R. R. W. Wang | Searcharxiv

arXiv2026

Observation of resonant monopole-dipole energy transfer between Rydberg atoms and polar molecules

Resonant energy transfer (RET), between equal parity 1s65s$^3\mathrm{S}_1$ and 1s66s$^3\mathrm{S}_1$ Rydberg levels in helium has been observed in low-temperature ($\sim80$ mK) collisions with ammonia molecules which undergo inversion transitions in their X$^1$A$_1$ ground electronic state. This hybrid Rydberg-atom-polar-molecule RET represents a monopole-dipole energy exchange reaction that necessarily requires spatial overlap of the Rydberg-electron and molecular wavefunctions. Calculations, that account explicitly for the charge-dipole interaction between the Rydberg electron and the molecule, provide a quantitative explanation of the observations. Total parity is conserved in the reaction through the mixing of collisional angular momentum in the atom-molecule complex. This work opens opportunities to expand the toolbox for quantum science with charge-dipole-mediated energy exchange in hybrid neutral-atom-polar-molecule platforms.

physics.atom-ph↗

arXiv2021

Accurate determination of the scattering length of erbium atoms

An accurate knowledge of the scattering length is fundamental in ultracold quantum gas experiments and essential for the characterisation of the system as well as for a meaningful comparison to theoretical models. Here, we perform a careful characterisation of the s-wave scattering length $a_s$ for the four highest-abundance isotopes of erbium, in the magnetic field range from 0G to 5G. We report on cross-dimensional thermalization measurements and apply the Enskog equations of change to numerically simulate the thermalization process and to analytically extract an expression for the so-called number of collisions per re-thermalization (NCPR) to obtain $a_s$ from our experimental data. We benchmark the applied cross-dimensional thermalization technique with the experimentally more demanding lattice modulation spectroscopy and find good agreement for our parameter regime. Our experiments are compatible with a dependence of the NCPR with $a_s$, as theoretically expected in the case of strongly dipolar gases. Surprisingly, we experimentally observe a dependency of the NCPR on the density, which might arise due to deviations from an ideal harmonic trapping configuration. Finally, we apply a model for the dependency of the background scattering length with the isotope mass, allowing to estimate the number of bound states of erbium.

cond-mat.quant-gas↗