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R. Sahai

Publications and source records attributed to R. Sahai.

At least 19 recordsLinked to original sources

CO rotational line emission in very red carbon stars in the Magellanic Clouds

Stars of low and intermediate initial mass lose most of their stellar mass at the end of their lives during the asymptotic giant branch (AGB) phase. Determining their gas and dust mass-loss rates (MLRs) is crucial for quantifying the contribution of evolved stars to the life cycle of dust and gas in the Universe. The Atacama Large Millimeter/submillimeter Array was used to observe 38 carbon stars (C stars) in the large Magellanic cloud (LMC) and three C stars in the small Magellanic cloud (SMC) in the CO J= 2-1 line. Line profiles were fitted to derive stellar velocities and wind-expansion velocities (Vexp). CO emission is detected in two C stars in the SMC and 33 C stars in the LMC. This is the first detection of carbon monoxide around an AGB star in the SMC. One object in the LMC shows emission in $^{13}$CO. The wind-expansion velocity ranges from \sim7.5 to \sim30 km/s. Archival data were used to determine the pulsation periods as well as construct and model the spectral energy distributions using two dust radiative transfer codes. Mass-loss rates were independently derived from these two codes as well as from the intensity of the CO line, using a simple formula. On average, the dust-based MLRs higher than the MLRs based on the CO line by a factor of 1.6. Additional CO data in other transitions, combined with proper modelling, is required to further investigate this possible discrepancy. Mass-loss rates, pulsation periods, and expansion velocities were compared to a sample of Galactic C stars. There is a strong bias, as the Magellanic Cloud targets sample the highest MLRs and luminosities, yet they represent only a minority of stars in a Galactic sample. Comparing this sample with a similarly extreme set of Galactic stars with periods longer than 500 days, we identify no correlation between metallicity and either the MLR or Vexp.

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Dust in the very metal-poor galaxy Sextans A with JWST. I: Characterizing the evolved stellar population of Sextans A based on JWST observations and stellar evolution models

The nearby star-forming dwarf galaxy Sextans A offers a unique window into galaxy evolution in the early Universe, owing to its extremely low metallicity (about 1-7% Zsun). Recent JWST imaging of Sextans A spanning 1-21 micron enables a detailed characterization of its dusty stellar populations and interstellar medium. In this work, we compare the observed JWST color-magnitude distributions of evolved stars with stellar evolution and dust-formation models to characterize the properties of the asymptotic giant branch (AGB) population, including progenitor mass, formation epoch, metallicity, and dust production. Evolutionary tracks for 0.8-7 Msun stars with metallicity Z=10^-3 provide good agreement with the overall distribution of AGB stars in Sextans A. More than 90% of the AGB population occupies a nearly vertical sequence in the color-magnitude diagrams, corresponding to stars spanning a wide range of masses and ages but exhibiting little or no circumstellar dust. This sequence appears to be dominated by oxygen-rich (M-type) AGB stars and reveals that the F444W flux is a robust luminosity diagnostic. A small subset of sources displays strong infrared excesses and is dominated by carbon stars descending from 1.25-1.5 Msun progenitors that formed about 2-3 Gyr ago and are currently in the final AGB phases. Their MIRI colors imply very low metallicities, consistent with estimates from the red giant branch morphology (about 1-2% Zsun). Finally, we show that the JWST/NIRCam F277W-F444W color serves as an effective proxy for the dust production rate, with models predicting rates up to 10^-7 Msun/yr for the reddest sources in Sextans A.

