arXiv subjects

R. Stern

Publications and source records attributed to R. Stern.

18 recordsLinked to original sources

arXiv2025

Normal state and superconducting state properties of high entropy Ta0.2Nb0.2V0.2Ti0.2X0.2 (X = Zr and Hf )

High entropy alloy superconductors represent a unique blend of advanced material systems and quantum physics, offering significant potential for advancing superconducting technologies. In this study, we report a detailed theoretical and experimental investigation of high entropy alloy superconductors Ta0.2Nb0.2V0.2Ti0.2X0.2 (X = Zr and Hf). Our study unveils that both the materials crystallize in a body-centered cubic structure (space group: I m -3 m) and exhibit bulk superconductivity with a superconducting onset temperature of (Tonset C ) of 5 K for X = Hf and 6.19 K for X = Zr sample. Our detailed analysis, including magnetization, resistivity, heat capacity measurements, and density functional theory (DFT) calculations indicates moderately coupled isotropic s-wave superconductivity in these materials. Our DFT results find significant spectral weight at the Fermi energy and phonon spectra is free of imaginary modes, confirming the dynamical stability and metallic nature of these alloys. Remarkably, we have observed a high upper critical field (HC2(0)) surpassing the Pauli paramagnetic limit for the X = Hf sample and explained it on the basis of the increased spin-orbit coupling in the structure. Ta0.2Nb0.2V0.2Ti0.2Zr0.2, on the other hand, shows a conventional HC2 behaviour. With the dynamical stability of these alloys, excellent normal state metallic nature, high micro-hardness, and high upper critical field, these samples emerge as potential candidates for future applications in superconducting devices.

cond-mat.supr-con↗

arXiv2020

A Unifying Framework for Formal Theories of Novelty:Framework, Examples and Discussion

Managing inputs that are novel, unknown, or out-of-distribution is critical as an agent moves from the lab to the open world. Novelty-related problems include being tolerant to novel perturbations of the normal input, detecting when the input includes novel items, and adapting to novel inputs. While significant research has been undertaken in these areas, a noticeable gap exists in the lack of a formalized definition of novelty that transcends problem domains. As a team of researchers spanning multiple research groups and different domains, we have seen, first hand, the difficulties that arise from ill-specified novelty problems, as well as inconsistent definitions and terminology. Therefore, we present the first unified framework for formal theories of novelty and use the framework to formally define a family of novelty types. Our framework can be applied across a wide range of domains, from symbolic AI to reinforcement learning, and beyond to open world image recognition. Thus, it can be used to help kick-start new research efforts and accelerate ongoing work on these important novelty-related problems. This extended version of our AAAI 2021 paper included more details and examples in multiple domains.

cs.AI↗

arXiv2020

Freezing of molecular rotation in a paramagnetic crystal studied by $^{31}$P NMR

We present a detailed $^{31}$P nuclear magnetic resonance (NMR) study of the molecular rotation in the compound [Cu(pz)$_{2}$(2-HOpy)$_{2}$](PF$_{6}$)$_{2}$, where pz = C$_4$H$_4$N$_2$ and 2-HOpy = C$_5$H$_4$NHO. Here, a freezing of the PF$_6$ rotation modes is revealed by several steplike increases of the temperature-dependent second spectral moment, with accompanying broad peaks of the longitudinal and transverse nuclear spin-relaxation rates. An analysis based on the Bloembergen-Purcell-Pound (BPP) theory quantifies the related activation energies as $E_{a}/k_{B}$ = 250 and 1400 K. Further, the anisotropy of the second spectral moment of the $^{31}$P absorption line was calculated for the rigid lattice, as well as in the presence of several sets of PF$_6$ reorientation modes, and is in excellent agreement with the experimental data. Whereas the anisotropy of the frequency shift and enhancement of nuclear spin-relaxation rates is driven by the molecular rotation with respect to the dipole fields stemming from the Cu ions, the second spectral moment is determined by the intramolecular interaction of nuclear $^{19}$F and $^{31}$P moments in the presence of the distinct rotation modes.

