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R. Moreno

Publications and source records attributed to R. Moreno.

At least 19 recordsLinked to original sources

New 12C/13C and 14N/15N isotopic ratio measurements in Jupiter's stratosphere revealed by ALMA

The collision of comet SL9 with Jupiter in 1994 changed the chemical composition of the Jovian stratosphere for decades. New molecules were detected minutes after the impacts (HCN, CO, CS, etc.) and some are still present today. They were deposited in the stratosphere at pressures lower than 0.1 mbar and were most probably formed by shock-induced chemistry recombining Jovian and cometary material. However, the question of the origin of these molecules is still not completely understood. One way to address this open question is to determine the isotopic composition of the new molecules. Isotopic ratios have long been measured in the Solar System. They present a variety of values depending on the object or the molecule and therefore trace different reservoirs of material. Derivations of carbon and nitrogen isotopic ratios in HCN four years after SL9 showed atypical depletions in the heavier isotopes that had never been observed before in the Solar System. These results suggested an unusual cometary composition or an unknown fractionation mechanism in the hot and shocked air parcels. We aim to measure carbon and nitrogen isotopic ratios in HCN to shed light on the puzzling results of 1998. With Atacama Large Millimeter/submillimeter Array data from 2017 and radiative-transfer calculations, we derived the abundance of two HCN isotopologues, H13CN and HC15N, at pressures probed from 0.03 to 1.8 mbar. We find 12C/13C = $73\pm5$ and 14N/15N = $245\pm29$, respectively (0.76-0.87) and (0.80-1.00) times the terrestrial references, and (0.69-0.87) and (0.42-0.70) times the solar-Jovian bulk values. In contrast to the strong depletions reported in 1998, our values are instead compatible with an enrichment in the heavier isotopes relative to the Jovian bulk. We interpret these enrichments as the direct signature of the cometary contribution in HCN and/or as 23 years of chemical evolution.

astro-ph.EP

Detection of stratospheric HCN and tropospheric CO in Uranus and the implication for their sources

Uranus belongs to the category of ice giants that are common in our Galaxy. However, Uranus is one of the least explored and understood planets in our Solar System. This work aims to constrain the deep oxygen abundance of Uranus to better understand its formation. Another goal concerns the origin of exogeneous species, such as CO and HCN, found in the upper stratospheres of giant planets. We used spectral mapping observations of the CO (J=3-2) and HCN (J=4-3) rotational submillimeter lines obtained with ALMA in 2022 and 2024. We combined them with radiative transfer and thermochemical modeling to determine the tropospheric abundance of CO and the deep O/H ratio of Uranus. We used radiative transfer simulations with physical models of various sources of external CO and HCN to constrain the vertical and meridional distributions of these species and narrow down the nature of their external sources. We also applied a wind retrieval algorithm to search for zonal winds in the stratosphere of Uranus at the levels probed by the CO and HCN lines. We unambiguously detect tropospheric CO for the first time with a mole fraction of 5.8$\pm$0.3 ppb and stratospheric HCN with a mole faction of (1.8$\pm$0.2)$\times10^{-11}$ restricted to pressures lower than 0.2 mbar. Thermochemical calculations suggest that the deep interior of Uranus is enriched in oxygen with respect to the protoplanetary nebula by at least a factor of 52$^{+30}_{-20}$. We also find that the stratospheric CO is rather uniform over the observed latitudes and that the CO lines are best fit by an old comet impact model, in which a large comet hit the planet several centuries ago. CO therefore has a dual origin in Uranus. Finally, we do not detect stratospheric winds from these data, but the CO data indicate that zonal winds in the 10$^\circ$S-10$^\circ$N latitudinal range are likely retrograde at submillibar pressures.

astro-ph.EP

Perihelion observations of interstellar comet 3I/ATLAS with the IRAM 30-m telescope

