arXiv subjects

Rasmus S. Christensen

Publications and source records attributed to Rasmus S. Christensen.

4 recordsLinked to original sources

arXiv2023

Oxide layer formation prevents deteriorating ion migration in thermoelectric Cu$_2$Se during operation in air

Cu$_2$Se is a mixed ionic-electronic conductor with outstanding thermoelectric performance originally envisioned for space missions. Applications were discontinued due to material instability, where elemental Cu grows at the electrode interfaces during operation in vacuum. Here, we show that when Cu$_2$Se is operating in air, formation of an oxide surface layer suppresses Cu$^+$ migration along the current direction. In operando X-ray scattering and electrical resistivity measurements quantify Cu$^+$ migration through refinement of atomic occupancies and phase composition analysis. Cu deposition can be prevented during operation in air, irrespective of a critical voltage, if the thermal gradient is applied along the current direction. Maximum entropy electron density analysis provides experimental evidence that Cu$^+$ migration pathways under thermal and electrical gradients differ substantially from equilibrium diffusion. The study establishes new promise for inexpensive sustainable Cu$_2$Se in thermoelectric applications, and it underscores the importance of atomistic insight into materials during thermoelectric operating conditions.

cond-mat.mtrl-sci↗

arXiv2017

Finite-temperature behavior of the Bose polaron

We consider a mobile impurity immersed in a Bose gas at finite temperature. Using perturbation theory valid for weak coupling between the impurity and the bosons, we derive analytical results for the energy and damping of the impurity for low and high temperatures, as well as for temperatures close to the critical temperature $T_c$ for Bose-Einstein condensation. These results show that the properties of the impurity vary strongly with temperature. In particular, the energy exhibits a non-monotonic behavior close to $T_c$, and the damping rises sharply close to $T_c$. We argue that this behaviour is generic for impurities immersed in an environment undergoing a phase transition that breaks a continuous symmetry. Finally, we discuss how these effects can be detected experimentally.

cond-mat.quant-gas↗

arXiv2016

Observation of Attractive and Repulsive Polarons in a Bose-Einstein Condensate

The problem of an impurity particle moving through a bosonic medium plays a fundamental role in physics. However, the canonical scenario of a mobile impurity immersed in a Bose-Einstein condensate (BEC) has not yet been realized. Here, we use radio frequency spectroscopy of ultracold bosonic $^{39}$K atoms to experimentally demonstrate the existence of a well-defined quasiparticle state of an impurity interacting with a BEC. We measure the energy of the impurity both for attractive and repulsive interactions, and find excellent agreement with theories that incorporate three-body correlations, both in the weak-coupling limits and across unitarity. The spectral response consists of a well-defined quasiparticle peak at weak coupling, while for increasing interaction strength, the spectrum is strongly broadened and becomes dominated by the many-body continuum of excited states. Crucially, no significant effects of three-body decay are observed. Our results open up exciting prospects for studying mobile impurities in a bosonic environment and strongly interacting Bose systems in general.

cond-mat.quant-gas↗

arXiv2015

Decoherence of Impurities in a Fermi Sea of Ultracold Atoms

We investigate the decoherence of $^{40}$K impurities interacting with a three-dimensional Fermi sea of $^{6}$Li across an interspecies Feshbach resonance. The decoherence is measured as a function of the interaction strength and temperature using a spin-echo atom interferometry method. For weak to moderate interaction strengths, we interpret our measurements in terms of scattering of K quasiparticles by the Fermi sea and find very good agreement with a Fermi liquid calculation. For strong interactions, we observe significant enhancement of the decoherence rate, which is largely independent of temperature, pointing to behavior that is beyond the Fermi liquid picture.

cond-mat.quant-gas↗