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ATOMIUM: Inner circumstellar envelopes of oxygen-rich AGB stars as revealed by highly excited SiO lines

Silicon monoxide (SiO) traces the physical conditions and dynamics in the circumstellar envelopes (CSEs) of AGB stars. We present high-resolution ALMA Band 6 observations of highly excited SiO emission in 14 oxygen-rich AGB stars. We cover transitions from v = 0 to v = 8, including first detections of 28SiO v = 3, 4, 8, J = 6-5, 29SiO v = 6, J = 6-5, and 30SiO v = 4, 5, J = 6-5, some of which are masers. The v = 8 transition is the highest v-state observed in an AGB star yet. Masers in v = 0 are detected clearly in V PsA and IRC+10011 and tentatively in T Mic. R Hya exhibits the richest SiO spectrum. SiO J = 6-5 absorption is seen in R Aql, R Hya, S Pav, and T Mic, with features indicative of both infalls and outflows, and tentative detection of 28SiO v = 8, J = 6-5 absorption is found towards S Pav and R Aql. Highly excited SiO emission is often distributed in arcs or clumps with velocity gradients; components in R Hya and U Her align with predicted shock fronts. Detection rates show no significant difference between low and high mass-loss rate stars, although line overlap may affect some intensities. Maser detections appear uncorrelated with pulsation period or phase. The radius enclosing 90 per cent of compact SiO emission shows a tentative correlation with mass-loss rate. These results highlight the role of mass loss and CSE geometry in shaping high-excitation SiO emission.

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Mid-infrared JWST spectra of carbon stars in the Large Magellanic Cloud

Mid-infrared spectra from the Medium Resolution Spectrometer on the James Webb Space Telescope have revealed the molecular chemistry of carbon stars in the Large Magellanic Cloud with better resolution and sensitivity than previously possible. Our sample spans a range of dust-production rates and includes three relatively dust-free semiregular variables and six dustier Mira variables. All were observed 15-20 yr earlier with the Infrared Spectrograph on the Spitzer Space Telescope at lower spectral resolution. The new spectra show that the C3 molecule is responsible for a strong absorption band centered at 5.2 um. CS is clearly present in some of the sample, especially the stars with less dust. HCN also appears to be present. Some of the spectra have changed significantly between the Spitzer epoch and the MRS observations in 2023 and 2024, and in most cases these changes can be attributed to the stellar pulsation cycle. One exception is the disappearance of a dust emission feature at ~18 um in one of the Miras. The new spectra reveal a dip centered at ~10 um, which could arise either from an unknown carrier or from variable molecular emission to the red and blue. The presence of this spectral structure on the short-wavelength side of the SiC dust emission feature at ~11.3 um along with the broad C2H2 band centered at 14 um raise the possibility that some previously reported detections of weak SiC dust emission in other carbon stars may not be real.

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Discovery of SiC and Iron Dust Around AGB Stars in the very Metal-Poor Sextans A Dwarf Galaxy with JWST: Implications for Dust Production at High Redshift

Low-resolution infrared spectroscopy from JWST confirms the presence of SiC and likely metallic iron dust around asymptotic giant branch (AGB) stars in the Sextans A dwarf galaxy, which has a metallicity ~1%-7% Z_sun. While metal-poor carbon-rich AGB stars are known to produce copious amounts of amorphous carbon dust owing to the dredge up of newly synthesized carbon, this is the first time that Si- and Fe-bearing dust has been detected at this extreme metallicity. Of the six AGB stars observed, one is an intermediate-mass (~1.2-4 M_sun) carbon star showing SiC dust, and another is an oxygen-rich M-type star with mass ~4-5 M_sun that is likely undergoing hot bottom burning. The infrared excess of the M-type star is strong, but featureless. We tested multiple dust species, and find that it is best fit with metallic iron dust. Assuming its dust-production rate stays constant over the final 2-3x10^4 yr of its evolution, this star will produce ~0.9-3.7 times the iron dust mass predicted by models, with the range depending on the adopted stellar mass. The implications for dust production in high-redshift galaxies are potentially significant, especially regarding the assumed dust species used in dust evolution models and the timescale of AGB dust formation. Stars on the upper end of the AGB mass range can begin producing dust as early as 30-50 Myr after they form, and they may therefore rival dust production by supernovae at high redshift.