cond-mat.str-el↗

arXiv2020

Extremely well isolated 2D spin-$1/2$ antiferromagnetic Heisenberg layers with small exchange coupling in the molecular-based magnet CuPOF

We report on a comprehensive characterization of the newly synthesized Cu$^{2+}$-based molecular magnet [Cu(pz)$_2$(2-HOpy)$_2$](PF$_6$)$_2$ (CuPOF), where pz = C$_4$H$_4$N$_2$ and 2-HOpy = C$_5$H$_4$NHO. From a comparison of theoretical modeling to results of bulk magnetometry, specific heat, $\mu^+$SR, ESR, and NMR spectroscopy, this material is determined as an excellent realization of the 2D square-lattice $S=1/2$ antiferromagnetic Heisenberg model with a moderate intraplane nearest-neighbor exchange coupling of $J/k_\mathrm{B} = 6.80(5)$ K, and an extremely small interlayer interaction of about 1 mK. At zero field, the bulk magnetometry reveals a temperature-driven crossover of spin correlations from isotropic to $XY$ type, caused by the presence of a weak intrinsic easy-plane anisotropy. A transition to long-range order, driven by the low-temperature $XY$ anisotropy under the influence of the interlayer coupling, occurs at $T_\mathrm{N} = 1.38(2)$ K, as revealed by $\mu^+$SR. In applied magnetic fields, our $^1$H-NMR data reveal a strong increase of the magnetic anisotropy, manifested by a pronounced enhancement of the transition temperature to commensurate long-range order at $T_\mathrm{N} =2.8$ K and 7 T.

cond-mat.str-el↗

arXiv2019

NMR, magnetization, and heat capacity studies of the uniform spin-1/2 chain compound Bi6V3O16

We report the local (NMR) and bulk (magnetization and heat capacity) properties of the vanadium-based S=1/2 uniform spin chain compound Bi6V3O16(Bi4V2O10.66). In the low-temperature {\alpha} phase, the magnetic ions (V4+) are arranged in one-dimensional chains. The magnetic susceptibility shows a broad maximum around 50 K signifying a short-range magnetic order. Heat capacity measurements also reveal low-dimensional magnetism. The 51V magic angle spinning nuclear magnetic resonance measurements clearly show that the magnetic V4+ and nonmagnetic V5+ species are located on different crystallographic sites with no mixed occupation. The spin susceptibility calculated from the shift of the 51V NMR spectra reproduces the behavior observed in magnetic susceptibility and agrees well with the S=1/2 uniform spin chain model with J=113(5) K.

cond-mat.str-el↗

arXiv2018

Single crystal growth of Cu4(OH)6BrF and universal behavior in quantum spin liquid candidates synthetic barlowite and herbertsmithite

Synthetic barlowite, Cu4(OH)6BrF, has emerged as a new quantum spin liquid (QSL) host, containing kagome layers of S=1/2 Cu2+ ions separated by interlayer Cu2+ ions. Similar to synthetic herbertsmithite, ZnCu3(OH)6Cl2, it has been reported that Zn2+ substitution for the interlayer Cu2+ induces a QSL ground state. Here we report a scalable synthesis of single crystals of Cu4(OH)6BrF. Through x-ray, neutron, and electron diffraction measurements coupled with magic angle spinning 19F and 1H NMR spectroscopy, we resolve the previously reported positional disorder of the interlayer Cu2+ ions and find that the structure is best described in the orthorhombic space group, Cmcm, with lattice parameters a = 6.665(13) A, b = 11.521(2) A, c = 9.256(18) A and an ordered arrangement of interlayer Cu2+ ions. Infrared spectroscopy measurements of the O-H and F-H stretching frequencies demonstrate that the orthorhombic symmetry persists upon substitution of Zn2+ for Cu2+. Specific heat and magnetic susceptibility measurements of Zn-substituted barlowite, ZnxCu4-x(OH)6BrF, reveal striking similarities with the behavior of ZnxCu4-x(OH)6Cl2. These parallels imply universal behavior of copper kagome lattices even in the presence of small symmetry breaking distortions. Thus synthetic barlowite demonstrates universality of the physics of synthetic Cu2+ kagome minerals and furthers the development of real QSL states.

