arXiv subjects

R. S. Gonnelli

Publications and source records attributed to R. S. Gonnelli.

At least 37 records · Page 2Linked to original sources

arXiv2013

Effects of isoelectronic Ru substitution at the Fe site on the energy gaps of optimally F-doped SmFeAsO

We studied the effects of isoelectronic Ru substitution at the Fe site on the energy gaps of optimally F-doped SmFeAsO by means of point-contact Andreev reflection spectroscopy. The results show that the SmFe_{1-x}Ru_{x}AsO_{0.85}F_{0.15} system keeps a multigap character at least up to x=0.50, and that the gap amplitudes Delta_1 and Delta_2 scale almost linearly with the local critical temperature TcA. The gap ratios 2Delta_i/(kB Tc) remain approximately constant only as long as Tc > 30 K, but increase dramatically when Tc decreases further. This trend seems to be common to many Fe-based superconductors, irrespective of their family. Based on first-principle calculations of the bandstructure and of the density of states projected on the different bands, we show that this trend, as well as the Tc dependence of the gaps and the reduction of Tc upon Ru doping, can be explained within an effective three-band Eliashberg model as being due to a suppression of the superfluid density at finite temperature that, in turns, modifies the temperature dependence of the characteristic spin-fluctuation energy.

cond-mat.supr-con↗

arXiv2013

Normal and superconducting properties of LiFeAs explained in the framework of four-band Eliashberg Theory

In this paper we propose a model to reproduce superconductive and normal properties of the iron pnictide LiFeAs in the framework of the four-band spm wave Eliashberg theory. A confirmation of the multiband nature of the system rises from the experimental measurements of the superconductive gaps and resistivity as function of temperature. We found that the most plausible mechanism is the antiferromagnetic spin fluctuation and the estimated values of the total antiferromagnetic spin fluctuation coupling constant in the superconductive and normal state are lambda{tot}=2.00 and lambda{tot,tr}=0.77.

cond-mat.supr-con↗

arXiv2011

Directional point-contact Andreev-reflection spectroscopy of Fe-based superconductors: Fermi surface topology, gap symmetry, and electron-boson interaction

Point-contact Andreev reflection spectroscopy (PCAR) has proven to be one of the most powerful tools in the investigation of superconductors, where it provides information on the order parameter (OP), a fundamental property of the superconducting state. In the past 20 years, successive improvements of the models used to analyze the spectra have continuously extended its capabilities, making it suited to study new superconductors with "exotic" properties such as anisotropic, nodal and multiple OPs. In Fe-based superconductors, the complex compound- and doping-dependent Fermi surface and the predicted sensitivity of the OP to fine structural details present unprecedent challenges for this technique. Nevertheless, we show here that PCAR measurements in Fe-based superconductors carried out so far have already greatly contributed to our understanding of these materials, despite some apparent inconsistencies that can be overcome if a homogeneous treatment of the data is used. We also demonstrate that, if properly extended theoretical models for Andreev reflection are used, directional PCAR spectroscopy can provide detailed information not only on the amplitude and symmetry of the OPs, but also on the nature of the pairing boson, and even give some hints about the shape of the Fermi surface.

cond-mat.supr-con↗

arXiv2011

Large conductance modulation of gold thin films by huge charge injection via electrochemical gating

By using an electrochemical gating technique with a new combination of polymer and electrolyte, we were able to inject surface charge densities n_2D as high as 3.5 \times 10^15 e/cm^2 in gold films and to observe large relative variations in the film resistance, DeltaR/R', up to 10% at low temperature. DeltaR/R' is a linear function of n_2D - as expected within a free-electron model - if the film is thick enough (> 25 nm), otherwise a tendency to saturation due to size effects is observed. The application of this technique to 2D materials will allow extending the field-effect experiments to a range of charge doping where giant conductance modulations and, in some cases, even the occurrence of superconductivity are expected.

cond-mat.mes-hall↗

arXiv2011

Interplay of composition, structure, magnetism, and superconductivity in SmFeAs1-xPxO1-y