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Exploring circumstellar chemistry in X-ray emitting AGB stars

Aims. Our goal is to characterize the chemistry and physical conditions of the circumstellar envelopes (CSEs) of Asymptotic Giant Branch (AGB) binary candidate stars with UV-excess and X-ray emission, in particular, to identify the effects of the internal X-ray emission in the abundance of certain key molecules. Methods. We observed the 86.0-94.0 and 260.0-272.5 GHz spectral ranges searching for rotational transitions of the X-ray sensitive molecule $HCO^{+}$ in four AGB stars, two of them detected in both UV and X-ray emission and the other two detected only in UV. We derived the CSEs's physical parameters from previous CO observations and determined the molecular abundances of the detected species using radiative transfer models. We developed chemical kinetics models that account for the effects of internal X-ray emission (as well as UV radiation) and compared our predictions with observations. Results. We report the detection of $HCO^{+}$ in the X-ray emitting C-rich AGB T\,Dra, while it remains undetected in the spectra of the other three sources. In T\,Dra we also detect SiO, HCN, HNC, $HC_{3}N$, $SiC_{2}$, $C_{2}H$ and SiS. For the other targets only HCN and SiO are detected. The high fractional abundance of $HCO^{+}$ derived for T\,Dra ($[1.5-3.0]\times 10^{-8}$) is in good agreement with the predictions from our chemical kinetics models including the effects of internal X-ray emission, and one order of magnitude higher than the values expected for C-rich AGB stars. Additionally, we identify abundance enhancements for HNC, and $HC_{3}N$ alongside a depletion of CO in the innermost regions of T\,Dra's envelope. Conclusions. An internal X-ray source can significantly alter molecular abundances in AGB CSEs, enhancing $HCO^{+}$, $N_{2}H^{+}$, HNC, and $HC_{3}N$ while depleting parent species like CO. UV radiation has a weaker effect unless the envelope is optically thin or porous.

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An accreting dwarf star orbiting the S-type giant star pi1 Gru

Aims. We aim to characterize the properties of the inner companion of the S-type AGB star pi1 Gru and to identify plausible future evolutionary scenarios for this triple system. Methods. We observed pi1 Gru with ALMA and VLT/SPHERE. In addition, we collected archival photometry data and used the Hipparcos-Gaia proper motion anomaly. We derive the best orbital parameters from Bayesian inference. Results. In June-July 2019, the inner companion, pi1 Gru C, was located at 37.4 +/- 2.0 mas from the primary (a projected separation of 6.05 +/- 0.55 au at 161.7 +/- 11.7 pc). The best orbital solution yields a companion mass of 0.86 (+0.22/-0.20) Msun (using the derived mass of the primary) and a semi-major axis of 7.05(+0.54/-0.57) au, corresponding to an orbital period of 11.0 (+1.7/-1.5) yr. The preferred solution is an elliptical orbit with eccentricity e = 0.35(+0.18/-0.17), although a circular orbit cannot be fully excluded. The close companion could be either a K1V (F9.5V to K7V) star or a white dwarf (WD). Ultraviolet and millimeter continuum photometry are consistent with the presence of an accretion disk around the close companion. The ultraviolet emission may originate from hot spots in an overall cooler disk, or from a hot disk if the companion is a WD. Conclusions. Although the close companion and the AGB star are interacting and an accretion disk is observed around the companion, the mass-accretion rate is too low to trigger a Type Ia supernova, but it could produce novae every ~900 yr. Short-wavelength, spatially resolved observations are required to further constrain the nature of the C companion. Searches for close-in companions similar to this system will improve our understanding of the physics of mass and angular momentum transfer, as well as orbital evolution during late evolutionary stages.

