arXiv subjects

Rajveer Jha

Publications and source records attributed to Rajveer Jha.

At least 55 records · Page 3Linked to original sources

arXiv2015

PdTe a 4.5K Type II BCS Superconductor

We report on the structure and physical properties of bulk Palladium Tellurium superconductor, which is synthesized via quartz vacuum encapsulation technique at 750 C. The as synthesized compound is crystallized in hexagonal crystal structure. Magnetization and Magneto-transport measurements provided the values of lower and upper critical field to be 250 and 1200 Gauss respectively at 2 Kelvin. The Coherence length and GL parameter are estimated from the experimentally determined upper and lower critical fields, which are 45 nm and 1.48 respectively. The jump in Cp(T) at Tc is found to be 1.33 and the Debye temperature and electronic specific heat constant are 203 Kelvin and 6.01mJ/mole-K2 respectively.

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arXiv2015

Effect of hydrostatic pressures on the superconductivity of new BiS2 based REO0.5F0.5BiS2 (RE-La, Pr and Nd) superconductors

We study the impact of hydrostatic pressure on superconductivity of new BiS2 based layered REO0.5F0.5BiS2 (RE-La, Pr, and Nd) compounds through the measurements of dc electrical resistivity. The REO0.5F0.5BiS2 (RE-La, Pr and Nd) compounds synthesized by solid state reaction route via vacuum encapsulation are crystallized in the tetragonal P4/nmm space group. At ambient pressure the superconducting transition onset temperatures are 2.7K, 3.5K and 4.5K which are enhanced substantially under external hydrostatic pressure to 10.5K, 7.8K and 7.5K for LaO0.5F0.5BiS2, PrO0.5F0.5BiS2 and NdO0.5F0.5BiS2 respectively at 1.68GPa. The normal state electrical resistivity decreases with applied pressure for REO0.5F0.5BiS2 (RE-La, Pr and Nd). The electrical resistivity under magnetic field and applied pressure has been measured to estimate upper critical field, the values of which are 15.9Tesla, 8.8Tesla and 8.2Tesla for LaO0.5F0.5BiS2, PrO0.5F0.5BiS2 and NdO0.5F0.5BiS2 compounds. Substantial enhancement of superconductivity under moderate pressures in studied new BiS2 based superconductors call for the attention of condensed matter physics community.

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arXiv2015

Appearance of bulk Superconductivity under Hydrostatic Pressure in Sr0.5RE0.5FBiS2 (RE = Ce, Nd, Pr and Sm) compounds

We report the appearance of superconductivity under hydrostatic pressure (0.35 to 2.5GPa) in Sr0.5RE0.5FBiS2 with RE = Ce, Nd, Pr and Sm. The studied compounds, synthesized by solid state reaction route, are crystallized in tetragonal P4/nmm space group. At ambient pressure though the RE = Ce exhibit the onset of superconductivity below 2.5K, the Nd, Pr and Sm samples are not superconducting down to 2K. With application of hydrostatic pressure (up to 2.5GPa), superconducting transition temperature is increased to around 10K for all the studied samples. The magneto-transport measurements are carried out on all the samples with maximum Tc i.e., at under 2.5GPa pressure and their upper critical fields are determined. The new superconducting compounds appear to be quite robust against magnetic field but within Pauli paramagnetic limit. The new superconducting compounds with various RE (Ce, Nd, Pr and Sm) belonging to Sr0.5La0.5FBiS2 family are successfully synthesized for the first time and superconductivity is induced in them under hydrostatic pressure.

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arXiv2014

Role of MgO impurity on the superconducting properties of MgB2

We address the effect of MgO impurity on the superconducting properties of MgB2. The synthesis of MgB2 is very crucial because of sensitivity of Mg to oxidation which may lead to MgO as a secondary phase. Rietveld refinement was performed to determine the quantitative volume fraction of MgO in the samples synthesized by two different techniques. Both the samples were subjected to magnetization measurements under dc and ac applied magnetic fields and the observed results were compared as a function of temperature. Paramagnetic Meissner effect has been observed in a sample of MgB2 having more amount of MgO (with Tc = 37.1K) whereas the pure sample MgB2 having minor quantity of MgO shows diamagnetic Meissner effect with Tc = 38.8K. M-H measurements at 10K reveal a slight difference in irreversibility field which is due to MgO impurity along with wide transition observed from ac magnetic susceptibility measurements. The magnetotransport measurements R(T)H using RN = 90%, 50% and 10% criterion on pure sample of MgB2 has been used to determine the upper critical field whereas the sample having large quantity of MgO does not allow these measurements due to its high resistance.