Polycrystalline samples and single crystals of SmFeAs1-xPxO1-y were synthesized and grown employing different synthesis methods and annealing conditions. Depending on the phosphorus and oxygen content, the samples are either magnetic or superconducting. In the fully oxygenated compounds the main impact of phosphorus substitution is to suppress the Néel temperature TN of the spin density wave (SDW) state, and to strongly reduce the local magnetic field in the SDW state, as deduced from muon spin rotation measurements. On the other hand the superconducting state is observed in the oxygen deficient samples only after heat treatment under high pressure. Oxygen deficiency as a result of synthesis at high pressure brings the Sm-O layer closer to the superconducting As/P-Fe-As/P block and provides additional electron transfer. Interestingly, the structural modifications in response to this variation of the electron count are significantly different when phosphorus is partly substituting arsenic. Point contact spectra are well described with two superconducting gaps. Magnetic and resistance measurements on single crystals indicate an in-plane magnetic penetration depth of 200 nm and an anisotropy of the upper critical field slope of 4-5. PACS number(s): 74.70.Xa, 74.62.Bf, 74.25.-q, 81.20.-n

cond-mat.supr-con↗

arXiv2010

Multigap superconductivity and strong electron-boson coupling in Fe-based superconductors: A point-contact Andreev-reflection study of Ba(Fe1-xCox)2As2 single crystals

Directional point-contact Andreev-reflection (PCAR) measurements in Ba(Fe1-xCox)2As2 single crystals (Tc=24.5 K) indicate the presence of two superconducting gaps with no line nodes on the Fermi surface. The PCAR spectra also feature additional structures related to the electron-boson interaction, from which the characteristic boson energy Omega_b(T) is obtained, very similar to the spin-resonance energy observed in neutron scattering experiments. Both the gaps and the additional structures can be reproduced within a three-band s+- Eliashberg model by using an electron-boson spectral function peaked at Omega_0 = 12 meV ~ Omega_b(0).

cond-mat.supr-con↗

arXiv2009

Probing multiband superconductivity by point-contact spectroscopy

Point-contact spectroscopy was originally developed for the determination of the electron-phonon spectral function in normal metals. However, in the past 20 years it has become an important tool in the investigation of superconductors. As a matter of fact, point contacts between a normal metal and a superconductor can provide information on the amplitude and symmetry of the energy gap that, in the superconducting state, opens up at the Fermi level. In this paper we review the experimental and theoretical aspects of point-contact spectroscopy in superconductors, and we give an experimental survey of the most recent applications of this technique to anisotropic and multiband superconductors.

cond-mat.supr-con↗

arXiv2009

Coexistence of two order parameters and a pseudogaplike feature in the iron-based superconductor LaFeAsO_(1-x)F_x

The nature and value of the order parameters (OPs) in the superconducting Fe-based oxypnictides REFeAsO_(1-x)F_x (RE = rare earth) are a matter of intense debate, also connected to the pairing mechanism which is probably unconventional. Point-contact Andreev-reflection experiments on LaFeAsO_(1-x)F_x gave us direct evidence of three energy scales in the superconducting state: a nodeless superconducting OP, Delta1 = 2.8-4.6 meV, which scales with the local Tc of the contact; a larger unconventional OP that gives conductance peaks at 9.8-12 meV, apparently closes below Tc and decreases on increasing the Tc of the contact; a pseudogaplike feature (i.e. a depression in the conductance around zero bias), that survives in the normal state up to T* ~ 140 K (close to the Neel temperature of the undoped compound), which we associate to antiferromagnetic spin fluctuations (AF SF) coexisting with superconductivity. These findings point toward a complex, unconventional nature of superconductivity in LaFeAsO_(1-x)F_x.

cond-mat.supr-con↗

arXiv2009

Three-band s+- Eliashberg theory and the superconducting gaps of iron pnictides

The experimental critical temperatures and gap values of the superconducting pnictides of both the 1111 and 122 families can be simultaneously reproduced within the Eliashberg theory by using a three-band model where the dominant role is played by interband interactions and the order parameter undergoes a sigh reversal between hole and electron bands (s+- wave symmetry). High values of the electron-boson coupling constants and small typical boson energies (in agreement with experiments) are necessary to obtain the values of all the gaps and to correctly reproduce their temperature dependence.

cond-mat.supr-con↗

arXiv2009

Point-contact Andreev-reflection spectroscopy in ReFeAsO_{1-x}F_x (Re = La, Sm): Possible evidence for two nodeless gaps

