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Ramin Golestanian

Publications and source records attributed to Ramin Golestanian.

At least 55 records · Page 3Linked to original sources
arXiv2024

Chemotactic particles as strong electrolytes: Debye-Hückel approximation and effective mobility law

We consider a binary mixture of chemically active particles, that produce or consume solute molecules, and that interact with each other through the long-range concentrations fields they generate. We analytically calculate the effective phoretic mobility of these particles when the mixture is submitted to a constant, external concentration gradient, at leading order in the overall concentration. Relying on a analogy with the modeling of strong electrolytes, we show that the effective phoretic mobility decays with the square-root of the concentration: our result is therefore a nonequilibrium counterpart to the celebrated Kohlrausch and Debye-Hückel-Onsager conductivity laws for electrolytes, which are extended here to particles with long-range nonreciprocal interactions. The effective mobility law we derive reveals the existence of a regime of maximal mobility, and could find applications in the description of nanoscale transport phenomena in living cells.

cond-mat.soft↗
arXiv2024

Molecular Dynamics Simulations of Microscopic Structural Transition and Macroscopic Mechanical Properties of Magnetic Gels

Magnetic gels with embedded micro/nano-sized magnetic particles in crosslinked polymer networks can be actuated by external magnetic fields, with changes in their internal microscopic structures and macroscopic mechanical properties. We investigate the responses of such magnetic gels to an external magnetic field, by means of coarse-grained molecular dynamics simulations. We find that the dynamics of magnetic particles are determined by the interplay of between magnetic dipole-dipole interactions, polymer elasticity and thermal fluctuations. The corresponding microscopic structures formed by the magnetic particles such as elongated chains can be controlled by the external magnetic field. Furthermore, the magnetic gels can exhibit reinforced macroscopic mechanical properties, where the elastic modulus increases algebraically with the magnetic moments of the particles in the form of $\propto(m-m_{\mathrm{c}})^{2}$ when magnetic chains are formed. This simulation work can not only serve as a tool for studying the microscopic and the macroscopic responses of the magnetic gels, but also facilitate future fabrications and practical controls of magnetic composites with desired physical properties.

cond-mat.soft↗
arXiv2024

Dynamical theory of topological defects II: Universal aspects of defect motion

We study the dynamics of topological defects in continuum theories governed by a free energy minimization principle, building on our recently developed framework [Romano J, Mahault B and Golestanian R 2023 J. Stat. Mech.: Theory Exp. 083211]. We show how the equation of motion of point defects, domain walls, disclination lines and any other singularity can be understood with one unifying mathematical framework. For disclination lines, this also allows us to study the interplay between the internal line tension and the interaction with other lines. This interplay is non-trivial, allowing defect loops to expand, instead of contracting, due to external interaction. We also use this framework to obtain an analytical description of two long-lasting problems in point defect motion, namely the scale dependence of the defect mobility and the role of elastic anisotropy in the motion of defects in liquid crystals. For the former, we show that the effective defect mobility is strongly problem-dependent, but it can be computed with high accuracy for a pair of annihilating defects. For the latter, we show that at the first order in perturbation theory, anisotropy causes a non-radial force, making the trajectory of annihilating defects deviate from a straight line. At higher orders, it also induces a correction in the mobility, which becomes non-isotropic for the $+1/2$ defect. We argue that, due to its generality, our method can help to shed light on the motion of singularities in many different systems, including driven and active non-equilibrium theories.

cond-mat.soft↗
arXiv2024

Scale-dependent heat transport in dissipative media via electromagnetic fluctuations

We develop a theory for heat transport via electromagnetic waves inside media, and use it to derive a spatially nonlocal thermal conductivity tensor, in terms of the electromagnetic Green's function and potential, for any given system. While typically negligible for optically dense bulk media, the electromagnetic component of conductivity can be significant for optically dilute media, and shows regimes of Fourier transport as well as unhindered transport. Moreover, the electromagnetic contribution is relevant even for dense media, when in presence of interfaces, as exemplified for the in-plane conductivity of a nanosheet, which shows a variety of phenomena, including absence of a Fourier regime.

