arXiv subjects

R. S. Freedman

Publications and source records attributed to R. S. Freedman.

14 recordsLinked to original sources

arXiv2012

Chemical consequences of the C/O ratio on hot Jupiters: Examples from WASP-12b,CoRoT-2b, XO-1b, and HD 189733b

Motivated by recent spectroscopic evidence for carbon-rich atmospheres on some transiting exoplanets, we investigate the influence of the C/O ratio on the chemistry, composition, and spectra of extrasolar giant planets both from a thermochemical-equilibrium perspective and from consideration of disequilibrium processes like photochemistry and transport-induced quenching. We find that although CO is predicted to be a major atmospheric constituent on hot Jupiters for all C/O ratios, other oxygen-bearing molecules like H2O and CO2 are much more abundant when C/O < 1, whereas CH4, HCN, and C2H2 gain significantly in abundance when C/O > 1. Disequilibrium processes tend to enhance the abundance of CH4, NH3, HCN, and C2H2 over a wide range of C/O ratios. We compare the results of our models with secondary-eclipse photometric data from the Spitzer Space Telescope and conclude that (1) disequilibrium models with C/O ~ 1 are consistent with spectra of WASP-12b, XO-1b, and CoRoT-2b, confirming the possible carbon-rich nature of these planets, (2) spectra from HD 189733b are consistent with C/O ~< 1, but as the assumed metallicity is increased above solar, the required C/O ratio must increase toward 1 to prevent too much H2O absorption, (3) species like HCN can have a significant influence on spectral behavior in the 3.6 and 8.0 um Spitzer channels, potentially providing even more opacity than CH4 when C/O > 1, and (4) the very high CO2 abundance inferred for HD 189733b from near-infrared observations cannot be explained through equilibrium or disequilibrium chemistry in a H2-dominated atmosphere. We discuss possible formation mechanisms for carbon-rich hot Jupiters. The C/O ratio and bulk atmospheric metallicity provide important clues regarding the formation and evolution of the giant planets.

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arXiv2012

New H2 collision-induced absorption and NH3 opacity and the spectra of the coolest brown dwarfs

We present new cloudy and cloudless model atmospheres for brown dwarfs using recent ab initio calculations of the line list of ammonia (NH3) and of the collision-induced absorption of molecular hydrogen (H2). We compare the new synthetic spectra with models based on an earlier description of the H2 and NH3 opacities. We find a significant improvement in fitting the nearly complete spectral energy distribution of the T7p dwarf Gliese 570D and in near infrared color-magnitude diagrams of field brown dwarfs. We apply these new models to the identification of NH3 absorption in the H band peak of very late T dwarfs and the new Y dwarfs and discuss the observed trend in the NH3-H spectral index. The new NH3 line list also allows a detailed study of the medium resolution spectrum of the T9/T10 dwarf UGPS J072227.51-054031.2 where we identify several specific features caused by NH3.

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arXiv2009

Transmission Spectra of Three-Dimensional Hot Jupiter Model Atmospheres

We compute models of the transmission spectra of planets HD 209458b, HD 189733b, and generic hot Jupiters. We examine the effects of temperature, surface gravity, and metallicity for the generic planets as a guide to understanding transmission spectra in general. We find that carbon dioxide absorption at 4.4 and 15 microns is prominent at high metallicity, and is a clear metallicity indicator. For HD 209458b and HD 189733b, we compute spectra for both one-dimensional and three-dimensional model atmospheres and examine the differences between them. The differences are usually small, but can be large if atmospheric temperatures are near important chemical abundance boundaries. The calculations for the 3D atmospheres, and their comparison with data, serve as constraints on these dynamical models that complement the secondary eclipse and light curve data sets. For HD 209458b, even if TiO and VO gases are abundant on the day side, their abundances can be considerably reduced on the cooler planetary limb. However, given the predicted limb temperatures and TiO abundances, the model's optical opacity is too high. For HD 189733b we find a good match with some infrared data sets and constrain the altitude of a postulated haze layer. For this planet, substantial differences can exist between the transmission spectra of the leading and trailing hemispheres, which is an excellent probe of carbon chemistry. In thermochemical equilibrium, the cooler leading hemisphere is methane-dominated, and the hotter trailing hemisphere is CO-dominated, but these differences may be eliminated by non-equilibrium chemistry due to vertical mixing. It may be possible to constrain the carbon chemistry of this planet, and its spatial variation, with JWST.