cond-mat.str-el↗

arXiv2016

Magnetic anisotropy in the frustrated spin chain compound $\beta$-TeVO$_4$

Isotropic and anisotropic magnetic behavior of the frustrated spin chain compound $\beta$-TeVO$_4$ is reported. Three magnetic transitions observed in zero magnetic field are tracked in fields applied along different crystallographic directions using magnetization, heat capacity, and magnetostriction measurements. Qualitatively different temperature-field diagrams are obtained below 10 T for the field applied along $a$ or $b$ and along $c$, respectively. In contrast, a nearly isotropic high-field phase emerges above 18 T and persists up to the saturation that occurs around 22.5 T. Upon cooling in low fields, the transitions at $T_{\rm N1}$ and $T_{\rm N2}$ toward the spin-density-wave and stripe phases are of the second order, whereas the transition at $T_{\rm N3}$ toward the helical state is of the first order and entails a lattice component. Our microscopic analysis identifies frustrated $J_1-J_2$ spin chains with a sizable antiferromagnetic interchain coupling in the $bc$ plane and ferromagnetic couplings along the $a$ direction. The competition between these ferromagnetic interchain couplings and the helical order within the chain underlies the incommensurate order along the $a$-direction, as observed experimentally. Although a helical state is triggered by the competition between $J_1$ and $J_2$ within the chain, the plane of the helix is not uniquely defined because of competing magnetic anisotropies. Using high-resolution synchrotron diffraction and $^{125}$Te nuclear magnetic resonance, we also demonstrate that the crystal structure of $\beta$-TeVO$_4$ does not change down to 10 K, and the orbital state of V$^{4+}$ is preserved.

cond-mat.mtrl-sci↗

arXiv2013

Spatially Resolved Magnetization in the Bose-Einstein Condensed State of BaCuSi2O6: Evidence for Imperfect Frustration

In order to understand the nature of the two-dimensional Bose-Einstein condensed (BEC) phase in BaCuSi2O6, we performed detailed 63Cu and 29Si NMR above the critical magnetic field, Hc1= 23.4 T. The two different alternating layers present in the system have very different local magnetizations close to Hc1; one is very weak, and its size and field dependence are highly sensitive to the nature of inter-layer coupling. Its precise value could only be determined by "on-site" 63Cu NMR, and the data are fully reproduced by a model of interacting hard-core bosons in which the perfect frustration associated to tetragonal symmetry is slightly lifted, leading to the conclusion that the population of the less populated layers is not fully incoherent but must be partially condensed.

cond-mat.str-el↗

arXiv2012

Two types of adjacent dimer layers in the low temperature phase of BaCuSi2O6

The low-temperature crystal structure of BaCuSi2O6 has been investigated with high-resolution synchrotron x-ray and neutron powder diffraction techniques and has been found to be on average (ignoring the incommensurate modulation) orthorhombic, with the most probable space group Ibam. The Cu-Cu dimers in this material are forming two types of layers with distinctly different interatomic distances. Subtle changes also modify the partially frustrated interlayer Cu-Cu exchange paths. The present results corroborate the interpretation of low-temperature nuclear magnetic resonance and inelastic neutron scattering data in terms of distinct dimer layers.

cond-mat.str-el↗

arXiv2011

PHA: Finding the Shortest Path with A in An Unknown Physical Environment

We address the problem of finding the shortest path between two points in an unknown real physical environment, where a traveling agent must move around in the environment to explore unknown territory. We introduce the Physical-A* algorithm (PHA*) for solving this problem. PHA* expands all the mandatory nodes that A* would expand and returns the shortest path between the two points. However, due to the physical nature of the problem, the complexity of the algorithm is measured by the traveling effort of the moving agent and not by the number of generated nodes, as in standard A*. PHA* is presented as a two-level algorithm, such that its high level, A*, chooses the next node to be expanded and its low level directs the agent to that node in order to explore it. We present a number of variations for both the high-level and low-level procedures and evaluate their performance theoretically and experimentally. We show that the travel cost of our best variation is fairly close to the optimal travel cost, assuming that the mandatory nodes of A* are known in advance. We then generalize our algorithm to the multi-agent case, where a number of cooperative agents are designed to solve the problem. Specifically, we provide an experimental implementation for such a system. It should be noted that the problem addressed here is not a navigation problem, but rather a problem of finding the shortest path between two points for future usage.