3I/ATLAS is the third interstellar comet identified as passing through the Solar System. Its high outgassing activity and favourable perihelion passage on October 29, 2025 UT provided an excellent opportunity to investigate the composition of its coma gases through millimeter spectroscopy. We present observations undertaken with the IRAM 30-m telescope on November 1--3, 2025 at an heliocentric distance of 1.36--1.37 au. Lines of HCN, CH$_3$OH, CO, and H$_2$CO are well detected, and $\sim$4$\sigma$ detections are obtained for CS and CH$_3$CN. The search for H$_2$S was unsuccessful. Abundances of CO, H$_2$CO, CH$_3$OH, and CH$_3$CN relative to HCN are in the upper ranges of values measured in Solar System comets. The sulfur-to-carbon abundance ratio in 3I/ATLAS's coma is at most the minimum value observed in comets. The unusually low expansion velocity of coma gases suggests a near-nucleus gas flow driven by heavy molecules such as CO$_2$, and/or a large fraction of the gaseous production coming from subliming icy grains.

astro-ph.EP

Defect-induced multiferroicity in bulk solid solutions of WSe$_2$ and WTe$_2$

Transition metal dichalcogenides provide a versatile platform for tunable ferroic phenomena at the atomic scale owing to their reduced dimensionality. Here we investigate the structural, magnetic, and ferroelectric properties of bulk solid solution W(Se1-xTex)2(1-delta) single crystals synthesized by chemical vapor transport. The room temperature behavior is analyzed as a function of tellurium concentration (x) and chalcogen defect fraction (delta). X ray diffraction and Raman spectroscopy reveal lattice expansion and symmetry reduction with increasing x, consistent with a 2H to 1Td structural transition above a critical composition xc about 18 percent. Piezoresponse force microscopy identifies piezoelectricity near stoichiometric compositions (delta less than 5 percent) and switchable ferroelectricity in the chalcogen deficient regime (delta greater than 20 percent). Magnetometry measurements show a corresponding evolution from paramagnetic to ferromagnetic behavior with increasing delta. Near stoichiometric Te poor samples exhibit piezoelectric and paramagnetic responses, whereas multiferroic states characterized by the coexistence of ferroelectric and ferromagnetic responses emerge at high vacancy concentrations. The performed characterizations indicate that x primarily governs structural symmetry, while delta controls the emergence of both ferromagnetic and ferroelectric responses. These trends are summarized in a configurational phase diagram highlighting the cooperative influence of dopants and defects on ferroic behavior. Overall, controlled stoichiometry and vacancy engineering offer an effective strategy to tailor ferroic responses in transition metal dichalcogenides.

cond-mat.mtrl-sci

Observations of the temporal evolution of Saturn's stratosphere following the Great Storm of 2010-2011. II. Latitudinal distribution of CO and stratospheric winds

Saturn's Great Storm of 2010-2011 has produced two stratospheric hot spots, the "beacons," that eventually merged to produce a gigantic one in April and May 2011. This beacon perturbed stratospheric temperatures, hydrocarbon, and water abundances for several years. We aim to assess whether the beacon induced any perturbation in another oxygen species, namely CO. A second goal is to measure how the vortex perturbed the stratospheric wind regime. We conducted interferometric observations of Saturn in the submillimeter range with SMA and ALMA to spatially resolve the CO (J=3-2) and (J=2-1) emissions, respectively. We used a previously determined CO vertical profile as a template, to search for (i) the meridional distribution of CO and (ii) variations of the CO abundance associated with the storm. The high spatial and spectral resolutions of the ALMA observations enabled us to retrieve the winds from the Doppler shifts induced by the winds on the lines. Despite limitations resulting from the removal of baseline ripples, we find a relatively constant meridional distribution of CO. The average CO mole fraction implied by the adopted and rescaled 220-year-old-comet-impact vertical profile is (1.7$\pm$0.7)$\times10^{-7}$ at 0.3\,mbar, i.e., where the contribution functions peak. We also find that the CO abundance has not been noticeably altered in the beacon. The winds measured at 1\,mbar show striking differences with those measured in 2018, after the demise of the beacon. We find the signature of the vortex as an anticyclonic feature. The equatorial prograde jet is 100 to 200 m.s$^{-1}$ slower, and broader in latitude, than in quiescent conditions. We also detect several prograde jets in the southern hemisphere. Finally, we detect a retrograde jet at 74$^\circ$N which could be a polar jet caused by the interaction of the Saturn magnetosphere with its atmosphere.