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arXiv2009

Atmospheric Sulfur Photochemistry on Hot Jupiters

We develop a new 1D photochemical kinetics code to address stratospheric chemistry and stratospheric heating in hot Jupiters. Here we address optically active S-containing species and CO2 at 1200 < T < 2000 K. HS (mercapto) and S2 are highly reactive species that are generated photochemically and thermochemically from H2S with peak abundances between 1-10 mbar. S2 absorbs UV between 240 and 340 nm and is optically thick for metallicities [SH] > 0 at T > 1200 K. HS is probably more important than S2, as it is generally more abundant than S2 under hot Jupiter conditions and it absorbs at somewhat redder wavelengths. We use molecular theory to compute an HS absorption spectrum from sparse available data and find that HS should absorb strongly between 300 and 460 nm, with absorption at the longer wavelengths being temperature sensitive. When the two absorbers are combined, radiative heating (per kg of gas) peaks at 100 microbars, with a total stratospheric heating of about 8 x 10^4 W/m^2 for a jovian planet orbiting a solar-twin at 0.032 AU. Total heating is insensitive to metallicity. The CO2 mixing ratio is a well-behaved quadratic function of metallicity, ranging from 1.6 x 10^-8 to 1.6 x 10^-4 for -0.3 < [M/H] < 1.7. CO2 is insensitive to insolation, vertical mixing, temperature (1200 < T <2000 K), and gravity. The photochemical calculations confirm that CO2 should prove a useful probe of planetary metallicity.

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arXiv2006

Physical parameters of two very cool T dwarfs

We present new infrared spectra of the T8 brown dwarf 2MASS J04151954-0935066: 2.9-4.1 micron spectra obtained with the Infrared Camera and Spectrograph on the Subaru Telescope, and 5.2-14.5 micron spectra obtained with the Infrared Spectrograph on the Spitzer Space Telescope. We use these data and models to determine an accurate bolometric luminosity of log L_bol/L_sun=-5.67 and to constrain the effective temperature, gravity, mass and age to 725-775K, log g=5.00-5.37, M=33-58 M_Jupiter and age=3-10Gyr. We perform the same analysis using published 0.6-15 micron spectra for the T7.5 dwarf 2MASS J12171110-0311131, for which we find a metal-rich composition ([Fe/H]~0.3) and log L_bol/L_sun=-5.31, T_eff=850-950K, log g=4.80-5.42, M=25-66M_Jupiter and age=1-10Gyr. These luminosities and effective temperatures straddle those determined with the same method and models for Gl 570D by Saumon et al. (2006) and make 2MASS J04151954-0935066 the coolest and least luminous T dwarf with well-determined properties. We find that synthetic spectra generated by the models reproduce the observed red through mid-infrared spectra of 2MASS J04151954-0935066 and 2MASS J12171110-0311131 very well, except for known discrepancies which are most likely due to the incomplete CH4 opacities. Both objects show evidence of departures from strict chemical equilibrium and we discuss this result in the context of other late T dwarfs where disequilibrium phenomena have been observed.

