arXiv subjects
Publications and source records attributed to Randall D. Kamien.
Boundary effects in liquid-crystalline phases can be large due to long-ranged orientational correlations. We show that the chiral hexatic phase can be locked into an apparent three-dimensional N+6 phase via such effects. Simple numerical estimates suggest that the recently discovered "polymer hexatic" may actually be this locked phase.
Large twist-angle grain boundaries in layered structures are often described by Scherk's first surface whereas small twist-angle grain boundaries are usually described in terms of an array of screw dislocations. We show that there is no essential distinction between these two descriptions and that, in particular, their comparative energetics depends crucially on the core structure of their screw-dislocation topological defects.
We calculate the second and third virial coefficients of the effective sphere-sphere interaction due to polymer depletion. By utilizing the anisotropy of a typical polymer conformation, we can consider polymers that are roughly the same size as the spherical inclusions. We argue that recent experiments can confirm this anisotropy.
In the hexagonal columnar phase of chiral polymers a bias towards cholesteric twist competes with braiding along an average direction. When the chirality is strong, topological defects proliferate, leading to either a tilt grain boundary phase or a new ``moire state'' with twisted bond order. This moire phase can melt leading to a new phase: the chiral hexatic. I will discuss some recent experimental results from the NIH on DNA liquid crystals in the context of these theories.
We study force-free configurations of Abrikosov flux lines in the line-liquid and line-crystal limit, near the melting transition at H_m. We show that the condition for zero force configurations can be solved by appealing to the structure of chiral liquid crystalline phases.
Molecular chirality leads to a wonderful variety of equilibrium structures, from the simple cholesteric phase to the twist-grain-boundary phases, and it is responsible for interesting and technologically important materials like ferroelectric liquid crystals. This paper will review some recent advances in our understanding of the connection between the chiral geometry of individual molecules and the important phenomenological parameters that determine macroscopic chiral structure. It will then consider chiral structure in columnar systems and propose a new equilibrium phase consisting of a regular lattice of twisted ropes.
We present an elastic model of B-form DNA as a stack of thin, rigid plates or base pairs that are not permitted to deform. The symmetry of DNA and the constraint of plate rigidity limit the number of bulk elastic constants contributing to a macroscopic elasticity theory of DNA to four. We derive an effective twist-stretch energy in terms of the macroscopic stretch epsilon along and relative excess twist sigma about the DNA molecular axis. In addition to the bulk stretch and twist moduli found previously, we obtain a twist-stretch modulus with the following remarkable properties: 1) it vanishes when the radius of the helical curve following the geometric center of each plate is zero, 2) it vanishes with the elastic constant K_{23} that couples compression normal to the plates to a shear strain, if the plates are perpendicular to the molecular axis, and 3) it is nonzero if the plates are tilted relative to the molecular axis. This implies that a laminated helical structure carved out of an isotropic elastic medium will not twist in response to a stretching force, but an isotropic material will twist if it is bent into the shape of a helix.
We map self-avoiding random walks with a chemical potential for writhe to the three-dimensional complex O(N) Chern-Simons theory as N -> 0. We argue that at the Wilson-Fisher fixed point which characterizes normal self-avoiding walks (with radius of gyration exponent nu = 0.588) a small chemical potential for writhe is irrelevant and the Chern-Simons field does not modify the monomer- monomer correlation function. For a large chemical potential the polymer collapses.
We present an alternative local definition of the writhe of a self-avoiding closed loop which differs from the traditional non-local definition by an integer. When studying dynamics this difference is immaterial. We employ a formula due to Aldinger, Klapper and Tabor for the change in writhe and propose a set of local, link preserving dynamics in an attempt to unravel some puzzles about actin.
I propose a double-twist texture with local smectic order, which may have been seen in recent experiments. As in the Renn-Lubensky TGB phase, the smectic order is broken only through a lattice of screw dislocations. A melted lattice of screw dislocations can produce a double-twist texture as can an unmelted lattice. In the latter case I show that geometry only allows for certain angles between smectic regions. I discuss the possibility of connecting these double-twist tubes together to form a smectic blue phase.
We present a microscopic analysis of the instability of the nematic phase to chirality when molecular chirality is introduced perturbatively. We show that previously neglected short-range biaxial correlations play a crucial role in determining the cholesteric pitch. We propose an order parameter which quantifies the chirality of a molecule.
We consider a smectic-A* in a capillary with surface anchoring that favors parallel alignment. If the bulk phase of the smectic is the standard twist-grain-boundary phase of chiral smectics, then there will be a critical radius below which the smectic will not have any topological defects. Above this radius a single screw dislocation in the center of the capillary will be favored. Along with surface anchoring, a magnetic field will also suppress the formation of a screw dislocation. In this note, we calculate the critical field at which a defect is energetically preferred as a function of the surface anchoring strength and the capillary radius. Experiments at a few different radii could thus determine the anchoring strength.
We present a Monte Carlo simulation of a polymer nematic for varying volume fractions, concentrating on the structure function of the sample. We achieve nematic ordering with stiff polymers made of spherical monomers that would otherwise not form a nematic state. Our results are in good qualitative agreement with theoretical and experimental predictions, most notably the bowtie pattern in the static structure function.
The symmetries of the DNA double helix require a new term in its linear response to stress: the coupling between twist and stretch. Recent experiments with torsionally-constrained single molecules give the first direct measurement of this important material parameter. We extract its value from a recent experiment of Strick, et al. and find rough agreement with an independent experimental estimate recently given by Marko. We also present a very simple microscopic theory predicting a value comparable to the one observed.
The symmetries of the DNA double helix require a new term in its linear response to stress: the coupling between twist and stretch. Recent experiments with torsionally-constrained single molecules give the first direct measurement of this important material parameter. We extract its value from a recent experiment of Strick et al. [Science 271 (1996) 1835] and find rough agreement with an independent experimental estimate recently given by Marko. We also present a very simple microscopic theory predicting a value comparable to the one observed.
Recent experiments on aligned DNA show hexatic order with no sign of macroscopic chirality. I make the analogy between smectic liquid crystals and chiral hexatics and show how the absence of chirality cannot occur in a thermodynamic phase of chiral molecules. In addition, I discuss the microscopic origin of chiral mesophases in liquid crystals and show that, within the context of central forces between "atoms" on "molecules", chiral interactions can occur only if there are biaxial correlations between the mesogens. Weak biaxial correlations can therefore lead to small cholesteric pitches.
The molecules in lyotropic membranes are typically aligned with the surface normal. When these molecules are chiral, there is a tendency for the molecular direction to twist. These competing effects can reach a compromise by producing helicoidal defects in the membranes. Unlike thermotropic smectics, the centers of these defects are hollow and thus their energy cost comes from the line energy of an exposed lamellar surface. We describe both the twist-grain-boundary phase of chiral lamellar phases as well as the isolated helicoidal defects.
Chiral molecules form a number of non-chiral structures, the simplest being an isotropic fluid phase. In a mesophase of achiral molecules the fluctuations will on average be achiral as well: left-handed twists and right-handed twists will occur with the same probability. In a system composed of chiral molecules, however, the fluctuations will be biased in one direction or the other, and there will be optical effects such as a non-zero fluctuation induced rotary power {\sl in addition} to the molecular rotary power of the individual molecules. We discuss this effect in a number of contexts, including lyotropic lamellar phases. When the tendency to twist is strong enough or the line energy of having an exposed edge is small enough, a new, defect riddled ground state of a lyotropic lamella, akin to the Renn-Lubensky twist-grain-boundary phase of thermotropic smectics, can occur.