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arXiv2014

Hydrostatic Pressure Studies on Parent Phase SrFBiS2 of BiS2-based Superconducting Family

In the present work, we measure the temperature dependent electrical resistivity from 300K down to 2K under applied hydrostatic pressure of upto 2.5GPa for SrFBiS2, which is the parent compound for the BiS2 based superconductors. Though the normal state resistivity of the compound decreases with pressure, the same is not superconducting down to 2K under applied pressure of up to 2.5Gpa.

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arXiv2014

Superconductivity at 4K in Pd deficient layered Ta_2Pd_xS_6

Here in this short note, we report on the low dimensional 4d and 5d transition metals-chalcogenide based compounds i.e., Ta2PdxS6, showing semiconducting to superconducting transition around 4K with upper critical field outside Pauli paramagnetic limit. It seems couple of different superconducting phases do exist in these new set of compounds. Our short note in this regards is thought provoking, asking to explore various unearthed possible superconducting phases in (Nb/Ta)2Pdx(S/Se/Te)y systems.

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arXiv2014

Superconductivity at 25K under hydrostatic pressure for FeTe0.5Se0.5 superconductor

We report the impact of hydrostatic pressure on the superconductivity and normal state resistivity of FeTe0.5Se0.5 superconductor. At the ambient pressure the FeTe0.5Se0.5 compound shows the superconducting transition temperature Tconset at above 13K and TcR=0 at 11.5K. We measure pressure dependent resistivity from 250K to 5K, which shows that the normal state resistivity increases initially for the applied pressures of up to 0.55GPa and then the same is decreased monotonically with increasing pressure of up to 1.97GPa. On the other hand the superconducting transition temperatures (Tconset and TcR=0) increase monotonically with increasing pressure. Namely the Tconset increases from 13K to 25K and TcR=0 from 11.5K to 20K for the pressures range of 0-1.97GPa. Our results suggest that superconductivity in this class of Fe-based compounds is very sensitive to pressure as the estimated pressure coefficient dTc(onset)/dP is 5.8K/GPa. It may be suggested that FeTe0.5Se0.5 superconductor is a strong electron correlated system. The enhancement of Tc with applying pressure is mainly attributed to an increase of charge carriers at Fermi surface.

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arXiv2014

Significant enhancement of superconductivity under hydrostatic pressure in CeO0.5F0.5BiS2 superconductor

We report the effect of hydrostatic pressure (0-1.97GPa) on the superconductivity of BiS2 based CeO0.5F0.5BiS2 compound. The CeO0.5F0.5BiS2 superconductor was synthesized by the solid state reaction route and the compound is crystallized in tetragonal P4/nmm space group. The studied compound shows superconductivity with transition temperature of 2.5K (Tconset) at ambient pressure, which has been enhanced to 8 K at applied pressure of 1.97 GPa. The observed normal resistivity exhibited semiconducting behavior. The data of normal state resistivity R(T) has been fitted by activation type equation and it is found that the energy gap is significantly reduced with pressure. Resistivity measurements under magnetic field for the highest applied pressure of 1.97GPa (Tconset = 8K) exhibits the upper critical field of above 5Tesla. The observation of fourfold increase in Tc accompanied with improved normal state conduction under hydrostatic pressure on CeO0.5F0.5BiS2 superconductor calls for the attention of solid state physics community.

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arXiv2014

Magnetotransport studies of FeSe under hydrostatic pressure

The discoveries of iron-based superconductors with relatively high transition temperature are under intense experimental and theoretical investigation. Here we present magnetotransport measurements on FeSe superconductor under hydrostatic pressure. We show that in Fe-deficient tetragonal FeSe binary compound, the onset of superconducting transition is almost doubled under 1.98GPa pressure and the estimated upper critical field of 26.7Tesla is increased to 47.5Tesla.

