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Rajeev Gupta

Publications and source records attributed to Rajeev Gupta.

At least 37 records · Page 2Linked to original sources

On a Question of N. Th. Varopoulos and the constant $C_2(n)$

Let $\mathbb C_k[Z_1,\ldots, Z_n]$ denote the set of all polynomials of degree at most $k$ in $n$ complex variables and $\mathscr{C}_n$ denote the set of all $n$ - tuple $\boldsymbol T=(T_1,\ldots,T_n)$ of commuting contractions on some Hilbert space $\mathbb{H}.$ The interesting inequality $$K_{G}^{\mathbb C}\leq \lim_{n\to \infty}C_2(n)\leq 2 K^\mathbb C_G,$$ where \[C_k(n)=\sup\big\{\|p(\boldsymbol T)\|:\|p\|_{\mathbb D^n,\infty}\leq 1, p\in \mathbb C_k[Z_1,\ldots,Z_n],\boldsymbol T\in\mathscr{C}_n \big\}\] and $K_{G}^{\mathbb C}$ is the complex Grothendieck constant, is due to Varopoulos. We answer a long--standing question by showing that the limit $\lim_{n\to\infty} \frac{C_2(n)}{K^\mathbb C_G}$ is strictly bigger than $1.$ Let $\mathbb C_2^s[Z_1,\ldots , Z_n]$ denote the set of all complex valued homogeneous polynomials $p(z_1,\ldots,z_n)$ $=\sum_{j,k=1}^{n}a_{jk}z_jz_k$ of degree two in $n$ - variables, where $(\!(a_{jk})\!)$ is a $n\times n$ complex symmetric matrix. For each $n\in\mathbb{N},$ define the linear map $\mathscr{A}_n:\big (\mathbb C_2^s[Z_1,\ldots , Z_n],\|\cdot\|_{\mathbb D^n, \infty}\big ) \to \big (M_n, \|\cdot \|_{\infty \to 1}\big )$ to be $\mathscr{A}_n\big (p) = (\!(a_{jk})\!).$ We show that the supremum (over $n$) of the norm of the operators $\mathscr{A}_n;\,n\in\mathbb{N},$ is bounded below by the constant $π^2/8.$ Using a class of operators, first introduced by Varopoulos, we also construct a large class of explicit polynomials for which the von Neumann inequality fails. We prove that the original Varopoulos--Kaijser polynomial is extremal among a, suitably chosen, large class of homogeneous polynomials of degree two. We also study the behaviour of the constant $C_k(n)$ as $n \to \infty.$

math.FA↗

The Carathéodory-Fejér interpolation problem for the polydisc

We give an algorithm for finding a solution to the Carathéodory-Fejér interpolation problem on the polydisc $\mathbb D^n,$ whenever it exists. A necessary condition for the existence of a solution becomes apparent from this algorithm. A generalization of the well-known theorem due to Nehari has been obtained. A proof of the Korányi--Pukánszky theorem is given using the spectral theorem.

math.FA↗

Room temperature multiferroism in polycrystalline thin films of gallium ferrite

Sol-gel deposited (010) textured polycrystalline thin films of gallium ferrite (GaFeO3 or GFO) on n-Si(100) and Pt/Si(111) substrates are characterized for room temperature multiferroism. Structural characterization using X-ray diffraction and Raman spectroscopy confirms formation of single phase with nano-sized crystallites. Temperature dependent magnetization study demonstrates ferri to paramagnetic transition at ~300 K. Room temperature piezoresponse force microscopic analysis reveals local 180 degree phase switching of ferroelectric domains at very high coercive field EC, ~ 1350 kV/cm consistent with recent experimental and first-principles studies. Our study opens up possibility of integrating polycrystalline GFO in novel room temperature multiferroic devices.

cond-mat.mtrl-sci↗

Operator Space Structures on $\ell^1(n).$

We show that the complex normed linear space $\ell^1(n),$ $n>1,$ has no isometric embedding into $k\times k$ complex matrices for any $k\in \mathbb{N}$ and discuss a class of infinite dimensional operator space structures on it.

