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R. Peyton Cline

Publications and source records attributed to R. Peyton Cline.

3 recordsLinked to original sources

Resource Estimation via Efficient Compilation of Key Quantum Primitives

Resource estimation is a significant challenge in evaluating fault tolerant quantum computers. Existing approaches often rely on either fixed architectural assumptions or coarse analytical models that fail to capture the interaction between hardware constraints and circuit compilation. This challenge is particularly acute for neutral atom quantum computers, where architectural features such as atom movement, measurement zones, and multi-species arrays introduce a broad design space for implementing fault tolerant computation. Addressing the need for a tighter feedback loop between hardware design and practical application development, we present a compilation-driven framework for quantum resource estimation that translates arbitrary quantum circuits into logical primitive operations with known physical resource costs. This framework allows for easily configurable hardware assumptions that enable rapid comparison of different architectural design choices. We apply our approach to two early fault tolerant quantum simulation and optimization workloads, assuming the use of the surface code, revealing several architectural trends. While the production of magic states continues to be the dominant source of overhead for these benchmarks, access to movement can save time on cultivation and important transversal gates. As problem size grows, routing and qubit movement become dominant bottlenecks, highlighting the need for movement-aware compiler optimizations and frugal routing strategies. Finally, our results suggest that neutral atom architectures combining dual-species arrays with controlled qubit movement offer a promising path toward near-term advantage on fault tolerant devices.

quant-ph

Efficient Photon Upconversion Enabled by Strong Coupling Between Organic Molecules and Quantum Dots

Hybrid structures formed between organic molecules and inorganic quantum dots can accomplish unique photophysical transformations by taking advantage of their disparate properties. The electronic coupling between these materials is typically weak, leading photoexcited charge carriers to spatially localize to a dot or a molecule at its surface. However, we show that by converting a chemical linker that covalently binds anthracene molecules to silicon quantum dots from a carbon-carbon single bond to a double bond, we access a strong-coupling regime where excited carriers spatially delocalize across both anthracene and silicon. By pushing the system to delocalize, we design a photon upconversion system with a higher efficiency (17.2%) and lower threshold intensity (0.5 W/cm^2) than that of a corresponding weakly-coupled system. Our results show that strong coupling between molecules and nanostructures achieved through targeted linking chemistry provides a new route for tailoring properties in materials for light-driven applications.

physics.chem-ph

On the Nature of Trapped-Hole States in CdS Nanocrystals and the Mechanism of their Diffusion

Recent transient absorption experiments on CdS nanorods suggest that photoexcited holes rapidly trap to the surface of these particles and then undergo diffusion along the rod surface. In this paper, we present a semiperiodic DFT model for the CdS nanocrystal surface, analyze it, and comment on the nature of both the hole-trap states and the mechanism by which the holes diffuse. Hole states near the top of the valence band form an energetic near continuum with the bulk, and localize to the non-bonding sp$^3$ orbitals on surface sulfur atoms. After localization, the holes form nonadiabatic small polarons that move between the sulfur orbitals on the surface of the particle in a series of uncorrelated, incoherent, thermally-activated hops at room temperature. The surface-trapped holes are deeply in the weak-electronic coupling limit and, as a result, undergo slow diffusion.

physics.chem-ph