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ATOMIUM: Continuum emission and evidence of dust enhancement from binary motion

Low- and intermediate-mass stars on the asymptotic giant branch (AGB) account for a significant portion of the dust and chemical enrichment in their host galaxy. Here we present ALMA observations of the continuum emission at 1.24 mm around a sample of 17 stars from the ATOMIUM survey. From our analysis of the stellar contributions to the continuum flux, we find that the semi-regular variables all have smaller physical radii and fainter monochromatic luminosities than the Mira variables. Comparing these properties with pulsation periods, we find a positive trend between stellar radius and period only for the Mira variables with periods above 300 days and a positive trend between the period and the monochromatic luminosity only for the red supergiants and the most extreme AGB stars with periods above 500 days. We find that the continuum emission at 1.2 mm can be classified into four groups. "Featureless" continuum emission is confined to the (unresolved) regions close to the star for five stars in our sample, relatively uniform extended flux is seen for four stars, tentative elongated features are seen for three stars, and the remaining five stars have unique or unusual morphological features in their continuum maps. These features can be explained by binary companions to 10 out of the 14 AGB stars in our sample. Based on our results we conclude that there are two modes of dust formation: well established pulsation-enhanced dust formation and our newly proposed companion-enhanced dust formation. If the companion is located close to the AGB star, in the wind acceleration region, then additional dust formed in the wake of the companion can increase the mass lost through the dust driven wind. This explains the different dust morphologies seen around our stars and partly accounts for a large scatter in literature mass-loss rates, especially among semiregular stars with small pulsation periods.

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ALMA observations of CO isotopologues towards six obscured post-AGB stars

Low- and intermediate-mass stars evolve through the asymptotic giant branch (AGB), when an efficient mass-loss process removes a significant fraction of their initial mass. A substantial increase in the mass-loss rate at the end of the AGB is observed for at least some stars for unknown reasons. This creates post-AGB objects that are completely enshrouded in thick dusty envelopes and might be associated with binary interactions. We observed the $J=2-1$ line of $^{13}$CO, C$^{17}$O, and C$^{18}$O with the Atacama Large Millimeter / submillimeter Array (ALMA) towards six obscured post-AGB stars (four C-rich and two O-rich sources) to constrain the properties of their circumstellar envelopes, recent mass-loss histories, and initial mass of the central stars. Based on the inferred $^{17}$O/$^{18}$O isotopic ratios, we find all stars to have relatively low initial masses ($< 2~M_\odot$) contrary to suggestions in the literature of higher masses for some sources. We infer a mass for HD~187885 $\sim 1.15~M_\odot$, which is relatively low for a carbon star. For all but one source (GLMP~950), we observe kinematic components with velocities $\gtrsim 30$~km~s$^{-1}$, which are faster than typical AGB wind expansion velocities. For most sources, these higher-velocity outflows display point-symmetric morphologies. The case of Hen~3-1475 is particularly spectacular, with the high-velocity molecular outflow interleaved with the high-velocity outflow of ionised gas observed at optical wavelengths. Based on the size of the emission regions of the slow components of the outflows, we derive typical kinematic ages associated with the C$^{18}$O~$J=2-1$ emission $\lesssim 1500$~years and obtain relatively high associated mass-loss rates ($\gtrsim10^{-4}~M_\odot~{\rm yr}^{-1}$). The sources with known spectral types are found to have evolved faster than expected based on stellar evolutionary models.

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Temporal Changes in the Infrared Spectra of Magellanic Carbon Stars

The Medium-Resolution Spectrometer on the Mid-Infrared Instrument on JWST obtained spectra of three carbon stars in the Large Magellanic Cloud. Two of the spectra differ significantly from spectra obtained ~16-19 years earlier with the Infrared Spectrograph on the Spitzer Space Telescope. The one semi-regular variable among the three has changed little. The long-period Mira variable in the sample shows changes consistent with its pulsation cycle. The short-period Mira shows dramatic changes in the strength of its molecular absorption bands, with some bands growing weaker and some stronger. Whether these variations result from its pulsation cycle or its evolution is not clear.