math.FA↗

The Carathéodory-Fejér Interpolation Problems and the von-Neumann Inequality

The validity of the von-Neumann inequality for commuting $n$ - tuples of $3\times 3$ matrices remains open for $n\geq 3$. We give a partial answer to this question, which is used to obtain a necessary condition for the Carathéodory-Fejér interpolation problem on the polydisc $\mathbb D^n.$ In the special case of $n=2$ (which follows from Ando's theorem as well), this necessary condition is made explicit. An alternative approach to the Carathéodory-Fejér interpolation problem, in the special case of $n=2,$ adapting a theorem of Korányi and Pukánzsky is given. As a consequence, a class of polynomials are isolated for which a complete solution to the Carathéodory-Fejér interpolation problem is easily obtained. A natural generalization of the Hankel operators on the Hardy space of $H^2(\mathbb T^2)$ then becomes apparent. Many of our results remain valid for any $n\in \mathbb N,$ however, the computations are somewhat cumbersome for $n>2$ and are omitted. The inequality $\lim_{n\to \infty}C_2(n)\leq 2 K^\mathbb C_G$, where $K_G^\mathbb C$ is the complex Grothendieck constant and \[C_2(n)=\sup\big\{\|p(\boldsymbol T)\|:\|p\|_{\mathbb D^n,\infty}\leq 1, \|\boldsymbol T\|_{\infty} \leq 1 \big\}\] is due to Varopoulos. Here the supremum is taken over all complex polynomials $p$ in $n$ variables of degree at most $2$ and commuting $n$ - tuples $\boldsymbol T:=(T_1,\ldots,T_n)$ of contractions. We show that \[\lim_{n\to \infty}C_2(n)\leq \frac{3\sqrt{3}}{4} K^\mathbb C_G\] obtaining a slight improvement in the inequality of Varopoulos. We show that the normed linear space $\ell^1(n),$ $n>1,$ has no isometric embedding into $k\times k$ complex matrices for any $k\in \mathbb N$ and discuss several infinite dimensional operator space structures on it.

math.FA↗

Ferroelectric polarization switching with a remarkably high activation-energy in orthorhombic GaFeO3 thin films

Orthorhombic GaFeO3 (o-GFO) with the polar Pna21 space group is a prominent ferrite by virtue of its piezoelectricity and ferrimagnetism, coupled with magneto-electric effects. Herein, we unequivocally demonstrate a large ferroelectric remanent polarization in undoped o-GFO thin films by adopting either a hexagonal strontium titanate (STO) or a cubic yttrium-stabilized zirconia (YSZ) substrate. The polarization-electric-field hysteresis curves of the polar c-axis-grown o-GFO film on a SrTiO3/STO substrate show the net switching polarization of ~35 μC/cm2 with an unusually high coercive field of +-1400 kV/cm at room temperature. The PUND measurement also demonstrates the switching polarization of ~26 μC/cm2. The activation energy for the polarization switching, as obtained by density-functional theory calculations, is remarkably high, 1.05 eV per formula unit. This high value accounts for the observed stability of the polar Pna21 phase over a wide range of temperature up to 1368 K.

cond-mat.mtrl-sci↗

Room Temperature Nanoscale Ferroelectricity in Magnetoelectric GaFeO3 Epitaxial Thin Films

We demonstrate room temperature ferroelectricity in the epitaxial thin films of magnetoelectric GaFeO3. Piezo-force measurements show a 180o phase shift of piezoresponse upon switching the electric field indicating nanoscale ferroelectricity in epitaxial thin films of gallium ferrite. Further, temperature dependent impedance analysis with and without the presence of an external magnetic field clearly reveals a pronounced magneto-dielectric effect across the magnetic transition temperature. In addition, our first principles calculations show that Fe ions are not only responsible for ferrimagnetism as observed earlier, but also give rise to the observed ferroelectricity, making GFO an unique single phase multiferroic.

cond-mat.mtrl-sci↗

Effect of Site-disorder, Off-stoichiometry and Epitaxial Strain on the Optical Properties of Magnetoelectric Gallium Ferrite

We present a combined experimental-theoretical study demonstrating the role of site disorder, off-stoichiometry and strain on the optical behavior of magnetoelectric gallium ferrite. Optical properties such as band-gap, refractive indices and dielectric constants were experimentally obtained by performing ellipsometric studies over the energy range 0.8 eV to 4.2 eV on pulsed laser deposited epitaxial thin films of stoichiometric gallium ferrite with b-axis orientation and the data was compared with theoretical results. Calculations on the ground state structure show that the optical activity in GaFeO3 arises primarily from O2p-Fe3d transitions. Further, inclusion of site disorder and epitaxial strain in the ground state structure significantly improves the agreement between the theory and the room temperature experimental data substantiating the presence of site-disorder in the experimentally derived strained GaFeO3 films at room temperature. We attribute the modification of the ground state optical behavior upon inclusion of site disorder to the corresponding changes in the electronic band structure, especially in Fe3d states leading to a lowered band-gap of the material.

