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R. P. Amaral

Publications and source records attributed to R. P. Amaral.

3 recordsLinked to original sources

Dynamic magnetism in the disordered hexagonal double perovskite BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$

Magnetic frustration and disorder are key ingredients to prevent the onset of magnetic order. In the disordered hexagonal double perovskite BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$, Mn$^{4+}$ cations, with $S=3/2$ spins, can either form highly correlated states of magnetic trimers or dimers or remain as weakly interacting orphan spins. At low temperature ($T$), the dimer response is negligible, and magnetism is dominated by the trimers and orphans. To explore the role of magnetic frustration, disorder and possibly of quantum fluctuations, the low-$T$ magnetic properties of the remaining magnetic degrees of freedom of BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$ are investigated. Heat-capacity data and magnetic susceptibility display no evidence for a phase transition to a magnetically ordered phase but indicate the formation of a correlated spin state. The low-temperature spin dynamics of this state is then explored by $μ$SR experiments. The zero field $μ^{+}$ relaxation rate data show no static magnetism down to $T=19$ mK and longitudinal field experiments support as well that dynamic magnetism persists at low $T$. Our results are interpreted in terms of a spin glass state which stems from a disordered lattice of orphans spins and trimers. A spin liquid state in BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$, however, is not excluded and is also discussed.

cond-mat.str-el

Antiferromagnetism weakening with Y-substitution in the TbRhIn$_5$ intermetallic system

We report measurements of the temperature dependence specific heat, magnetic susceptibility in single crystals of the series of intermetallic compounds Tb$_{1-x}$Y$_x$RhIn$_5$ (nominal concentrations $x= 0.15, 0.30, 0.40, 0.50$ and $0.70$). A mean field approximation to simulate the macroscopic properties along the series has been used. Neutron diffraction data in powdered sample of nominal concentration Tb$_{0.6}$Y$_{0.4}$RhIn$_5$ reveal AFM propagation vector $k=[\frac{1}{2}~0~\frac{1}{2}]$ with the magnetic moments oriented close to the tetragonal \textit{c} axis. We discuss the role of combined effects of crystalline electric field (CEF) perturbations and dilution in the magnetic properties evolution with Y content. In particular, we suggest that changes in the Tb-In first neighbors distances, i.e. the TbIn$_3$ cuboctahedra distortion, are responsible for changes in the Tb crystalline potential and the possible reorientation of Tb magnetic moments for $x>$0.4. This reflects non negligible variations of the $B^{m}_{n}$ crystal field parameters and the energy levels splitting with \textit{x}.

cond-mat.str-el

Magnetic dimers and trimers in the disordered $S=3/2$ spin system BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$

We report a structural/magnetic investigation by X-ray absorption spectroscopy (XAS), neutron diffraction, dc-susceptibility ($χ_{\mbox{dc}}$) and electron spin resonance (ESR) of the 12R-type perovskite BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$. Our structural analysis by neutron diffraction supports the existence of structural trimers with chemically disordered occupancy of Mn$^{4+}$ and Ti$^{4+}$ ions, with the valence of the Mn ions confirmed by the XAS measurements. The magnetic properties are explored by combining dc-susceptibility and $X$-band ($9.4$ GHz) electron spin resonance, both in the temperature interval of $2\leq T\leq1000$ K. A scenario is presented under which the magnetism is explained by considering magnetic dimers and trimers, with exchange constants $J_{a}/k_{B}=200(2)$ K and $J_{b}/k_{B}=130(10)$ K, and orphan spins. Thus, BaTi$_{1/2}$Mn$_{1/2}$O$_{3}$ is proposed as a rare case of an intrinsically disordered $S=3/2$ spin gap system with a frustrated ground state.

cond-mat.str-el