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ALMA detection of Masers and Dasars in the Hydrogen Recombination Lines of the Planetary Nebula Mz3

The hydrogen recombination lines H30$\alpha$, H40$\alpha$, H42$\alpha$, H50$\beta$ and H57$\gamma$ and the underlying bremsstrahlung continuum emission were detected with ALMA in the bipolar nebula Mz3. The source was not spatially resolved, but the velocity profile of the H30$\alpha$ line shows clear indication of maser amplification, confirming previous reports of laser amplification in the far infrared H recombination lines observed with Herschel Space Observatory. Comparison between the flux densities of the H50$\beta$, H40$\alpha$ and H42$\alpha$ lines show overcooling, or darkness amplification by stimulated absorption (dasar effect) at the LSR velocity of about $-25$ km s$^{-1}$, which constrains the density of the absorbing region to about 10$^3$ cm$^{-3}$. The H30$\alpha$ line, on the other hand, presents maser lines at LSR velocities of $-69$ and $-98$ km s$^{-1}$, which indicates ionized gas with densities close to 10$^7$ cm$^{-3}$. Although the source of emission was not resolved, it was possible to find the central position of the images for each velocity interval, which resulted in a well defined position-velocity distribution.

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Chemical tracers of a highly eccentric AGB-main sequence star binary

Binary interactions have been proposed to explain a variety of circumstellar structures seen around evolved stars, including asymptotic giant branch (AGB) stars and planetary nebulae. Studies resolving the circumstellar envelopes of AGB stars have revealed spirals, discs and bipolar outflows, with shaping attributed to interactions with a companion. For the first time, we have used a combined chemical and dynamical analysis to reveal a highly eccentric and long-period orbit for W Aquilae, a binary system containing an AGB star and a main sequence companion. Our results are based on anisotropic SiN emission, the first detections of NS and SiC towards an S-type star, and density structures observed in the CO emission. These features are all interpreted as having formed during periastron interactions. Our astrochemistry-based method can yield stringent constraints on the orbital parameters of long-period binaries containing AGB stars, and will be applicable to other systems.

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ATOMIUM: Molecular inventory of 17 oxygen-rich evolved stars observed with ALMA

The dusty winds of cool evolved stars are a major contributor of the newly synthesised material enriching the Galaxy and future generations of stars. However, the details of the physics and chemistry behind dust formation and wind launching have yet to be pinpointed. Recent spatially resolved observations show the importance of gaining a more comprehensive view of the circumstellar chemistry, but a comparative study of the intricate interplay between chemistry and physics is still difficult because observational details such as frequencies and angular resolutions are rarely comparable. Aiming to overcome these deficiencies, ATOMIUM is an ALMA Large Programme to study the physics and chemistry of the circumstellar envelopes of a diverse set of oxygen-rich evolved stars under homogeneous observing conditions at three angular resolutions between ~0.02"-1.4". Here we summarize the molecular inventory of these sources, and the correlations between stellar parameters and molecular content. Seventeen oxygen-rich or S-type asymptotic giant branch (AGB) and red supergiant (RSG) stars have been observed in several tunings with ALMA Band 6, targeting a range of molecules to probe the circumstellar envelope and especially the chemistry of dust formation close to the star. We systematically assigned the molecular carriers of the spectral lines and measured their spectroscopic parameters and the angular extent of the emission of each line from integrated intensity maps. Across the ATOMIUM sample, we detect 291 transitions of 24 different molecules and their isotopologues. This includes several first detections in oxygen-rich AGB/RSG stars: PO v=1, SO2 v1=1 and v2=2, and several high energy H2O transitions. We also find several first detections in S-type AGB stars: vibrationally excited HCN v2=2,3 and SiS v=4,5,6, as well as first detections of the molecules SiC, AlCl, and AlF in W Aql...