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arXiv2006

The Influence of Atmospheric Dynamics on the Infrared Spectra and Light Curves of Hot Jupiters

We explore the infrared spectrum of a three-dimensional dynamical model of planet HD209458b as a function of orbital phase. The dynamical model predicts day-side atmospheric pressure-temperature profiles that are much more isothermal at pressures less than 1 bar than one-dimensional radiative-convective models have found. The resulting day-side thermal spectra are very similar to a blackbody, and only weak water absorption features are seen at short wavelengths. The dayside emission is consequently in significantly better agreement with ground-based and space-based secondary eclipse data than any previous models, which predict strong flux peaks and deep absorption features. At other orbital phases, absorption due to carbon monoxide and methane is also predicted. We compute the spectra under two treatments of atmospheric chemistry: one uses the predictions of equilibrium chemistry, and the other uses non-equilibrium chemistry, which ties the timescales of methane and carbon monoxide chemistry to dynamical timescales. As a function of orbital phase, we predict planet-to-star flux ratios for standard infrared bands and all Spitzer Space Telescope bands. In Spitzer bands, we predict 2-fold to 15-fold variation in planetary flux as a function of orbital phase with equilibrium chemistry, and 2-fold to 4-fold variation with non-equilibrium chemistry. Variation is generally more pronounced in bands from 3-10 $μ$m than at longer wavelengths. The orbital phase of maximum thermal emission in infrared bands is 15--45 orbital degrees before the time of secondary eclipse. Changes in flux as a function of orbital phase for HD209458b should be observable with Spitzer, given the previously acheived observational error bars.

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arXiv2006

Ammonia as a tracer of chemical equilibrium in the T7.5 dwarf Gliese 570D

We present the first analysis of an optical to mid-infrared spectrum of the T7.5 dwarf Gliese 570D with model atmospheres, synthetic spectra, and brown dwarf evolution sequences. We obtain precise values for the basic parameters of Gl 570D: Teff=800 - 820K, log g (cm/s^2)=5.09 - 5.23, and log L/Lsun= -5.525 to -5.551. The Spitzer IRS spectrum shows prominent features of ammonia (NH3) that can only be fitted by reducing the abundance of NH3 by about one order of magnitude from the value obtained with chemical equilibrium models. We model departures from chemical equilibrium in the atmosphere of Gl 570D by considering the kinetics of nitrogen and carbon chemistry in the presence of vertical mixing. The resulting model spectrum reproduces the data very well.

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arXiv2006

Atmosphere, Interior, and Evolution of the Metal-Rich Transiting Planet HD 149026b

We investigate the atmosphere and interior of the new transiting planet HD 149026b, which appears to be very rich in heavy elements. We first compute model atmospheres at metallicities ranging from solar to ten times solar, and show how for cases with high metallicity or inefficient redistribution of energy from the day side, the planet may develop a hot stratosphere due to absorption of stellar flux by TiO and VO. The spectra predicted by these models are very different than cooler atmosphere models without stratospheres. The spectral effects are potentially detectable with the Spitzer Space Telescope. In addition the models with hot stratospheres lead to a large limb brightening, rather than darkening. We compare the atmosphere of HD 149026b to other well-known transiting planets, including the recently discovered HD 189733b, which we show have planet-to-star flux ratios twice that of HD 209458 and TrES-1. The methane abundance in the atmosphere of HD 189733b is a sensitive indicator of atmospheric temperature and metallicity and can be constrained with Spitzer IRAC observations. We then turn to interior studies of HD 149026b and use a grid of self-consistent model atmospheres and high-pressure equations of state for all components to compute thermal evolution models of the planet. We estimate that the mass of heavy elements within the planet is in the range of 60 to 93 M_earth. Finally, we discuss trends in the radii of transiting planets with metallicity in light of this new member of the class.

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arXiv2002

Non-equilibrium chemistry in the atmospheres of brown dwarfs

Carbon monoxide and ammonia have been detected in the spectrum of Gl 229B at abundances that differ substantially from those obtained from chemical equilibrium. Vertical mixing in the atmosphere is a mechanism that can drive slowly reacting species out of chemical equilibrium. We explore the effects of vertical mixing as a function of mixing efficiency and effective temperature on the chemical abundances in the atmospheres of brown dwarfs and on their spectra. The models compare favorably with the observational evidence and indicate that vertical mixing plays an important role in brown dwarf atmospheres.