A deep understanding of the character of superconductivity in the recently discovered Fe-based oxypnictides ReFeAsO1-xFx (Re = rare-earth) necessarily requires the determination of the number of the gaps and their symmetry in k space, which are fundamental ingredients of any model for the pairing mechanism in these new superconductors. In the present paper, we show that point-contact Andreev-reflection experiments performed on LaFeAsO1-xFx (La-1111) polycrystals with Tc ~ 27 K and SmFeAsO0.8F0.2 (Sm-1111) ones with Tc ~ 53 K gave differential conductance curves exhibiting two peaks at low bias and two additional structures (peaks or shoulders) at higher bias, an experimental situation quite similar to that observed by the same technique in pure and doped MgB2. The single-band Blonder-Tinkham-Klapwijk model is totally unable to properly fit the conductance curves, while the two-gap one accounts remarkably well for the shape of the whole experimental dI/dV vs. V curves. These results give direct evidence of two nodeless gaps in the superconducting state of ReFeAsO1-xFx (Re = La, Sm): a small gap, Delta1, smaller than the BCS value (2Delta1/kBTc ~ 2.2 - 3.2) and a much larger gap Delta2 which gives a ratio 2Delta2/kBTc ~ 6.5 - 9. In Sm-1111 both gaps close at the same temperature, very similar to the bulk Tc, and follow a BCS-like behaviour, while in La-1111 the situation is more complex, the temperature dependence of the gaps showing remarkable deviations from the BCS behaviour at T close to Tc. The normal-state conductance reproducibly shows an unusual, but different, shape in La-1111 and Sm-1111 with a depression or a hump at zero bias, respectively. These structures survive up to T* ~ 140 K, close to the temperatures at which structural and magnetic transitions occur in the parent, undoped compound.

cond-mat.supr-con↗

arXiv2008

Evidence for two-gap nodeless superconductivity in SmFeAsO$_{0.8}$F$_{0.2}$ from point-contact Andreev-reflection spectroscopy

Point-contact Andreev-reflection measurements were performed in SmFeAsO_{0.8}F_{0.2} polycrystals with T_c \simeq 53 K. The experimental conductance curves reproducibly exhibit peaks around \pm 6 mV and shoulders at V \sim 16-20 mV, indicating the presence of two nodeless superconducting gaps. While the single-band Blonder-Tinkham-Klapwijk fit can only reproduce a small central portion of the conductance curve, the two-gap one accounts remarkably well for the shape of the whole experimental dI/dV. The fits of the normalized curves give Delta_1(0) = 6.15 \pm 0.45 meV and Delta_2(0) = 18 \pm 3 meV. Both gaps close at the same temperature and follow a BCS-like behavior.

cond-mat.supr-con↗

arXiv2008

Evidence for gap anisotropy in CaC6 from directional point-contact spectroscopy

We present the first results of directional point-contact spectroscopy in high quality CaC6 samples both along the ab plane and in the c-axis direction. The superconducting order parameter Δ(0), obtained by fitting the Andreev-reflection (AR) conductance curves at temperatures down to 400 mK with the single-band 3D Blonder-Tinkham-Klapwijk model, presents two different distributions in the two directions of the main current injection, peaked at 1.35 and 1.71 meV, respectively. By ab-initio calculations of the AR conductance spectra, we show that the experimental results are in good agreement with the recent predictions of gap anisotropy in CaC6.

cond-mat.supr-con↗

arXiv2008

Point-contact Andreev-reflection spectroscopy in segregation-free Mg_{1-x}Al_{x}B_2 single crystals up to x=0.32

We present new results of point-contact Andreev-reflection (PCAR) spectroscopy in single-phase Mg_{1-x}Al_{x}B_{2} single crystals with x up to 0.32. Fitting the conductance curves of our point contacts with the two-band Blonder-Tinkham-Klapwijk model allowed us to extract the gap amplitudes Delta_{sigma} and Delta_{pi}. The gap values agree rather well with other PCAR results in Al-doped crystals and polycrystals up to x=0.2 reported in literature, and extend them to higher Al contents. In the low-doping regime, however, we observed an increase in the small gap Delta_{pi} on increasing x (or decreasing the local critical temperature of the junctions, T_{c}^{A}) which is not as clearly found in other samples. On further decreasing T_{c}^{A} below 30 K, both the gaps decrease and, up to the highest doping level x=0.32 and down to T_{c}^{A}= 12 K, no gap merging is observed. A detailed analysis of the data within the two-band Eliashberg theory shows that this gap trend can be explained as being mainly due to the band filling and to an increase in the interband scattering which is necessary to account for the increase in Delta_{pi} at low Al contents (x < 0.1). We suggest to interpret the following decrease of Delta_{pi} for T_{c}^{A} < 30 K as being governed by the onset of inhomogeneity and disorder in the Al distribution that partly mask the intrinsic effects of doping and is not taken into account in standard theoretical approaches.