physics.class-ph↗
arXiv2024

Nonreciprocal collective dynamics in a mixture of phoretic Janus colloids

A multicomponent mixture of Janus colloids with distinct catalytic coats and phoretic mobilities is a promising theoretical system to explore the collective behavior arising from nonreciprocal interactions. An active colloid produces (or consumes) chemicals, self-propels, drifts along chemical gradients, and rotates its intrinsic polarity to align with a gradient. As a result the connection from microscopics to continuum theories through coarse-graining couples densities and polarization fields in unique ways. Focusing on a binary mixture, we show that these couplings render the unpatterned reference state unstable to small perturbations through a variety of instabilities including oscillatory ones which arise on crossing an exceptional point or through a Hopf bifurcation. For fast relaxation of the polar fields, they can be eliminated in favor of the density fields to obtain a microscopic realization of the Nonreciprocal Cahn-Hilliard model for two conserved species with two distinct sources of non-reciprocity, one in the interaction coefficient and the other in the interfacial tension. Our work establishes Janus colloids as a versatile model for a bottom-up approach to both scalar and polar active mixtures.

cond-mat.soft↗
arXiv2024

Hydrodynamic efficiency limit on a Marangoni surfer

A Marangoni surfer is an object embedded in a gas-liquid interface, propelled by gradients in surface tension. We derive an analytical theorem for the lower bound on the viscous dissipation by a Marangoni surfer in the limit of small Reynolds and capillary numbers. The minimum dissipation can be expressed with the reciprocal difference between drag coefficients of two passive bodies of the same shape as the Marangoni surfer, one in a force-free interface and the other in an interface with surface incompressibility. The distribution of surface tension that gives the optimal propulsion is given by the surface tension of the solution for the incompressible surface and the flow is a superposition of both solutions. For a surfer taking the form of a thin circular disk, the minimum dissipation is $16μa V^2$, giving a Lighthill efficiency of $1/3$. This places the Marangoni surfers among the hydrodynamically most efficient microswimmers.

physics.flu-dyn↗
arXiv2024

Anomalous fluctuations in a droplet of chemically active colloids or enzymes

Chemically active colloids or enzymes cluster into dense droplets driven by their phoretic response to collectively generated chemical gradients. Employing Brownian dynamics simulation techniques, our study of the dynamics of such a chemically active droplet uncovers a rich variety of structures and dynamical properties, including the full range of fluid-like to solid-like behaviour, and non-Gaussian positional fluctuations. Our work sheds light on the complex dynamics of the active constituents of metabolic clusters, which are the main drivers of non-equilibrium activity in living systems.

cond-mat.soft↗
arXiv2023

Enhanced diffusion of tracer particles in nonreciprocal mixtures

We study the diffusivity of a tagged particle in a binary mixture of Brownian particles with non-reciprocal interactions. Numerical simulations reveal that, for a broad class of interaction potentials, non-reciprocity can significantly increase the effective diffusion coefficient of tracer particles, and that this diffusion enhancement is associated with a breakdown of the Einstein relation. These observations are quantified and confirmed via two different and complementary analytical approaches: (i) a linearized stochastic density field theory, which is particularly accurate in the limit of soft interactions; (ii) a reduced two-body description, which is exact at leading order in the density of particles. The latter reveals that diffusion enhancement can be attributed to the formation of transiently propelled dimers of particles, whose cohesion and speed are controlled by the non-reciprocal interactions.

cond-mat.soft↗
arXiv2023

Mutual information as a measure of mixing efficiency in viscous fluids

Because of the kinematic reversibility of the Stokes equation, fluid mixing at the microscale requires an interplay between advection and diffusion. Here we introduce mutual information between particle positions before and after mixing as a measure of mixing efficiency. We demonstrate its application in a Couette flow in an annulus and show that non-uniform rotation sequences can lead to more efficient mixing. We also determine mutual information from Brownian dynamics simulations using data compression algorithms. Our results show that mutual information provides a universal and assumption-free measure of mixing efficiency in microscale flows.

physics.flu-dyn↗
arXiv2023

Entropy production and thermodynamic inference for stochastic microswimmers

The question of characterization of the degree of non-equilibrium activity in active matter systems is studied in the context of a stochastic microswimmer model driven by a chemical cycle. The resulting dynamical properties and entropy production rate unravel a complex interplay between the chemical and the hydrodynamic degrees of freedom beyond linear response, which is not captured by conventional phenomenological approaches. By studying the precision-dissipation trade-off, a new protocol is proposed in which microscopic chemical driving forces can be inferred experimentally. Our findings highlight subtleties associated with the stochastic thermodynamics of autonomous microswimmers.