cs.AI↗

arXiv2011

Spin-Peierls transition in TiPO$_4$

We investigated the magnetic and structural properties of the quasi-one dimensional 3$d^1$-quantum chain system TiPO$_4$ ($J \sim$ 965 K) by magnetic susceptibility, heat capacity, ESR, x-ray diffraction, NMR measurements, and by density functional calculations. TiPO$_4$ undergoes two magnetostructural phase transitions, one at 111 K and the other at 74 K. Below 74 K, NMR detects two different $^{31}$P signals and the magnetic susceptibility vanishes, while DFT calculations evidence a bond alternation of the Ti...Ti distances within each chain. Thus, the 74 K phase transition is a spin-Peierls transition which evolves from an incommensurate phase existing between 111 K and 74 K.

cond-mat.str-el↗

arXiv2010

Science Objectives for an X-Ray Microcalorimeter Observing the Sun

We present the science case for a broadband X-ray imager with high-resolution spectroscopy, including simulations of X-ray spectral diagnostics of both active regions and solar flares. This is part of a trilogy of white papers discussing science, instrument (Bandler et al. 2010), and missions (Bookbinder et al. 2010) to exploit major advances recently made in transition-edge sensor (TES) detector technology that enable resolution better than 2 eV in an array that can handle high count rates. Combined with a modest X-ray mirror, this instrument would combine arcsecondscale imaging with high-resolution spectra over a field of view sufficiently large for the study of active regions and flares, enabling a wide range of studies such as the detection of microheating in active regions, ion-resolved velocity flows, and the presence of non-thermal electrons in hot plasmas. It would also enable more direct comparisons between solar and stellar soft X-ray spectra, a waveband in which (unusually) we currently have much better stellar data than we do of the Sun.

astro-ph.SR↗

arXiv2007

NMR evidence for a strong modulation of the Bose-Einstein Condensate in BaCuSi$_2$O$_6$

We present a $^{63,65}$Cu and $^{29}$Si NMR study of the quasi-2D coupled spin 1/2 dimer compound BaCuSi$_2$O$_6$ in the magnetic field range 13-26 T and at temperatures as low as 50 mK. NMR data in the gapped phase reveal that below 90 K different intra-dimer exchange couplings and different gaps ($Δ_{\rm{B}}/Δ_{\rm{A}}$ = 1.16) exist in every second plane along the c-axis, in addition to a planar incommensurate (IC) modulation. $^{29}$Si spectra in the field induced magnetic ordered phase reveal that close to the quantum critical point at $H_{\rm{c1}}$ = 23.35 T the average boson density $\bar{n}$ of the Bose-Einstein condensate is strongly modulated along the c-axis with a density ratio for every second plane $\bar{n}_{\rm{A}}/\bar{n}_{\rm{B}} \simeq 5$. An IC modulation of the local density is also present in each plane. This adds new constraints for the understanding of the 2D value $ϕ$ = 1 of the critical exponent describing the phase boundary.

cond-mat.str-el↗

arXiv2006

Molecular orientational dynamics of the endohedral fullerene Sc$_{3}$N@C$_{80}$ as probed by $^{13}$C and $^{45}$Sc NMR

We measure 13C and 45Sc NMR lineshapes and spin-lattice relaxation times (T1) to probe the orientational dynamics of the endohedral metallofullerene Sc3N@C80. The measurements show an activated behavior for molecular reorientations over the full temperature range with a similar behavior for the temperature dependence of the 13C and 45Sc data. Combined with spectral data from Magic Angle Spinning (MAS) NMR, the measurements can be interpreted to mean the motion of the encapsulated Sc3N molecule is independent of that of the C80 cage, although this requires the similar temperature dependence of the 13C and 45Sc spin-lattice relaxation times to be coincidental. For the Sc3N to be fixed to the C80 cage, one must overcome the symmetry breaking effect this has on the Sc3N@C80 system since this would result in more than the observed two 13C lines.