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arXiv2014

Robust superconductivity with large upper critical field in Nb2PdS5

We report synthesis, structural details and complete superconducting characterization of very recently discovered Nb2PdS5 new superconductor. The synthesized compound is crystallized in mono-clinic structure. Bulk superconductivity is seen in both magnetic susceptibility and electrical resistivity measurements with superconducting transition temperature (Tc) at 6K. The upper critical field (Hc2), being estimated from high field magneto-transport measure-ments is above 240kOe. The estimated Hc2(0) is clearly above the Pauli paramagnetic limit. Heat capacity measurements show clear transition with well defined peak at Tc, but with lower jump than as expected for a BCS type superconductor. The Sommerfield constant and Debye temperature as determined from low temperature fitting of heat capacity data are 32mJ/moleK2 and 263K respectively. Hall coefficients and resistivity in conjugation with electronic heat capacity indicates multiple gap superconductivity signatures in Nb2PdS5. We also studied the impact of hydrostatic pressure on superconductivity of Nb2PdS5 and found nearly no change in Tc for the given pressure range.

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arXiv2014

Impact of hydrostatic pressure on superconductivity of Sr0.5La0.5FBiS2

We report the impact of hydrostatic pressure (0-1.97GPa) on superconductivity of recently discovered 2K superconductor Sr0.5La0.5FBiS2. Resistivity under pressure measurements are performed by using HPC-33 Piston type pressure cell with Quantum design DC resistivity Option. The superconducting transition temperature (Tc) is increased by 5 fold to around 10K with just above 1GPa pressure, which remains nearly unaltered for studied higher pressures of up to 1.97GPa. The fivefold increase in Tc of Sr0.5La0.5FBiS2 with just above 1GPa pressure suggests very strong electron correlations in these systems and the same calls for the attention of solid state physics community.

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arXiv2014

Superconducting properties of BiS2 based superconductor NdO1-xFxBiS2 (x=0 to 0.9)

We report the phase diagram of NdO1-xFxBiS2 (x=0.1, 0.3, 0.5, 0.7, 0.9) compound. The samples synthesized by the vacuum encapsulation technique are crystallized in a tetragonal P4/nmm space group. The superconductivity of all samples is confirmed by DC magnetic susceptibility and electrical transport measurements. The maximum Tc of 5.25K is seen for x = 0.7 sample. The upper critical field is calculated from magneto transport measurements. The Thermal activated flux flow - TAFF studies are also carried out. Hall measurements show that electrons are the dominating charge carriers in these systems.

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arXiv2014

Effect of Se doping in recently discovered layered Bi4O4S3 Superconductor

We report suppression of superconductivity in Bi4O4S3 compound by Se doping at S site. Bulk polycrystalline samples are synthesized by solid state reaction route. The Rietveld refined of XRD data of all the studied samples show that the same are crystallized in tetragonal I4/mmm space group with slightly increased c lattice constant with the Se doping. Superconductivity is observed at below 4.5 K in both dc magnetization and resistivity with temperature measurements for all Bi4O4S3-xSex (x = 0, 0.03, 0.09 and 0.15) samples, though the same is decreased slightly with increase in Se content. The upper critical field of the Bi4O4S3 is estimated from resistivity under magnetic field [R(T)H] measurements of up to 2T (Tesla), and the same decreases for Se doped samples. The flux flow activation energies being obtained by fitting to the the Arrhenius equation are 18.60 meV for Bi4O4S3, 13.69 meV for Bi4O4S2.97Se0.03 and 13.16 meV for Bi4O4S2.85Se0.15 samples in applied magnetic field of 200 Oe. In conclusion the S site Se substitution showed detrimental effect on superconductivity of Bi4O4S3.

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arXiv2014

Superconductivity in layered CeO0.5F0.5BiS2

We report appearance of superconductivity in CeO0.5F0.5BiS2. The bulk polycrystalline samples CeOBiS2 and CeO0.5F0.5BiS2 are synthesized by conventional solid state reaction route via vacuum encapsulation technique. Detailed structural analysis showed that the studied CeO0.5F0.5BiS2 compound is crystallized in tetragonal P4/nmm space group with lattice parameters a = 4.016(3) A, c = 13.604(2) A. DC magnetization measurement (MT-curve) shows the ferromagnetic signal at the low temperature region. The superconductivity is established in CeO0.5F0.5BiS2 at Tconset = 2.5K by electrical transport measurement. Under applied magnetic field both Tc onset and Tc (ρ =0) decrease to lower temperatures and an upper critical field [Hc2(0)] above 1.2Tesla is estimated. The results suggest coexistence of ferromagnetism and superconductivity for the CeO0.5F0.5BiS2 sample.