cond-mat.stat-mech↗
arXiv2023

A DNA turbine powered by a transmembrane potential across a nanopore

Rotary motors play key roles in energy transduction, from macroscale windmills to nanoscale turbines such as ATP synthase in cells. Despite our capabilities to construct engines at many scales, developing functional synthetic turbines at the nanoscale has remained challenging. Here, we experimentally demonstrate rationally designed nanoscale DNA-origami turbines with three chiral blades. These DNA nanoturbines are 24-27 nm in height and diameter and can utilise transmembrane electrochemical potentials across nanopores to drive DNA bundles into sustained unidirectional rotations of up to 10 revolutions/s. The rotation direction is set by the designed chirality of the turbine. All-atom molecular dynamics simulations show how hydrodynamic flows drive this turbine. At high salt concentrations, the rotation direction of turbines with the same chirality is reversed, which is explained by a change in the anisotropy of the electrophoretic mobility. Our artificial turbines operate autonomously in physiological conditions, converting energy from naturally abundant electrochemical potentials into mechanical work. The results open new possibilities for engineering active robotics at the nanoscale.

physics.bio-ph↗
arXiv2023

Dynamical pattern formation without self-attraction in quorum-sensing active matter: the interplay between nonreciprocity and motility

We study a minimal model involving two species of particles interacting via quorum-sensing rules. Combining simulations of the microscopic model and linear stability analysis of the associated coarse-grained field theory, we identify a mechanism for dynamical pattern formation that does not rely on the standard route of intra-species effective attractive interactions. Instead, our results reveal a highly dynamical phase of chasing bands induced only by the combined effects of self-propulsion and nonreciprocity in the inter-species couplings. Turning on self-attraction, we find that the system may phase separate into a macroscopic domain of such chaotic chasing bands coexisting with a dilute gas. We show that the chaotic dynamics of bands at the interfaces of this phase-separated phase results in anomalously slow coarsening.

cond-mat.stat-mech↗
arXiv2023

Lorentz Reciprocal Theorem in Fluids with Odd Viscosity

The Lorentz reciprocal theorem -- that is used to study various transport phenomena in hydrodynamics -- is violated in chiral active fluids that feature odd viscosity with broken time-reversal and parity symmetries. Here we show that the theorem can be generalized to fluids with odd viscosity by choosing an auxiliary problem with the opposite sign of the odd viscosity. We demonstrate the application of the theorem to two categories of microswimmers. Swimmers with prescribed surface velocity are not affected by odd viscosity, while those with prescribed active forces are. In particular, a torque-dipole can lead to directed motion.

cond-mat.soft↗
arXiv2023

Scaling transition of active turbulence from two to three dimensions

Turbulent flows are observed in low-Reynolds active fluids. They are intrinsically different from the classical inertial turbulence and behave distinctively in two- and three-dimensions. Understanding the behaviors of this new type of turbulence and their dependence on the system dimensionality is a fundamental challenge in non-equilibrium physics. We experimentally measure flow structures and energy spectra of bacterial turbulence between two large parallel plates spaced by different heights $H$. The turbulence exhibits three regimes as H increases, resulting from the competition of bacterial length, vortex size and H. This is marked by two critical heights ($H_0$ and $H_1$) and a $H^{0.5}$ scaling law of vortex size in the large-$H$ limit. Meanwhile, the spectra display distinct universal scaling laws in quasi-two-dimensional (2D) and three-dimensional (3D) regimes, independent of bacterial activity, length and $H$, whereas scaling exponents exhibit transitions in the crossover. To understand the scaling laws, we develop a hydrodynamic model using image systems to represent the effect of no-slip confining boundaries. This model predicts universal 1 and -4 scaling on large and small length scales, respectively, and -2 and -1 on intermediate length scales in 2D and 3D, respectively, which are consistent with the experimental results. Our study suggests a framework for investigating the effect of dimensionality on non-equilibrium self-organized systems.