cond-mat.mtrl-sci↗

arXiv2006

Spin-Triplet Excitons in the $S=1/2$ Gapped Antiferromagnet BaCuSi$_2$O$_6$: Electron Paramagnetic Resonance Studies

BaCuSi$_2$O$_6$, a $S=1/2$ quantum antiferromagnet with a double-layer structure of Cu$^{2+}$ ions in a distorted planar-rectangular coordination and with a dimerized spin singlet ground state, is studied by means of the electron paramagnetic resonance technique. It is argued that multiple absorptions observed at low temperatures are intimately related to a thermally-activated spin-triplet exciton superstructure. Analysis of the angular dependence of exciton modes in BaCuSi$_2$O$_6$ allows us to accurately estimate anisotropy parameters. In addition, the temperature dependence of EPR intensity and linewidth is discussed.

cond-mat.other↗

arXiv2004

Magnetic Field-Induced Condensation of Triplons in Han Purple Pigment BaCuSi$_2$O$_6$

Besides being an ancient pigment, BaCuSi$_2$O$_6$ is a quasi-2D magnetic insulator with a gapped spin dimer ground state. The application of strong magnetic fields closes this gap creating a gas of bosonic spin triplet excitations called triplons. The topology of the spin lattice makes BaCuSi$_2$O$_6$ an ideal candidate for studying the Bose-Einstein condensation of triplons as a function of the external magnetic field, which acts as a chemical potential. In agreement with quantum Monte Carlo numerical simulations, we observe a distinct lambda-anomaly in the specific heat together with a maximum in the magnetic susceptibility upon cooling down to liquid Helium temperatures.

cond-mat.str-el↗

arXiv2004

High Field Specific Heat of 2D Quantum Spin System SrCu2(BO3)2

We report measurements of the specific heat of the quantum spin liquid system SrCu2(BO3)2 in continuous magnetic fields H of up to 33 T. The specific heat vs temperature at zero field shows an anomaly at 8 K, marking the opening of a gap in the spin singlet excitations. At fields H~12 T, we clearly see a second anomaly that shifts to lower temperatures as H is increased. We attribute its origin to single triplet excitations of the singlet dimer ground state. This conclusion is supported by calculations of the specific heat, which reproduce the experimental data, made using the finite temperature Lanczos method to solve a Shastry-Sutherland Hamiltonian including nearest and next-nearest neighbor Dzyaloshinsky-Moriya interactions. The parameters used to fit the data are the exchange constants J = 74 K and J'/J = 0.62, and the Dzyaloshinsky-Moriya coupling constants |D|=6.1K, and $|D'|=2.2K.

cond-mat.str-el↗

arXiv1994

Spin pseudo-gap and interplane coupling in Y_2Ba_4Cu_7O_{15}: a ^{63}Cu nuclear spin-spin relaxation study

We report measurements of the Gaussian contribution, T_{2G}, to the plane ^{63}Cu nuclear spin--spin relaxation time in the YBa_2Cu_3O_7 and YBa_2Cu_4O_8 blocks of normal and superconducting Y_2Ba_4Cu_7O_{15}. The data confirm our previous results that adjacent CuO_2 planes have different doping levels and that these planes are strongly coupled. -- The static spin susceptibility at the anti-ferromagnetic wave vector exhibits a Curie--Weiss like temperature dependence in the normal state. -- The Y_2Ba_4Cu_7O_{15} data are incompatible with a phase diagram based on a single CuO_2 plane theory and suggest that the appearance of a spin gap implies interplane coupling. Additional data for YBa_2Cu_4O_8 and YBa_2Cu_3O_{6.982} are in accord with the single plane theory. -- The temperature dependence of T_{2G,ind} below T_c excludes isotropic s-wave superconductivity in all three compounds.

supr-con↗