astro-ph.EP

Chemical composition of comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF) from radio spectroscopy and the abundance of HCOOH and HNCO in comets

We present the results of a molecular survey of long period comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF). Comet C/2021 A1 was observed with the IRAM 30-m radio telescope in November-December 2021 before perihelion when it was closest to the Earth. We observed C/2022 E3 in January-February 2023 with the Odin 1-m space telescope and IRAM 30-m, shortly after its perihelion, and when it was closest to the Earth. Snapshots were obtained during 12-16 November 2021 period for comet C/2021 A1. Spectral surveys were undertaken over the 8-13 December 2021 period for comet C/2021 A1 (8, 16, and 61 GHz bandwidth in the 3 mm, 2 mm, and 1 mm window) and over the 3-7 February 2023 period for comet C/2022 E3 (25 and 61 GHz at 2 and 1mm). We report detections of 14 molecular species (HCN, HNC, CH3CN, HNCO, NH2CHO, CH3OH, H2CO, HCOOH, CH3CHO, H2S, CS, OCS, C2H5OH and aGg-(CH2OH)2 ) in both comets plus HC3N and CH2OHCHO marginally detected in C/2021 A1 and CO and H2O (with Odin detected in C/2022 E3. The spatial distribution of several species is investigated. Significant upper limits on the abundances of other molecules and isotopic ratios are also presented. The activity of comet C/2021 A1 did not vary significantly between 13 November and 13 December 2021. Short-term variability in the outgassing of comet C/2022 E3 on the order of +-20% is present and possibly linked to its 8h rotation period. Both comets exhibit rather low abundances relative to water for volatiles species such as CO (< 2%) and H2S (0.15%). Methanol is also rather depleted in comet C/2021 A1 (0.9%). Following their revised photo-destruction rates, HNCO and HCOOH abundances in comets have been reevaluated. Both molecules are relatively enriched in these two comets (0.2% relative to water). We cannot exclude that these species could be produced by the dissociation of ammonium salts.

astro-ph.EP

Radiative-convective models of the atmospheres of Uranus and Neptune: heating sources and seasonal effects

The observations made during the Voyager 2 flyby have shown that the stratosphere of Uranus and Neptune are warmer than expected by previous models. In addition, no seasonal variability of the thermal structure has been observed on Uranus since Voyager 2 era and significant subseasonal variations have been revealed on Neptune. In this paper, we evaluate different realistic heat sources that can induce sufficient heating to warm the atmosphere of these planets and we estimate the seasonal effects on the thermal structure. The seasonal radiative-convective model developed by the Laboratoire de M\'et\'eorologie Dynamique is used to reproduce the thermal structure of these planets. Three hypotheses for the heating sources are explored separately: aerosol layers, a higher methane mole fraction, and thermospheric conduction. Our modelling indicates that aerosols with plausible scattering properties can produce the requisite heating for Uranus, but not for Neptune. Alternatively, greater stratospheric methane abundances can provide the missing heating on both planets, but the large values needed are inconsistent with current observational constraints. In contrast, adding thermospheric conduction cannot warm alone the stratosphere of both planets. The combination of these heat sources is also investigated. In the upper troposphere of both planets, the meridional thermal structures produced by our model are found inconsistent with those retrieved from Voyager 2/IRIS data. Furthermore, our models predict seasonal variations should exist within the stratospheres of both planets while observations showed that Uranus seems to be invariant to meridional contrasts and only subseasonal temperature trends are visible on Neptune. However, a warm south pole is seen in our simulations of Neptune as observed since 2003.

astro-ph.EP

Tuning domain wall oscillation frequency in bent nanowires through a mechanical analogy

