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Raghuveer Chimata

Publications and source records attributed to Raghuveer Chimata.

6 recordsLinked to original sources

Magnetization dynamics in Fe$_x$Co$_{1-x}$ in presence of chemical disorder

In this paper, we present a theoretical formulation of magnetization dynamics in disordered binary alloys based on Kubo linear response theory interfaced with the combination of seamlessly three approaches; density functional based tight-binding linear muffin-tin orbitals, generalized recursion and Augmented space formalism. We apply this method to study the magnetization dynamics in chemically disordered Fe$_x$Co$_{1-x}$ ($x$ = 0.2, 0.5, 0.8) alloys. We reported that the magnon energies decrease with an increase in Co concentration. Significant magnon softening has been observed in Fe$_{20}$Co$_{80}$ at the Brillouin zone boundary. The magnon-electron scattering increases with increasing Co content which in turn modifies the hybridization between the Fe and Co atoms. This reduces the exchange energy between the atoms and soften down the magnon energy. The lowest magnon lifetime in found in Fe$_{50}$Co$_{50}$, where disorder is maximum. This clearly indicates that the damping of magnon energies in Fe$_x$Co$_{1-x}$ is governed by the hybridization between Fe and Co whereas the magnon lifetime is controlled by disorder configuration. Our atomistic spin dynamics simulations show a reasonable agreement with our theoretical approach in magnon dispersion for different alloy compositions.

cond-mat.mtrl-sci

Analysis of the linear relationship between asymmetry and magnetic moment at the M-edge of 3d transition metals

The magneto-optical response of Fe and Ni during ultrafast demagnetization is studied experimentally and theoretically. We have performed pump-probe experiments in the transverse magneto-optical Kerr effect (T-MOKE) geometry using photon energies that cover the M-absorption edges of Fe and Ni between 40 to 72 eV. The asymmetry was detected by measuring the reflection of light for two different orientations of the sample magnetization. Density functional theory (DFT) wasused to calculate the magneto-optical response of different magnetic configurations, representing different types of excitations: long-wavelength magnons, short wavelength magnons, and Stoner excitations. In the case of Fe, we find that the calculated asymmetry is strongly dependent on the specific type of magnetic excitation. Our modelling also reveals that during remagnetization Fe is, to a reasonable approximation, described by magnons, even though small non-linear contributions could indicate some degree of Stoner excitations as well. In contrast, we find that the calculated asymmetry in Ni is rather insensitive to the type of magnetic excitations. However, there is a weak non-linearity in the relation between asymmetry and the off-diagonal component of the dielectric tensor, which does not originate from the modifications of the electronic structure. Our experimental and theoretical results thus emphasize the need of considering a coupling between asymmetry and magnetization that may be more complex that a simple linear relationship. This insight is crucial for the microscopic interpretation of ultrafast magnetization experiments.

cond-mat.mtrl-sci

Defect energetics of cubic hafnia from quantum Monte Carlo simulations

Cubic hafnia (HfO$_2$) is of great interest for a number of applications in electronics because of its high dielectric constant. However, common defects in such applications degrade the properties of hafina. We have investigated the electronic properties of oxygen vacancies and nitrogen substitution in cubic HfO$_2$ using first principles calculations based on density functional theory (DFT) and many-body diffusion Monte Carlo (DMC) methods. We investigate five different charge defect states of oxygen vacancies, as well as substitutional N defects which can lead to local magnetic moments. Both DMC and DFT calculations shows that an oxygen vacancy induces strong lattice relaxations around the defect. Finally, we compare defect formation energies, charge and spin densities obtained from DMC with results obtained using DFT. While the obtained formation energies from DMC are 0.6~eV -- 1.5~eV larger than those from GGA+U, the agreement for the most important defects, neutral and positively charged oxygen vacancies, and nitrogen substitutional defect, under oxygen-poor conditions are in reasonably good agreement. Our work confirms that nitrogen can act to passivate cubic hafnia for applications in electronics.

cond-mat.mtrl-sci

Exchange dependent ultrafast magnetization dynamics in Fe$_{1-x}$Ni$_{x}$ alloys

Element specific ultrafast demagnetization was studied in Fe$_{1-x}$Ni$_{x}$ alloys, covering the concentration range between $0.1<x<0.9$. For all compositions, we observe a delay in the onset of Ni demagnetization relative to the Fe demagnetization. We find that the delay is correlated to the Curie temperature and hence also the exchange interaction. The temporal evolution of demagnetization is fitted to a magnon diffusion model based on the presupposition of enhanced ultrafast magnon generation in the Fe sublattice. The spin wave stiffness extracted from this model correspond well to known experimental values.

cond-mat.mtrl-sci

All-thermal switching of amorphous Gd-Fe alloys: analysis of structural properties and magnetization dynamics

In recent years, there has been an intense interest in understanding the microscopic mechanism of thermally induced magnetization switching driven by a femtosecond laser pulse. Most of the effort has been dedicated to periodic crystalline structures while the amorphous counterparts have been less studied. By using a multiscale approach, i.e. first-principles density functional theory combined with atomistic spin dynamics, we report here on the very intricate structural and magnetic nature of amorphous Gd-Fe alloys for a wide range of Gd and Fe atomic concentrations at the nanoscale level. Both structural and dynamical properties of Gd-Fe alloys reported in this work are in good agreement with previous experiments. We calculated the dynamic behavior of homogeneous and inhomogeneous amorphous Gd-Fe alloys and their response under the influence of a femtosecond laser pulse. In the homogeneous sample, the Fe sublattice switches its magnetization before the Gd one. However, the temporal sequence of the switching of the two sublattices is reversed in the inhomogeneous sample. We propose a possible explanation based on a mechanism driven by a combination of the Dzyaloshiskii-Moriya interaction and exchange frustration, modeled by an antiferromagnetic second-neighbour exchange interaction between Gd atoms in the Gd-rich region. We also report on the influence of laser fluence and damping effects in the all-thermal switching.

cond-mat.mtrl-sci

A microscopic model for ultrafast remagnetization dynamics

In this letter, we provide a microscopic model for the ultrafast remagnetization of atomic moments already quenched above Stoner-Curie temperature by a strong laser fluence. Combining first principles density functional theory, atomistic spin dynamics utilizing the Landau-Lifshitz-Gilbert equation and a three temperature model, we show the temporal evolution of atomic moments as well as the macroscopic magnetization of bcc Fe and hcp Co covering a broad time scale, ranging from femtoseconds to picoseconds. Our simulations show a variety of complex temporal behavior of the magnetic properties resulting from an interplay between electron, spin and lattice subsystems, which causes an intricate time evolution of the atomic moment, where longitudinal and transversal fluctuations result in a macro spin moment that evolves non-monotonically.

cond-mat.mtrl-sci