundances and yields for comparison to observations. However, there are many uncertainties that reduce the accuracy of these predictions. One such uncertainty involves the treatment of low-temperature molecular opacities that account for the surface abundance variations of C, N, and O. A number of prior calculations of intermediate-mass AGB stellar models that incorporate both efficient third dredge-up and hot bottom burning include a molecular opacity treatment which does not consider the depletion of C and O due to hot bottom burning. Here we update the molecular opacity treatment and investigate the effect of this improvement on calculations of intermediate-mass AGB stellar models. We perform tests on two masses, 5 M$_{\odot}$ and 6 M$_{\odot}$, and two metallicities, $Z~=~0.001$ and $Z~=~0.02$, to quantify the variations between two opacity treatments. We find that several evolutionary properties (e.g. radius, $T_{\rm eff}$ and $T_{\rm bce}$) are dependent on the opacity treatment. Larger structural differences occur for the $Z~=~0.001$ models compared to the $Z~=~0.02$ models indicating that the opacity treatment has a more significant effect at lower metallicity. As a consequence of the structural changes, the predictions of isotopic yields are slightly affected with most isotopes experiencing changes up to 60 per cent for the $Z~=~0.001$ models and 20 per cent for the $Z~=~0.02$ models. Despite this moderate effect, we conclude that it is more fitting to use variable molecular opacities for models undergoing hot bottom burning.

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arXiv2013

The Asymptotic Giant Branches of GCs: Selective Entry Only

The handful of available observations of AGB stars in Galactic Globular Clusters suggest that the GC AGB populations are dominated by cyanogen-weak stars. This contrasts strongly with the distributions in the RGB (and other) populations, which generally show a 50:50 bimodality in CN band strength. If it is true that the AGB populations show very different distributions then it presents a serious problem for low mass stellar evolution theory, since such a surface abundance change going from the RGB to AGB is not predicted by stellar models. However this is only a tentative conclusion, since it is based on very small AGB sample sizes. To test whether this problem really exists we have carried out an observational campaign specifically targeting AGB stars in GCs. We have obtained medium resolution spectra for about 250 AGB stars across 9 Galactic GCs using the multi-object spectrograph on the AAT (2df/AAOmega). We present some of the preliminary findings of the study for the second parameter trio of GCs: NGC 288, NGC 362 and NGC 1851. The results indeed show that there is a deficiency of stars with strong CN bands on the AGB. To confirm that this phenomenon is robust and not just confined to CN band strengths and their vagaries, we have made observations using FLAMES/VLT to measure elemental abundances for NGC 6752.We present some initial results from this study also. Our sodium abundance results show conclusively that only a subset of stars in GCs experience the AGB phase of evolution. This is the first direct, concrete confirmation of the phenomenon.

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arXiv2013

Detection of a magnetic field in three old and inactive solar-like planet-hosting stars

Our understanding of magnetic fields in late-type stars is strongly driven by what we know of the solar magnetic field. For this reason, it is crucial to understand how typical the solar dynamo is. To do this we need to compare the solar magnetic field with that of other stars as similar to the Sun as possible, both in stellar parameters and age, hence activity. We present here the detection of a magnetic field in three planet-hosting solar-like stars having a mass, age, and activity level comparable to that of the Sun. We used the HARPSpol spectropolarimeter to obtain high-resolution high-quality circularly polarised spectra of HD 70642, HD 117207, and HD 154088, using the Least-Squares Deconvolution technique to detect the magnetic field. From the Stokes I spectra, we calculated the logR activity index for each star. We compared the position of the stars in the Hertzsprung-Russell diagram to evolutionary tracks, to estimate their mass and age. We used the lithium abundance, derived from the Stokes I spectra, to further constrain the ages. We obtained a definite magnetic field detection for both HD 70642 and HD 154088, while for HD 117207 we obtained a marginal detection. Due to the lower signal-to-noise ratio of the observations, we were unable to detect the magnetic field in the second set of observations available for HD 117207 and HD 154088. On the basis of effective temperature, mass, age, and activity level the three stars can be considered solar analogs. HD 70642, HD 117207, and HD 154088 are ideal targets for a comparative study between the solar magnetic field and that of solar analogs.

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arXiv2012

Cyanogen in NGC 1851 RGB and AGB Stars: Quadrimodal Distributions

The Galactic globular cluster NGC 1851 has raised much interest since HST photometry revealed that it hosts a double subgiant branch. Here we report on our homogeneous study into the cyanogen (CN) bandstrengths in the RGB population (17 stars) and AGB population (21 stars) using AAOmega/2dF spectra with R $\sim 3000$. We discover that NGC 1851 hosts a quadrimodal distribution of CN bandstrengths in its RGB and AGB populations. This result supports the merger formation scenario proposed for this cluster, such that the CN quadrimodality could be explained by the superposition of two `normal' bimodal populations. A small sample overlap with an abundance catalogue allowed us to tentatively explore the relationship between our CN populations and a range of elemental abundances. We found a striking correlation between CN and [O/Na]. We also found that the four CN peaks may be paired -- the two CN-weaker populations being associated with low Ba and the two CN-stronger populations with high Ba. If true then s-process abundances would be a good diagnostic for disentangling the two original clusters in the merger scenario. More observations are needed to confirm the quadrimodality, and also the relationship between the subpopulations. We also report CN results for NGC 288 as a comparison. Our relatively large samples of AGB stars show that both clusters have a bias towards CN-weak AGB populations.

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