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Long-period maser-bearing Miras in the Galactic center: period-luminosity relations and extinction estimates

We establish a sample of 370 Mira variables that are likely near the Galactic center (GC). The sources have been selected from the OGLE and BAaDE surveys based on their sky coordinates, OGLE classifications, and BAaDE maser-derived line-of-sight velocities. As the distance to the GC is known to a high accuracy, this sample is a test bed for reddening and extinction studies toward the GC and in Mira envelopes. We calculated separate interstellar- and circumstellar-extinction values for individual sources, showing that there is a wide range of circumstellar extinction values (up to four magnitudes in the K$_s$ band) in the sample, and that circumstellar reddening is statistically different from interstellar reddening laws. Further, the reddening laws in the circumstellar environments of our sample and the circumstellar environments of Large Magellanic Cloud (LMC) Miras are strikingly similar despite the different metallicities of the samples. Period-magnitude relations for the mid-infrared (MIR) WISE and MSX bands are also explored, and in the WISE bands we compare these to period-magnitude relationships derived from Miras in the LMC as it is important to compare these LMC relations to those in a higher metallicity environment. Emission from the envelope itself may contaminate MIR magnitudes altering the relations, especially for sources with thick envelopes.

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The VLT/SPHERE view of the ATOMIUM cool evolved star sample. I. Overview: Sample characterization through polarization analysis

Aims. Through the ATOMIUM project, based on an ALMA large program, we aim to present a consistent view of a sample of 17 nearby cool evolved stars (Aymptotic Giant Branch and red supergiant stars). Methods. Here we present VLT/SPHERE-ZIMPOL polarimetric maps obtained in the visible of 14 out of the 17 ATOMIUM sources. They were obtained contemporaneously with the ALMA high spatial resolution data. To help interpret the polarized signal, we produced synthetic maps of light scattering by dust, through 3D radiative transfer simulations with the RADMC3D code. Results. The degree of linear polarization (DoLP) observed by ZIMPOL spreads across several optical filters. We infer that it primarily probes dust located just outside of the point spread function, and in or near the plane of the sky, with a total optical depth close to unity in the line of sight, representing only a fraction of the total circumstellar dust. The maximum DoLP ranges from 0.03-0.38 depending on the source, fractions that can be reproduced by our 3D pilot models for grains composed of common dust species. The spatial structure of the DoLP shows a diverse set of shapes. Only for three sources do we note a correlation between the ALMA CO and SiO lines, which trace the gas density, and the DoLP, which traces the dust. Conclusion. The clumpiness of the DoLP and the lack of a consistent correlation between the gas and the dust location show that, in the inner circumstellar environment (CSE), dust formation occurs at very specific sites. This has potential consequences for the derived mass-loss rates and dust-to-gas ratio in the inner region of the CSE. Except for $\pi^1$~Gru and perhaps GY Aql, we do not detect interactions between the circumstellar wind and the hypothesized companions that shape the wind at larger scales. This suggests that the orbits of any other companions are tilted out of the plane of the sky.

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The Rapidly Evolving AGB Star, V Hya: ALMA finds a Multi-Ring Circus with High-Velocity Outflows

We have observed the mass-losing carbon star V Hya that is apparently transitioning from an AGB star to a bipolar planetary nebula, at an unprecedented angular resolution of ~0".4-0".6 with the Atacama Large Millimeter/submillimeter Wave Array (ALMA). Our 13CO and 12CO (J=3-2 and J=2-1) images have led to the discovery of a remarkable set of six expanding rings within a flared, warped Disk structure Undergoing Dynamical Expansion (DUDE) that lies in the system's equatorial plane. We also find, for the first time, several bipolar, high-velocity outflows, some of which have parabolic morphologies, implying wide opening angles, while one (found previously) is clumpy and highly collimated. The latter is likely associated with the high-velocity bullet-like ejections of ionized gas from V Hya; a possible molecular counterpart to the oldest of the 4 bullets can be seen in the 12CO images. We find a bright, unresolved central source of continuum emission (FWHM size <~165 au); about 40% of this emission can be produced in a standard radio photosphere, while the remaining 60% is likely due to thermal emission from very large (mm-sized) grains, having mass >~10^{-5} Msun. We have used a radiative transfer model to fit the salient characteristics of the DUDE's 13CO and 12CO emission out to a radius of 8" (3200 au) with a flared disk of mass 1.7 x 10^{-3} Msun, whose expansion velocity increases increases very rapidly with radius inside a central region of size ~200 au, and then more slowly outside it, from 9.5 to 11.5 km/s. The DUDE's underlying density decreases radially, interspersed with local increases that represent the observationally well-characterised innermost three rings.