In this work, we present a theoretical model for domain wall (DW) oscillations in a curved magnetic nanowire with a constant curvature under the action of a uniaxial magnetic field. Our results show that the DW dynamics can be described as that of the mechanical pendulum, and both the NW curvature and the external magnetic field influence its oscillatory frequency. A comparison between our theoretical approach and experimental data in the literature shows an excellent agreement. The results presented here can be used to design devices demanding the proper control of the DW oscillatory motion in NWs.

cond-mat.mes-hall

Water, hydrogen cyanide, carbon monoxide, and dust production from distant comet 29P/Schwassmann-Wachmann 1

29P/Schwassmann-Wachmann 1 is a distant Centaur/comet, showing persistent CO-driven activity and frequent outbursts. We used the Herschel space observatory in 2010, 2011, and 2013 to observe H$_2$O and NH$_3$ and to image the dust coma. Observations with the IRAM 30 m were undertaken in 2007, 2010, 2011, and 2021 to monitor the CO production rate and to search for HCN. Modeling was performed to constrain the size of the sublimating icy grains and to derive the dust production rate. HCN is detected for the first time in comet 29P (at 5$\sigma$ in the line area). H$_2$O is detected as well, but not NH$_3$. H$_2$O and HCN line shapes differ strongly from the CO line shape, indicating that these two species are released from icy grains. CO production rates are in the range (2.9-5.6) $\times$ 10$^{28}$ s$^{-1}$ (1400--2600 kg s$^{-1}$). A correlation between the CO production rate and coma brightness is observed, as is a correlation between CO and H$_2$O production. The correlation obtained between the excess of CO production and excess of dust brightness with respect to the quiescent state is similar to that established for the continuous activity of comet Hale-Bopp. The measured $Q$(H$_2$O)/$Q$(CO) and $Q$(HCN)/$Q$(CO) production rate ratios are 10.0 $\pm$ 1.5 % and 0.12 $\pm$ 0.03 %, respectively, averaging the April-May 2010 measurements ($Q$(H$_2$O) = (4.1 $\pm$ 0.6) $\times$ 10$^{27}$ s$^{-1}$, $Q$(HCN) = (4.8 $\pm$ 1.1) $\times$ 10$^{25}$ s$^{-1}$). We derive three independent and similar values of the effective radius of the nucleus, $\sim$ 31 $\pm$ 3 km. The inferred dust mass-loss rates during quiescent phases are in the range 30-120 kg s$^{-1}$, indicating a dust-to-gas mass ratio $<$ 0.1 during quiescent activity. We conclude that strong local heterogeneities exist on the surface of 29P, with quenched dust activity from most of the surface, but not in outbursting regions.

astro-ph.EP

Domain wall damped harmonic oscillations induced by curvature gradients in elliptical magnetic nanowires

Understanding the domain wall (DW) dynamics in magnetic nanowires (NW) is crucial for spintronic-based applications demanding the use of DWs as information carriers. This work focuses on the dynamics of a DW displacing along a bent NW with an elliptical shape under the action of spin-polarized electric currents and external magnetic fields. Our results evidence that a curvature gradient induces an exchange-driven effective tangential field responsible for pinning a DW near the maximum curvature point in a NW. The DW equilibrium position depends on the competition between the torques produced by the external stimuli and the curvature-induced effective fields. When the external stimuli are below a certain threshold, the DW follows a damped harmonic oscillation around the equilibrium position. Above this threshold, DW displaces along the NW under an oscillatory translational motion.

cond-mat.mes-hall

Size and albedo of the largest detected Oort-cloud object: comet C/2014 UN 271 (Bernardinelli-Bernstein)