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arXiv2014

Revisiting heat capacity of bulk polycrystalline YBa2Cu3O7-δ

In this letter, we present the superconducting property characterization of a phase pure reasonably good quality YBa2Cu3O7-δ sample. Studied compound is crystallized in orthorhombic Pmmm space group with lattice parameters a, b, and c are 3.829(2) Å, 3.887(1) Å and 11.666(3) Å respectively. Bulk superconductivity is observed below 90K as evidenced by resistivity and dc/ac magnetization measurements. The resistivity under magnetic field (ρTH) measurements showed clearly both the intra-grain and inter-grain transitions, which are supplemented by detailed (varying frequency and amplitude) ac susceptibility studies as well. The upper critical field at 0K i.e., Hc2(0) being determined from ρTH measurements with 50% criteria of resistivity drope is ~ 70 Tesla. Studied polycrystalline YBa2Cu3O7-δ is subjected to detailed heat capacity (CP) studies. Cp exhibited well defined anomaly at below 90 K, which decreases with applied field. Though the Cp anomaly/peak at Tc reduces with applied field, the same is not completely suppressed in high applied fields of up to 12 Tesla. The Sommerfeld constant (γ) and Debye temperature (ΘD) as determined from low temperature fitting of CP(T) data to Sommerfeld-Debye model, are 10.65 mJ/mole-K2 and 312.3 K respectively. The results are compared with existing literature on bulk polycrystalline superconducting YBa2Cu3O7-δ sample

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arXiv2014

Superconducting and magneto-transport properties of BiS2 based superconductor PrO1-xFxBiS2 (x = 0 to 0.9)

We report superconducting properties of PrO1-xFxBiS2 compounds, synthesized by the vacuum encapsulation technique. The synthesized PrO1-xFxBiS2 (x=0.1, 0.3, 0.5, 0.7 and 0.9) samples are crystallized in a tetragonal P4/nmm space group. Both transport and DC magnetic susceptibility measurements showed bulk superconductivity below 4 K. The maximum Tc is obtained for x = 0.7 sample. Under applied magnetic field both Tc onset and Tc (R =0) decrease to lower temperatures. We estimated highest upper critical field [Hc2(0)] for PrO0.3F0.7BiS2 sample to be above 4 T (Tesla). The thermally activated flux flow (TAFF) activation energy (U0) is estimated 54.63 meV in 0.05 Tesla field for PrO0.3F0.7BiS2 sample. Hall measurement results showed that electron charge carriers are the dominating ones in these compounds. Thermoelectric effects (Thermal conductivity and Seebeck coefficient) data suggest strong electron-electron correlations in this material.

cond-mat.supr-con↗

arXiv2013

Impact of Gd doping on morphology and superconductivity of NbN sputtered thin films

We report effect of Gd inclusion in the NbN superconductor thin films. The films are deposited on single crystalline Silicon (100) by DC reactive sputtering technique i.e., deposition of Nb and Gd in presence of reactive N2 gas. The fabricated relatively thick films (400 nm) are crystallized in cubic structure. These films are characterized for their morphology, elemental analysis and roughness by Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectroscopy (EDAX) and Atomic Force Microscopy (AFM) respectively. The optimized film (maximum Tc) is achieved with gas ratio of Ar:N2 (80:20) for both pristine and Gd doped films. The optimized NbN film possesses Tc (R=0) in zero and 140kOe fields are at 14.8K and 8.8K respectively. The Gd doped NbN film showed Tc (R=0) in zero and 130kOe fields at 11.2K and 6.8 K respectively. The upper critical field Hc2(0) of the studied superconducting films is calculated from the magneto-transport [R(T)H] measurements using GL equations. It is found that Gd doping deteriorated the superconducting performance of NbN.

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arXiv2013

Hydrostatic pressures dependence of superconductivity in PrO0.5F0.5BiS2 superconductor

In this communication, we report the temperature dependence (3 to 300K) of the electrical resistivity of BiS2 based layered PrO0.5F0.5BiS2 superconductor at ambient and hydrostatic pressure of up to 3GPa. It is observed that Tc increases with pressure at the rate of dTc/dP=0.45/GPa for PrO0.5F0.5BiS2 compound. It is envisaged that one may increase the Superconducting transition temperature (Tc) of recently discovered PrO0.5F0.5BiS2 superconductor by applying hydrostatic external or internal chemical pressure via suitable on site substitutions.

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