cond-mat.mtrl-sci↗

Spin Glass-like Phase below ~ 210 K in Magnetoelectric Gallium Ferrite

In this letter we show the presence of a spin-glass like phase in single crystals of magnetoelectric gallium ferrite (GaFeO3) below ~210 K via temperature dependent ac and dc magnetization studies. Analysis of frequency dispersion of the susceptibility peak at ~210 K using the critical slowing down model and Vogel-Fulcher law strongly suggests the existence of a classical spin-glass like phase. This classical spin glass behavior of GaFeO3 is understood in terms of an outcome of geometrical frustration arising from the inherent site disorder among the antiferromagnetically coupled Fe ions located at octahedral Ga and Fe sites.

cond-mat.mtrl-sci↗

Probing Magnetoelastic Coupling and Structural Changes in Magnetoelectric Gallium Ferrite

Temperature dependent X-ray diffraction and Raman spectroscopic studies were carried out on the flux grown single crystals of gallium ferrite with Ga:Fe ratio of 0.9:1.1. Site occupancy calculations from the Rietveld refinement of the X-ray data led to the estimated magnetic moment of ~0.60 \muB /f.u. which was in good agreement with the experimental data. Combination of these two measurements indicates that there is no structural phase transition in the material between 18 K to 700 K. A detailed line shape analysis of the Raman mode at ~375 cm^-1 revealed a discontinuity in the peak position data indicating the presence of spin-phonon coupling in gallium ferrite. A correlation of the peak frequency with the magnetization data led to two distinct regions across a temperature ~180 K with appreciable change in the spin-phonon coupling strength from ~ 0.9 cm^-1 (T < 180 K) to 0.12 cm-1 (180 K < T < Tc). This abrupt change in the coupling strength at ~180 K strongly suggests an altered spin dynamics across this temperature.

cond-mat.mtrl-sci↗

Composition Dependence of Structural Parameters and Properties of Gallium Ferrite

We show the effect of composition on structural and magnetic characteristics of pure phase polycrystalline Ga<2-x>Fe O<3> (GFO) for compositions between 0.8 <= x <= 1.3. X-ray analysis reveals that lattice parameters of GFO exhibit a linear dependence on Fe content in single phase region indicating manifestation of Vegard's law. Increasing Fe content of the samples also leads to stretching of bonds as indicated by the Raman peak shifts. Further, low temperature magnetic measurements show that the coercivity of the samples is maximum for Ga:Fe ratio of 1:1 driven by a competition between decreasing crystallite size and increasing magnetic anisotropy.

cond-mat.mtrl-sci↗

Electronic Structures, Born Effective Charges and Spontaneous Polarization in Magnetoelectric Gallium Ferrite

We present a theoretical study of the structure-property correlation in gallium ferrite, based on the first principles calculations followed by a subsequent comparison with the experiments. Local spin density approximation (LSDA+U) of the density functional theory has been used to calculate the ground state structure, electronic band structure, density of states and Born effective charges. Calculations reveal that the ground state structure is orthorhombic Pc21n having A-type antiferromagnetic spin configuration, with lattice parameters matching well with those obtained experimentally. Plots of partial density of states of constituent ions exhibit noticeable hybridization of Fe 3d, Ga 4s, Ga 4p and O 2p states. However, the calculated charge density and electron localization function show largely ionic character of the Ga/Fe-O bonds which is also supported by lack of any significant anomaly in the calculated Born effective charges with respect to the corresponding nominal ionic charges. The calculations show a spontaneous polarization of ~ 59 microC/cm^2 along b-axis which is largely due to asymmetrically placed Ga1, Fe1, O1, O2 and O6 ions.

cond-mat.mtrl-sci↗

Suppression of Jahn-Teller distortion by chromium and magnesium doping in spinel LiMn2O4: A first-principles study using GGA and GGA+U

The effect of doping spinel LiMn2O4 with chromium and magnesium has been studied using the first-principles spin density functional theory within GGA (generalized gradient approximation) and GGA+U. We find that GGA and GGA+U give different ground states for pristine LiMn2O4 and same ground state for doped systems. For LiMn2O4 the body centered tetragonal phase was found to be the ground state structure using GGA and face centered orthorhombic using GGA+U, while for LiM0.5Mn1.5O4 (M= Cr or Mg) it was base centered monoclinic and for LiMMnO4 (M= Cr or Mg) it was body centered orthorhombic in both GGA and GGA+U. We find that GGA predicts the pristine LiMn2O4 to be metallic while GGA+U predicts it to be the insulating which is in accordance with the experimental observations. For doped spinels, GGA predicts the ground state to be half metallic while GGA+U predicts it to be insulating or metallic depending on the doping concentration. GGA+U predicts insulator-metal-insulator transition as a function of doping in case of Cr and in case of Mg the ground state is found to go from insulating to a half metallic state as a function of doping. Analysis of the charge density and the density of states suggest a charge transfer from the dopants to the neighboring oxygen atoms and manganese atoms. We have calculated the Jahn-Teller active mode displacement Q3 for doped compounds using GGA and GGA+U. The bond lengths calculated from GGA+U are found to be in better agreement with the experimental bond lengths. Based on the bond lengths of metal and oxygen, we have also estimated the average oxidation states of the dopants.