The recently announced Oort-cloud comet C/2014 UN271 (Bernardinelli-Bernstein) is remarkable in at least three respects: (i) it was discovered inbound as far as ~29 au from the Sun (with prediscovery images up to ~34 au); (ii) it showed cometary activity already at almost 24 au; and (iii) its nuclear magnitude (Hr ~ 8.0) indicates an exceptionally large object. Detection of gases is expected in the upcoming years as the comet is heading towards a ~11 au perihelion in 2031. We used ALMA in extended configuration (resolution ~0.064") to measure the 1287 um (233 GHz) continuum flux of the comet. Observations were performed on August 8, 2021 at a 20.0 au distance from the Sun. The high spatial resolution was chosen in order to filter out any dust contribution. We detected the thermal emission of the object at ~10 sigma, with a flux of 0.128+/-0.012 mJy. Based on observational constraints and our theoretical estimates of the dust contribution, the entirety of the measured flux can be attributed to the nucleus. From NEATM modelling combined with the Hr magnitude, we determine a surface-equivalent diameter of 137+/-17 km and a red geometric albedo of 5.3+/-1.2 %. This confirms that 2014 UN271 is by far the largest Oort-cloud object ever found (almost twice as large as comet C/1995 O1 Hale-Bopp), and except for the Centaur 95P/Chiron which shows outburst-like activity, the largest known comet in the Solar System. On the other hand, the object albedo is typical of comets, adding credence for a "universal" comet nucleus albedo. With its distant perihelion and uniquely large size, 2014 UN271 is the prominent archetype of distant comets, whose activity is driven by hypervolatiles. Post-perihelion thermal measurements will permit to study possible albedo changes, such as a surface brightening compared to pre-perihelion, as was observed for Hale-Bopp.

astro-ph.EP

Ground-based HCN submillimetre measurements in Titan's atmosphere: an intercomparison with Herschel observations

The aim of this study is to measure the vertical distribution of HCN on Titan's stratosphere using ground-based submm observations acquired quasi-simultaneously with the Herschel ones. This allows us to perform a consistency check between space and ground-based observations and to build a reference mean HCN vertical profile in Titan's stratosphere. Using APEX and IRAM 30-m, we obtained the spectral emission of HCN (4-3) and (3-2) lines. We applied a line-by-line radiative transfer code to calculate the synthetic spectra of HCN, and a retrieval algorithm based on optimal estimation to retrieve the temperature and HCN distributions. Our derived HCN abundance profiles are consistent with an increase from 40 ppb at ~100 km to 4 ppm at ~200 km, which is an altitude region where the HCN signatures are sensitive. We also demonstrate that the retrieved HCN distribution is sensitive to the data information. Comparisons between our results and the values from Herschel show similar abundance distributions, with maximum differences of 2.5 ppm ranging between 100 and 300 km. These comparisons also allow us to inter-validate both data sets and indicate reliable and consistent measurements. The inferred abundances are also consistent with the distribution in previous observational studies, with the profiles from ALMA, Cassini/CIRS, and SMA (the latest ones below ~230 km). Our HCN profile is also comparable to photochemical models by Krasnopolsky (2014) and Vuitton et al. (2019) below 230 km and consistent with that of Loison et al. (2015) above 250 km. However, it appears to show large differences with respect to the estimates by Loison et al. (2015), Dobrijevic & Loison (2018), and Lora et al. (2018) below 170 km, and by Dobrijevic & Loison (2018) and Lora et al. (2018) above 400 km, although they are similar in shape. We conclude that these particular photochemical models need improvement.

astro-ph.EP

First Leptophobic Dark Matter Search from Coherent CAPTAIN-Mills

We report the first results of a search for leptophobic dark matter (DM) from the Coherent CAPTAIN-Mills (CCM) liquid argon (LAr) detector. An engineering run with 120 photomultiplier tubes (PMTs) and $17.9 \times 10^{20}$ protons-on-target (POT) was performed in Fall 2019 to study the characteristics of the CCM detector. The operation of this 10-ton detector was strictly light-based with a threshold of 50 keV and used coherent elastic scattering off argon nuclei to detect DM. Despite only 1.5 months of accumulated luminosity, contaminated LAr, and non-optimized shielding, CCM's first engineering run already achieved sensitivity to previously unexplored parameter space of light dark matter (LDM) models with a baryonic vector portal. With an expected background of 115,005 events, we observe 115,005+16.5 events which is compatible with background expectations. For a benchmark mediator-to-dark matter mass ratio of $m_{_{V_B}}/m_{\chi}=2.1$, DM masses within the range $9\,\text{MeV} \lesssim m_\chi \lesssim 50\,\text{MeV}$ have been excluded at 90% C.L. in the leptophobic model after applying the Feldman-Cousins test statistic. CCM's upgraded run with 200 PMTs, filtered LAr, improved shielding, and ten times more POT will be able to exclude the remaining thermal relic density parameter space of this model, as well as probe new parameter space of other leptophobic DM models.