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ATOMIUM: ALMA tracing the origins of molecules in dust forming oxygen rich M-type stars: Motivation, sample, calibration, and initial results

This overview paper presents ATOMIUM, a Large Programme in Cycle 6 with the Atacama Large Millimeter-submillimeter Array (ALMA). The goal of ATOMIUM is to understand the dynamics and the gas phase and dust formation chemistry in the winds of evolved asymptotic giant branch (AGB) and red supergiant (RSG) stars. A more general aim is to identify chemical processes applicable to other astrophysical environments. 17 oxygen-rich AGB and RSG stars spanning a range in (circum)stellar parameters and evolutionary phases were observed in a homogeneous observing strategy allowing for an unambiguous comparison. Data were obtained between 213.83 and 269.71 GHz at high (0.025-0.050 arcsec), medium (0.13-0.24 arcsec), and low (about 1 arcsec) angular resolution. The sensitivity per 1.3 km/s channel was 1.5-5 mJy/beam. 13 molecules were designated as primary molecules in the survey: CO, SiO, AlO, AlOH, TiO, TiO2, HCN, SO, SO2, SiS, CS, H2O, and NaCl. The scientific motivation, survey design, sample properties, data reduction, and an overview of the data products are described; and we highlight one scientific result - the wind kinematics of the ATOMIUM sources. The ATOMIUM sources often have a slow wind acceleration, and a fraction of the gas reaches a velocity which can be up to a factor of two times larger than previously reported terminal velocities assuming isotropic expansion, and the wind kinematic profiles establish that the radial velocity described by the momentum equation for a spherical wind structure cannot capture the complexity of the velocity field. In 15 sources, some molecular transitions other than 12CO v=0 J=2-1 reach a higher outflow velocity, with a spatial emission zone that is often greater than 30 stellar radii, but much less than the extent of CO. Binary interaction with a (sub)stellar companion might (partly) explain the non-monotonic behaviour of the projected velocity field.

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ATOMIUM: Halide molecules around the S-type AGB star W Aquilae

S-type asymptotic giant branch (AGB) stars are thought to be intermediates in the evolution of oxygen- to carbon-rich AGB stars. The chemical compositions of their circumstellar envelopes are also intermediate, but have not been studied in as much detail as their carbon- and oxygen-rich counterparts. We aim to determine the abundances of AlCl and AlF from rotational lines, which have been observed for the first time towards an S-type AGB star, W Aql. In combination with models based on PACS observations, we aim to update our chemical kinetics network based on these results. We analyse ALMA observations towards W Aql of AlCl in the ground and first two vibrationally excited states and AlF in the ground vibrational state. Using radiative transfer models, we determine the abundances and spatial abundance distributions of Al$^{35}$Cl, Al$^{37}$Cl, and AlF. We also model HCl and HF emission and compare these models to PACS spectra to constrain the abundances of these species. AlCl is found in clumps very close to the star, with emission confined within 0.1$^{\prime\prime}$ of the star. AlF emission is more extended, with faint emission extending 0.2$^{\prime\prime}$ to 0.6$^{\prime\prime}$ from the continuum peak. We find peak abundances, relative to H$_2$, of $1.7\times 10^{-7}$ for Al$^{35}$Cl, $7\times 10^{-8}$ for Al$^{37}$Cl and $1\times 10^{-7}$ for AlF. From the PACS spectra, we find abundances of $9.7\times 10^{-8}$ and $\leq 10^{-8}$, relative to H$_2$, for HCl and HF, respectively. The AlF abundance exceeds the solar F abundance, indicating that fluorine synthesised in the AGB star has already been dredged up to the surface of the star and ejected into the circumstellar envelope. From our analysis of chemical reactions in the wind, we conclude that AlF may participate in the dust formation process, but we cannot fully explain the rapid depletion of AlCl seen in the wind.

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