cond-mat.mtrl-sci↗

Field- and pressure-induced phases in Sr$_{4}$Ru$_{3}$O$_{10}$: A spectroscopic investigation

We have investigated the magnetic-field- and pressure-induced structural and magnetic phases of the triple-layer ruthenate - Sr$_{4}$Ru$_{3}$O$_{10}$. Magnetic-field-induced changes in the phonon spectra reveal dramatic spin-reorientation transitions and strong magneto-elastic coupling in this material. Additionally, pressure-dependent Raman measurements at different temperatures reveal an anomalous negative Gruneisen-parameter associated with the B$_{1g}$ mode ($\sim$ 380 cm$^{-1}$) at low temperatures (T $<$ 75K), which can be explained consistently with the field dependent Raman data.

cond-mat.str-el↗

Raman Scattering in charge ordered Pr_{0.63}Ca_{0.37}MnO_{3} : Anomalous Temperature Dependence of Linewidth

We report the evolution of the Raman active A_g phonon modes in the charge-ordered manganite Pr_{0.63}Ca_{0.37}MnO_{3} as a function of temperature from 300K to 25K. Our studies reveal that the linewidths of A_g(2) and A_g(4) phonons increase as temperature decreases. This anomalous temperature dependence of phonon lineshapes, seen for the first time in charge ordered manganites, can be quantitatively understood in terms of strong spin-phonon coupling involving t_{2g} spins and A_g phonons.

cond-mat.str-el↗

Temperature-dependent electron paramagnetic resonance studies of charge ordered Nd_0.5Ca_0.5MnO_3

We report Electron Paramagnetic Resonance measurements on single crystalline and powder samples of Nd_0.5Ca_0.5MnO_3 across the charge-ordering transition at T_co=240 K down to the antiferromagnetic ordering transition at T_N = 140 K. The changes in the linewidth, g-factor and intensity as functions of temperature are studied to understand the nature of spin-dynamics in the system. We explain the observed large decrease in the linewidth from T_N to T_co in terms of motional narrowing caused by the hopping of the Jahn-Teller polarons yielding an activation energy of E_a = 0.13 eV. Similar analysis of data on Pr_0.6Ca_0.4MnO_3 published earlier gives E_a=0.2 eV. Below T_co, the g-value increases continuously suggesting a gradual strengthening of the orbital ordering. We give a qualitative explanation of the temperature dependence and of the maximum in the asymmetry ratio A/B observed at T_co in single crystal spectra which also supports the themodel of motional narrowing.

cond-mat.str-el↗

Origin of the unusual dependence of Raman D band on excitation wavelength in graphite-like materials

We have revisited the still unresolved puzzle of the dispersion of the Raman disordered-induced D band as a function of laser excitation photon energy E$_L$ in graphite-like materials. We propose that the D-mode is a combination of an optic phonon at the K-point in the Brillioun zone and an acoustic phonon whose momentum is determined uniquely by the double resonance condition. The fit of the experimental data with the double-resonance model yields the reduced effective mass of 0.025m$_{e}$ for the electron-hole pairs corresponding to the A$_{2}$ transition, in agreement with other experiments. The model can also explain the difference between $ω_S$ and $ω_{AS}$ for D and D$^{\star}$ modes, and predicts its dependence on the Raman excitation frequency.

cond-mat.dis-nn↗

An electron paramagnetic resonance study of Pr_{0.6}Ca_{0.4}MnO_{3} across the charge ordering transition

We report the first electron paramagnetic resonance studies of single crystals and powders of Pr_{0.6}Ca_{0.4}MnO_{3} in the 300-4.2 K range, covering the charge ordering transition at ~ 240 K and antiferromagnetic transition (T_N) at ~ 170 K. The asymmetry parameter for the Dysonian single crystal spectra shows anomalous increase at T_{co}. Below T_{co} the g-value increases continuously, suggesting a gradual strengthening of orbital ordering. The linewidth undergoes a sudden increase at T_{co} and continues to increase down to T_N. The intensity increases as the temperature is decreased till T_{co} due to the renormalization of magnetic susceptibility arising from the build up of ferromagnetic correlations. The value of the exchange constant, J, is estimated to be 154 K.

cond-mat.str-el↗