hep-ex

Pluto's atmosphere observations with ALMA: spatially-resolved maps of CO and HCN emission and first detection of HNC

Following the detection of CO and HCN in Pluto's atmosphere, we report on new ALMA observations of Pluto with two main goals: (i) obtaining spatially-resolved measurements (~0.06'' on the ~0.15'' disk subtended by Pluto and its atmosphere) of CO(3-2) and HCN(4-3) (ii) targetting new chemical compounds, primarily hydrogen isocyanide (HNC). The CO line shows an absorption core at beam positions within Pluto's disk, a direct signature of Pluto's cold mesosphere. Analysis provides tentative evidence for a non-uniform temperature field in the lower atmosphere (near 30 km), with summer pole latitudes being 7$\pm$3.5 K warmer than low latitudes. This unexpected result may point to shorter radiative timescales in the atmosphere than previously thought. The HCN emission is considerably more extended than CO, peaking at radial distances beyond Pluto limb, and providing a new method to determine Pluto's HCN vertical profile in 2017. The mean (column-averaged) location of HCN is at 690+/-75 km altitude, with an upper atmosphere (> 800 km) mixing ratio of ~ 1.8 x 10$^{-4}$. Little or no HCN (<5 x 10$^{-9}$ at 65 km) is present in the lower atmosphere, implying undersaturation of HCN there. The HCN emission appears enhanced above the low-latitude limb, but interpretation, in terms of an enhanced HCN abundance or a warmer upper atmosphere there, is uncertain. The first detection of HNC is reported, with a (7.0$\pm$2.1) x 10$^{12}$ cm$^{-2}$ column density, referred to Pluto surface, and a HNC / HCN ratio of 0.095+/-0.026, very similar to their values in Titan's atmosphere. We also obtain upper limits on CH3CN (< 2.6 x 10$^{13}$ cm$^{-2}$) and CH$_3$CCH (< 8.5 x 10$^{14}$ cm$^{-2}$); the latter value is inconsistent with the reported detection of CH$_3$CCH from New Horizons. These upper limits also point to incomplete resublimation of ice-coated aerosols in the lower atmosphere.

astro-ph.EP

First Dark Matter Search Results From Coherent CAPTAIN-Mills

This paper describes the operation of the Coherent CAPTAIN-Mills (CCM) detector located at the Lujan Neutron Science Center (LANSCE) at Los Alamos National Laboratory (LANL). CCM is a 10-ton liquid argon (LAr) detector located 20 meters from a high flux neutron/neutrino source and is designed to search for sterile neutrinos ($\nu_s$) and light dark matter (LDM). An engineering run was performed in Fall 2019 to study the characteristics of the CCM120 detector by searching for coherent scattering signals consistent with $\nu_s$'s and LDM resulting from $\pi^+$ and $\pi^0$ decays in the tungsten target. New parameter space in a leptophobic dark matter model was excluded for DM masses between $\sim2.0$ and 30 MeV. The lessons learned from this run have guided the development and construction of the new CCM200 detector that will begin operations in 2021 and significantly improve on these searches.

hep-ex

First direct measurement of auroral and equatorial jets in the stratosphere of Jupiter