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arXiv2000

Molecular Abundances in the Atmosphere of the T Dwarf Gl 229B

We present new, high resolution, infrared spectra of the T dwarf Gliese 229B in the J, H, and K bandpasses. We analyze each of these as well as previously published spectra to determine its metallicity and the abundances of NH3 and CO in terms of the surface gravity of Gl 229B, which remains poorly constrained. The metallicity increases with increasing gravity and is below the solar value unless Gl 229B is a high-gravity brown dwarf with log g(cgs) ~ 5.5. The NH3 abundance is determined from both the H and the K band spectra which probe two different levels in the atmosphere. We find that the abundance from the K band data is well below that expected from chemical equilibrium, which we interpret as strong evidence for dynamical transport of NH3 in the atmosphere. This is consistent with the previous detection of CO and provides additional constraints on the dynamics of the atmosphere of this T dwarf.

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arXiv1997

Extrasolar Giant Planet and Brown Dwarf Models

With the discovery of the companions of 51 Peg, 55 Cnc, $τ$ Boo, $\upsilon$ And, 70 Vir, 47 UMa, and Gl229, evolutionary and spectral models of gas giants and/or brown dwarfs with masses from 0.3 through 60 times that of Jupiter assume a new and central role in the emerging field of extrasolar planetary studies. In this contribution, we describe the structural, spectral, and evolutionary characteristics of such exotic objects, as determined by our recent theoretical calculations. These calculations can be used to establish direct search strategies via SIRTF, ISO, and HST (NICMOS), and via various ground-based adaptive optics and interferometric platforms planned for the near future.

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arXiv1997

Liquid metallic hydrogen and the structure of brown dwarfs and giant planets

Electron-degenerate, pressure-ionized hydrogen (usually referred to as metallic hydrogen) is the principal constituent of brown dwarfs, the long-sought objects which lie in the mass range between the lowest-mass stars (about eighty times the mass of Jupiter) and the giant planets. The thermodynamics and transport properties of metallic hydrogen are important for understanding the properties of these objects, which, unlike stars, continually and slowly cool from initial nondegenerate (gaseous) states. Within the last year, a brown dwarf (Gliese 229 B) has been detected and its spectrum observed and analyzed, and several examples of extrasolar giant planets have been discovered. The brown dwarf appears to have a mass of about forty to fifty Jupiter masses and is now too cool to be fusing hydrogen or deuterium, although we predict that it will have consumed all of its primordial deuterium. This paper reviews the current understanding of the interrelationship between its interior properties and its observed spectrum, and also discusses the current status of research on the structure of giant planets, both in our solar system and elsewhere.

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arXiv1996

Theortetical Models of Extrasolar Giant Planets

The recent discoveries of giant planets around nearby stars have galvanized the planetary science community, astronomers, and the public at large. Since {\it direct} detection is now feasible, and is suggested by the recent acquisition of Gl229 B, it is crucial for the future of extrasolar planet searches that the fluxes, evolution, and physical structure of objects from Saturn's mass to 15 Juipter masses be theoretically investigated. We discuss our first attempts to explore the characteristics of extrasolar giant planets (EGPs), in aid of both NASA's and ESA's recent plans to search for such planets around nearby stars.

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arXiv1996

Atmospheric, Evolutionary, and Spectral Models of the Brown Dwarf Gliese 229 B

Theoretical spectra and evolutionary models that span the giant planet--brown dwarf continuum have been computed based on the recent discovery of the brown dwarf, Gliese 229 B. A flux enhancement in the 4--5 micron window is a universal feature from Jovian planets to brown dwarfs. We confirm the existence of methane and water in Gl 229 B's spectrum and find its mass to be 30 to 55 Jovian masses. Although these calculations focus on Gliese 229 B, they are also meant to guide future searches for extra-solar giant planets and brown dwarfs.

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