cond-mat.soft↗
arXiv2023

Hydrodynamics of an odd active surfer in a chiral fluid

We theoretically and computationally study the low-Reynolds-number hydrodynamics of a linear active microswimmer surfing on a compressible thin fluid layer characterized by an odd viscosity. Since the underlying three-dimensional fluid is assumed to be very thin compared to any lateral size of the fluid layer, the model is effectively two-dimensional. In the limit of small odd viscosity compared to the even viscosities of the fluid layer, we obtain analytical expressions for the self-induced flow field, which includes non-reciprocal components due to the odd viscosity. On this basis, we fully analyze the behavior of a single linear swimmer, finding that it follows a circular path, the radius of which is, to leading order, inversely proportional to the magnitude of the odd viscosity. In addition, we show that a pair of swimmers exhibits a wealth of two-body dynamics that depends on the initial relative orientation angles as well as on the propulsion mechanism adopted by each swimmer. In particular, the pusher-pusher and pusher-puller-type swimmer pairs exhibit a generic spiral motion, while the puller-puller pair is found to either co-rotate in the steady state along a circular trajectory or exhibit a more complex chaotic behavior resulting from the interplay between hydrodynamic and steric interactions. Our theoretical predictions may pave the way toward a better understanding of active transport in active chiral fluids with odd viscosity, and may find potential applications in the quantitative microrheological characterization of odd-viscous fluids.

cond-mat.soft↗
arXiv2023

Energetic cost of microswimmer navigation: the role of body shape

We study the energetic efficiency of navigating microswimmers by explicitly taking into account the geometry of their body. We show that, as their shape transitions from prolate to oblate, non-steering microswimmers rotated by flow gradients naturally follow increasingly time-optimal trajectories. At the same time, they also require larger dissipation to swim. The coupling between body geometry and hydrodynamics thus leads to a generic trade-off between the energetic costs associated with propulsion and navigation, which is accompanied by the selection of a finite optimal aspect ratio. We derive from optimal control theory the steering policy ensuring overall minimum energy dissipation, and characterize how navigation performances vary with the swimmer shape. Our results highlight the important role of the swimmer geometry in realistic navigation problems.

cond-mat.soft↗
arXiv2023

Dynamical theory of topological defects I: the multivalued solution of the diffusion equation

Point-like topological defects are singular configurations that occur in a variety of in and out of equilibrium systems with two-dimensional orientational order. As they are associated with a nonzero circuitation condition, the presence of defects induces a long-range perturbation of the orientation landscape around them. The effective dynamics of defects is thus generally described in terms of quasi-particles interacting through the orientation field they produce, whose evolution in the simplest setting is governed by the diffusion equation. Due to the multivalued nature of the orientation field, its expression for a defect moving with an arbitrary trajectory cannot be obtained straightforwardly and is often evaluated in the quasi-static approximation. Here, we instead propose an approach that allows to derive the exact expression for the orientation created by multiple moving defects, which we find to depend on their past trajectories and thus to be nonlocal in time. Performing various expansions in relevant regimes, we show how improved approximations with respect to the quasi-static defect solution can be obtained. Moreover, our results lead to so far unnoticed structures in the orientation field of moving defects which we discuss in light of existing experimental results.

cond-mat.stat-mech↗
arXiv2023

Axisymmetric monopole and dipole flow singularities in proximity of a stationary no-slip plate immersed in a Brinkman fluid

Green's function plays an important role in many areas of physical sciences and is a prime tool for solving diverse hydrodynamic equations in the linear regime. In the present contribution, the axisymmetric low-Reynolds-number Brinkman flow induced by monopole and dipole singularities in proximity of a stationary plate of circular shape is theoretically investigated. The flow singularities are directed along the central axis of the plate. No-slip boundary conditions are assumed to hold at the surface of the plate. The Green's functions are determined to a large extent analytically, reducing the solution of the linear hydrodynamic equations to well-behaved one-dimensional integrals amenable to numerical computation. In our approach, the Brinkman flow problem is formulated as a mixed boundary value problem that is subsequently mapped in the form of dual integral equations on the domain boundaries. Thereupon, the solution of the equations of fluid motion is eventually reduced to the solution of two independent Fredholm integral equations of the first kind. The overall flow structure and emerging eddy patterns are found to strongly depend on the magnitude of the relevant geometrical and physical parameters of the system. Moreover, the effect of the confining plate on the dynamics of externally driven or force-free particles is assessed through the calculation of the relevant hydrodynamic reaction functions. The effect of the plate on the locomotory behavior of a self-propelling active dipole swimmer is shown to be maximum when the radius of the plate is comparable to the distance separating the swimmer from the plate. Our results may prove useful for characterizing transport processes in microfluidic devices and may pave the way toward understanding and controlling of small-scale flows in porous media.

cond-mat.soft↗