arXiv subjects

Rajesh Srivastava

Publications and source records attributed to Rajesh Srivastava.

5 recordsLinked to original sources

arXiv2026

Relativistic calculations of electron impact excitation cross-sections of neutral tungsten

Reliable tungsten spectroscopy is essential for modelling and diagnosing tungsten-containing plasmas, particularly in edge/divertor conditions where neutral tungsten (WI) is produced by sputtering and contributes to visible/near-UV emission. In this work, we present fine-structure-resolved EIE cross sections for W I computed using the relativistic distorted-wave (RDW) method. Target states are described by multi-configurational Dirac-Fock (MCDF)wave functions with an extensive configuration-interaction (CI) expansion including valence-valence and core-valence correlation through hole and deeper-core configurations. The resulting energies are bench marked against available theoretical results and the recommended values from the NIST database. Fine-structure-resolved cross sections are reported for excitations from the ground level 5d4 6s2 (5 D0) and six metastable levels 5d4 6s2 (5D1 , 5D2 , 5D3, 5D4 , 3P0) and 5d5 (6S)6s (7S3 ) into excited levels belonging primarily to the 5d4 6s(6 D)6p and 5d5 (6S)6p configurations, over incident electron energies from threshold to 500 eV. With the exception of a limited set of previously studied transitions, most of the reported fine-structure-resolved cross sections are presented here for the first time. The results show a strong dependence on the initial level and indicate that excitation from the metastable state yields the largest cross sections among the states considered, highlighting the importance of metastable populations in W I modelling. In addition, radiative transition probabilities for selected prominent transitions are calculated and compared with existing data. The present dataset is expected to be valuable for collisional-radiative modelling and spectroscopic diagnostics of tungsten plasmas in the 1-50 eV range.

physics.atom-ph↗

arXiv2025

Simulation study of neutral tungsten emissions for fusion applications

The article reports electron-impact excitation cross-sections and rate coefficients for neutral tungsten for three transitions (400.87 nm, 429.46 nm, and 430.21 nm) using the relativistic distorted wave approach within the flexible atomic code. Some of these lines are also observed in tokamak plasma. Cross-sections are computed for incident electron energy up to 30 keV. The energy levels in flexible atomic code were corrected to match the NIST database. The electron impact excitation rate coefficients are also provided.

physics.plasm-ph↗

arXiv2022

Two-dipole and three-dipole interaction coefficients of GROUP XII elements

The study of long-range interactions is increasingly becoming essential due to its various applications in cold atomic physics. These interactions can be conveniently expressed in terms of dispersion coefficients. In the present work, theoretical calculations have been carried out to estimate the two-dipole ($C_6$) and three-dipole ($C_9$) dispersion coefficients between the group XII atoms and their ions, \textit{viz.}, Zn, Cd, Hg, Zn$^+$, Cd$^+$, and Hg$^+$. To obtain these coefficients, the dynamic dipole polarizabilities and reduced matrix elements required are evaluated using the relativistic methods for both the considered atoms and ions. Further, using the calculated matrix elements, the oscillator strengths corresponding to leading transitions and static dipole polarizabilities are determined. These are compared with the available values in the literature through which the accuracy of the present calculations ascertains. However, the oscillator strengths for few transitions of Zn, Cd, Hg, Zn$^+$, Cd$^+$, and Hg$^+$, are not reported earlier, and we have provided their values in this work. Thereafter, the dispersion $C_6$ and $C_9$ coefficients are calculated for various combinations of the group XII elements, and most of these coefficients were not reported earlier in the literature. Furthermore, the combinations for which the other theoretical and experimental values were available for comparison showed good agreement. We, therefore, believe that our results reported for $C_6$ and $C_9$ coefficients for various combinations of group XII elements are reliable.

physics.atom-ph↗

arXiv2022

Dispersion $C_3$ coefficients for physisorption of heavy ions and atoms with graphene and carbon nanotubes

In the present work, the calculations have been performed for dispersion interaction between heavy elements (Zn$^+$, Cd$^+$, Hg$^+$, Pb$^+$, Zn, Cd, Hg, and Pb) with graphene and carbon nanotubes by evaluating van der Waals $C_3$ coefficients using well-known Lifshitz theory. The dispersion coefficients are expressed in terms of reflection coefficients of graphene and carbon nanotubes which are calculated within the framework of Dirac model. In addition, accurate values of dynamic dipole polarizabilities at imaginary frequencies of considered ions and atoms which are vital, have been calculated using relativistic methods. The comparisons of our calculated static dipole polarizabilities for the considered elements with the values reported in the literature are also presented. The dispersion interactions of the considered heavy elements with the graphene and carbon nanotubes of different radii in a wide range of separation distances have been studied. The results have also been analysed with another subtle variable, i.e., gap parameter of graphene wall. The interaction coefficients obtained for both the materials, i.e., for graphene and carbon nanotubes are mutually compared and it is found that graphene can be said as preferable material for adsorption of these toxic heavy elements.

physics.atom-ph↗

arXiv2020

Two-dipole and three-dipole dispersion coefficients for interaction of alkaline-earth atoms with alkaline-earth atoms and alkaline-earth ions

Apropos to the growing interest in the study of long-range interactions which for their applications in cold atom physics, we have performed theoretical calculation for the two-dipole $C_6$ and three-dipole $C_9$ dispersion coefficients involving alkaline-earth atoms with alkaline-earth atoms and alkaline-earth ions. The $C_6$ and $C_9$ coefficients are expressed in terms of the dynamic dipole polarizabilities, which are calculated using relativistic methods. Thereafter, the calculated $C_6$ coefficients for the considered alkaline-earth atoms among themselves are compared with the previously reported values. Due to unavailability of any other earlier theoretical or experimental results, for the $C_6$ coefficients for alkaline-earth atoms with alkaline-earth ions and the $C_9$ coefficients, we have performed separate fitting calculations and compared. Our calculations match in an excellent manner with the fitting calculations. We have also reported the oscillator strengths for the leading transitions and static dipole polarizabilities for the ground states of the alkaline-earth ions, i.e., Mg$^+$, Ca$^+$, Sr$^+$, and Ba$^+$ as well as the alkaline-earth atoms, i.e., Mg, Ca, Sr, and Ba. These, when compared with the available experimental results, show good agreement.

physics.atom-ph↗