cond-mat.supr-con↗

arXiv2006

Point-contact spectroscopy in neutron-irradiated Mg^{11}B_2

We report on recent results of point-contact spectroscopy measurements in Mg^{11}B_2 polycrystals irradiated at different neutron fluences up to 1.4 x 10^{20} cm^{-2}. The point contacts were made by putting a small drop of Ag paint -- acting as the counterelectrode -- on the cleaved surface of the samples. The gap amplitudes were extracted from the experimental conductance curves, showing Andreev-reflection features, through a two-band Blonder-Tinkham-Klapwijk fit and reported as a function of the Andreev critical temperature of the junctions, TcA. The resulting Delta_sigma(TcA) and Delta_pi(TcA) curves show a clear merging of the gaps when TcA ~ 9K that perfectly confirms the findings of specific-heat measurements in the same samples. Anomalous contacts with TcA > Tc (being Tc the bulk critical temperature) were often obtained, particularly in samples irradiated at very high fluences. Their fit gave a different dependence of Delta_pi on TcA. The possible origin of these contacts is discussed in terms of local current-induced annealing and/or nanoscale inhomogeneities observed by STM in the most irradiated samples.

cond-mat.supr-con↗

arXiv2006

The effect of magnetic impurities in a two-band superconductor: A point-contact study of Mn-substituted MgB2 single crystals

We present the first results of directional point-contact measurements in Mg_{1-x}Mn_{x}B_2 single crystals, with x up to 0.015 and bulk T_c down to 13.3 K. The order parameters Delta_{sigma} and Delta_{pi} were obtained by fitting the conductance curves with the two-band Blonder-Tinkham-Klapwijk (BTK) model. Both Delta_{pi} and Delta_{sigma} decrease with the critical temperature of the junctions T_c^A, but remain clearly distinct up to the highest Mn content. Once analyzed within the Eliashberg theory, the results indicate that spin-flip scattering is dominant in the sigma band, as also confirmed by first-principle band structure calculations.

cond-mat.supr-con↗

arXiv2004

A Study of Carbon Substitutions in MgB_2 within the two-band Eliashberg theory

We study the effects of C substitutions in MgB_2 within the two-band model in the Eliashberg formulation. We use as input the B-B stretching-mode frequency and the partial densities of states N_{sigma}(EF) and N_{pi}(EF), recently calculated for Mg(B_{1-x}C_{x})_2 at various x values from first-principles density functional methods. We then take the prefactor in the Coulomb pseudopotential matrix, mu, and the interband scattering parameter, Gamma^{sigma pi}, as the only adjustable parameters. The dependence on the C content of Tc and of the gaps (Delta_{sigma} and Delta_{pi}) recently measured in Mg(B_{1-x}C_{x})_2 single crystals indicate an almost linear decrease of mu on increasing x, with an increase in interband scattering that makes the gaps merge at x=0.132. In polycrystals, instead, where the gap merging is not observed, no interband scattering is required to fit the experimental data.

cond-mat.supr-con↗

arXiv2004

Two-band Eliashberg equations and the experimental Tc of the diboride Mg1-xAlxB2

The variation of the superconducting critical temperature Tc as a function of x in the diboride Mg1-xAlxB2 has been studied in the framework of the two-bands Eliashberg theory and traditional phonon coupling mechanism. We have solved the two-bands Eliashberg equations using first-principle calculations or simple assumptions for the variation of the relevant physical quantities. We have found that the experimental Tc curve can be explained only if the Coulomb pseudopotential changes with x by tuning the Fermi level toward the sigma band edge. In polycrystal samples the x dependence of the sigma and pi-band gap has been found and is in agreement with experiments.

cond-mat.supr-con↗

arXiv2004

Evidence for Single-gap Superconductivity in Mg(B_{1-x}C_x)_2 Single Crystals with x=0.132 from Point-Contact Spectroscopy

We report the results of the first directional point-contact measurements in Mg(B_{1-x}C_{x})_2 single crystals with 0.047 <= x <= 0.132. The two-gap superconductivity typical of MgB_2 persists up to x=0.105. In this region, the values of the gaps Delta_{sigma} and Delta_{pi} were determined by fitting the Andreev-reflection conductance curves with a two-band Blonder-Tinkham-Klapwijk (BTK) model, and confirmed by the single-band BTK fit of the sigma- and pi-band conductances, separated by means of a magnetic field. At x=0.132, when T_{c}=19 K, we clearly observed for the first time the merging of the two gaps into one of amplitude Delta~3 meV.

cond-mat.supr-con↗