Context. The tropospheric wind pattern in Jupiter consists of alternating prograde and retrograde zonal jets with typical velocities of up to 100 m/s around the equator. At much higher altitudes, in the ionosphere, strong auroral jets have been discovered with velocities of 1-2 km/s. There is no such direct measurement in the stratosphere of the planet. Aims. In this paper, we bridge the altitude gap between these measurements by directly measuring the wind speeds in Jupiter's stratosphere. Methods. We use the Atacama Large Millimeter/submillimeter Array's very high spectral and angular resolution imaging of the stratosphere of Jupiter to retrieve the wind speeds as a function of latitude by fitting the Doppler shifts induced by the winds on the spectral lines. Results. We detect for the first time equatorial zonal jets that reside at 1 mbar, i.e. above the altitudes where Jupiter's Quasi-Quadrennial Oscillation occurs. Most noticeably, we find 300-400 m/s non-zonal winds at 0.1 mbar over the polar regions underneath the main auroral ovals. They are in counter-rotation and lie several hundreds of kilometers below the ionospheric auroral winds. We suspect them to be the lower tail of the ionospheric auroral winds. Conclusions. We detect directly and for the first time strong winds in Jupiter's stratosphere. They are zonal at low-to-mid latitudes and non-zonal at polar latitudes. The wind system found at polar latitudes may help increase the effciency of chemical complexification by confining the photochemical products in a region of large energetic electron precipitation.

astro-ph.EP

Molecular composition of comet 46P/Wirtanen from millimetre-wave spectroscopy

We present the results of a molecular survey of comet 46P/Wirtanen undertaken with the IRAM 30-m and NOEMA radio telescopes in December 2018. Observations at IRAM 30-m during the 12-18 Dec. period comprise a 2 mm spectral survey covering 25 GHz and a 1 mm survey covering 62 GHz. The gas outflow velocity and kinetic temperature have been accurately constrained by the observations. We derive abundances of 11 molecules, some being identified remotely for the first time in a Jupiter-family comet, including complex organic molecules such as formamide, ethylene glycol, acetaldehyde, or ethanol. Sensitive upper limits on the abundances of 24 other molecules are obtained. The comet is found to be relatively rich in methanol (3.4 percent relative to water), but relatively depleted in CO, CS, HNC, HNCO, and HCOOH.

astro-ph.EP

18-year long monitoring of the evolution of H2O vapor in the stratosphere of Jupiter with the Odin space telescope

Comet Shoemaker-Levy 9 impacted Jupiter in July 1994, leaving its stratosphere with several new species, among them water vapor (H2O). With the aid of a photochemical model H2O can be used as a dynamical tracer in the jovian stratosphere. In this paper, we aim at constraining vertical eddy diffusion (Kzz) at the levels where H2O resides. We monitored the H2O disk-averaged emission at 556.936 GHz with the Odin space telescope between 2002 and 2019, covering nearly two decades. We analyzed the data with a combination of 1D photochemical and radiative transfer models to constrain vertical eddy diffusion in the stratosphere of Jupiter. The Odin observations show us that the emission of H2O has an almost linear decrease of about 40% between 2002 and 2019.We can only reproduce our time series if we increase the magnitude of Kzz in the pressure range where H2O diffuses downward from 2002 to 2019, i.e. from ~0.2 mbar to ~5 mbar. However, this modified Kzz is incompatible with hydrocarbon observations. We find that, even if allowance is made for the initially large abundances of H2O and CO at the impact latitudes, the photochemical conversion of H2O to CO2 is not sufficient to explain the progressive decline of the H2O line emission, suggestive of additional loss mechanisms. The Kzz we derived from the Odin observations of H2O can only be viewed as an upper limit in the ~0.2 mbar to ~5 mbar pressure range. The incompatibility between the interpretations made from H2O and hydrocarbon observations probably results from 1D modeling limitations. Meridional variability of H2O, most probably at auroral latitudes, would need to be assessed and compared with that of hydrocarbons to quantify the role of auroral chemistry in the temporal evolution of the H2O abundance since the SL9 impacts. Modeling the temporal evolution of SL9 species with a 2D model would be the next natural step.

astro-ph.EP